• Journal of the Korea Institute of Military Science and Technology
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• v.21 no.6
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• pp.744-751
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• 2018

In this paper, we propose a fast detection and identification algorithm of chemical gases with a passive FTIR spectrometer. We use a pre-detection algorithm that can reduce the spatial region effectively for gas detection and the candidates of the target. It is possible to remove background spectra effectively from measured spectra with the least-squares method. The CC(Correlation Coefficients) and the SNR(Signal-to-Noise Ratio) methods are used for the detection of target gases. The proposed pre-detection algorithm allows the total process of chemical gas detection to be performed with lower complexity compared with the conventional algorithms. This paper can help developing real-time chemical detection instruments and various applications of FTIR spectrometers.

• Korean Journal of Optics and Photonics
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• v.17 no.5
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• pp.391-395
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• 2006

In this paper, radiometric calibration of a FTIR spectrometer for passive remote sensing application was introduced and verified. Radiometric calibration is a significant signal processing procedure to retrieve the object radiance from the measured spectrum. The object radiance is measured and registered distorted by the detector's responsivity dependent on wavelength and instrument self-emission. Radiance of two temperature points, hot temperature and cold temperature, from a well-controlled blackbody was measured and used to obtain the scale factor and offset factor which are required for radiometric calibration. For gas phase C2H5OH. radiometric calibration was done and verified through comparison of its emission line width and intensity with the standard spectrum.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.6 no.1
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• pp.58-63
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• 2005

PTFE (polytetrafluoroethylene) thin films were prepared from the pellets of the graphite doped PTFE via pulsed laser ablation with 1064 nm Nd:YAG laser. The graphite powder converts the absorbed photon energy into thermal energy which is transmitted to nearby PTFE. The PTFE is decomposed by thermal process. The deposited films were transparent and crystalline. SEM (scanning electron microscopy) and AFM (atomic force microscopy) analyses indicated that the film surface morphology changed to fibrous structure with increasing thickness. The fluorine to carbon ratios of the film were 1.7 and molecular axis was parallel with (100) Si-wafer substrate. These results obtained by XPS (X-ray photoelectron spectroscopy), FTIR (fourier transform infrared spectroscopy) and XRD (X-ray diffraction).

• The Journal of the Petrological Society of Korea
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• v.22 no.1
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• pp.1-8
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• 2013

Physical properties, XRF, UV-Vis, FTIR studies were carried out in order to characterize gemological features of ruby from Tajikistan. Fluorescence reaction of the Tajikistan ruby to short wave ultraviolet was moderate to very strong in red and long wave ultraviolet rays was weakly detected. UV-visible analysis strong absorption bands at 468.5, 475, 476.5 nm and broaden bands at 550 nm were observed for ruby due to $Cr^{3+}$. According to FT-IR analysis, all rubies from Tajikistan showed the similar patterns and kaolinite peaks at 3500, 3617, 3630, $3677cm^{-1}$ and boehmite broaden absorption bands at 3085 and $3320cm^{-1}$. Inclusions in Tajikistan ruby are observed solid inclusions, negative crystals, needle and silk inclusions. These distinctive characteristics mentioned above can be used to identify the locality and source of ruby stones from Tajikistan.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.5 no.5
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• pp.395-402
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• 2004

We need to develop technology of identifying high temperature high pressure(HTHP) synthetic diamond and HTHP treated natural diamonds from untreated natural diamonds to cope with sophisticated diamond enhancing technology. We had successfully identified synthetic diamonds using a vibrating sample magnetometer due to their ferromagnetic property. In addition, we identified the HTHP enhanced TypeIa, TypeIIa diamonds by employing non-destructive Fourier Transform Infrared(FTIR) spectroscopy.

• Proceedings of the KAIS Fall Conference
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• 2010.05b
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• pp.1108-1111
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• 2010

고온 고압 조건하에서 합성된 나노 다이아몬드는 비평형의 고속 생성조건으로 인하여 특이한 물리화학적 구조와 광학적 특성을 나타내는 최근의 신물질이다. 본 연구에서는 본 XRD, EDS, FTIR, 라만 분광기, DSC, BET 및 AFM의 분석장치를 이용하여 폭발 및 산처리 나노 다이아몬드의 표면 특성을 조사하고자 한다.

