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Tb3+ and Ce3+ Intercalated Laponite Powder: The Influence of Ce3+ Ions on Thermal Stability and Optical Properties of Tb3+ Intercalated Laponite

  • Lee, Han-Na;Kim, You-Hyuk
    • Bulletin of the Korean Chemical Society
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    • v.32 no.4
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    • pp.1273-1276
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    • 2011
  • Laponite samples intercalated with $Tb^{3+}$ or $Tb^{3+},Ce^{3+}$ ions were prepared by exchange of Na+ ions in interlayers with $Tb^{3+}$ or $Ce^{3+}$ ions. Strong green and weak blue emissions under vacuum ultraviolet (VUV) excitation (${\lambda}$ = 158 nm) were observed due to the $^5D_4{\rightarrow}^7F_J$ and $^5D_3{\rightarrow}^7F_J$ emission lines, respectively. $Tb^{3+}$ ions in an interlayer of laponite mainly existed in ion pairs or clusters, as evidenced by the concentration-dependent luminescence of the $Tb^{3+}$ ions on the relative intensities of the $^5D_3{\rightarrow}^7F_J$ and the $^5D_4{\rightarrow}^7F_J$ emission lines, due to the action of a cross-relaxation process. The addition of $Ce^{3+}$ ions increased the thermal stability of $Tb^{3+}$ intercalated laponite up to $650^{\circ}C$ and quenched the $^5D_3{\rightarrow}^7F_J$ emission lines, probably by promoting the formation of $Tb^{3+}$ ion pairs at relatively low $Tb^{3+}$ concentrations.

Magnetic Properties of $NdFe_{10.7}Ti_{1.3}N_x$ ($NdFe_{10.7}Ti_{1.3}N_x $의 자기특성)

  • 김희태;김윤배;김창석;김택기
    • Journal of the Korean Magnetics Society
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    • v.2 no.2
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    • pp.114-118
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    • 1992
  • 아크로를 이용하여 제작한 NdF $e_{12-x}$ $Ti_{x}$ (1 .leq. x .leq. 2) 합금의 상분석 결과 이들 합금은 ThM $n_{12}$ 구조의 경자성상(1-12상) 과 반강자성의 F $e_{2}$Ti 및 연자성의 .alpha. -Fe 등으로 구성되며, x=1.3 인 NdF $e_{10.7}$ $Ti_{1.3}$ 조성에서 단상에 가까운 ThM $n_{2}$ 구조가 얻어짐이 밝혀졌다. 한편, 합금중의 1-12 상은 50 .mu. m - 100 .mu. m 의 사각주 형태로 생성되며, FeTi은 1-12상의 결정립계에 고립된 입자의 형태로 존재한다. NdF $e_{10.7}$ $Ti_{1.3}$ 합금을 질화처리할 경우 단위포의 체적, 자화, 이방성자장 및 큐리온도가 증가하며, 이합금을 500 .deg. C 에서 15분간 질화처리한 NdF $e_{10.7}$ $Ti_{1.3}$ $N_{x}$ 의 비포화자화, 이방성자장 및 큐리온 도는 각각, .sigma. $_{s}$ =128 A $m^{2}$/kg $H_{A}$=6400 kA/m (80 kOe) 및 Tc=470 .deg. C로 질화처리 전에 비하여 크게 증가한다.크게 증가한다. 증가한다.

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Production of a Keratinolytic Protease by a Feather-Degrading Bacterium, Bacillus megaterium F7-1 (우모분해세균 Bacillus megaterium F7-1에 의한 Keratinolytic Protease의 생산)

  • 손홍주;박근태;김용균
    • Korean Journal of Microbiology
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    • v.40 no.1
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    • pp.43-48
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    • 2004
  • Bacillus megaterium F7-1 producing keratinolytic protease was isolated from decayed chicken feather. The optimal culture conditions for the production of keratinolytic protease by B. megaterium F7-1 were investigated. The composition of optimal medium for the keratinolytic protease was 0.2% glucose, 0.8% skim milk, 0.05% NaCl, 0.01 % $(K_2HPO_4$, 0.02%, $(KH_2PO_4$ and 0.01 % $MgCl_2$. Especially, skim milk was found to be the most effective compound in keratinolytic protease production. The optimal temperature and initial pH were 6.5 and $25^{\circ}C$, respectively. The keratinolytic protease production under optimal condition reached a maximum of 269 U/ml after 5 days of cultivation. B. megaterium F7-1 degraded 98% of the feather used in the optimized medium within 6 days.

