• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2018.06a
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• pp.23-23
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• 2018

In this study, new titanium alloys were prepared by adding elements such as tantalum (Ta), zirconium (Zr) and the like to complement the biological, chemical and mechanical properties of titanium alloys. The Ti-40Ta-xZr ternary alloy was formed on the basis of Ti-40Ta alloy with the contents of Zr in the contents of 0, 3, 7 and 15 wt. %. Plasma electrolytic oxidation (PEO), which combines high-voltage sparks and electrochemical oxidation, is a novel method to form ceramic coatings on light metals such as Ti and its alloys. These oxide film produced by the electrochemical surface treatment is a thick and uniform porous form. It is also composed of hydroxyapatite and calcium phosphate-based phases, so it has the characteristics of bone inorganic, non-toxic and very high bioactivity and biocompatibility. Ti-40Ta-xZr alloys were homogenized in an Ar atmosphere at $1050^{\circ}C$ for 1 hour and then quenched in ice water. The electrochemical oxide film was applied by using a power supply of 280 V for 3 minutes in 0.15 M calcium acetate monohydrate ($Ca(CH_3COO)_2{\cdot}H_2O$) and 0.02 M calcium glycerophosphate ($C_3H_7CaO_6P$) electrolyte. A small amount of 0.0075M zinc acetate and magnesium acetate were added to the electrolyte to enhance the bioactivity. The mechanical properties of the coated surface of Ti-40Ta-xZr alloys were evaluated by Vickers hardness, roughness test, and elastic modulus using nano-indentation, and the surface wettability was evaluated by measuring the contact angle of the coated surface. In addition, cell activation and differentiation were examined by cell culture of HEK 293 (Human embryonic kidney 293) cell proliferation. Surface properties of the alloys were analyzed by scanning electron microscopy(FE-SEM), EDS, and X-ray diffraction analysis (XRD).

• Journal of the Korean Society of Clothing and Textiles
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• v.33 no.3
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• pp.391-400
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• 2009

The purpose of this study is to investigate the efficacy of safflower yellow colorant as a natural dye for hair coloring. The dyeing properties of safflower yellow colorant on hair were explored to obtain optimum conditions. Also, the effect of mordant was studied in terms of dye uptake, colorfastness, and hair damage to better understand the characteristics of the colorant. Tensile strength measurement and SEM analysis were carried out for investigating hair damage to light exposure and washing. On the basis of obtained results considering possible hair damage, optimum dyeing conditions were set 100%(o.w.h.) colorant concentration, pH 5, $40^{\circ}C$, and 20min. Dye uptake was improved more effectively by repeated dyeing rather than by increasing concentration. Pre-mordanting method improved dye uptake slightly, irrespective of mordant type. The safflower yellow colorant produced Y colors on hair. Cu and Fe mordants improved washing and light fastness slightly. Better strength retention was obtained with the mordanted-dyed hair than the unmordanted-dyed hair after light irradiation for 40 hours and 10 repeated washing. The hair was more damaged by light exposure than by washing. It was concluded that the safflower yellow colorant can be used as a natural semi-permanent hair dye producing Y color without mordanting.

• Transactions of the Korean Society of Automotive Engineers
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• v.17 no.1
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• pp.114-119
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• 2009

The authors have investigated the NVH problems of drive system in full vehicle test. However it is difficult to define the NVH problems of driveline system. Since it is hard to measure the rotating part and it is vague that only the drive system induces the NVH problem. Vibration in a driveline is presented in this paper. In the experiment, the rear sub-frame and propeller shafts and axle were composed and mounted with rubber each other. For applying the vibration input instead of the torsional vibration effect of an engine, the shaker was taken. In particular, torsional vibration due to fluctuating forced vibration excitation across the joint between driveline and rear sub-frame was carefully examined. Accordingly, the joint response was checked from experiments and the FE-simulation using FRF (frequency response function) analysis was performed. All test results were signal processed and validated against numerical simulations. In present study, the new test bench for measuring the vibration signal and simulating the vehicle chassis system was proposed. The modal value and the mode shape of components were analyzed using the CAE model to identify the important components affecting driveline noise and vibration. It could be reached that the simplified test bench could be well established and be used for design guide and development of the vehicle chassis components.

