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Effect of Impurity Addition on the Microwave Dielectric Properties of $(Ba_{0.93}Sr_{0.07}O)-0.5Sm_2O_3-4.5TiO_2$ Ceramics ($(Ba_{0.93}Sr_{0.07}O)-0.5Sm_2O_3-4.5TiO_2$계 세라믹스의 불순물 첨가에 따른 마이크로파 유전특성)

  • Kim, Tae-Joong;Jang, Jae-Hoon;Lee, Hee-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.1148-1151
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    • 2002
  • Dielectric ceramics with nominal composition of $(Ba_{0.93}Sr_{0.07}O)-0.5Sm_2O_3-4.5TiO_2$ was prepared using the conventional mixed oxide process-derived powder. Effect of $SiO_2$, $MnO_2$ and $Al_2O_3$ impurity addition on the microwave properties was examined in some detail. Measured relative permittivity $(\varepsilon_r)$ values were in the range of 53 to 59 and showed little dependence on impurity addition. In contrast, quality factor $(Q{\cdot}f)$ and temperature coefficient of resonant frequency $(\tau_f)$ values were greatly influenced by the type and the amount of impurities. It was found that 0.1~0.2wt% addition of $Al_2O_3$ was most effective for improving the properties, where ${\varepsilon}_r$, $Q{\cdot}f$ and $\tau_f$ values were 57.7, 10000, and +7ppm/$^{\circ}C$, respectively.

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The Studies on Characteristics of Home Range Size and Habitat Use of the Asiatic Black Bear Released in Jirisan (지리산에 방사한 반달가슴곰의 행동권 크기 및 서식지 이용 특성 연구)

  • Yang, Doo-Ha;Kim, Bo-Hyun;Jung, Dae-Ho;Jeong, Hyuk-Dong;Jeong, Woo-Jin;Lee, Bae-Geun
    • Korean Journal of Environment and Ecology
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    • v.22 no.4
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    • pp.427-434
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    • 2008
  • The studies of seven individuals of Asiatic black bears were carried out with radio telemetry from October 2004 to December 2006 in Jirisan National Park. They were attached radio-transmitter and calculated by the 95%MCP and fixed kernel method(95%, 50%). As a result, Mean annual home ranges for female and male asiatic black bears were 71.66$km^2$ and 90.20$km^2$. The seasonal home ranges were calculated 19.81$km^2$ for females and 33.47$km^2$ for males in spring, 30.48$km^2$ for females and 20.26$km^2$ for males in summer, 22.63$km^2$ for females and 23.23$km^2$ for males in autumn and 0.22$km^2$ for females and 0.78$km^2$ for males in winter(F=4.193, P<0.05). The degree of home range overlapped 38%, 12.5% among females, 22.4% among males. Mean elevation of seven bears was 744$\pm$236m in spring, 682$\pm$253m in summer, 937$\pm$218m in fall and 975$\pm$137m in winter(F=8.526, P<0.001). It is assumed that home range sizes and location were closely correlated to environmental characteristics of the habitats and the seasonal variation of home-range was related to distribution of food sources.

The Effects of LaF3 Coating on the Electrochemical Property of Li[Ni0.3Co0.4Mn0.3]O2 Cathode Material

  • Yun, Su-Hyun;Kim, Seuk-Buom;Park, Yong-Joon
    • Bulletin of the Korean Chemical Society
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    • v.30 no.11
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    • pp.2584-2588
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    • 2009
  • The effect of $LaF_3$ coating on the structural and electrochemical properties of $Li[Ni_{0.3}Co_{0.4}Mn_{0.3}]O_{2}$ cathodes was investigated using XRD, SEM, TEM, and a cycler. The coating layer consisted of nano-sized particles attached nonuniformly to the surface of pristine powder. Despite the surface coating treatment, phase difference by $LaF_3$ coating was not detected. The discharge capacities of coated electrodes were a little lower than that of pristine sample at a 1 C rate. However, as the C rate increases, the capacity retention of the coated sample becomes obviously superior to that of the pristine sample. The cyclic performances of the electrodes in the voltage range of 4.8 $\sim$ 3.0 V were also improved by the surface coating. Such enhancement is attributed to the presence of the $LaF_3$ coating layer, which effectively suppressd the reaction between electrodes and electrolytes on the surface of the $Li[Ni_{0.3}Co_{0.4}Mn_{0.3}]O_{2}$ electrode.

