• Title/Summary/Keyword: FRP-Recycling

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A Study on the Preparation and Mechanical Properties of Hybrid Composites Reinforced Waste FRP and Urethane Foam (폐 FRP/Urethane Foam 충진 혼성복합재의 제조 및 기계적 물성에 관한 연구)

  • 황택성;신경섭;박진원
    • Polymer(Korea)
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    • v.24 no.4
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    • pp.564-570
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    • 2000
  • The waste FRP occured in the fabrication of SMC (sheet molding compound) bathtubs and the waste polyurethane foam occured in electronic manufacture and waste insulator were applied as a soundproof and light weight pannel in the waste FRP unsaturated polyester matrix resin composites to recycle. The effect of filler contents on the mechanical properties and interfacial phenomena of the filler and matrix on the composites was evaluated. The tensile strength of composites reached its maximum value of 82.34 MPa when the filler content was 70 wt%, and the more content of reinforcement is increased, the more tensile modulus was decreased. The flexural strength and modulus of composites, reinforced 70 wt% with filler content, were dominant compared to the other samples to 72.5 MPa, 958.4 MPa respectively. When composite of reinforced 70 wt% with filler content, it was confirmed that pull out phenomena and cracks did not occur in the interface of reinforcement and matrix resin through the SEM observation. Also, waste FRP and urethane foam were dispersed well into matrix resin as filler.

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A Study on the Preparation ana Mechanical Properties of Composites Reinforced FRP Waste and Rock-Crush Sludge (폐 FRP/석분슬러지 충전 복합재의 제조 및 기계적 물성에 관한 연구)

  • 황택성;박진원;이철호
    • Polymer(Korea)
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    • v.24 no.6
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    • pp.829-836
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    • 2000
  • In order to recyle the FRP waste from SMC bathtubs and rock-crush sludge obtained as a byproduct of stones, the composite consisting of the FRP and rock-crush sludge and the unsaturated polyester matrix resin were prepared. To enhance the interfacial bonding force between the reinforcements and the matrix resin, the rock-crush sludge was treated with silane coupling agent, ${\gamma}$-methacryloxypropyltrimethoxysilane (${\gamma}$-MPS) and their mechanical properties and interface phenomena were examined. The flexural modulus of the composite containing 10 wt% rock-crush powder treated with 3 wt% silane coupling agent showed the maximum value. And also the initial thermal degradation temperature of composites were in the range of 352~359$^{\circ}C$. From these results, we observed that the weight loss of composites was almost constant regardless of the concentration of silane coupling agent. It is confirmed that the interface of the composites containing filler treated with ${\gamma}$-MPS was improved in that there were no pull-out phenomena between the reinforcement and matrix resin.

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Comparative LCA of three types of Interior Panel(IP) in Electric Motor Unit(EMU) (전동차 내장패널(Interior Panel)에 대한 비교 전과정평가)

  • Choi, Yo-Han;Lee, Sang-Yong;Kim, Yong-Ki;Lee, Kun-Mo
    • Proceedings of the KSR Conference
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    • 2007.05a
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    • pp.584-588
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    • 2007
  • A comparative Life Cycle Assessment(LCA) among three types of Electric Motor Unit(EMU) Interior Panel(IP) was conducted. A functional unit for comparative LCA is a weight of IP for 1 EMU. It assumed that Manufacturing stage and its upstream processes, Use stage and End of Life(EoL) stage are included in the boundary of product system. For Use stage, the weight of IP causes electricity consumption. It is assumed that aluminum IP is recycled and the other IPs are incinerated at the EoL stage. As comparison results, aluminum IP has much larger environmental impact(5.162pt) than others(FRP IP; 4.069pt, Phenol IP; 4.053pt) even though recycling consideration is included. The manufacturing stage of aluminum has relative big envrionmental impact(1.824pt) and this point make the most important difference from other IPs(FRP IP; 0.1617pt, Phenol IP; 0.4534pt)). Despite of large weight difference between FRP IP(888.56Kg) and phenol IP(315Kg), the final environmental impact result has only little difference(0.016pt, 0.39%). With this result, the EMU designer can choose IP with a consideration of the environmental performance of IP.