• The Korean Journal of Food And Nutrition
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• v.31 no.2
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• pp.301-307
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• 2018

In this study, a relatively effective process is used to sterilize Escherichia coli on the surface of micro-sized calcium citrate powder using nitrogen and argon as process gases in a low-temperature vacuum plasma treatment. The purpose of this study is to confirm and to introduce the effectiveness of homogeneous surface treatment for the sterilization of fine inorganic powder by the rotatable low-temperature RF plasma system designed by ourselves. The results of the test using 3M petrifilm showed that there were no remarkable spots in the case of the surface of plasma treated powder, whereas the untreated powder showed many blue spots, which indicating that the E. coli was alive. After 5 days, in the same samples, the blue spots were seen to be larger and darker than before, while the plasma-treated powder showed no changes. The results from FE-SEM analysis showed that the E. coli was damaged and/or destroyed by reactive species generated in the plasma space, resulting in the E. coli being sterilized. Furthermore, the sterilization effects according to the selected parameters ($N_2$ and Ar; flow rate 30 and 50 sccm) adapted in this study were mutually similar, regardless of such different process parameters, and this indicates that homogeneous treatment of powder surfaces could be more effective than conventional methods. Therefore, the plasma apparatus used in this study may be a practical method to use in a powerful sterilization process in powder-type food.

• Steel and Composite Structures
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• v.1 no.1
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• pp.17-32
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• 2001

The Rosette-joining system is a completely new press-joining method for cold-formed steel structures. One Rosette-joint has a shear capacity equal to that of approximately four screws or rivets. The Rosette thin-walled steel truss system presents a new fully integrated prefabricated alternative to light-weight roof truss structures. The trusses are built up on special industrial production lines from modified top hat sections used as top and bottom chords and channel sections used as webs which are joined together with the Rosette press-joining technique to form a completed structure easy to transport and install. A single web section is used when sufficient but can be strengthened by double-nesting two separate sections or by using two lateral profiles where greater compressive axial forces are met. An individual joint in the truss can be strengthened by introducing a hollow bolt into the joint hole. The bolt gives the connection capacity a boost of approximately 20%. A series of laboratory tests have been carried out in order to verify the Rosette truss system in practice. In addition to compression tests on individual sections of different lengths, tests have also been done on small structural assemblies and on actual full-scale trusses of a span of 10 metres. Design calculations have been performed on selected roof truss geometries based on the test results, FE-analysis and on the Eurocode 3 and U.S.(AISI) design codes.

• Korean Journal of Agricultural Science
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• v.39 no.2
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• pp.255-261
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• 2012

A bacterium AB-55, isolated from waste mushroom bed of Agaricus bisporus in Sukseong-myeon, Buyeo-gun, Chungcheongnam-do, Korea, was screened onto xylan agar congo-red plate by the xylanolysis method and was used to produce an xylanase in shaker buffle flask cultures containing oat spelt xylans. The phylogenetic analysis using 16S rRNA gene sequence data showed that the strain AB-55 had the highest homology (99.0%) with Bacillus subtilis and it was named as Bacillus subtilis AB-55. A xylanase was purified by ammonium sulfate precipitation (50~80%), gel filtration on sephacryl S-300, and ion exchange chromatography on DEAE sepharose FF. The molecular weight of the xylanase was estimated as 44 kDa by SDS-PAGE. Optimal pH and temperature for the xylanase activity was pH 7 and $50^{\circ}C$, respectively. N-terminal amino acid sequence of the enzyme was identified as Ser-Ala-Val-Lys-His-Gly-Ala-Ile-Val-Phe. The substrate specificity of the enzyme exhibited that it hydrolyzed efficiently oat spelt xylan as well as beechwood xylan, but showed no activity against Avicel and carboxymethyl clellulose (CMC). The enzyme activity was enhanced by $Fe^{2+}$ and $Mn^{2+}$ whereas was entirely inhibited by $Hg^+$.

