• Title/Summary/Keyword: F/H ratio

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Micro-morphological Features of Liquid Urea-Formaldehyde Resins during Curing Process at Different Levels of Hardener and Curing Time Assessed by Transmission Electron Microscopy

  • Nuryawan, Arif;Park, Byung-Dae
    • Current Research on Agriculture and Life Sciences
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    • v.32 no.3
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    • pp.125-130
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    • 2014
  • This study used transmission electron microscopy (TEM) to investigate the micro-morphological features of two formaldehyde to urea (F/U) mole ratio liquid urea-formaldehyde (UF) resins with three hardener levels as a function of the curing time. The micro-morphological features of the liquid UF resins were characterized after different curing times. As a result, the TEM examination revealed the presence of globular/nodular structures in both liquid UF resins, while spherical particles were only visible in the low F/U mole ratio resins. The high F/U mole ratio liquid UF resins also showed extensive particle coalescence after adding the hardener, along with the appearance of complex filamentous networks. When the resins were cured with a higher amount of hardener and longer curing time, the spherical particles disappeared. For the low mole UF resins, the particles tended to coalesce with a higher amount of hardener and longer curing time, although discrete spherical particles were still observed in some regions. This is the first report on the distinct features of the crystal structures in low F/U mole ratio UF resins cured with 5% hardener and after 0.5 h of curing time. In conclusion, the present results indicate that the crystal structures of low F/U mole ratio UF resins are formed during the curing process.

H/F Variation in Wolframites According to Depth and Temperature of Mineralization at Ssangjeon, Weolag, Cheongyang and Sannae Mines, Korea (쌍전, 월악, 청양 및 산내 철·망간중석 광산의 유체포유물 온도와 심도에 따른 H/F 값의 변화)

  • Park, Maeng-Eon
    • Economic and Environmental Geology
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    • v.26 no.3
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    • pp.259-265
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    • 1993
  • The variation of H/F coefficient (Hubnerite/Feberite coefficient) and the temperature of formation with depth have been studied for the hydrothermal tungsten-quartz veins from Ssangjeon, Weolag, Cheongyang, and Sannae mines. All samples were selected at the same paragenetic stage and mineral assemblege according to depth. The studied mines provide an opportunity to examine and regional variations in wolframite composition in different provinces. The formation temperature is linearly related to the depth. At the Weolag, Cheongyang and Sannae mines, the H/F ratio of wolframite and filling temperatures of fluid inclusions in quartz show a general tendency to decrease at shallow levels, in spite of different geological settings. This implies the pH of fluid will decrease vertically with falling temperature and the high H/F ratio of wolframite in deep zone result in an increase of pH with depth. The Ssangjeon mine exhibits a tendency to increase slightly upwards at shallow level. This implies a different geochemical environment (high pH environment) for the Ssangjeon mine, as compared to the other three mines. The H/F coefficient pattern suggests that it is a useful geothermometer for vein-type tungsten deposits in Korea. The H/F coefficient as an indication of depth should be examined for use in exploration.

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Effects of oscillation parameters on aerodynamic behavior of a rectangular 5:1 cylinder near resonance frequency

  • Pengcheng Zou;Shuyang Cao;Jinxin Cao
    • Wind and Structures
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    • v.38 no.1
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    • pp.59-74
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    • 2024
  • Large Eddy Simulation (LES) is used to explore the influence of vibration frequency and amplitude on the aerodynamic performance of a rectangular cylinder with an aspect ratio of B/D=5 (B: breadth; D: depth of cylinder) at a Reynolds number of 22,000 near resonance frequency. In smooth flow conditions, the research employs a sequence of three-dimensional simulations under forced vibration with diverse frequency ratios fe / fo = 0.8-1.2 (fe : oscillation frequency; fo : Strouhal frequency when the rectangular cylinder is stationary ) and oscillation amplitudes Ah/D = 0.05 - 0.3. The individual influences of fe / fo and Ah/D on the characteristics of integrated and distributed aerodynamic forces are the focal points of discussion. For the integrated aerodynamic force, particular emphasis is placed on the analysis of the dependence of velocity-proportional component C1 and displacement-proportional component C2 of unsteady aerodynamic force on amplitude and frequency ratio. Near the resonance frequency, the dependencies of C1 and C2 on amplitude are stronger than that of frequency ratio. For the distributed aerodynamic force, the increase in frequency and amplitude promotes the position of the main vortex core and reattachment to the leading edge in the streamwise direction. In the spanwise direction, vibration enhances the spanwise correlation of aerodynamic force to weaken the three-dimensional effect of the flow field, and a lower frequency ratio and larger amplitude amplify this effect.

Induced Mutant by Gamma Rays and Genetic Analysis for Mutant Characters in Flue-cured Tobacco Variety (Nicotiana tabacum L.) I. Induced Mutations and Characteristics of Mutant (황색종 연초 품종의 Gamma선에 의한 돌연변이 유수 및 변이형질의 유전분석 I. 돌연변이 유기 및 변이체의 특징)

  • Jung, Seok-Hun;Lee, S.C.;Kim, H.B.
    • Journal of the Korean Society of Tobacco Science
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    • v.14 no.1
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    • pp.12-23
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    • 1992
  • This experiment was conducted to determine the optimum dosage of gamma rays for inducing artificial mutation of several mutant characters in the flue-cured tobacco. 1) In Hicks and BY 104, the gammarays irradiation has no significantly different effect on seed germination from the control. However, the average dosage for 50% growth inhibition was 25-30kr for all the varieties tested, which inhibition 46-52% and 43-57% of the seedling growths for Hicks and BY 104, respectively. 2) A mutant line 83H-5 was selected from Hicks by irradiation gamma ray at the level of 30kr. It has white flower, more resistance to bacterial wilt, Pssudomonas solanacearum, lower plant and stalk height, narrower leaf width, larger leaf shape index(lento width) and later days to flower when compared with the original variety Hicks. 3) White flower was recessive to pink flower in F, and Br (F1 X Hicks) progenies. F2 population of the cross gave segregation ratio of 3 pink flower:1 white flower, and B, (F1 X 83H-5) Population gave 1:1 ratio. Results showed that the white flower character is governed by a single recessive gene.

