• Bulletin of the Korean Chemical Society
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• v.32 no.2
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• pp.444-450
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• 2011

A novel method that utilizes poly(5-methyl-2-thiozyl methacrylamide-co-2-acrylamido-2-methyl-1-propanesulfonic acid-co-divinylbenzene) [MTMAAm/AMPS/DVB] as a solid-phase extractant was developed for simultaneous preconcentration of trace Cd(II), Co(II), Cr(III), Cu(II), Fe(III), Mn(II), Ni(II), Pb(II), and Zn(II) prior to the measurement by flame atomic absorpiton spectrometry (FAAS). Experimental conditions for effective adsorption of the metal ions were optimized using column procedures. The optimum pH value for the simultaneously separation of the metal ions on the new adsorbent was 2.5. Effects of concentration and volume of elution solution, sample flow rate, sample volume and interfering ions on the recovery of the analytes were investigated. A high preconcentration factor, 100, and low relative standard deviation values, $\leq$1.5% (n = 10), were obtained. The detection limits (${\mu}gL^{-1}$) based on the 3s criterion were 0.18 for Cd(II), 0.11 for Co(II), 0.07 for Cr(III), 0.12 for Cu(II), 0.18 for Fe(III), 0.67 for Mn(II), 0.13 for Ni(II), 0.06 for Pb(II), and 0.09 for Zn(II). The validation of the procedure was performed by the analysis of two certified reference materials. The presented method was applied to the determination of the analytes in various environmental samples with satisfactory results.

• Journal of the Korean Society of Radiology
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• v.14 no.4
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• pp.391-396
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• 2020

In this study, we developed a phosphor film screen that can be applied to radiographs during non-destructive testing using Gd₂O₂S:Tb phosphor compounds. The image uniformity of the fabricated phosphor screen film was analyzed by FE-SEM, RMS and RDS analysis. In addition, the tensile strength, elongation, and modulus of elasticity of the Gd₂O₂S:Tb phosphor screen were evaluated by measuring the stress-strain characteristic curve. As a result, it was evaluated that the RSD value had an excellent image uniformity within 10% of the evaluation criteria. In addition, as a result of evaluation of physical properties, the tensile strength was 1.1760 N/㎟, the tensile strength at break was 1.1515 N/㎟. These results suggest that the Gd₂O₂S:Tb phosphor screen fabricated using the room temperature gel-printing method could be applied to digital radiography detectors for radiography.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.08a
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• pp.281-281
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• 2010

Very low refractive index (<1.4) materials have been proved to be the key factor improving the performance of various optical components, such as reflectors, filters, photonic crystals, LEDs, and solar cell. Highly porous SiO2 are logically designed for ultralow refractive index materials because of the direct relation between porosity and index of refraction. Among them, ordered macroporous SiO2 is of potential material since their theoretically low refractive index ~1.10. However, in the conventional synthesis of ordered macroporous SiO2, the time required for the crystallization of organic nanoparticles, such as polystyrene (PS), from colloidal solution into well ordered template is typical long (several days for 1 cm substrate) due to the low interaction between particles and particle - substrate. In this study, polystyrene - polyacrylic acid (PS-AA) nanoparticles synthesized by miniemulsion polymerization method have hydrophilic polyacrylic acid tails on the surface of particles which increase the interaction between particle and with substrate giving rise to the formation of PS-AA film by simply spin - coating method. Less ordered with controlled thickness films of PS-AA on silicon wafer were successfully fabricated by changing the spinning speed or concentration of colloidal solution, as confirmed by FE-SEM. Based on these template films, a series of macroporous SiO2 films whose thicknesses varied from 300nm to ~1000nm were fabricated either by conventional sol - gel infiltration or gas phase deposition followed by thermal removal of organic template. Formations of SiO2 films consist of interconnected air balls with size ~100 nm were confirmed by FE-SEM and TEM. These highly porous SiO2 show very low refractive indices (<1.18) over a wide range of wavelength (from 200 to 1000nm) as shown by SE measurement. Refraction indices of SiO2 films at 633nm reported here are of ~1.10 which, to our best knowledge, are among the lowest values having been announced.

• Journal of the Korean Chemical Society
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• v.38 no.8
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• pp.576-584
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• 1994

The method described offers rapid and efficient sample preparation using on-line microwave digestion of metal oxides in water sample with direct elemental detection by ICP-AES. The open tubing digestion system(OTD) and the restraint tubing digestion system(RTD) for flow injection(FI) were designed and tested to find the optimum conditions. Comparison of OTD and RTD indicated that RTD was 3 times faster on the digestion time, and 10 times higher on sample mass. Finally, the results of RTD agree well with those by conventional microwave open vessel in all cases and show good precision; Fe and Cu show good with about 5% of RSD, while Zn and Co more or less than 10% RSD.

