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Calculations of radical and ion densities in a $CF_4$ plasma using global model (글로벌 모델에 의한 $CF_4$플라즈마에서의 라디칼 및 이온 밀도 계산)

  • 이호준;태흥식;이정희;이용현;황기웅
    • Journal of the Korean Vacuum Society
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    • v.7 no.4
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    • pp.374-380
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    • 1998
  • Radical and ion densities in a $CF_4$plasma have been calculated as a function of input power density, gas pressure and feed gas flow rate using simple 0 dimensional global model. Fluorine atom is found to be the most abundant neutral particle. Highly fragmented species such as CF and $CF^+$ become dominant neutral and ionic radical at the high power condition. As the pressure increase, ion density increases but ionization rate decreases due to the decrease in electron temperature. The fractional dissociation of $CF_4$feed gas decreases with pressure after increasing at the low pressure range. Electron density and temperature are almost independent of flow rate within calculation conditions studied. The fractional dissociation of $CF_4$monotonically decreases with flow rate, which results in increase in $CF_3$and decrease in CF density. The calculation results show that the $SiO_2$etch selectivity improvement correlates to the increase in the relative density of fluorocarbon ion and neutral radicals which has high C/F ratio.

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Photoluminescence Properties of CaAl2O4:RE3+(RE = Tb, Dy) Phosphors (CaAl2O4:RE3+(RE = Tb, Dy) 형광체의 발광 특성)

  • Cho, Shinho
    • Korean Journal of Materials Research
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    • v.26 no.3
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    • pp.143-148
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    • 2016
  • $CaAl_2O_4:RE^{3+}$(RE = Tb or Dy) phosphor powders were synthesized with different contents of activator ions $Tb^{3+}$ and $Dy^{3+}$ by using the solid-state reaction method. The effects of the content of activator ions on the crystal structure, morphology, and emission and excitation properties of the resulting phosphor particles were investigated. XRD patterns showed that all the synthesized phosphors had a monoclinic system with a main (220) diffraction peak, irrespective of the content and type of $Tb^{3+}$ and $Dy^{3+}$ ions. For the $Tb^{3+}$-doped $CaAl_2O_4$ phosphor powders, the excitation spectra consisted of one broad band centered at 271 nm in the range of 220-320 nm and several weak peaks; the main emission band showed a strong green band at 552 nm that originated from the $^5D_4{\rightarrow}^7F_5$ transition of $Tb^{3+}$ ions. For the $Dy^{3+}$-doped $CaAl_2O_4$ phosphor, the emission spectra under ultraviolet excitation at 298 nm exhibited one strong yellow band centered at 581 nm and two weak bands at 488 and 672 nm. Concentration-dependent quenching was observed at 0.05 mol of $Tb^{3+}$ and $Dy^{3+}$ contents in the $CaAl_2O_4$ host lattice.

Relationship Between Dietary Culture of Housewives and Their Attitude of Traditional Fermented Foods Consumption - in Puchon City - (부천지역 주부의 식문화와 전통발효식품 소비태도와의 관계)

  • 고경희
    • Journal of the Korean Home Economics Association
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    • v.37 no.11
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    • pp.139-156
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    • 1999
  • Food choice is influenced by many factors including physical, social, psychological and food technological developments. This research is based on the survey on Puchon housewives dietary culture according to season and special occasions and the current consumption pattern of traditional fermented foods. The objective is to find out the current consumption and to use this data as the principal element needed to explore changes in consumption patterns and to uphold and develop the consumption of traditional fermented food. Questionnaires were collected 282 housewives in Puchon city. Data were analysed with SAS software package for t-test, F-test and Duncan’s multiple range test. Results of relationship between dietary culture of Puchon housewives and consumption patterns of traditional fermented food items; 1. If we look at seasonal foods, Puchon housewives responded that they normally prepare traditional foods for such special occasions as Chusok(89%), New Year(84%) and January full moon Day(77%). For family celebrations, they cook on their in-laws birthdays(91%), their husbands birthday(84%), childrens birthdays(73%) and their own birthday(32%). They also responded that they eat out on their own birthday(41%), on Christmas Day(19%), on childrens birthdays(17%) and on their husbands birthday(11%). 2. If we look at the age of housewives and their dietary culture, more young housewives tend to eat out on their own, their husbands and their childrens birthdays. As for their educational background, less educated housewives tend to prepare flood at home on New Years Day, while more educated housewives would eat out on their own birthdays. As for the type of family, mere housewives in nucleus families eat out on Christmas Days compared to those in extended families. Also, those in extended families tend to make food at home rather than eating out on their own birthdays. In case of the husbands birthday, there was some difference according to family income (p<0.03).