Optical Characteristics of ZnS/CaF2/ZnS/Cu with Different Optical Thickness of CaF2 Layer (CaF2 두께 변화에 따른 ZnS/CaF2/ZnS/Cu 다층 박막의 광특성)

  • Kim, Jun-Sik;Jang, Gun-Eik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.7
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    • pp.584-588
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    • 2009
  • Layered ZnS/$CaF_2$/ZnS/Cu film was deposited on glass substrate by using evaporation method. ZnS and $CaF_2$ were chosen as high and low refractive materials. Cu was used as mid-reflective layer. Reflectance with different optical thickness of $CaF_2$ ranging from $0.25{\lambda}\;to\;0.5{\lambda}$ were systematically investigated by using spectrophotometer. In order to expect the experimental results, the simulation program, the Essential Macleod Program(EMP) was adopted and compared with the experimental data. Based on the results taken by spectrophotometer, the ZnS/$CaF_2$/ZnS/Cu multi-layered thin film show the maximum reflectance of 80% at 625nm $(0.25{\lambda}\;in\;CaF_2)$ and 42% at 660nm $(0.5{\lambda}\;in\;CaF_2)$ respectively. As compared with the experimental results and simulation data, it was confirmed the experimental data is well matched with the EMP data.

A Study on the Variation of the Body surface Area by the Arm movements to Somatotype -The Subject of the College Men- (체형별 상복동작에 따른 상체의 체표면 변화에 관한 연구 -남자대학생을 중심으로-)

  • 김진경
    • Journal of the Korean Home Economics Association
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    • v.26 no.2
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    • pp.1-13
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    • 1988
  • The purpose of this study was to classify somatotype of males, to show changes of the body skin surface by the somatotype. The size of sample was 156 males between age 20 and 24. Somatotype classified into Bending somatotype, Standard somatotype, Turning over somatotype. And according to the somatotype, changing of the upper part of the body by the arm movements analyzed through gypsum experiment. The result obtained from this study were as follows; 1. the variation of the upper part of the body form by changing the am movements, by the increasing of movements, shoulder-point ws moved to be inside or upside, the anterior armpit point & armpit point were moved to the upside. 2. As a result of investigating into the rate of the expansion and contraction of the basic lines and body surface area by the arm movements, the rate of expansion and contraction of the basic lines by the arm movements, the side sea length showed the maximum rate of extension in 135 degrees, the shoulder length showed the maximum rate of contraction in 135 degrees. The rate of expansion and contraction on the body surface area by the arm movements showed the phenomenon of contraction, of items F1, F6, B1, B9 showed the phenomenon of extension, of items F3, F4, F8, F9, B8, B9. 3. According to somatotypes, items which show the significant difference were, of items f3, f8, b3, b8, F2, F7, F8, B3, B7, in all movements.

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A Study on the Consumptive Use of Irrigated Water in Upland (II) (전작물 수분 소비량 조사 연구(II))

  • 김시원;최덕수
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.27 no.1
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    • pp.37-45
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    • 1985
  • To define the amount of consumptive use of upland crops, the moisture consumption characters were investigated with different soil moisture content by soil properties(loam, sandy loam, sand) at the experimental farm of Kon-Kuk University from April 20 to July 20 1984. The results obtained are summarized as follows; 1. Total moisture consumption under bare soil condition had an order of loam> sandy loam> sand and showed an order of pF 1.5> pF2. 1> pF 2.7 by re-irrigation point and the average during the experimental period (92days) was 435. 9mm and the daily average moisture consumption was 4. 7mm. 2. The moisture consumption characters of bare soil plot obtained showed that the amount of irrigation water per one time and the days of intermission increased and, on the contrary, the times of irrigation and the total amount of irrigation water decreased by the increment of re-irrigation point in the same soil 3. Total moisture consumption of spring cabbage under open cultivation showed 528.6 rim in maximum and had an order of loam> sandy loam> sand. In the aspect of rc-irrigation point, it had an order of pFl. 5> pF 2.1> pF 2.7. In case the planning basic year was taken into account, the amount of irrigation water needed for open cultivation was 456. 3 mm and its average daily moisture consumption was 6. 2mm. 4. Total moisture consumption of summer cucumber under open cultivation showed 635. 8mm in maximum and had an order of loam> sandy loam> sand. In the aspect of re-irrigation point, it had an order of pF 1.5> pF2. 1> pF2. 7 In case the planning basic year was taken into consideration, the amount of irrigation water was 516. 9mm and its aversge daily moisture consumption was 6. 5mm. 5. The result of cabbage cultivation showed its maximum yield in loam soil when the pF values were maintained from 1,5 to 2.1 and then the evapotranspiration ratio was 1, 76 and also when the amount of irrigation water were similar, it showed effective to reduce the days of intermtission. 6. The result of cucumber cultivation showed its maximum yield in sandy loam soil when the pF value maintained from 1.5 to 1.7 and when the irrigation point maintained at pF 2,7 in sandy soil, its yield was severely decreased.