Microwave dielectric properties according to the additions of NiO to $(Zr_{0.65}, Sn_{0.35})Ti_{1.04}O_{4.04}$ ceramics ($(Zr_{0.65}, Sn_{0.35})Ti_{1.04}O_{4.04}$세라믹스의 NiO첨가에 따른 고주파 유전 특성)

  • 윤중락;권정열;이헌용;김경용
    • Electrical & Electronic Materials
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    • v.8 no.5
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    • pp.594-600
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    • 1995
  • Dielectric properties at microwave frequencies of ($Zr_{0.65}$, $Sn_{0.35}$) $Ti_{1.04}$ $O_{4.04}$ ceramics with additives, NiO as an agent to improve dielectric properties and $B_{2}$ $O_{3}$ as a firing agent were investigated. When 0.5 - 1.5 wt% of NiO is add, the grain growth is inhibited and the shape of the grain is uniformed, Dielectric constant(Fr) and bulk density are increased with raising amount of NiO at sintering temperature of 1330 - 1360.deg. C, but the temperature coefficient of resonant frquency(.epsilon.$_{r}$) decreased gradually as the NiO content increased. The value of Qx $f_{o}$ was increased as the amount of NiO was increased in the range of 0.5 to 1.0 wt% and the Qx $f_{o}$, was decreased slightly with raising sintering temperature. With NiO of 1.0 wt% and at sintering temperature of 1360.deg. C, this ceramics was found to have excellent microwave properties of .epsilon.$_{r}$=37.8, Qx $f_{o}$ = 48.600 and .tau.$_{f}$ = 7 ppm/.deg. C.C.. C.. C.C.. C.. C.

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Quality Monitoring of Specification of Crataegi Fructus in the Korean Pharmacopoeia and Studies HPLC Standard Chromatogram (산사(山楂)의 규격 기준 모니터링 및 HPLC 표준크로마토그램 연구)

  • Kim, Kyoung Hee;Kim, Sun Mi;Lee, Young Jong;Baek, Wan Sook
    • The Korea Journal of Herbology
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    • v.32 no.1
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    • pp.55-62
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    • 2017
  • Objectives : Crataegi Fructus has been used as traditional medicines for more digestion action, amenorrhea due to blood stasis, and hyperlipemia. The aim of this study was to compare of Crataegi Fructus in South Korea collected during three years according to the standards in monographs of the Korean Pharmacopoeia Eleventh edition (KP 11). Methods : Crataegi Fructus was carried out identification test (Qualitative reaction, Thin layer chromatography), heavy metal test, and total ash registered at KP. Add to we tested loss on dry, contents of ethanol-soluble extracts, and HPLC profiling. Results : Identification test (TLC) was on comparing with ursolic acid standard solution in $R_f$ value, all samples showed red purple spot ($R_f$ value 0.9). Ursolic acid spot in $R_f$ value 0.35 showed by changing mobile phase condition. Heavy metals showed contents for Pb, Cd, As, and Hg range of 0.0 ~ 0.5 ppm, 0.0 ~ 0.2 ppm, 0.0 ~ 0.3 ppm, and 0.0 ~ 0.1 ppm. Loss on drying was ranged from 5.5 to 11.9 %, total ash was between the range 2.7 ~ 4.0 %. Contents of ethanol-soluble extracts was ranged from 17.8 to 44.9 %. The content of chlorogenic acid was ranged from 0.0 to 0.1 % based on the chlorogenic acid standard curve. Conclusion : We have verified the current specification standard of Crataegi Fructus and standard that is not set. We hope that it will help the standardization of Crataegi Fructus.