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A Study on the Soft Ground Distubance Characteristics by Large Block Sample (대형자연시료를 이용한 지반교란 특성에 관한 연구)

  • Yu, Seong-Jin
    • Journal of the Korea Construction Safety Engineering Association
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    • s.43
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    • pp.98-106
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    • 2007
  • In this paper, a ground disturbance effects, strength and consolidation characteristics of soft clay through using the large block samples($\theta$:300mm, H:400mm) and the piston samples, f hose which had been gathered in west coast and south coast. Especially, we have assessed the coefficient of horizontal consolidation when penetrating the mandrel considering the variance of ratio between diameter and height in drainage sample through the experiment of the oedometer test and Rowecell and also investigated the disturbance area in smear zone by interior model test, the strength originated by disturbance, the variance in characteristics of the consolidation. As the result, the large block sample has been investigated that ihe uniaxial compression test(qu) was shown bigger than the piston sample by about 11-19%. Under the size of anistropy in consolidation, the coefficient ratio of consolidation(ch/cv,) perfomed by standard consolidation test(SC) was shown bigger than that of (Cro/Cv) by the Rowecell test. And the coefficient ratio of consolidation(Cro/Cv) perfomed by piston sample was evaluated bigger than that Of (Cro/Cv) by the large block sample by about 0.9-1.9. The coefficient ratio of consolidation along with the variance in ratio of between diameter and height when penetrating the mandrel was shown big difference according to the characteristics of soil of the specimen. In addition, ds/dw of smear zone at the marine clay in west-south was ranged from 1.6 to 4.2. The width of variance in rat io[(qud)/(quud)] of strength n the area between disturbance and undisturbance was shown big as about 72-91% but the principle was judged with the similiar range when the decrease of the strength in smear zone become the zone under 25% in unditurbance area.

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Synthesis and Characterization of Spherical SiO2@Y2O3 : Eu Core-Shell Composite Phosphors (구형 SiO2@Y2O3: Eu 코어-쉘 복합체 형광체 합성 및 특성)

  • Song, Woo-Seuk;Yang, Hee-Sun
    • Journal of the Korean Ceramic Society
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    • v.48 no.5
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    • pp.447-453
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    • 2011
  • The monodisperse spherical $SiO_2$ particles were overcoated with $Y_2O_3:Eu^{3+}$ phosphor layers via a Pechini sol-gel process and the resulting $SiO_2@Y_2O_3:Eu^{3+}$ core-shell phosphors were subsequently annealed at $800^{\circ}C$ at an ambient atmosphere. The crystallographic structure, morphology, and luminescent property of core-shell structured $SiO_2@Y_2O_3:Eu^{3+}$ phosphors were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and photoluminescence (PL). The spherical, nonagglomerated $SiO_2$ particles prepared by a Stober method exhibited a relatively narrow size distribution in the range of 260-300 nm. The thickness of phosphor shell layer in the core-shell particles can be facilely controlled by varying the coating number of $Y_2O_3:Eu^{3+}$ phosphors. The core-shell structured $SiO_2@Y_2O_3:Eu^{3+}$ phosphors showed a strong red emission, which was dominated by the $^5D_0-^7F_2$ transition (610 nm) of $Eu^{3+}$ ion under the ultraviolet excitation (263 nm). The PL emission properties of $SiO_2@Y_2O_3:Eu^{3+}$ phosphors were also compared with pure $Y_2O_3:Eu^{3+}$ nanophosphors.

