• Title/Summary/Keyword: F0 modification

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Studies on Chemical Strutures and Adhesion Performance of pMDI Adhesives Modified by Ozonized Soybean Oil with Different Mixing Ratios (오존산화 콩기름의 구조분석 및 이를 이용한 변성 pMDI 접착제의 중량비에 따른 접착력 변화)

  • You, Young Sam;Lee, Hyun Jong;Lee, Taek Jun;Park, Heon
    • Journal of the Korean Wood Science and Technology
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    • v.37 no.1
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    • pp.56-64
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    • 2009
  • The purpose of this study was to investigate and develop an eco-friendly wood adhesive based on vegetable oil (especially soybean oil), the renewable and sustainable natural resources, using ozonification technology for the chemical structure modification. The soybean oil (SBO) was reacted with $O_3$ at the rate of 7.13 g/h for different times, 15 minutes, 30 minutes, 60 minutes, and 120 minutes. The investigation of the modified chemical structure of the ozonized SBOs were conducted using FT-IR, $^1H$-NMR, MALDI-TOF MS, and GC/MS. As ozonification time increased, the peak of the unsaturated double bonds was disappeared and aldehyde or carboxyl peak appeared because ozonification broke the oil into small molecules. The plywoods were made at $110^{\circ}C$ with 30 seconds/mm hot-press time using the different ozonized SBO/pMDI adhesives and were tested for the dry, wet, cyclic boil test according to the Korea Industrial Standard F3101 Ordinary plywood. The bond strengths gradually increased with increasing ozonification time. The weight ratio 1:1 (ozonized SBO/pMDI), all strengths in 15, 30 and 60 minuets, exceeded constantly the dry, wet, cyclic boiling standard requirement. The range of ozonification time and weight ratio can fulfil1 the requirment of the wet test standard were 30~60 minutes and more than 0.5 pMDI. From the comprehensive view on the results of above experiments, it could be confirmed through experiments that ozonized SBO/pMDI has characteristics of effective reactivity and wet stability showed as an excellent candidate of wood adhesive applications.

Detection of Anticancer Activity from the Root of Angelica gigas In Vitro

  • Ahn, Kyung-Seop;Sim, Woong-Seop;Kim, Ik-Hwan
    • Journal of Microbiology and Biotechnology
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    • v.5 no.2
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    • pp.105-109
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    • 1995
  • Anticancer activity of a fraction of the ethanol extract from the root of Korean angelica (Angelica gigas Nakai) was recognized in human cancer cell lines HeLa $S_3$, K-562, and Hep $G_2$. The extract blocked the phorbol ester-inducing megakaryocytic differentiation of K-562 cells, which indicated the modification of protein kinase C (PKC) activity. In vitro assay showed the activation of PKC by the extract. An effective fraction of the Angelica gigas extract, of which $R_f$ value was 0.64 in a thin layer chromatography, was a different component from those of European angelicas. The $ED_50$ value of the fraction was 8, 9, and $16\;\mu\textrm{m}/ml$ against HeLa $S_3\;Hep\;G_2$, and K-562 cells, respectively, while the fraction showed higher $ED_50$ values against normal cell lines.

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Effect of Control Method and Plunger Profile of Variable Valve on Flow Control of a Liquid Rocket Engine (액체로켓엔진의 유량조절에 가변밸브의 조절기법과 플런저 형상이 미치는 영향)

  • Lee, Joong-Youp;Huh, Hwan-Il
    • Journal of the Korean Society of Propulsion Engineers
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    • v.15 no.5
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    • pp.35-47
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    • 2011
  • Dynamic characteristics of a flow control valve, which plays an important role in thrust and O/F control of liquid rocket engines, have been analyzed by the AMESim simulator modeling. The speed control method was proposed for the control of the flow valve equipped with a BLDC motor. The experimental results demonstrated the feasibility of systematical application as well as the performance of the speed control method. Moreover, the speed control method for BLDC motor is much simpler than the P control method in complex flow systems. With the speed control method, the control flow characteristics were evaluated according to plunger shapes. Consequently, same plunger shape proved to be more efficient in the mixture ratio control operated by two flow valves. It was also shown that the appropriate modification of plunger shapes could reduce the mixture ratio perturbation by 0.5%.

Bond Strength of Plywood Manufactured with Adhesive of pMDI-Ozonized Waste Cooking Oil (오존산화 폐식용유와 pMDI접착제의 합판 접착력)