Synthesis, Structural and Electrical Characterizations of $Pr_{2-x}Ba_xNiO_{4{\pm}\delta}{^\$}$

  • 장영기;권영구;변송호
    • Bulletin of the Korean Chemical Society
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    • v.16 no.2
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    • pp.120-125
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    • 1995
  • Solid solutions of Pr2-xBaxNiO4±δ with K2NiF4-type structure were prepared in air and characterized by powder X-ray diffraction, Rietveld refinements, iodometry titrations, and conductivity measurements. The range of the solid solution was 0 ≤ x < 0.5. The crystal structure changes from orthorhombic (Fmmm) for x ≤ 0.1 to pseudo-tetragonal (I4/mmm) for x ≥ 0.2. The orthorhombic structure of x=0.1 transforms to tetragonal at low temperature. The bond distances obtained from the Rietvel analyses did not vary significantly with the Ba content except that of Ni-O (parallel to the c-axis) which showed an abrupt increase from x=0.1 to 0.2. The excess oxygen content (δ) decreases from 0.241 to 0.03 with increasing substituted Ba contents within the solution range. The samples are all semiconductors at the temperature range 4 < T < 300 K.

Preoperative Nodal 18F-FDG Avidity Rather than Primary Tumor Avidity Determines the Prognosis of Patients with Advanced Gastric Cancer

  • Kwon, Hyun Woo;An, Liang;Kwon, Hye Ryeong;Park, Sungsoo;Kim, Sungeun
    • Journal of Gastric Cancer
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    • v.18 no.3
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    • pp.218-229
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    • 2018
  • Purpose: This study investigated whether the metabolic avidity of primary tumors and/or metastatic lymph nodes (LNs) measured by $^{18}F$-fluorodeoxyglucose ($^{18}F-FDG$) positron emission tomography/computed tomography (PET/CT) was related to survival after surgery in patients with advanced gastric cancer (AGC). Materials and Methods: One hundred sixty-eight patients with AGC who underwent preoperative $^{18}F-FDG$ PET/CT and curative resection were included. The $^{18}F-FDG$ avidity of the primary gastric tumor and LNs was determined quantitatively and qualitatively. The diagnostic performance of $^{18}F-FDG$ PET/CT was calculated, and the prognostic significance of $^{18}F-FDG$ avidity for recurrence-free survival (RFS) and overall survival (OS) was assessed. Results: In all, 51 (30.4%) patients experienced recurrence, and 32 (19.0%) died during follow-up (median follow-up duration, 35 months; range, 3-81 months); 119 (70.8%) and 33 (19.6%) patients showed $^{18}F-FDG$-avid primary tumors and LNs, respectively. $^{18}F-FDG$ PET/CT showed high sensitivity (73.8%) for the detection of advanced pathologic T ($pT{\geq}3$) stage and high specificity (92.2%) for the detection of advanced pN (${\geq}2$) stage. $^{18}F-FDG$ avidity of LNs was significantly associated with RFS (P=0.012), whereas that of primary tumors did not show significance (P=0.532). Univariate and multivariate analyses revealed that $^{18}F-FDG$ avidity of LNs was an independent prognostic factor for RFS (hazard ratio=2.068; P=0.029). Conclusions: $^{18}F-FDG$ avidity of LNs is an independent prognostic factor for predicting RFS. Preoperative $^{18}F-FDG$ PET/CT can be used to determine the risk and prognosis of patients with AGC after curative resection.