• Steel and Composite Structures
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• v.29 no.6
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• pp.717-734
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• 2018

This paper presents the flexural performance of steel beam-to-column joints composed of hollow structural section beams and columns. A finite element (FE) model was developed incorporating geometrical and material nonlinearities to evaluate the behaviour of joints subjected to bending moments. The numerical outcomes were validated with experimental results and compared with EN1993-1-8. The demountability of the structure was discussed based on the tested specimen. A parametric analysis was carried out to investigate the effects of steel yield strength, end-plate thickness, beam thickness, column wall thickness, bolt diameter, number of bolts and location. Consequently, an analytical model was derived based on the component method to predict the moment-rotation relationships for the sub-assemblies with extended end-plates. The accuracy of the proposed model was calibrated by the experimental and numerical results. It is found that the FE model is fairly reliable to predict the initial stiffness and moment capacity of the joints, while EN1993-1-8 overestimates the initial stiffness extensively. The beam-to-column joints are shown to be demountable and reusable with a moment up to 53% of the ultimate moment capacity. The end-plate thickness and column wall thickness have a significant influence on the joint behaviour, and the layout of double bolt-rows in tension is recommended for joints with extended end-plates. The derived analytical model is capable of predicting the moment-rotation relationship of the structure.

• Steel and Composite Structures
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• v.29 no.3
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• pp.333-348
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• 2018

An analytical method is developed for analysing the contact buckling response of infinitely long, thin corrugated plates and flat plates restrained by a Winkler tensionless foundation and subjected to linearly varying in-plane loadings, where the corrugated plates are modelled as orthotropic plates and the flat plates are modelled as isotropic plates. The critical step in the presented method is the explicit expression for the lateral buckling mode function, which is derived through using the energy method. Simply supported and clamped edges conditions on the unloaded edges are considered in this study. The acquired lateral deflection function is applied to the governing buckling equations to eliminate the lateral variable. Considering the boundary conditions and continuity conditions at the border line between the contact and non-contact zones, the buckling coefficients and the corresponding buckling modes are found. The analytical solution to the buckling coefficients is also expressed through a fitted approximate formula in terms of foundation stiffness, which is verified through previous studies and finite element (FE) method.

• Journal of Advanced Marine Engineering and Technology
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• v.34 no.2
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• pp.275-281
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• 2010

In this paper, a geometric similarity law is introduced to the performance test of a large-sized silencer used in ship engine or plant system. A test of scale-down model enable to yield the cost and time saving in developing large-sized silencer considerably. Two types of silencer, resonator and expansion chamber, were analyzed by a theoretical method and an acoustical FEM(finite element method) in order to obtain geometric similarity variables. A method is proposed to estimate the transmission loss of prototype model using the test results of scale-down model. Two actual large-sized silencer, which consist of resonator and expansion chamber, were analysed by an acoustical FE analysis. Consequently, the proposed method predicts effectively the performance of prototype silencers using those of scale-down models.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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• 2004.11a
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• pp.271-276
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• 2004

In this paper. dynamic behavior of the cracked beam under a moving mass is presented using the finite element method (FEM). Model accuracy is improved with the following consideration: (1) FE model with Timoshenko beam element (2) Additional flexibility matrix due to crack presence (3) Interaction forces between the moving mass and supported beam. The Timoshenko bean model with a two-node finite element is constructed based on Guyan condensation that leads to the results of classical formulations. but in a simple and systematic manner. The cracked section is represented by local flexibility matrix connecting two unchanged beam segments and the crack as modeled a massless rotational spring. The inertia force due to the moving mass is also involved with gravity force equivalent to a moving load. The numerical tests for various mass levels. crack sizes. locations and boundary conditions were performed.

• Journal of the Korean Society for Nondestructive Testing
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• v.36 no.1
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• pp.9-17
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• 2016

The elastic modulus of a 3D-printed Kelvin foam plate is investigated by measuring the acoustic wave velocity of 1 MHz ultrasound. An isotropic tetrakaidecahedron foam with 3 mm unit cell is designed and printed layer upon layer to fabricate a Kelvin foam plate of 14 mm thickness with a 3D CAD/printer using ABS plastic. The Kelvin foam plate is completely filled with paraffin wax for impedance matching, so that the acoustic wave may propagate through the porous foam plate. The acoustic wave velocity of the foam plate is measured using the time-of-flight (TOF) method and is used to calculate the elastic modulus of the Kelvin foam plate based on acousto-elasticity. Finite element method (FEM) and micromechanics is applied to the Kelvin foam plate to calculate the theoretical elastic modulus using a non-isotropic tetrakaidecahedron model. The predicted elastic modulus of the Kelvin foam plate from FEM and micromechanics model is similar, which is only 3-4% of the bulk material. The experimental value of the elastic modulus from the ultrasonic method is approximately twice as that of the numerical and theoretical methods because of the flexural deformation of the cell edges neglected in the ultrasonic method.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.31 no.3A
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• pp.145-152
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• 2011

Current Bridge Specification for Highway Bridges adopts a simplified method to determine sectional forces of abutment wing by dividing its area into four sections. This simplified method was developed in Japan when numerical analysis was not mature and computer resources were expensive. This simplified method has been with us without modification. This study evaluates the problem of current design practice to improve the design guideline for abutment wing. In this study, a finite element model of abutment wing based on shell elements was developed to obtain accurate sectional force. In addition, foreign design specifications regarding abutment wing were thoroughly examined. It has been observed that sectional forces obtained from the simplified method produce inaccurate results under various geometric shapes. Thus, it is recommended that two dimensional plate analyses should be adopted for future design of abutment wing wall.