• Title/Summary/Keyword: FT-IR analysis

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Analysis of RCD'S Material Degradation by Weathering Test (내후성시험에 의한 누전차단기 재질변화 분석)

  • Kim, Chong-Min;Bang, Sun-Bae;Shong, Kil-Mok;Yong, Shin-Jin;Kim, Chang-Hwan
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.59 no.2
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    • pp.232-237
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    • 2010
  • Fault rate of RCD is increasing due to deterioration and long period usage in domestic. According to Korean standards, the RCDs are installed in panel boards. When RCDs are installed at outdoor, the RCDs must be protected from uv, water etc. by using the housing. However, many RCDs are exposed to the external environment. As a results, many RCDs have malfunctions so that cause the electrical accidents. The RCDs manufactured by four makes were used as the sample to weathering test. Futhermore, those were analyzed the ingredients of RCD'S using SEM, EDX and FT-IR/TAR before and after weathering test.

Scientific Studies on Ancient Silk Fibers Used for Textiles Excavated at Archaeological Sites in Japan, Using Microscopic Fourier Transform Infrared Spectroscopy

  • SATO, Masanori
    • Journal of Conservation Science
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    • v.5 no.2 s.6
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    • pp.45-50
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    • 1996
  • Silk fibers excavated at Fujinoki mounted tomb, Shimoikeyana mounted tomb and Kuriyama site were examined using FT-IR microscope and two peaks called amide I and II present in modern silk fibers were compared with those of excavated fibers. It was found that amide ground in a polymer molecule decreased with the progress of degradation and peak intensity of amide group in infrared spectrum decreased correspondingly. The advantages of FT-IR microscopy for the analysis of organic remains in archaeological view point were evaluated and it was concluded that the systematic investigation of spectral change due to the degradation of respective material is essential.

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Studies on the Synthesis of (3 - Alkyl benzimidazolium)-TCNQ Complexes (유기전하 이동착체의 합성에 관한 연구)

  • Sohn, Byoung-Chung;Hwang, Kyo-Hyun;Jeong, Soon-Wook
    • Journal of the Korean Applied Science and Technology
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    • v.11 no.1
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    • pp.33-37
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    • 1994
  • In this research, (3-alkyl benzimidazalium)-TCNQ complexes were synthesized to obtain the necessary components for Langmuir-Blodgett Technique. (3- Alkyl benzimidazolium)-TCNQ complexes were prepared by the reaction of LiTCNQ with 3-alkyl benzimidazolium bromides and the products were confirmed by elemental analysis. FT-IR, UV-Visible spectroscopies. FT-IR spectra of (3-alkyl benzimidazolium) TCNQ(1:2) complexes were characterized by a broad band with a maximum at about $2900cm^{-1}$ appears and were ascribed to electronic rather than vibrational absorption.

A Study on Stabilization and Mechanical Properties of Polyacrylonitrile-based Fiber with Itaconic acid (이타콘산을 함유한 폴리아크릴로니트릴계 전구체섬유의 열안정화 및 그 물성에 관한 연구)

  • 신익기;이신희;박수민
    • Textile Coloration and Finishing
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    • v.15 no.2
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    • pp.76-85
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    • 2003
  • In this study, a continuous stabilization process is used to make high-performance carbon fiber from polyacrylonitrile(PAM)-based fibers. The effect of oxygen content of PAN-based fiber on the stabilization process and the properties of the resultant carbon fibers is investigated. In order to research the progress of stabilization reaction FT-IR, elemental analysis, density, DSC, etc are used. Stabilization is carried out in air atmosphere from the 200 to $300^\circ{C}$ temperature range. An increase of PAN-based fibers diameter reduces the oxygen content during the continuous stabilization process. A higher oxygen content increase the density, tensile strength and modulus in the resultant carbon fibers. The most appropriate oxygen content in the stabilized fiber should be about 12%. Fibers having more than 2% oxygen content yield carbon fibers with inferior properties. Those carbon fibers also have sufficient commercial availability.

Study on synthesis of CuPc derivative and preparation of its Langmuir- Blodgett Films. (($NO_{2}$가스센서용 phthalocyanine 유도체의 합성과 LB막의 제작 및 특성에 관한 연구)

  • Sohn, Byoung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.11 no.2
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    • pp.147-150
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    • 1994
  • Ultra thin films of HDSM-CuPc(Tetra-3-hexadecylsulphamoylcopperphthalocya-nine) were formed on various substrates by Langmuir-Blodgett method, where HDSM-CuPc was synthesized by attaching long-chain alkylamine(hexa-decylamine) to CuPc. The reaction product was identified with FT- IR, UV-visible absorption spectroscopies, elemental analysis and thin layer chromatography. The formation of ultrathin films of HDSM-CuPc was confirmed by FT-IR and UV-visible spectroscpies.