  • Kang, Chan-Young;Lee, Eung-Su;Seo, Jun-Won;Park, Heon
    • Journal of the Korean Wood Science and Technology
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    • v.39 no.6
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    • pp.498-504
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    • 2011
  • The purpose of this study was to investigate and develop an eco-frendly wood adhesive based on vegetable oil (especially soybean oil), the renewable and sustainable natural resources, using ozonification technology for the chemical structure modification. The waste soybean oil (WSBO) was reacted with $O_3$ at the rate of $450m{\ell}$(acetone) : $50m{\ell}$ (WSBO) for different times, 1, 2, 3 hrs. The investigation of the modified chemical strecture of the ozonied WSBOs were conducted using FT-IR. As ozonification time increased, the peak of the unsaturated double bonds was disappeared especially ozonized-3hrs and aldehyde or carboxyl peak appeared because ozonification broke the oil into small molecules. The plywood were made at $150^{\circ}C$ with 4 minutes hot-press time using the different ozonized 3 hrs WSBO/pMDI adhesives and were tested for the dry, wet, cyclic boil test according to the Korea Industrial Standard F3101 Ordinary plywood. The bond strengths gradually increased until 1 : 0.5~1 : 3, but it decreased 1 : 4, as the contents of pMDI increased. The results of the dry, wet and cyclic bond strengths the equivalent ratio was formed approximately between 1 : 2~1 : 3. And the 1 : 1~1 : 4 strengths met constantly the standard requirement of 7.0kgf/$cm^2$ (KS F3101). From the comprehensive view on the results of above experiment, it could be confirmed that ozonized WSBO/pMDI has characteristics of effective reactivity and wet stability showed as an excellent candidate of wood adhesive applications.

Coloration behaviors of phthalocyanine reactive dye on nylon substrates: experiments, empirical modeling and statistical analysis

  • Kim, Byung-Soon;Ravikumar, K.;Yoon, Seok-Han;Son, Young-A
    • Textile Coloration and Finishing
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    • v.19 no.2
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    • pp.14-23
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    • 2007
  • This research article explores the use of phthalocyanine reactive dye on nylon substrate. The effect of factors such as pH, temperature, liquor ratio and alkali addition on level of dye exhaustion, fixation and total fixation efficiency. Low pH, high temperature and low liquor ratio were found to be suitable conditions for maximum % exhaustion values. The effect of sulphatoethylsulphone(SES) and vinylsulphone(VS) form of the dyes on level of dye fixation was also discussed. The optimized exhaustion (%E), fixation(%F) and total fixation efficiency were determined. Modification of the dyeing process with alkali addition displayed that dye fixation(%) increased by alkali addition. Vinylsulphone(VS) moiety of the dye was found to be superior to. maximum fixation (%F). Appropriate predictable empirical models, relatively a new approach in dyeing processes, were developed incorporating interactions effects of temperature, pH and liquor ratio for predicting % exhaustion, fixation and total fixation efficiency. The significance of the mathematical model developed was ascertained using microsoft excel regression(solver) analysis module. High correlation coefficient was obtained (R2=0.9895 for % exhaustion, R2=0.9932 for fixation, R2=0.9965 for total fixation efficiency) for the model which shows prominent prediction capacity of the model for my conditions. The predictable polynomial equations developed from tile experimental results were thoroughly analyzed by ANOVA (Analysis of Variance) statistical concepts.

Gender Differences in Predictors of Health Behaviors Modification among Patients with Cardiovascular Disease (성별에 따른 심혈관질환자의 건강행위에 미치는 요인)

  • Xu, Lijuan;Ryu, Seungmi;Goong, Hwasoo
    • The Journal of the Korea Contents Association
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    • v.15 no.3
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    • pp.280-289
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    • 2015
  • Purpose: The purpose of the study was to investigate the difference of health behavior modification between male and female patients with cardiovascular disease; and to compare the predictors of health behavior between the male and female subjects. Methods: A comparative study design was used in the study. A total of 228 patients(male 114, female 114) with cardiovascular disease were recruited from outpatients clinics in 2 university hospitals in Korea. Data were analyzed using t-test, $X^2$, ANOVA, ANCOVA, Pearson correlation, and multiple regression with SPSS 20.0. Results: There was significant difference of health behavior between male and female patients with cardiovascular disease (F=9.45, p=0.002). The significant predictors of health behavior among male subjects were self-efficacy, perceived barriers, perceived susceptibility, medical support and autonomous motivation, accounting for 45%; the significant predictors of health behavior among female subjects were self-efficacy, medical support and autonomous motivation, accounting for 51%. Conclusions: It is suggested to take different health promotions strategies to maintain the performance of health behaviors among male and female patients with cardiovascular diseases.

Effects of Obesity Stress and Health Belief on Weight Control Behavior among Nursing Students (간호대학생의 비만스트레스와 건강신념이 체중조절행위에 미치는 영향)

  • Ham, Mi-Young;Lim, So-Hee
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.11
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    • pp.459-468
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    • 2017
  • This study investigated the factors influencing how obesity stress and health belief impact weight control behavior among nursing students. Data were collected from nursing students in U city between September 1 and October 10, 2016 and analyzed using descriptive statistics, t-test, ANOVA, Pearson's correlation coefficient, and hierarchical multiple regression. Among the general characteristics of the subjects, gender (t=2.30, p=0.044) and health status (F=8.03, p<0.001) significantly influenced weight control behavior. There were negative correlations between diet therapy of weight control behavior (r=-0.26, p<0.001), exercise therapy (r=-0.25, p<0.001), behavior modification therapy (r=-0.29, p<0.001), and perceived barriers in health belief. In addition, acquiring special knowledge for weight control behavior showed positive correlations in obesity stress (r=0.42, p<0.001), perceived susceptibility (r=0.25, p<0.001) and perceived benefits (r=0.19, p<0.001). Furthermore, the significant factors influencing weight control behavior were perceived barriers (${\beta}=-0.30$, p<0.001) and obesity stress (${\beta}=0.20$, p<0.05) in health belief, and these factors explained 17.2% of the variance. Based on the study results, it is necessary to develop and apply effective educational programs that can influence weight control behavior through gender, health status, obesity stress and health beliefs, which determine weight control behavior of nursing students.

