• Title/Summary/Keyword: Fast ion

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Medical Image CODEC Hardware Design based on MISD architecture (MISD 구조에 의한 의료 영상 CODEC의 하드웨어 설계)

  • Park, Sung-Wook;Yoo, Sun-Kook;Kim, Sun-Ho;Kim, Nam-Hyeon;Youn, Dae-Hee
    • Proceedings of the KOSOMBE Conference
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    • v.1994 no.12
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    • pp.92-95
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    • 1994
  • As computer systems to make medical practice easy are widely used, a special hardware system processing medical data fast becomes more important. To meet the urgent demand for high speed image processing, especially image compression and decompression, we designed and implemented the medical image CODEC (COder/BECoder) based on MISD(Multiple Instruction Single Data stream) architecture to adopt parallelism in it. Considering not being a standart scheme of medical mage compression/decompress ion, the CODEC is designed programable and general. In this paper, we use JPEG (Joint Photographic Experts Group) algorithm to process images fast and evalutate it.

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Experimental Determination of Equilibrium Constants of Copper Complexes in Aqueous Environment

  • Cho, Young-Il
    • Journal of Environmental Science International
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    • v.21 no.5
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    • pp.555-562
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    • 2012
  • The experimental determination of equilibrium constants is required to estimate concentrations of reagents and/or products in environmental chemical reactions. For an example, the choice of copper (Cu) complexation reactions was motivated by their fast kinetics and the ease of measurement of Cu by an ion-sensitive electrode. Each individual titrant of sulfate ($SO{_4}^{2-}$) and oxalate ($C_2O{_4}^{2-}$) was expected to have its own unique characteristics, depending on the bonding in Culigands connected to the aqueous species. The complexation reaction of Cu with $SO{_4}^{2-}$ somewhat fast reached equilibrium status compared with $C_2O{_4}^{2-}$. The experimental equilibrium constants ($K_{eq}$) of copper sulfate ($CuSO_4$) and copper oxalate ($CuC_2O_4$) were determined $10^{2.2}$ and $10^{3{\sim}4.3}$, respectively.

Fast visible dye staining of proteins in one- and two-dimensional sodium dodecyl sulfate-polyacrylamide gels compatible with matrix-assisted laser desorption/ionization-mass spectrometry

  • Jin, Li-Tai;Hwang, Sun-Young;Yoo, Gyurng-Soo;Choi, Jung-Kap
    • Proceedings of the PSK Conference
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    • 2003.10b
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    • pp.147.2-147.2
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    • 2003
  • A fast and matrix-assisted laser desorption/ionization-mass spectrometry compatible protein staining method in one- and two-dimensional sodium dodecyl sulfate-polyacrylamide gel electrophoresis is described. It is based on the counterion dye staining method that employs oppositely charged two dyes, Zincon and Ethyl Violet to form an ion-pair complex. It is safe to use since the methanol used previously in staining solution was replaced with ethanol, which is not toxic. The protocol including fixing, staining and quick washing steps can be completed in 1 to 1.5 h depending upon gel thickness. (omitted)

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Development of Active thin Film Optical Waveguide $C^{2+}$ -ion Sensor (능동형 박막 광도파로 칼슘 이온 센서의 개발)

  • Lee, Su-Mi;Gang, Sin-Won
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.37 no.4
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    • pp.49-54
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    • 2000
  • A new functional organic thin film optical waveguide ion sensor is designed, which can select a specific ion, i.e., $Ca^{2+}$ -ion. The sensing membrane was composed of PVC-PVAC-PVA copolymer matrix based on anionic cation-selective chromoionophor(ETH5294), neutral ionophore(K23El), anionic site and plasticizer and it was coated on the etched glass substrate as embeded type optical waveguide itself. The sensor sensitivity dependence on waveguide length and thickness, contence of chromoionophore, and each mode was investigated. And this sensor could detect $Ca^{2+}$ ion in concentrations ranging from 1$\times$10­6~1M(with 0.05M tris-HCI buffer solution of pH7.4) by measuring the absorbance change at 514nm of light. Utilizing thin film membrane, the fast response time and high sensitivity are obtained. Also, it is expected that this sensor can be applied to various biochemical important ions.ons.

