• Title/Summary/Keyword: Fe/Ni

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Electrodeposition Characteristics and Magnetic Properties of CoFeNi Thin Film Alloys

  • Song, Jae-Song;Yoon, Do-Young;Han, Choon;Kim, Dae-Heum;Park, Dyuk-Young;Myung, No-Sang
    • Journal of the Korean Electrochemical Society
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    • v.5 no.1
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    • pp.17-20
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    • 2002
  • Various compositions of CoFeNi alloys have been electrodeposited in chloride bath and in sulfate bath, and evaluated for electrodeposition characteristics and magnetic properties. For electrodeposited CoFeNi thin film alloys, the increase of Fe content in the deposits from sulfate bath was considerably faster than those from chloride bath. The current efficiencies in sulfate bath showed observable decrease from $75\%\;to\;50\%$ while those in chloride bath showed no significant decrease. From the low coercivity of 3 Oe in the minimum and the higher squarenesses of the alloys from sulfate bath than those from chloride bath, the alloy at Co, Fe, and Ni contents of $80wt.\%,\;10wt.\%,\;and\;10wt.\%$ can be considered to be the best CoFeNi alloy in this research for the soft magnetic material.

Wheastone-bridge type MR sensors of Si(001)/NiO(300 $\AA$)/NiFe bilayer system (Si(001)/NiO(300$\AA$)/NiFe계 휘스톤 브리지형 자기저항소자)

  • 이원재;민복기;송재성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.1050-1053
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    • 2001
  • There is great interest in developing magnetoresistance(MR) sensor, using ferromagnetic, electrically non-magnetic conducting and antiferromagnetic films, especially for the use in weak magnetic fields. Here, we report single and Wheatstone-bridge type of MR sensors made in Si(001)/HiO(300$\AA$)/NiFe bilayers. Angular dependence of MR profiles was measured in Si(001)/NiO(300$\AA$)/NiFe(450$\AA$) films as a function of an angle between current and applied field direction, also, linearity was determined. AMR characteristics of single MR sensors was well explained with single domain model. Good linearity in 45$^{\circ}$Wheatstone-bridge type of MR sensors consisting of 4 single MR sensors made in Si(001)/NiO(300$\AA$)/NiFe(450$\AA$) was shown in the range of about $\pm$50 Oe.

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The study of magnetoresistance and magnetic properties in [(CoO/NiO)/NiFe/Cu/NiFe] spin-valve thin films ([(CoO/NiO)/NiFe/Cu/NiFe] spin-valve 박막에서의 자기저항효과와 자기적 특성에 대한 연구)

  • 현준원
    • Electrical & Electronic Materials
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    • v.9 no.10
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    • pp.1060-1065
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    • 1996
  • We have studied the magnetoresistance phenomena on spin valve thin films of antiferromagnetic NiO/CoO. Interlayer coupling oscillates between the antiferrocoupling and ferrocoupling with the variation of Cu thickness. The exchange coupling strength between NiO (antiferromagnetic) and NiFe(ferromagnetic) as a function of NiO texture and interface roughness is investigated by CoO insertion. CoO has significantly higher anisotropy in the (111) plane and interface roughness. It seems that the MR-ratio is increased by CoO inserted films. From the AFM and XRD data, the increase of MR-ratio and exchange field is influenced by the roughness of CoO.

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Textures of Fe-Ni Alloy Thin Films Fabricated by Sputtering Method (스퍼터링 방법에 의한 Fe-Ni 합금 박막의 집합조직)

  • 박용범;임태흥
    • Journal of the Korean Vacuum Society
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    • v.10 no.2
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    • pp.201-206
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    • 2001
  • The evolution of textures in Fe-Ni alloy thin films fabricated by PVD using a sputtering method was investigated with parameters such as deposition time and chemical composition. The textures of the as-deposited films were characterized by fibre-type. In Invar alloy(Fe-36.5 wt%Ni) thin film, the <110>//ND fibre texture as a starting component changed to the <210>//ND fibre texture with increasing deposition time. In Permalloy(Fe-81 wt%Ni) thin film, a mixture of the <221>//ND and <311>//ND fibres developed at the early stage of deposition, and then transformed to the <210>//ND fibre with increasing deposition time. These texture changes were discussed in terms of relationship with the microstructural evolution of the films.