Modification of polyethersulfone hollow fiber membrane with different polymeric additives

  • Arahman, Nasrul;Mulyati, Sri;Lubis, Mirna Rahmah;Razi, Fachrul;Takagi, Ryosuke;Matsuyama, Hideto
    • Membrane and Water Treatment
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    • v.7 no.4
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    • pp.355-365
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    • 2016
  • The improvement of fouling resistance of porous polymeric membrane is one of the most important targets in membrane preparation for water purification in many process like wastewater treatment. Membranes can be modified by various techniques, including the treatment of polymer material, blending of hydrophilic polymer into polymer solution, and post treatment of fabricated membrane. This research proposed the modifications of morphology and surface property of hydrophobic membrane by blending polyethersulfone (PES) with three polymeric additives, polyvinylpyrrolidone (PVP), Pluronic F127 (Plu), and Tetronic 1307 (Tet). PES hollow fiber membranes were fabricated via dry-wet spinning process by using a spinneret with inner and outer diameter of 0.7 and 1.0 mm, respectively. The morphology changes of PES blend membrane by those additives, as well as the change of performance in ultrafiltration module were comparatively observed. The surface structure of membranes was characterized by atomic force microscopy and Fourier transform infra red spectroscopy. The cross section morphology of PES blend hollow fiber membranes was investigated by scanning electron microscopy. The results showed that all polymeric additives blended in this system affected to improve the performances of PES membrane. The ultra-filtration experiment confirmed that PES-PVP membrane showed the best performance among the three membranes on the basis of filtration stability.

Preparation of Higher Reinforced PVDF Hollow Fiber Microfiltration Membrane (고강도 PVDF 중공사 정밀여과막 제조 특성)

  • Choi, R.S.;Park, H.H.
    • Membrane Journal
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    • v.20 no.4
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    • pp.320-325
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    • 2010
  • This paper was carried out to study the preparation condition and the permeation flux of reinforced poly(vinylidene fluoride) (PVDF) hollow fiber microfiltration (MF) membrane with the solvent, additive, second miscible polymer, and preparation condition used poly(vinylidene fluoride) (PVDF) such as a material with the excellent chemical stability and the milder preparation condition. The performance of the reinforced MF membrane prepared obtained the average $0.3{\mu}m$ pore size, $42kg_f/cm^2$ tensile strength, and the high water flux of 600 LMH. The change of membrane performance with various additives was considerably affected on the water flux and rejection. For hydrophilic modification of hydrophobic PVDF MF membrane, the MF membrane might be prepared with a prefer water flux and rejection by addition of hydrophilic poly(methyl methacrylate) (PMMA).

Development of A Fractionated Stereotactic Radiotherapy System (분할 정위방사선 치료 시스템 개발 연구)

  • 이동한;지영훈;이동훈;조철구;김미숙;유형준;류성렬
    • Progress in Medical Physics
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    • v.13 no.1
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    • pp.9-14
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    • 2002
  • We invented the newly developed Fractionated Stereotactic Radiotherapy(F.S.R.T) system using combined techniques of couch mounting and pedestal mounting system. Head fixation frame consists of a milled alluminium alloy(duralumin) and is placed to the couch. This frame immobilized patient head using the dental bite, 3.2 mm frontal and occipital thermoplastic mask. To evaluate the coordinate of target isocenter, Brown-Revert-Walls C.T localizer can be attached to this frame. And also, we developed the frame mounting system by developing the modification of pedestal mounting system. This system is fixed to couch floor and can be used to evaluate the isocenteric accuracy of gantry, couch and collimator in Q.A procedure. In order to measure the relocation accuracy, the acrylic phantom and the accurate pointers have been made. The repositioning of the targets in the phantom were estimated by comparing C.T coordinates and E.C.L portal films taken with anterior-posterior and right-left direction. From the results of experiments, the average distance errors between the target isocenter and its mean position were 0.71$\pm$0.19 for lateral, 0.45$\pm$0.15 for inferior-superior, 0.63$\pm$0.18 for anterior-posterior. And the maximum distance error was less than 1.3 mm. The new head fixation frame and frame mounting system were non-invasive, accurately relocatable, easy to use, very light and well tolerable by the results of phantom tests. The major advantage of using this frame mounting system is complete access to any point in the Patients cranium especially posterior direction

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