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Mechanical and Electrochemical Characteristics of Welding Parts Surface for Friction Stir Welded 5456-H116 Al Alloy (마찰교반용접한 5456-H116 알루미늄 합금 용접부 표면의 기계적 및 전기화학적 특성)

  • Jang, Seok-Ki;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.41 no.4
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    • pp.156-162
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    • 2008
  • Small FRP(fiber-reinforced polymer) fishing ships have numerous problems with the point of the environmental and recycling perspectives. In light of these aspects, aluminum can be used as a material for ship building. It is environmental friendly, easy to recycle, and provides a high added value to fishing boats. In this paper, we report on mechanical and electrochemical characteristics of welding parts for friction stir welded 5456-H116 Al alloy. In friction stir welded at various traveling speeds under the rotation speed of 500 RPM, the best characteristics presented in traveling speed of 15mm/min. The anodic polarizations of base metal and welding metal were observed tendency which current density from the open circuit potential suddenly increase. The cathodic polarization presented concentrated polarization caused by the dissolved oxygen reduction reaction and activation polarization caused by hydrogen generation. From result of Tafel analysis, the corrosion potential of 5456 alloy(Base metal) was lower than that of friction stir welded part, as were its corrosion current densities.

Comparative LCA of three types of Interior Panel (IP) in Electric Motor Unit (EMU) (전동차 내장패널(Interior Panel)에 대한 비교 전과정평가)

  • Choi, Yo-Han;Lee, Sang-Yong;Kim, Yong-Ki;Lee, Kun-Mo
    • Journal of the Korean Society for Railway
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    • v.10 no.5
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    • pp.596-599
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    • 2007
  • A comparative Life Cycle Assessment (LCA) among three types of Electric Motor Unit (EMU) Interior Panel (IP) was conducted. A functional unit for comparative LCA is a weight of IP for 1 EMU. It is assumed that Manufacturing stage and its upstream processes, Use stage and End of Life (EoL) stage are included in the boundary of product system. For Use stage, the weight of IP causes electricity consumption. It is assumed that aluminum IP is recycled and the other IPs are incinerated at the EoL stage. As a comparison results, aluminum IP has much larger environmental impact (5.162pt) than others (FRP IP; 4.069pt, Phenol IP; 4.053pt) even though recycling consideration is included. The manufacturing stage of aluminum IP has relative big environmental impact (1.824pt) and this point make the most important difference from other IPs (FRP IP; 0.1617pt, Phenol IP; 0.4534pt)). Despite of large weight difference between FRP IP (888.96kg) and phenol IP (316kg), the final environmental impact result has only little difference (0.016pt, 0.39%). With this result, the EMU designer can choose IP with a consideration of the environmental performance of IP.

Investigation on optimum protection potential of high-strength Al alloy(5456-H116) for application in ships (선박용 고강도 Al합금(5456-H116)의 최적 방식 전위결정에 관한 연구)

  • Kim Sung-Jong;Ko Jae-Yong
    • Journal of Advanced Marine Engineering and Technology
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    • v.30 no.1
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    • pp.157-168
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    • 2006
  • Recently, interest in using Al alloys in ship construction instead of fiber-reinforced plastic (FRP) has increased because of the advantages of A) alloy ships over FRP ships, including high speed, increased load capacity. and ease of recycling. This paper investigated the mechanical and electrochemical properties of Al alloys in a slow strain rate test under various potential conditions. These results will provide reference data for ship design by determining the optimum protection potential regarding hydrogen embrittlement and stress corrosion cracking. In general, Al and Al alloys do not corrode on formation of a film that has resistance to corrosion in neutral solutions. In seawater, however, $Cl^-$ ions lead to the formation and destruction of a Passive film. In a potentiostatic experiment. the current density after 1200 sec in the Potential range of $-0.68\~-1.5\;V$ was low. This low current density indicates the protection potential range. Elongation at an applied potential of 0 V was high in this SSRT. However, corrosion protection under these conditions is impossible because the mechanical properties are worse owing to decreased strength resulting from the active dissolution reaction in parallel parts of the specimen. A film composed of $CaCO_3\;and\;Mg(OH)_2$ confers corrosion resistance. However, at potentials below -1.6 V forms non-uniform electrodeposition coating, since there is too little time to form a coating. Therefore, we concluded that the mechanical properties are poor because the effect of hydrogen gas generation exceeds that of electrodeposition. Comparison of the maximum tensile strength, elongation, and time to fracture indicated that the optimum protection potential range was from -1.45 to -0.9 V (SSCE).