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Fabrication of Low-cost and Flexible Potassium Ion Sensors based on Screen Printing and Their Electrochemical Characteristics (스크린 프린팅 기반 저가형의 플렉서블 칼륨 이온 센서 제조 및 이의 전기화학적 특성)

  • Son, Seon Gyu;Park, Hong Jun;Kim, Yeong Kyun;Cho, Hyeon-Sang;Choi, Bong Gill
    • Applied Chemistry for Engineering
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    • v.30 no.6
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    • pp.737-741
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    • 2019
  • A low-cost and flexible potassium ion (K+) sensor was fabricated through a screen-printed process. Uniform and conformal coating of conductive inks was verified by scanning electron microscopy and optical microscopy measurements. The K+-sensors showed a high sensitivity, fast response time, and low detection limit. The sensitivity of K+-sensor was similar to that of both mechanically normal and bent states. The K+-sensor exhibited a good reproducibility with no hysteresis effect and excellent long term stability. In addition, the K+-sensor showed an excellent selectivity for K+ concentrations in the presence of other interfering cation ions. Successful measurements of K+ concentrations in sports drink samples were demonstrated by comparing K+ concentration values from K+-sensor to those of using a commercial K+-meter.

Kinetics and Mechanism of Triethylamine Catalysed Michael Addition of Benzenethiol to 1-(2-Nitrovinyl)benzene in Acetonitrile

  • Sarathi, P.A.;Gnanasekaran, C.;Shunmugasundaram, A.
    • Bulletin of the Korean Chemical Society
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    • v.29 no.4
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    • pp.790-794
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    • 2008
  • Nucleophilic addition reaction of benzenethiols (PhSH) to 1-(2-nitrovinyl) benzenes ($\beta$ NS) in the presence of triethylamine (TEA) has been studied in acetonitrile at 25 ${^{\circ}C}$. The rate is first order with respect to [PhSH], [TEA] and [$\beta$ NS]. The reaction is found to proceed with the formation of ion-pair between benzenethiol and TEA. A suitable mechanism with the formation of an adduct between ion-pair and substrate in a slow step followed by its rearrangement to 1,2-addition product in a fast step has been proposed and corresponding rate law derived. From the rate law, the rate constants for the interaction between ion-pair and $\beta$NS have been evaluated. Interestingly, in both para-substituted substrates and benzenethiols the rate increases with the electron-withdrawing power of the substituents. The positive sign of $\rho_x$ in benzenethiols has been explained. The magnitude of cross-interaction constant, $\rho_{xy}$ is small (0.08). The magnitude of the Hammett $\rho_x$ values is higher than that of the Bronsted, $\beta_x$ values for benzenethiols. The kinetic isotope effect, $k_H/k_D$, is found to be greater than unity. A suitable transition state with simultaneous formation of $C_\beta$ -H and $B_\alpha$ -S bonds involving the ion-pair and $\beta$NS in a single concerted step has been proposed to account for these observations.

Adsorption of Uranium (VI) Ion on the 1-Aza-12-Crown-4-Styrene-DVB Synthetic Resin Adsorbent (1-Aza-12-Crown-4-Styrene-DVB 합성수지 흡착제에 의한 우라늄(VI) 이온의 흡착)

  • Kim, Joon-Tae
    • Applied Chemistry for Engineering
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    • v.19 no.3
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    • pp.304-309
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    • 2008
  • Cryptand series ion exchange resins were synthesized with 1-aza-12-crown-4 macrocyclic ligand attached to styrene (4 series dangerous matter) divinylbenzene (DVB) copolymer with crosslink of 1%, 2%, 4% and 8% by a substitution reaction. The synthesis of these resins was confirmed by content of chlorine, element analysis, electron micrograph, and IR-spectrum. The effects of pH, time, dielectric constant of solvent and crosslink on adsorption of uranium (${UO_2}^{2+}$) ion were investigated. The uranium ion showed a fast adsorption on the resins above pH 3. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in ethanol was in increasing order uranium (${UO_2}^{2+}$) > nickel ($Ni^{2+}$) > gadolinium ($Gd^{3+}$) ion. The adsorption was in order of 1%, 2%, 4%, and 8% crosslinked resin and adsorption of resin decreased in proportion to order of dielectric constant of solvents.