Analyses on Artifacts of Koryo Kynasty Excavated from Hyungok-ni Danyang (단양 현곡리 출토 고려시대 섬유류 및 지류 유물에 관한 연구)

  • 안춘수;박희현
    • Journal of the Korean Society of Clothing and Textiles
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    • v.23 no.8
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    • pp.1161-1169
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    • 1999
  • This research was aimed to identify the artifact type and their characteristics of the textile related materials excavated from Koryo Dynasty tombs of Hyungok-ni Danyang. Microscopy solubility test energy dispersive X-ray spectroscopy(EDS) and fourier transform infrared spectroscopy (FT-IR) fabric density test were used for the identification and when necessary standard samples were made in order to compare its characteristics with hose of the original artifact, the result indicated that the artifacts included both textile and paper. Artifacts from Burial 14 were comprised of textile fragments FT-IR and the solubility test conducted on the artifact indicated that the textiles were made with ramie woven with plain weave technique in a fairly loose fabric density. Rest of the artifacts were all comprised of paper.

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FT-IR Study of Dopant-wool Interactions During PPy Deposition

  • Varesano Alessio;Aluigi Annalisa;Tonin Claudio;Ferrero Franco
    • Fibers and Polymers
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    • v.7 no.2
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    • pp.105-111
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    • 2006
  • Coating the fibre surface by in situ oxidative chemical polymerisation of polypyrrole (using $FeCl_3$ as oxidant) is a readily industrial applicable way to give electrical properties to wool with good ageing stability [1], although pre-treatments are required to avoid damage of the cuticle surface due to the acidic condition of the process. FT-IR and EDX analysis reveal that organic sulphonates and sulphates, used as dopants, are absorbed by wool, while chlorine ions are preferably embedded on the polypyrrole layer. The resulting electrical conductivity seems mainly due to the presence of chlorine as counter-ion of polypyrrole; nevertheless, the presence of arylsulphonate in the polymerisation bath increases the electrical conductivity of the coating layer.

Ultraviolet Photografting Reaction of Acrylamide onto Styrene-Butadiene Rubber (Styrene-Butadiene 고무의 아크릴아미드 UV 광그라프팅 반응)

  • Lee, K.I.;Ryu, S.H.
    • Elastomers and Composites
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    • v.33 no.5
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    • pp.363-369
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    • 1998
  • Photografting reaction onto styrene-butadiene rubber (SBR) as a function of monomer concentration, irradiation time and carbon black content has been studied using ultraviolet (UV). Acrylamide and benzophenone are used as monomer and photoinitiator, respectively. FT-IR ATR and static contact angle analysis using distilled water are used to measure the graft ratio of acrylamide onto SBR surface. Graft ratio of acrylamide increases with acrylamide concentration and irradiation time and contact angle tends to decrease with increasing graft ratio. It is observed that graft ratio increases with carbon black content.

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Synthesis and Characterization of Three-dimensional Polymer Produced by Mutual Condensation of Ethylenediamine and $C_{60}$

  • Vovk, O.;Lee, Joong-Kee
    • Carbon letters
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    • v.5 no.2
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    • pp.68-74
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    • 2004
  • The polymer with contents of $C_{60}$ up to 57 wt.% was produced by mutual condensation of fullerene $C_{60}$ and ethylenediamine. The investigations of this polymer as well as pristine fullerene to comparison were carried out by FT-IR and UV-Vis spectroscopy, ToF-SIMS, TGA, and elemental analysis. At least three kinds of components was revealed as building blocks of polymer. The fullerene cage underwent only distortion but didn't destroy during formation of polymer. The pure fullerene was found as an intermediate of the thermal decomposition of polymer. The conclusion that this polymer could serve as precursor to produce carbon nanomaterial with high concentration curved graphene sheets and can be used for gas adsorption and electrochemical application was made.

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Cement Paste Hardened Body with High Temperature Exposure Time Fourier Transform Infrared Spectroscopy (고온 노출 시간에 따른 시멘트 페이스트 경화체의 푸리에 변환 적외분광 분석)

  • Kim, Min-Hyouck;Cho, Hyeon-Seo;Lee, Gun-cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.05a
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    • pp.120-121
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    • 2019
  • In this study, FT-IR analysis was performed by exposing cement paste to high temperature in order to characterize the change of hydration behavior of concrete structure damaged by fire accident. As the holding time increased, the Al-O vibration region increased due to the increase of Si-O symmetric Ca2(SiO4) and Brownilerite, and the OH stretching region tended to increase due to thermal decomposition of Ca(OH)2.

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