Effects of Water Cavitation Peening on Cavitation Characteristics of 5000 Series Al Alloys (5000계열 Al 합금의 캐비테이션 특성에 관한 워터 캐비테이션 피닝의 영향)

  • Kim, Seong-Jong;Hyun, Koang-Yong
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.18 no.5
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    • pp.481-487
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    • 2012
  • Recently, the construction of the small Al alloy ships is an increasing trend in viewpoint such as the disposal issue of a retired ship, the enhancement of environmental regulation and resources recycling etc. for FRP ships. However, Al alloy ship which can achieve high speed by light weight in marine environment is exposed to a problem on materials damage by cavitation-erosion which is generated by large impact pressure with the collapse of air bubbles due to cavitation. Consequently, in this study, water cavitation peening technology was applied in Al alloy for ship to enhance durability life by preventing cavitation damage. So, the water cavitaton peening application time that presented the excellent cavitation characteristic investigated. The weight-loss of 5456-H116, 5083-H321 and 5052-O Al alloy at the optimum water cavitation peening time were improved to 42.11 %, 50.0 % and 25.7 %, respectively.

Next Generation Lightweight Structural Composite Materials for Future Mobility Review: Applicability of Self-Reinforced Composites (미래모빌리티를 위한 차세대 경량구조복합재료 검토: 자기강화복합재료의 적용 가능성)

  • Mi Na Kim;Ji-un Jang;Hyeseong Lee;Myung Jun Oh;Seong Yun Kim
    • Composites Research
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    • v.36 no.1
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    • pp.1-15
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    • 2023
  • Demand for energy consumption reduction is increasing according to the development expectations of future mobility. Lightweight structural materials are known as a method to reduce greenhouse gas emissions and improve energy efficiency. In particular, fiber reinforced polymer composite (FRP) is attracting attention as a material that can replace existing metal alloys due to its excellent mechanical properties and light weight. In this paper, industrial applications and research trends of carbon fiber reinforced composites (CFRP, carbon FRP) and self-reinforced composites (SRC) were reviewed based on the reinforcement, polymer matrix, and manufacturing process. In order to overcome the expensive process cost and long manufacturing time of the epoxy resin-based autoclave method, which is mainly used in the aircraft field, mass production of CFRP-applied electric vehicles has been reported using a high-pressure resin transfer molding process including fast-curing epoxy. In addition, thermoplastic resin-based CFRP and interface enhancement methods to solve the recycling issue of carbon fiber composites were reviewed in terms of materials and processes. To form a perfect matrix-reinforcement interface, which is known as the major factor inducing the excellent mechanical properties of FRP, studies on SRC impregnated with the same matrix in polymer fibers have been reported. The physical and mechanical properties of SRC based on various thermoplastic polymers were reviewed in terms of polymer orientation and composite structure. In addition, a copolymer matrix strategy for extending the processing window of highly drawn polypropylene fiber-based SRC was discussed. The application of CFRP and SRC as lightweight structural materials can provide potential options for improving the energy efficiency of future mobility.

The Welding Surface and Mechanical Characteristics in Friction Stir Welding for 5456-H116 Alloy (마찰교반용접에 의한 5456-H116 합금의 용접 형상과 기계적 특성)

  • Kim, Seong-Jong;Han, Min-Su;Jang, Seok-Ki
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.18 no.3
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    • pp.273-278
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    • 2012
  • The use of Al alloys instead of fiber-reinforced plastic(FRP) in ship construction has increased because of the advantages of Al-alloy ships, including high speed, increased load capacity, and ease of recycling. This paper describes the effects of probe diameter on the optimum friction stir welding conditions of 5456-H116 alloy for leisure ship, measured by a tensile test. In friction stir welding using a probe diameter of 5 mm under various travel and rotation speed conditions, the best performance was achieved with a travel speed of 61 mm/min. Using a probe diameter of 6 mm, rotation speeds of 170-210 rpm, and a travel speed of 15 mm/min produced a rough surface and voids because of insufficient heat input produced by the low rotation speed. At 500-800 rpm, chips were observed, although there were no voids, and the weld surface was excellent. However, at 1100-2500 rpm, many chips were produced due to excessive heat input. Heat effects were very evident on the bottom. For a travel speed of 15 mm/min, heat input caused by friction increased as the rotation speed increased. The mechanical characteristics were degraded by accelerated softening due to increasing heat input.