Glutamic Acid-Grafted Metal-Organic Framework: Preparation, Characterization, and Heavy Metal Ion Removal Studies

  • Phani Brahma Somayajulu Rallapalli;Jeong Hyub Ha
    • Applied Chemistry for Engineering
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    • v.34 no.5
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    • pp.556-565
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    • 2023
  • Fast industrial and agricultural expansion result in the production of heavy metal ions (HMIs). These are exceedingly hazardous to both humans and the environment, and the necessity to eliminate them from aqueous systems prompts the development of novel materials. In the present study, a UIO-66 (COOH)2 metal-organic framework (MOF) containing free carboxylic acid groups was post-synthetically modified with L-glutamic acid via the solid-solid reaction route. Pristine and glutamic acid-treated MOF materials were characterized in detail using several physicochemical techniques. Single-ion batch adsorption studies of Pb(II) and Hg(II) ions were carried out using pristine as well as amino acid-modified MOFs. We further examined parameters that influence removal efficiency, such as the initial concentration and contact time. The bare MOF had a higher ion adsorption capacity for Pb(II) (261.87 mg/g) than for Hg(II) ions (10.54 mg/g) at an initial concentration of 150 ppm. In contrast, an increased Hg(II) ion adsorption capacity was observed for the glutamic acid-modified MOF (80.6 mg/g) as compared to the bare MOF. The Hg(II) ion adsorption capacity increased by almost 87% after modification with glutamic acid. Fitting results of isotherm and kinetic data models indicated that the adsorption of Pb(II) on both pristine and glutamic acid-modified MOFs was due to surface complexation of Pb(II) ions with available -COOH groups (pyromellitic acid). Adsorption of Hg(II) on the glutamic acid-modified MOF was attributed to chelation, in which glutamic acid grafted onto the surface of the MOF formed chelates with Hg(II) ions.

Test Facility of Battery Simulator for Dynamic Characteristics and Safety Evaluation in Lithium-ion Battery (리튬이온 배터리 동특성 및 안전성 평가를 위한 배터리 시뮬레이터 시험설비)

  • Sungin Jeong;Yongho Yoon
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.24 no.2
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    • pp.133-138
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    • 2024
  • Lithium-ion batteries are used in many fields due to their high energy density, fast charging conditions, and long cycle life. However, overcharging, over-discharging, physical damage, and use of lithium-ion batteries at high temperatures can reduce battery life and cause damage to people due to fire or explosion due to damage to the protection circuit. In order to reduce the risk of these batteries and improve battery performance, the characteristics of the charging and discharging process must be analyzed and understood. Therefore, in this paper, we analyze the charging and discharging characteristics of lithium-ion batteries using a battery charger and discharger and simulator to reduce the risk of loss of life due to overcharge and overdischarge, as well as casualties from fire and explosion due to damage to the protection circuit.

Swelling at high radiation damage levels of 120 and 240 dpa in 3.5 MeV self-ion irradiated ferritic/martensitic steels

  • Myeongkyu Lee;Geon Kim;Sangjoon Ahn
    • Nuclear Engineering and Technology
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    • v.56 no.10
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    • pp.4115-4126
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    • 2024
  • The swelling behavior of ferritic/martensitic steels (FC92-B/-N, HT9, and Gr.92) was investigated following 3.5 MeV Fe++ ion irradiation. Tested alloys were helium-pre-implanted up to the peak contents of 120 and 240 appm with He/dpa ratio of 1 appm/dpa at room temperature and then exposed to self-ion beam to the peak damage conditions of 120 and 240 dpa at 475 ℃. Field-emission transmission electron microscopy was used to characterize the cavity evolution. FC92-B exhibited the highest resistance to swelling among the irradiated alloys. The final volumetric swelling of FC92-B reached 1.3 % at 70 dpa and 2.9 % at 140 dpa. On the other hand, HT9 exhibited the highest swelling, reaching 7.4 % at 140 dpa. Comparing the present swelling results at 140 dpa/140 appm He with swelling data at 280 dpa/280 appm He from our previous study, it was observed that Gr.92 and FC92-N swelled more at 140 dpa/140 appm He than at 280 dpa/280 appm He. This negative correlation between swelling and dose in Gr.92 and FC92-N is primarily attributed to the helium-associated swelling suppression at higher helium concentration of 280 appm. A bimodal cavity size distribution appeared only in Gr.92 and FC92-N at 280 dpa/280 appm. This result demonstrates that the excess amount of helium over 200 appm promoted early-stabilization of new-born cavities, resulting in preferentially enhanced cavity nucleation, while impeding the growth of nucleated cavities. An inhibition in cavity growth possibly led to an extended duration of nucleation-dominant stages, finally suppressing swelling in ion-irradiated Gr.92 and FC92-N alloys.