• Title/Summary/Keyword: Fate and transport

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Three-Dimensional Numerical Modelling of Water Circulation and Thermal Diffusion (해수순환과 온배수 확산에 관한 3차원 수치모델링)

  • Jung Tae Sung;Kim Sang Ik;Kang See Whan
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.1 no.1
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    • pp.93-101
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    • 1998
  • Numerical models have been widely used to understand the structure of coastal currents and the transport mechanisms in regard to the fate of pollutants. This study focuses on the development of a three-dimensional model of coastal circulation and mass transport. The model was used to calculate coastal currents and temperature distributions of the thermal plume discharged from a power plant. The model results were compared with field-observed data. They showed the relatively good agreements with the data. The model can be used to estimate the currents and its mass transport in coastal waters.

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The Characteristics of Bioremediation for VOCs in Soil Column (VOCs처리를 위한 미생물의 토양복원화 특성)

  • 손종렬;장명배
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2002.04a
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    • pp.9-12
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    • 2002
  • Diffusive transport of volatile organic compounds(VOCs) and their degradation by bacteria in unsaturated soils are couple by poorly understood mass transfer kinetics at the gas/water interface. Determination of the fate of VOCs in unsaturated soil is necessary to evaluate the feasibility of natural attenuation as a VOC remediation strategy. The objective of this study was to develop a mechanistically based mathematical model that would consider the interdependence of VOC transport, microbial activity, and sorptive interaction in a moist, unsaturated soil. Because the focus of the model was on description of natural attenuation, the advective VOC transport that is induced in engineered remediation processes such as vapor extraction was not considered. The utility of the model was assessed through its ability to describe experimental observations form diffusion experiments using toluene as a representative VOC in well-defined soil columns that contained a toluene degrading bacterium, Pseudomonas Putida, as the sole active microbial species. The coefficient for gas-liquid mass-transfer, K$\sub$LA/, was found to be a key parameter controlling the ability of bacteria to degrade VOCs. This finding indicates that soil size and geometry are likely to be important parameters in assessing the possible success of natural attenuation of VOCs in contaminated unsaturated soils.

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Modeling Bacteria Facilitated Contaminant Transport in Porous Media with Kinetic Adsorption Relationships (동역학적 흡착 관계식을 이용한 다공 매질에서의 유동세균에 의한 유기성 오염물의 가속이송 예측 모델)

  • 김승현
    • Journal of the Korean Society of Groundwater Environment
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    • v.2 no.1
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    • pp.22-29
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    • 1995
  • Mobile bacterial particles can act as carriers and enhance the transport of hydrophobic contaminants in ground water by reducing retardation effects. Because of their colloidal size and favorable surface conditions, bacteria can act as efficient contaminant carriers. When such carriers exist in a porous medium, the system can be thought of as three phases: an aqueous phase, a carrier phase, and a stationary solid matrix phase. Contaminant can be present in either or all of these phases. In this study, a mathematical model based on mass balances is developed to describe the transport and fate of biodegradable contaminant in a porous medium. Bacterial mass transfer mechanism between aqueous and solid matrix phases, and contaminant mass transfer between aqueous and bacterial phases are represented by kinetic models. Governing equations are non-dimensionalized and solved to analyze the bacteria facilitated contaminant transport. The numerical results of the facilitation effect match favorably with experimental data reported in the literature. Results show that the contaminant transport can be described by local equilibrium assumption when Damkohler numbers are larger than 10. Significant sensitivities to model parameters, particularly bacterial growth rate and influent bacterial concentration, were discovered.

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Modeling Bacteria Facilitated Contaminant Transport in Porous Media with Equilibrium Adsorption Relationships (평형 모델을 이용한 다공매질에서의 유동 세균에 의한 유기성 오염물의 가속이송)

  • 신항식;김승현
    • Journal of the Korean Society of Groundwater Environment
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    • v.2 no.1
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    • pp.14-21
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    • 1995
  • Colloids such as exogenous biocolloids in a bioremediation operation can enhance the transport of contaminant in ground water by reducing retardation effects. Because of their colloidal size and favorable surface conditions in addition to their low density, bacteria can act as efficient contaminant carriers. When mobile bacteria are present in a subsurface environment, the system can be treated as consisting of three phases: water phase, bacterial phase, and the stationary solid matrix phase. In this work, a mathematical model based on mass balances is developed to describe the facilitated transport and fate of a contaminant in a porous medium. Bacterial partition between the bulk solution and the stationary solid matrix, and the contaminant partition among the three phases are represented by the equilibrium relationships. Solutions were obtained to provide estimates of contaminant and bacterial concentrations. A dimensionless analysis of the transport model was utilized to estimate model parameters from the experimental data. The model results matched with experimental data of Jenkins and Lion (1993). The presence of mobile bacteria enhances the contaminant transport. However, bacterial consumption of the contaminant which serves as a bacterial nutrient, can attenuate the contaminant concentration.

