• Title/Summary/Keyword: FT-Raman

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A study on the crystallization processing of photosensitive glass by FT-IR and FT-Raman spectroscopy (FT-IR과 FT-Raman 분광계를 이용한 광민감유리의 결정화 과정에 관한 연구)

  • 이명원;강원호
    • Electrical & Electronic Materials
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    • v.10 no.3
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    • pp.284-288
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    • 1997
  • FT-IR and FT-Raman spectra were measured for 15Li$_{2}$O.3Al$_{2}$O$_{3}$.78SiO$_{2}$. 4K$_{2}$O glass system after UV irradiations. Optimum UV irradiation time of Li$_{2}$O.SiO$_{2}$ crystalline phase was 60 seconds and crystalline phase of Li$_{2}$O.SiO$_{2}$ was leached out on 5% HF. 977 cm$^{1}$ band of FT-Raman spectra can be attributed to two-non bridging oxygen in unit cell for 1 hour and optimum crystallization was confirmed for 3 hrs, 630.deg. C.

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FT-IR and Raman Spectroscopy for the Interaction between Poly(2-hydroxyethylmethacrylate) and Amino Acids (Poly(2-hydroxyethylmethacrylate)와 아미노산과의 상호작용에 관한 FT-IR과 Raman 분광학적 연구(II))

  • 김의락;정봉진
    • KSBB Journal
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    • v.11 no.5
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    • pp.557-564
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    • 1996
  • The interaction between poly(2-hydroxyethylmethacrylate)(poly(HEMA)) which is a material of contact lens containing approximately 45%o water and water soluble amino acids (alanine, arginine, glycine, lysine, methionine, proline, and serine) was investigated by using FT-IR and Raman spectroscopy. The results revealed that arginine and lysine had the strongest interaction with poly(HEMA) among amino acids. The interaction depended on the quantity of charges on ammo acids. They interacted predominately with hydroxyl groups in poly(HEMA).

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Polarized Raman Spectroscopic Studies of Syndiotactic Polypropylene (편광 Raman 분광법을 이용한 Syndiotactic Polypropylene에 관한 연구)

  • 진정희;임현주;김성수;송기국
    • Polymer(Korea)
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    • v.26 no.6
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    • pp.745-751
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    • 2002
  • The anisotropic Raman scattering properties of oriented syndiotactic poly propylene have been investigated using FT-Raman spectrometer in which the fluore scent problem of polymer samples can be removed. To assign the observed Raman bands to their respective symmetry species, the anisotropic scattering results for four different combinations of incident and scattered polarization were compared with those predicted by normal coordinate analysis and infrared dichroism measurement data.

Vibrational Spectroscopic Studies of Crystallization in Mixed n-Paraffins (진동분광실험을 이용한 n-Paraffin혼합물의 결정화에 관한 연구)

  • 김도균;임현주;최선남;김성수;송기국
    • Polymer(Korea)
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    • v.26 no.6
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    • pp.752-758
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    • 2002
  • FTIR, FT-Raman, and X-ray diffraction techniques were used to determine chain segregations and lamellar structures of the mixed binary n-paraffins with different chain lengths. The results of three different techniques, infrared spectroscopic studies of crystal field splitting, the Raman longitudinal acoustic mode, and the SAXS long period measurements were compared one another to understand the crystallization mechanism of separated or mixed n- paraffin lamellae.

Compositional Analysis of Naphtha by FT-Raman Spectroscopy

  • 구민식;정호일
    • Bulletin of the Korean Chemical Society
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    • v.20 no.2
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    • pp.159-162
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    • 1999
  • Three different chemical compositions of total paraffin, total naphthene, total aromatic content in naphtha have been successfully analyzed using FT-Raman spectroscopy. Partial least squares (PLS) regression has been utilized to develop calibration models for each composition from Raman spectral bands. The PLS calibration results showed Blood correlation with those of gas chromatography (GC). Using PLS regression, the spectral information related to each composition has been successfully extracted from highly overlapped Raman spectra of naphtha.

Analysis of Structure and Physical and Chemical Properties of the Carbonized Powder of Pine Wood (Pinus densiflora Sieb. et Zucc.) (II) - FT-IR, Raman - (가열처리 및 탄화처리 소나무재(Pinus densiflora) 목분의 구조 및 물리·화학적 특성(II) - FT-IR, Raman -)

  • Lee, In-Ja;Lee, Won-Hee
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.4
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    • pp.52-57
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    • 2008
  • In this study, the effects of carbonization temperature on the physico-chemical properties of porous wood charcoal are studied by FT-IR and Raman spectroscopies. IR studies showed that cellulose and hemicellulose are mostly decomposed in the precarbonization stage at $500^{\circ}C$, while the decomposition reaction of relatively more stable lignin lasts up to $700^{\circ}C$. Above $900^{\circ}C$, the peak at $1575cm^{-1}$ disappears and a new peak at $1630cm^{-1}$, which seems to be related to the new carbon deposit phase, is evolved. The results of Raman studies, which show the red-shift of D-band and the increase in the relative intensity of D- to G-band, indicate that the size of the crystalline becomes smaller with increasing the carbonization temperature.

The 1320-nm Excited FT-Raman Spectra of Lightly Iodine-Doped trans-Polyacetylene

  • Kim, Jin-Yeol;Yukio Furukawa;Akira Sakamoto;Mitsuo Tasumi
    • Macromolecular Research
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    • v.10 no.5
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    • pp.286-290
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    • 2002
  • The FT-Raman spectra of trans-polyacetylene films doped lightly with iodine were obtained with the 1320-nm laser line. The observed Raman bands are attributed to positively charged domains created by acceptor doping. The observed Raman wavenumbers of the V$_2$, (CC stretch), V$_3$, and V$_4$ bands (mixed of CC stretch and CH in-plan bending) of iodine-doped form are slightly higher than those of the corresponding bands of pristine trans-polyacetylene, whereas the contrary is the case for V$_1$, and (C=C stretch) of iodine-doped form. In particular, these upshifts of the V$_2$ and V$_3$ bands are distinguished from the downshifts of these bands in donor doping. The origin of doping induced Raman bands is discussed in terms of solitons and polarons.

The Quantitative Analysis of SB Latex Contents in Coating Color and Coating Layer of Coated Paper Using FT/Raman Spectroscopy (FT/RAman을 이용한 도공액과 도공지의 도공층 내의 SB Latex 정량분석)

  • 이복진;정순기;윤동호;마금자
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.4
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    • pp.16-22
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    • 1999
  • The quantitative analysis of SB latex contents in coating color and coated paper was investigated with FT/Raman spectroscopy. From the measured FT/IR and FT/Ramon spectra, the peaks of coating color were compared with those of each compoents . Calibration curves were obtained by the area of latex peaks and PLS method of QuantIR program. The relation of predicted values in PLS method and actual values in coating mixtures and coating layer was examined. The components of coating layer in coated paper were investigated by EDS , X-mapping and SEM, The contents of latex in z-direction were calculated in the coating layer of unknown coated paper. The latex concentration measurements of Top layer and Pre layer in double coated paper show that each layer has different value. In single coated paper, it is clear that the latex concentration is highest at the surface and decreases with an increase of depth. From those results it is indicated that the latex migrates to the coated surface. The result of this study may be applied to the binder migration study and the quality control in paper mill.

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