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Skin Improvement Effect of Mask Pack with Snail Fermented Extract (달팽이 발효 추출물을 이용한 마스크 팩의 피부개선효과)

  • Zhoh, Choon-Koo;Lee, Min-Hee;Kim, In-Young;Shin, Ji-Young
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.1
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    • pp.30-40
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    • 2016
  • This study related to get skin improvement effect of sheet mask pack using 5% of $2^{nd}$ fermented snail extract. To the scientific study of the skin, it was used for this sheet mask of 100% cotton as cutting face shape. We reported the results of measurement of skin improvement effect with the placebo and Gene-SEM (general snail extract mask). First; moisturizing effect of 2F-SEM ($2^{nd}$ fermented snail extract mask) has been increased about 11% than the PM and Gene-SEM was improved about 4.7% more than the PM (placebo mask). Second; elasticity of the mask pack containing $2^{nd}$ fermented snail extract was 13.8% better than PM and Gene-SEM was improved about 6.7 % more than PM. Third; Skin roughness of 2F-SEM has improved 6.80% than PM and Gene-SEM was improved about 2.3% more than PM. Fourth; melanin reductive effect of 2F-SEM was improved about15.0% more than PM and Gene-SEM was improved about 8.7% more than PM. Fifth; fine wrinkle decline effect of 2F-SEM was about 8.0% better than PM and Gene-SEM was improved with 5.1% more than PM. Sixth; sensorial evaluation of 2F-SEM using $2^{nd}$ fermented snail extract was significantly showed difference merits regarding softness, moisture, fine-wrinkle improvement.

A study on the oscillatory feed cutting (振動移送切削 에 관한 硏究)

  • 박천경
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.7 no.2
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    • pp.204-211
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    • 1983
  • To investigate the effects of oscillatory feed cutting on the chip breaking and surface roughness and circularity, A prototype unit developed for the experiment is used. The results obtained are as follows. (1) It is obtained the region of chip breaking as Ftmin $f_{+min}$0.03mm ( = 0.3f). (2) The surface roughness becomes worse with increasing the value of A/f, but the type of variation with respect to n/N differs from the case of A/f>1, f<1. (3) The circularity of workpiece is increasing from the fundamental mode of n/N=i to the maximum value of n/N=i+0.5, and becomes worse with increasing the value of A/f. (4) From the viewpoint of above details and tool mechanics, the condition of A/f=1.0 and n/N=i.+-. .delta. (0.3<.delta.<0.4) is recommended.

Safety Enhanced Signal Phase Sequence Design of a Rotary with Five Leg Intersection (5지 신호교차로에서의 안전을 고려한 신호현시 설계)

  • 박재완;김진태;장명순
    • Journal of Korean Society of Transportation
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    • v.20 no.7
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    • pp.23-29
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    • 2002
  • Five and more leg intersections have been still in operation in many urban areas. The number of conflicts in five leg intersection is more than four leg intersection. The signal timing design in the five leg intersection should be performed not only to reduce delay but also to increase safety. This paper suggests safety enhanced signal phase sequence design of a rotary with five leg intersection such as phase sequence minimizing the number of conflict points at the rotary with five leg intersections and the phase-length-design procedure by utilizing the Traffic Network Study Tool(TRANSYT). Field data was collected from Gonguptap five leg intersection in Ulsan and TRANSYT-7F was applied for signal timing design model. Optimal signal phase length and sequence of TRANSYT-7F is rearranged based on the Principal of "two moving traffic flows per phase". In conclusion, proposed signal phase design increased delay by 6.2% compared with the optimal signal phase of TRANSYT-7F. However, it could decrease the number of conflict in the five leg intersection by 61.5%.

Calcium Sensitization Induced by Sodium Fluoride in Permeabilized Rat Mesenteric Arteries

  • Yang, En-Yue;Cho, Joon-Yong;Sohn, Uy-Dong;Kim, In-Kyeom
    • The Korean Journal of Physiology and Pharmacology
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    • v.14 no.1
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    • pp.51-57
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    • 2010
  • It was hypothesized that NaF induces calcium sensitization in $Ca^{2+}$-controlled solution in permeabilized rat mesenteric arteries. Rat mesenteric arteries were permeabilized with $\beta$-escin and subjected to tension measurement. NaF potentiated the concentration-response curves to $Ca^{2+}$ (decreased $EC_{50}$ and increased $E_{max}$). Cumulative addition of NaF (4.0, 8.0 and 16 mM) also increased vascular tension in $Ca^{2+}$-controlled solution at pCa 7.0 or pCa 6.5, but not at pCa 8.0. NaF-induced vasocontraction and $GTP{\gamma}S$-induced vasocontraction were not additive. NaF-induced vasocontraction at pCa 7.0 was inhibited by pretreatment with Rho kinase inhibitors H1152 or Y27632 but not with a MLCK inhibitor ML-7 or a PKC inhibitor Ro31-8220. NaF induces calcium sensitization in a $Ca^{2+}$ dependent manner in $\beta$-escin-permeabilized rat mesenteric arteries. These results suggest that NaF is an activator of the Rho kinase signaling pathway during vascular contraction.