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Hydrogen Absorption by Mg-Ni-Fe2O3 and Mg-Ni-Ti during Mechanical Grinding under Hydrogen

  • Kwak, Young Jun;Park, Hye Ryoung;Song, Myoung Youp
    • Korean Journal of Metals and Materials
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    • v.50 no.11
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    • pp.855-859
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    • 2012
  • Samples with compositions of 80 wt% Mg-14 wt% Ni-6 wt% $Fe_2O_3$ and 80 wt% Mg-14 wt% Ni-6 wt% Ti were prepared by mechanical grinding under hydrogen (reactive mechanical grinding). Their hydrogen absorptions during reactive mechanical grinding were examined. TGA and BET analysis were employed to investigate the hydrogen storage properties of the prepared alloys. TGA analysis of the $Mg-14Ni-6Fe_2O_3$ showed an absorbed hydrogen quantity of 6.91 wt% while that of Mg-14Ni-6Ti was 2.59 wt%. BET analysis showed that the specific surface areas of $Mg-14Ni-6Fe_2O_3$ and Mg-14Ni-6Ti after reactive mechanical grinding were $264m^2/g$ and $64m^2/g$, respectively. The larger absorbed hydrogen quantity and the larger specific surface area of $Mg-14Ni-6Fe_2O_3$ after RMG than those of Mg-14Ni-6Ti after RMG showed that the effects of $Fe_2O_3$ addition are much stronger than those of Ti addition during reactive mechanical grinding.

High Temperature SO2-gas Corrosion of Fe-18%Cr-10%Ni Steels for Coal-fired Power Plant (화력발전소용 Fe-18%Cr-10%Ni 강의 고온 SO2 가스 부식)

  • Lee, Dong-Bok
    • Journal of the Korean institute of surface engineering
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    • v.40 no.5
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    • pp.219-224
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    • 2007
  • The corrosion characteristics of Fe-18Cr-10Ni steels were studied between $600^{\circ}C$ and $1000^{\circ}C$ in Ar+(0.2, 1)%$SG_2$ gas for up to 300 hr in order to employ Fe-18Cr-10Ni steels in the coal-fired power plants. The corrosion resistance of Fe-18Cr-10Ni steels was good due mainly to the high amount of Cr, which formed $Cr_2O_3$ from the initial corrosion stage. Fe in the steels corroded to mainly $Fe_2O_3$ and $Fe_3O_4$. Ni was not susceptible to corrosion under the current corrosion condition. Relatively thin, single-layered scales formed.

The Effect of Composition on the Properties of NiCuZn ferrites (NiCuZn ferrite의 특성에 미치는 조성의 영향)

  • 남중희;정현학;신재영;오재희
    • Journal of the Korean Magnetics Society
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    • v.5 no.3
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    • pp.191-196
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    • 1995
  • NiCuZn ferrites were prepared by a solid-state reaction and sintered at $900^{\circ}C$ for 5 hours. Its properties were investigated by controlling the ferrite composition and processing. NiCuZn ferrite with a composition of ${(Ni_{0.2}Cu_{0.2}Zn_{0.6}O)}_{1.02}{(Fe_{2}O_{3})}_{0.98}$ was found to have the maximum initial permeability as a result of the variation of Cu content and the (Ni+Cu)/Zn ratio. Curie temperature($T_{c}$) of NiCuZn ferrite was decreased with the larger Cu content and increased with the larger Ni content. NiCuZn ferrites of ${(Ni_{0.2}Cu_{0.2}Zn_{0.6}O)}_{1-w}{(Fe_{2}O_{3})}_{1+w}$ composition milled for 20~80 hours had the maximum initial permeability at w=-0.015 and Curie temperature ($T_{c}$) was decreased with the increasing of $Fe_{2}O_{3}$ deficiency(w).