• Bulletin of the Korean Chemical Society
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• v.34 no.4
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• pp.1195-1198
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• 2013

Nickel hexacyanoferrate supported palladium nanoparticles (Pd-NiHCF NPs) were synthesized and studied for oxygen reduction reactions in direct methanol fuel cell. The NiHCF support was readily synthesized by a comixing of $Ni(OCOCH_3)_2$ and equimolar $K_3[Fe(CN)_6]$ solution into DI water under rigorous stirring. After the preparation of NiHCF support, Pd NPs were loaded on NiHCF via L-ascorbic acid reduction method at $80^{\circ}C$. Pd-NiHCF NPs were electrochemically active for oxygen reduction reaction in 0.1 M $HClO_4$ solution. X-ray absorption near edge structure analysis was conducted to measure the white line intensity of Pd-NiHCF to verify the OH adsorption. As a comparison, carbon supported Pd NPs exhibited same white line intensity. This study provides a general synthetic approach to easily load Pd NPs on porous coordination polymers such as NiHCF and can provide further light to load Pd based alloy NPs on NiHCF framework.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.20 no.4
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• pp.443-451
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• 2007

The improvement of stiffness by the increase of thickness of deck plate or the reinforcement of longitudinal rib is one method among the effective methods to control fatigue damages occurring in orthotropic steel deck. It is likely that the increase of stiffness is effective to restrain local deformation caused by axial load in the steel deck. Therefore, in this study, the parameter studies for the reinforced structural details such as the bulk-head plate and vertical rib which is established to reduce the resultant stresses in the connection parts of the longitudinal rib and floor beam were performed with FE analysis. From the results, it was known that the reinforced structural detail with the bulk-head plate in the longitudinal ribs reduced overall the principal stresses at the connection parts, but the stress concentration increased in the weld toe parts which are occurring fatigue cracks. Also, it was estimated that the reinforced structural detail with the vortical rib in the longitudinal ribs because of the reduction of stress concentration in the weld toe parts is more effective details than the bulk-head plate.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.5
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• pp.569-578
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• 2011

The $SiO_2$ membranes for polymer electrolyte membrane fuel cell (PEMFC) are preapared by electrospinning method. It leads to high porosity and surface area of membrane to accommodate the proton conducting materials. The composite membrane was prepared by impregnating of Nafion ionomer into the pores of electrospun $SiO_2$ membranes. The $SiO_2$:heteropolyacid (HPA) nano-particles as a inorganic proton conductor were prepared by microemulsion process and the particles are added to the Nafion ionomer. The characterization of the membranes was confirmed by field emission scanning electron microscope (FE-SEM), thermogravimetry analysis (TGA), and single cell performance test for PEMFC. The Nafion impregnated electrospun $SiO_2$ membrane showed good thermal stability, satisfactory mechanical properties and high proton conductivity. The addition of the $SiO_2$:HPA nano-particle improved proton conductivity of the composite membrane, which allow further extension for operation temperature in low humidity environments. The composite membrane exhibited a promising properties for the application in high temperature PEMFC.

• Structural Engineering and Mechanics
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• v.74 no.2
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• pp.227-241
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• 2020

The bi-axial and shear buckling behavior of laminated hypar shells having rhombic planforms are studied for various boundary conditions using the present mathematical model. In the present mathematical model, the variation of transverse shear stresses is represented by a second-order function across the thickness and the cross curvature effect in hypar shells is also included via strain relations. The transverse shear stresses free condition at the shell top and bottom surfaces are also satisfied. In this mathematical model having a realistic second-order distribution of transverse shear strains across the thickness of the shell requires unknown parameters only at the reference plane. For generality in the present analysis, nine nodes curved isoparametric element is used. So far, there exists no solution for the bi-axial and shear buckling problem of laminated composite rhombic (skew) hypar shells. As no result is available for the present problem, the present model is compared with suitable published results (experimental, FEM, analytical and 3D elasticity) and then it is extended to analyze bi-axial and shear buckling of laminated composite rhombic hypar shells. A C⁰ finite element (FE) coding in FORTRAN is developed to generate many new results for different boundary conditions, skew angles, lamination schemes, etc. It is seen that the dimensionless buckling load of rhombic hypar increases with an increase in c/a ratio (curvature). Between symmetric and anti-symmetric laminations, the symmetric laminates have a relatively higher value of dimensionless buckling load. The dimensionless buckling load of the hypar shell increases with an increase in skew angle.