Boron doping with fiber laser and lamp furnace heat treatment for p-a-Si:H layer for n-type solar cells

  • Kim, S.C.;Yoon, K.C.;Yi, J.S.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.322-322
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    • 2010
  • For boron doping on n-type silicon wafer, around $1,000^{\circ}C$ doping temperature is required, because of the relatively low solubility of boron in a crystalline silicon comparing to the phosphorus case. Boron doping by fiber laser annealing and lamp furnace heat treatment were carried out for the uniformly deposited p-a-Si:H layer. Since the uniformly deposited p-a-Si:H layer by cluster is highly needed to be doped with high temperature heat treatment. Amorphous silicon layer absorption range for fiber laser did not match well to be directly annealed. To improve the annealing effect, we introduce additional lamp furnace heat treatment. For p-a-Si:H layer with the ratio of $SiH_4:B_2H_6:H_2$=30:30:120, at $200^{\circ}C$, 50 W power, 0.2 Torr for 30 min. $20\;mm\;{\times}\;20\;mm$ size fiber laser cut wafers were activated by Q-switched fiber laser (1,064 nm) with different sets of power levels and periods, and for the lamp furnace annealing, $980^{\circ}C$ for 30 min heat treatment were implemented. To make the sheet resistance expectable and uniform as important processes for the $p^+$ layer on a polished n-type silicon wafer of (100) plane, the Q-switched fiber laser used. In consequence of comparing the results of lifetime measurement and sheet resistance relation, the fiber laser treatment showed the trade-offs between the lifetime and the sheet resistance as $100\;{\omega}/sq.$ and $11.8\;{\mu}s$ vs. $17\;{\omega}/sq.$ and $8.2\;{\mu}s$. Diode level device was made to confirm the electrical properties of these experimental results by measuring C-V(-F), I-V(-T) characteristics. Uniform and expectable boron heavy doped layers by fiber laser and lamp furnace are not only basic and essential conditions for the n-type crystalline silicon solar cell fabrication processes, but also the controllable doping concentration and depth can be established according to the deposition conditions of layers.

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A study of asbestos risk at some naturally occurring asbestos areas, Korea (우리나라 일부 자연발생석면 발생가능지역의 석면 위해도에 관한 연구)

  • Jung, Joon Sig;Shim, In Keun;Jung, Hyen Sung;Lee, Kyu Mok;Kim, Seong Mi;Kwon, Myung Hee;Chung, Hyen Mi
    • Journal of odor and indoor environment
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    • v.17 no.4
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    • pp.330-336
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    • 2018
  • The objective of this study was to determine whether crops and fruits absorb the naturally occurring asbestos (NOA). The concentration of asbestos in various crops and fruits grown in NOA areas was analyzed and background levels of asbestos in ambient air and soil samples were assessed. Actinolite/Tremolite asbestos were detected in all soil samples. Among 21 ambient air samples, 2 samples were recorded to contain 0.0005 f/cc (fiber per cubic centimeter) but no asbestos was detected in the other samples using transmission electron microscopy (TEM). However, no evidence suggesting that the crops and fruits could be contaminated by NOA was found in this study. The excess lifetime cancer risks (ELCRs) of ABS scenarios (agricultural activities) used in this study were calculated by using the Arithmetic (AM) and Geometric mean (GM) of ELCRs. The AM and GM of ELCRs estimated from digging soil and weeding activities did not exceed $1{\times}10^{-4}$, which was defined as the general acceptable risk range for exposure. The results of this study would be informative to NOA managers and related policy makers to make plans to prevent unexpected exposure to asbestos to residents living in an NOA area.

Genetic diversity and population genetic structure of Cambodian indigenous chickens

  • Ren, Theary;Nunome, Mitsuo;Suzuki, Takayuki;Matsuda, Yoichi
    • Animal Bioscience
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    • v.35 no.6
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    • pp.826-837
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    • 2022
  • Objective: Cambodia is located within the distribution range of the red junglefowl, the common ancestor of domestic chickens. Although a variety of indigenous chickens have been reared in Cambodia since ancient times, their genetic characteristics have yet to be sufficiently defined. Here, we conducted a large-scale population genetic study to investigate the genetic diversity and population genetic structure of Cambodian indigenous chickens and their phylogenetic relationships with other chicken breeds and native chickens worldwide. Methods: A Bayesian phylogenetic tree was constructed based on 625 mitochondrial DNA D-loop sequences, and Bayesian clustering analysis was performed for 666 individuals with 23 microsatellite markers, using samples collected from 28 indigenous chicken populations in 24 provinces and three commercial chicken breeds. Results: A total of 92 haplotypes of mitochondrial D-loop sequences belonging to haplogroups A to F and J were detected in Cambodian chickens; in the indigenous chickens, haplogroup D (44.4%) was the most common, and haplogroups A (21.0%) and B (13.2%) were also dominant. However, haplogroup J, which is rare in domestic chickens but abundant in Thai red junglefowl, was found at a high frequency (14.5%), whereas the frequency of haplogroup E was considerably lower (4.6%). Population genetic structure analysis based on microsatellite markers revealed the presence of three major genetic clusters in Cambodian indigenous chickens. Their genetic diversity was relatively high, which was similar to findings reported for indigenous chickens from other Southeast Asian countries. Conclusion: Cambodian indigenous chickens are characterized by mitochondrial D-loop haplotypes that are common to indigenous chickens throughout Southeast Asia, and may retain many of the haplotypes that originated from wild ancestral populations. These chickens exhibit high population genetic diversity, and the geographical distribution of three major clusters may be attributed to inter-regional trade and poultry transportation routes within Cambodia or international movement between Cambodia and other countries.