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Fabrication and Electrical Properties of Ni-Mn-Co-Fe Oxide Thick Film NTC Thermistors (Ni-Mn-Co-Fe 산화물 후막 NTC 서미스터의 제조 및 전기적 특성)

  • Park, Kyeong-Soon;Bang, Dae-Young;Yun, Sung-Jin;Choi, Byung-Hyun
    • Journal of the Korean Ceramic Society
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    • v.39 no.10
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    • pp.912-918
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    • 2002
  • Ni-Mn-Co-Fe oxide thick films were coated on an alumina substrate by screening printing technique. The microstructure and electrical properties of the thick films, as a function of composition and sintering temperature, were investigated. The components of the NTC thick films sintered at 1150${\circ}C$ were distributed homogeneously. On the other hand, in the case of the NTC thick films sintered at 1200 and 1250${\circ}C$, Co element was distributed homogeneously, but Ni, Mn and Fe elements were distributed heterogeneously, resulting in the formation of Ni rich and Mn-Fe rich regions. All the thick film NTC thermistors prepared showed a linear relationship between log resistance (log R) and the reciprocal of absolute temperature (1/T), indicative of NTC characteristics. At a given NiO and $Mn_3O_4$ content, the resistance, B constant and activation energy of $(Ni_{1.0}Mn_{1.0}Co_{1-x}Fe_x)O_4$ (0.25${\le}$x${\le}$0.75) and $(Ni_{0.75}Mn_{1.25}Co_{1-x}Fe_x)O_4$ (0.25${\le}$x${\le}$0.75) thermistors increased with increasing $Fe_2O_3$ content.

A Study on $Ni_{0.8}Cd_{0.2}Fe_2O_4$ by Mossbauer spectroscopy (Mossbauer 분광법을 이용한 $Ni_{0.8}Cd_{0.2}Fe_2O_4$)

  • Baek, Seung-Do
    • Korean Journal of Materials Research
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    • v.6 no.11
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    • pp.1107-1112
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    • 1996
  • Ni를 Cd로 대치시켜 세라믹 소결법으로 합성한 Ni0.8Cd0.2Fe2O4 의 X-ray 회절선을 측정하여 구조를 확인하고, 형성된 결정체의 격자 상수를 조사하였다. 이 시료의 Mossbauer 스펙트럼을 80K-900K의 온도 영역에서 측정 분석하여 Mossbauer parameter의 온도 의존성과 Fe 이온에 대한 자료를 얻고, 이 자료를 토대로 Ni0.8Cd0.2Fe2O4 의 자기 전이 현상과 Curied 온도 Tc와 격자 비열 및 Debye 온도와 같은 물성을 조사하였다.

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Nanocrystalline structure of electroformed Fe-Ni alloy thin foil (전주성형한 Fe-Ni 합금 극박재의 나노결정질 조직에 관한 연구)

  • Im, Tae-Hong;Lee, Heung-Ryeol;Gu, Seung-Hyeon
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2007.04a
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    • pp.27-28
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    • 2007
  • 전주는 표면코팅을 목적으로 하기보다 금속제품을 제조하기 위해 사용하는, 도금법과 유사한 기술이다. 다양한 조성의 Fe-Ni 합금들을 전주성형하여 극박형상으로 제조하였다. 2원계 Fe-Ni 합금의 결정립 크기는 10 nm 정도였으며 P 첨가에 의해 결정립 크기를 더욱 미세하게 할 수 있다. 전주한 2원계 Fe-Ni 합금들의 비저항은 전형적인 나노결정질 소재의 특성을 나타낸다.

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