• Polymer(Korea)
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• v.26 no.6
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• pp.737-744
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• 2002

Thermodynamic miscibility of the binary blends composed of semi-crystalline poly (butylene 2,6-naphthalate) (PBN) and amorphous poly (4-vinylphenol) (PVPh) was investigated using differential scanning calorimetry (DSC) and Fourier transform infrared (FTIR) spectroscopy. DSC scan results showed that there was a single glass transition temperature (T$\_$g/) for each blend. Crystalline melting temperature (T$\_$m/) depression of the PBN in the blends was also observed with the increase of PVPh content. Both results of the single T$\_$g/ and the depression of T$\_$m/ for the PBN/PVPh blends indicate that the blends are thermodynamically miscible at the molecular level. FTIR spectroscopic analysis confirmed that strong intermolecular hydrogen bonding interactions between the ester carbonyl groups of the PBN and the hydroxyl groups of the PVPh are occurred.

• Journal of the Mineralogical Society of Korea
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• v.14 no.2
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• pp.119-127
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• 2001

FTIR spectroscopic study was undertaken on dickite and pyrophyllite with Si and Al cations in the far-infrared(Far-IR) and mid-infrared (Mid-IR) regions, respectively. Attempts were made to present bonding information and make assignments on the absorption bands of dickite in the Far-IR region. Dickites contain a small proportions or kaolinite or nacrite layers. FTIR can be used as a potential tool for characterizing the presence of mixed-layer with different polytypes of the kaolin minerals. There is no clear relationship between Hinckley index and crystallinity of dickite. Although pyrophyllite shows a strong OH stretching band at 3673-3676 $cm^{-1}$ / corresponding to an inner hydroxyl group, the weak band at $3645-3648 cm^{-1}$ seems to be due to the symmetric vibration if the symmetry of the structure is not ideal, probably due to the presence of trace Fe or mixture phases of 1Tc and 2M polytypes.

• Journal of the Mineralogical Society of Korea
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• v.22 no.4
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• pp.385-393
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• 2009

The spectroscopic characteristics of Madagascar tourmaline were investigated by UV-Vis and FTIR spectroscopy. Physical features were similar to other region's tourmalines. The green and blue samples showed strong absorption band in the 714~743 nm due to $Fe^{3+}$, pink samples showed strong absorption band in the 510~530 nm due to $Mn^{3+}$, brown samples showed strong absorption at 324 nm due to $Mn^{2+}-Ti^{4+}$ IVCT and the colorless samples only revealed weak absorption at 406~413 nm or no absorptions due to low quantity of Mn. Combination of the stretching and bending mode cationic hydroxyl units (metal-OH) are observed in the 4300~4500 $cm^{-1}$. The parallel tube-shaped inclusions which contain hematite were detected generally. This investigation revealed that Cu was not detected but Fe and Mn were detected in the Madagascar tourmalines, and the various colors appear according to the amount of those impurity elements.

• Journal of the Mineralogical Society of Korea
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• v.21 no.2
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• pp.117-127
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• 2008

The characteristics of phosphate adsorption-desorption on kaolinite was studied by batch adsorption experiments and detailed adsorbed state of phosphate on kaolinite surface was investigated using ATR-FTIR (Attenuated Total Reflectance-Fourier Transform Infrared) spectroscopy. The phosphorous contents were measured using UV-VIS-IR spectrophotometer with 820 nm wavelength. The adsorbed P was generally increased with increasing pH value in the range of pH 4 to pH 9, however it is not distinct. Moreover the adsorbed P was significantly changed with different initial phosphate concentration. The adsorption isotherms were well fitted with the Langmuir equation, Temkin equation, and Freundlich equation in descending order. The maximum Langmuir adsorption capacity of kaolinite KGa-2 is 232.5 ($204.1{\sim}256.5$) mg/kg and has very higher value than that of kaolinite KGa-1b. Most of adsorbed phosphate on kaolinite were not easily desorbed to aqueous solution, but might fixed on kaolinite surface. However it needs further research about the exact desorption experiment. It was impossible to recognize phosphorous adsorption bands on kaolinite in ATR-FTIR spectrum from kaolinite bands themselves, because the absorption peaks of phosphorous have very similar positions with those of kaolinite, and the intensities of the former were very weak in comparison with those of the latter.