Water Sorption/Desorption Characteristics of Eutectic LiCl-KCl Salt-Occluded Zeolites

  • Harward, Allison;Gardner, Levi;Oldham, Claire M. Decker;Carlson, Krista;Yoo, Tae-Sic;Fredrickson, Guy;Patterson, Michael;Simpson, Michael F.
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.20 no.3
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    • pp.259-268
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    • 2022
  • Molten salt consisting primarily of eutectic LiCl-KCl is currently being used in electrorefiners in the Fuel Conditioning Facility at Idaho National Laboratory. Options are currently being evaluated for storing this salt outside of the argon atmosphere hot cell. The hygroscopic nature of eutectic LiCl-KCl makes is susceptible to deliquescence in air followed by extreme corrosion of metallic cannisters. In this study, the effect of occluding the salt into a zeolite on water sorption/desorption was tested. Two zeolites were investigated: Na-Y and zeolite 4A. Na-Y was ineffective at occluding a high percentage of the salt at either 10 or 20wt% loading. Zeolite-4A was effective at occluding the salt with high efficiency at both loading levels. Weight gain in salt occluded zeolite-4A (SOZ) from water sorption at 20% relative humidity and 40℃ was 17wt% for 10% SOZ and 10wt% for 20% SOZ. In both cases, neither deliquescence nor corrosion occurred over a period of 31 days. After hydration, most of the water could be driven off by heating the hydrated salt occluded zeolite to 530℃. However, some HCl forms during dehydration due to salt hydrolysis. Over a wide range of temperatures (320-700℃) and ramp rates (5, 10, and 20℃ min-1), HCl formation was no more than 0.6% of the Cl- in the original salt.

Performance Evaluation of ResNet-based Pneumonia Detection Model with the Small Number of Layers Using Chest X-ray Images (흉부 X선 영상을 이용한 작은 층수 ResNet 기반 폐렴 진단 모델의 성능 평가)

  • Youngeun Choi;Seungwan Lee
    • Journal of radiological science and technology
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    • v.46 no.4
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    • pp.277-285
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    • 2023
  • In this study, pneumonia identification networks with the small number of layers were constructed by using chest X-ray images. The networks had similar trainable-parameters, and the performance of the trained models was quantitatively evaluated with the modification of the network architectures. A total of 6 networks were constructed: convolutional neural network (CNN), VGGNet, GoogleNet, residual network with identity blocks, ResNet with bottleneck blocks and ResNet with identity and bottleneck blocks. Trainable parameters for the 6 networks were set in a range of 273,921-294,817 by adjusting the output channels of convolution layers. The network training was implemented with binary cross entropy (BCE) loss function, sigmoid activation function, adaptive moment estimation (Adam) optimizer and 100 epochs. The performance of the trained models was evaluated in terms of training time, accuracy, precision, recall, specificity and F1-score. The results showed that the trained models with the small number of layers precisely detect pneumonia from chest X-ray images. In particular, the overall quantitative performance of the trained models based on the ResNets was above 0.9, and the performance levels were similar or superior to those based on the CNN, VGGNet and GoogleNet. Also, the residual blocks affected the performance of the trained models based on the ResNets. Therefore, in this study, we demonstrated that the object detection networks with the small number of layers are suitable for detecting pneumonia using chest X-ray images. And, the trained models based on the ResNets can be optimized by applying appropriate residual-blocks.