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Environmental Fate Tracking of Manure-borne NH3-N in Paddy Field Based on a Fugacity Model (Fugacity 모델에 기초한 논토양에서의 액비살포에 따른 암모니아성 질소 거동추적)

  • Kim, Mi-Sug;Kwak, Dong-Heui
    • Journal of Korean Society on Water Environment
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    • v.35 no.3
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    • pp.224-233
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    • 2019
  • Nitrogen components in liquid manure can reduce safety and quality of environment harmfully. To minimize the environmental risks of manure, understanding fate of manure in environment is necessary. This study aimed at investigating applicability of a simplified Level III fugacity model for simulating $NH_3-N$ component to analyze environmental fate and transport of $NH_3-N$ in liquid manure and to provide basis for improving management of N in the liquid manure system and for minimizing the environmental impacts of N. The model simulation conducted for four environmental compartments (air, water, soil, and rice plants) during rice-cropping to trace $NH_3-N$ component and provided applicability of the Level III fugacity model in studying the environmental fate of $NH_3-N$ in manure. Most of $NH_3-N$ was found in water body and in rice plants depending upon the physicochemical properties and proper removal processes. For more precise model results, the model is needed to modify with the detailed removal processes in each compartment and to collect proper and accurate information for input parameters. Further study should be about simulations of various N-typed fertilizers to compare with the liquid manure based on a modified and relatively simplified Level III fugacity model.

Model Study of the Fate of Hydrocarbons in the Soil-Plant Environment (녹지 토양내 탄화수소화합물의 분포변화에 관한 모델링 연구)

  • Yoon-Young Chang;Kyung-Yub Hwang
    • Journal of Korea Soil Environment Society
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    • v.1 no.2
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    • pp.91-101
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    • 1996
  • In recent years, phytoremediation, the use of plants to detoxify hydrocarbons, has been a promising new area of research, particularly in situ cleanup of large volumes of slightly contaminated soils. There is increasing need for a mathematical model that can be used as a predictive tool prior to actual field implementation of such a relatively new technique. Although a number of models exist for solute-plant interaction in the vegetated zone of soil, most of them have focused on ionic nutrients and some metals. In this study, we developed a mathematical model for simulation of bioremediation of hydrocarbons in soil, associated with plant root systems. The proposed model includes root interactions with soil-water and hydrocarbons in time and space, as well as advective and dispersive transport in unsaturated soil. The developed model considers gas phase diffusion and liquid-gas mass exchanges. For simulation of temporal and spatial changes in root behavior on soil-water and with hydrocarbons, time-specific distribution of root quantity through soil was incorporated into the simulation model. Hydrocarbon absorption and subsequent uptake into roots with water were simulated with empirical equations. In addition, microbial activity in the rhizosphere, a zone of unique interaction between roots and soil microorganisms, was modeled using a biofilm theory. This mathematical model for understanding and predicting fate and transport of compound in plant-aided remediation will assist effective application of plant-aided remediation to field contamination.

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Mesenteric Lymphatic Delivery of Oral Anticancer Tegafur by Emulsion Formulations (유제화에 의한 경구용 항암제인 테가푸르의 장관 임파수송)