Fatigue Crack Propagation and Fatigue Life Evaluation of High-Performance Steel using Modified Forman Model (수정 Forman 모델을 이용한 고성능 강재의 피로균열전파와 피로수명평가)

  • Choi, Sung-Won;Kang, Dong-Hwan;Lee, Jong-Kwan;Kim, Tae-Won
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.35 no.11
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    • pp.1361-1368
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    • 2011
  • Fatigue crack propagation behavior and the fatigue life in-high performance steel were investigated by means of fatigue crack propagation tests under constant loading conditions of 'R=0.1 and f=0.1 Hz', 'R=0.3 and f=0.3 Hz', and 'R=0.5 and f=0.5 Hz' for the load ratio and frequency, respectively. A modified Forman model was developed to describe the fatigue crack propagation behavior for the conditions. The modified Forman model is applicable to all fatigue crack propagation regions I, II, and III by implementing the threshold stress intensity factor range and the effective stress intensity factor range caused by crack closure. The results show that predicted fatigue lives of Forman and modified Forman models were 8,814 and 12,292 cycles, respectively when the crack propagated approximately 5.0 mm and the load ratio and frequency were both 0.1. Comparison of the test results indicates that the modified Forman model showed much more effective fatigue crack propagation behavior in high-performance steel.

Relationship between Self concept and Depression of Middle-Aged Women (중년 여성의 자아개념과 우울과의 관계)

  • 성미혜
    • Korean Journal of Health Education and Promotion
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    • v.19 no.1
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    • pp.171-184
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    • 2002
  • The purpose of this study was to investigate the relationship between self concept and depression of middle-aged women. The Subjects were 102 middle-aged women whose age range were 40-59 years old living in urban area. The instruments used in this study were self concept scale developed by Rosenberg and the depression scale developed by Zung. Data were collected done from July 1 to July 31, 2001 by a structured questionnaire. The Data were analyzed by the SPSS/PC+ program using t-test, ANOV A and Pearson Correlation Coefficient. The results of the study were as followed : 1. Mean score of self concept was 2.35. 2. Mean score of depression scale was 2.43 3. The relationship between self concept and depression was statistically negative correlation(r=-0.3769, P〈0.001). 4. There were statistically significant differences in the score of middle-aged women's self concept to the age(F=3.41, P〈0.05), education(F=2.97, P〈0.05), Occupation(t=1.84, P〈0.05). 5. General characteristics variables were significantly related to the level of depression were the age(F=3.12, P〈0.05), numbers of children(t=3.59,P〈0.05). Obstetrical characteristics variables were significantly related to the level of depression were age of menarche(F=4.03, P〈0.05), times of abortion(t=10.09, P〈0.001). In conclusion, this study revealed that self esteem was an important factor related to depression. I suggest that to decrease depression, it should be encouraged self esteem.

Effect of PbO on Microwave Dielectric Properties of (Pb, Ca) (Fe, Nb, Sn) O3 Ceramics

  • Yoon, Seok-Jin;Park, Ji-Won;Kang, Chong-Yun;Kim, Hyun-Jai;Jung, Hyung-Jin;Sergey Kucheiko;Cho, Bong-Hee
    • The Korean Journal of Ceramics
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    • v.4 no.3
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    • pp.249-253
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    • 1998
  • The influence of PbO additive on dielectric properties and sintering behavior of $(Pb_{0.46}Ca_{0.55})$ {$(Fe__1/2}Nb_{1/2}){0.9}Sn_{{0.1}$}$O_3$ ceramics has been investigated. The incorporation of a limited excess PbO ($\leq$2.0 wt. %) in the starting materials is quite beneficial for densification in the temperature range of 1150~$1175^{\circ}C$ in air. At a small doping level (0.8 wt. %) the ceramics prepared from powders calcined at $900^{\circ}C$ showed the best dielectric properties. The dielectric constants ($\varepsilon_r$) and Q.f were found to be 85.8~85.6 and 8530~8600 GHz, respectively. The temperature coefficient of resonant frequency ($\tau_f$) varied in the range of -2~4 $ppm/^{\circ}C$. Examination of the microstructure as well as analysis of the second phases in these materials revealed the presence of the pyrochlore-type phase which is detrimental to the dielectrics.

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