  • Lee, Yong-Bok;Nam, Kweon-Ho;Chang, Woo-Ik;Oh, In-Joon;Koh, Ik-Bae
    • Journal of Pharmaceutical Investigation
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    • v.25 no.1
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    • pp.55-62
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    • 1995
  • W/O and O/W emulsions of tegafur (50 mg/5 ml/kg) were orally administered to rats to compare with their mesenteric lymphatic delivery effects. And also in order to demonstrate the lymph targeting associated to the oral route, it was deemed necessary to investigate the fate of solution after oral administration as a control. Lymph and plasma samples were periodically taken from each subject of mesenteric lymphatic duct cannulated rats. Then, lymph and plasma levels of tegafur and its active metabolite, 5-FU, were simultaneously observed. Also pharmacokinetic parameters were compared with each others. On the other hand, most previous studies of lymphatic transport have not addressed the question of whether an increase in mesenteric or thoracic lymph transport by the manipulation of a suspected variable was due to a selective delivery to the intestinal lymphatics or an overall increase availability. Therefore, based on a physiologically based pharmacokinetic model which represents the characteristics of lymphatic systems, we are also going to determine the contributions of mesenteric lymph transport versus thoracic lymph transport of tegafur reported in reference(13). In comparison with tegafur solution, AUC and mean residence time of plasma tegafur were significantly increased in W/O emulsion but significantly decreased in O/W emulsion. Lymph flow rates were similar in both solution and W/O emulsion but half in O/W emulsion. AUC of tegafur in mesenteric lymph and in plasma for W/O emulsion were 3.7 times and 2.9 times more than those for O/W emulsion, respectively. And AUC of 5-FU in thoracic lymph for W/O emulsion was 3.7 times more than that for O/W emulsion. These results suggested that lymphatic delivery or tegafur by W/O emulsion was more effective than that by on emulsion due to its differences or formation ability of chylomicrons.

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Simulation, design optimization, and experimental validation of a silver SPND for neutron flux mapping in the Tehran MTR

  • Saghafi, Mahdi;Ayyoubzadeh, Seyed Mohsen;Terman, Mohammad Sadegh
    • Nuclear Engineering and Technology
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    • v.52 no.12
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    • pp.2852-2859
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    • 2020
  • This paper deals with the simulation-based design optimization and experimental validation of the characteristics of an in-core silver Self-Powered Neutron Detector (SPND). Optimized dimensions of the SPND are determined by combining Monte Carlo simulations and analytical methods. As a first step, the Monte Carlo transport code MCNPX is used to follow the trajectory and fate of the neutrons emitted from an external source. This simulation is able to seamlessly integrate various phenomena, including neutron slowing-down and shielding effects. Then, the expected number of beta particles and their energy spectrum following a neutron capture reaction in the silver emitter are fetched from the TENDEL database using the JANIS software interface and integrated with the data from the first step to yield the origin and spectrum of the source electrons. Eventually, the MCNPX transport code is used for the Monte Carlo calculation of the ballistic current of beta particles in the various regions of the SPND. Then, the output current and the maximum insulator thickness to avoid breakdown are determined. The optimum design of the SPND is then manufactured and experimental tests are conducted. The calculated design parameters of this detector have been found in good agreement with the obtained experimental results.

A Two-dimensional Numerical Simulation of Cohesive Sediment Transport in the Mokpo Coastal Zone (목포해역의 점착성 퇴적물 이동에 관한 2차원 수치모의)

  • Choi, Jong-Hwa;Jung, Tae-Sung
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.24 no.4
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    • pp.287-294
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    • 2012
  • Sedimentary environment in coastal zone has been changing due to a large number of coastal structures and continuous coastal development. As a result, the environment has been changing. In particular, the economic and environmental damage can occur due to cohesive sediment transport closely related with the fate of pollutants. Due to large sea wall construction the ebb dominance in the Mokpo coastal waters has been clearer. Cohesive sediment transport was simulated by the EFDC model. The simulated SS showed good agreements with the observed SS. From the sensitivity analysis of sediment parameters, we found out that the erosion rate, the critical shear stresses for erosion and deposition, and the settling velocity are important factors in cohesive sediment transport modeling.

Analysis of Solids in Runoff to Prevent Solids Pollution (오염저감 기법개발을 위한 유출수내 고형물질 특성 규명)

  • Lee, Young-Soo
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.1
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    • pp.22-28
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    • 2004
  • The fate and transport mechanism of pollutants which have affinities to particles, such as trace metals and some petroleum product based compounds, can be effectively explained by the movement of sediment. The sediment release from lands to adjacent water bodies due to rainfall events was investigated in an effort to predict the total suspended solids (TSS) concentrations in runoff. The contribution of sediment from land origin to the river TSS can be better understood by the relationship between TSS concentration and particle size in runoff. The sieve analysis was used to determine the particle size distribution and these results were incorporated into statistical models. The critical size of particles was set to $74{\mu}m$ which contributes to the river TSS concentration since fine particles (wash load) of the sediment in the runoff play the key role in constituting TSS in a water column of the river. Empirical relationships were developed to predict TSS in runoff from the percentage of the critical particle size and were proven statistically to be valid.