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Precise Air-Fuel Ratio Control on Transient Conditions with the PC-ECU in SI Engine (PC-ECU를 이용한 SI 기관의 비정상상태 정밀공연비 제어)

  • Yoon, S.H.
    • Journal of ILASS-Korea
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    • v.5 no.3
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    • pp.9-16
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    • 2000
  • In a SI engine, three-way catalyst converter has the best efficiency when A/F ratio is near the stoichiometry. The feedback control using oxygen sensors in the commercial engine has limits caused by the system delays. So it is necessary to control fuel quantity in accordance with intake air amount in order to reduce exhaust emission and improve the specific fuel consumption. Precise A/F ratio control requires measurement of air amount with respect to the cylinder and injection fuel according to the air amount In this paper, we applied nonlinear fuel injection model and developed the algorithm of A/F ratio control. This algorithm includes the methods of measurement of transient air mass flowing into each cylinder, of calculation of injection pulse width for measured air mass, and the method of feedback and engine control by using lambda sensor. Also we developed control program for IBM-PC by using C++ Builder, and tested it in the commercial engine.

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Elution Behavior of Protein and Pullulan in Asymmetrical Flow Field-flow Fractionation (AsFlFFF)

  • Ji, Eun-Sun;Choe, Seong-Ho;Yun, Guk-Ro;Chun, Jong-Han;Lee, Seung-Ho
    • Bulletin of the Korean Chemical Society
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    • v.27 no.9
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    • pp.1433-1438
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    • 2006
  • An AsFlFFF channel was designed and built, and then tested for analysis of pullulans and proteins. Pullulans and proteins having various nominal molecular weights were injected at various conditions of the cross-flow rate ($F_c$) and the channel-out flow rate ($F_{out}$). The retention (measured by the retention ratio R) and the zone broadening (measured by the plate height H) were measured, and then compared with theory. When the incoming flow rate, $f_{in}$ (and thus $F_{out}$) was varied with $F_c$ fixed at 2.5 mL/min, the plate height measured for the pullulan with nominal molecular weight (M) of about 100,000 showed the trend expected by the longitudinal diffusion theory (H decreases with increasing flow rate). In contrast, when $F_{out}$ was varied with the flow rate ratio, $F_c/F_{out}$, fixed constant at 5, the plate height measured for the same sample showed the trend expected from the non-equilibrium theory (H increases with increasing flow rate). Calibration plots (log D vs. log M) obtained with pullulans and proteins were not coincide, probably due to the difference in molecular conformation, suggesting the analysis of pullulans and proteins using AsFlFFF requires independent calibration. It was found that the linearity of the protein-calibration plot was improved by using a buffer solution as the carrier.

RELATIVE CLASS NUMBER ONE PROBLEM OF REAL QUADRATIC FIELDS AND CONTINUED FRACTION OF $\sqrt{m}$ WITH PERIOD 6

  • Lee, Jun Ho
    • East Asian mathematical journal
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    • v.37 no.5
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    • pp.613-617
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    • 2021
  • Abstract. For a positive square-free integer m, let K = ℚ($\sqrt{m}$) be a real quadratic field. The relative class number Hd(f) of K of discriminant d is the ratio of class numbers 𝒪K and 𝒪f, where 𝒪K is the ring of integers of K and 𝒪f is the order of conductor f given by ℤ + f𝒪K. In 1856, Dirichlet showed that for certain m there exists an infinite number of f such that the relative class number Hd(f) is one. But it remained open as to whether there exists such an f for each m. In this paper, we give a result for existence of real quadratic field ℚ($\sqrt{m}$) with relative class number one where the period of continued fraction expansion of $\sqrt{m}$ is 6.

Influence of Initial Molar Ratios on the Performance of Low Molar Ratio Urea-Formaldehyde Resin Adhesives

  • LUBIS, Muhammad Adly Rahandi;PARK, Byung-Dae
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.2
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    • pp.136-153
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    • 2020
  • In this paper, the influence of initial formaldehyde/urea (F/U) molar ratios on the performance of low molar ratio (1.0) urea-formaldehyde (UF) resin adhesives has been investigated. Two initial F/U molar ratios, i.e., the first and second initial molar ratios were used for the alkaline addition reaction. Three levels of the first initial F/U molar ratios (2.0, 3.0, and 4.0) and two levels of the second initial molar ratios (2.0 and 1.7) were employed to prepare a total of six UF resins with an identical final molar ratio (1.0). The basis properties, functional groups, molecular weight, crystallinity, and thermal curing properties of the UF resins were characterized in detail. Higher levels (3.0 and 4.0) of the first initial F/U molar ratio provided the UF resins with better properties (non-volatile solids content, viscosity, gelation time, pH, and specific gravity) than those of the resins prepared with the conventional level F/U molar ratio of 2.0. Statistical analysis suggested that combining the first and second initial molar ratio of 4.0 with 1.7 would result in UF resins with greater adhesion strength and lower formaldehyde emission than those of the resins prepared with other molar ratios. The results showed that higher levels of the first initial molar ratio resulted in a more branched structure, as indicated by GPC, FTIR, DSC, XRD, and greater adhesion strength than those of the other UF resins with an identical final molar ratio of 1.0.

Effects of Fertilizer Treatment on the Growth Performance of 1-Year-Old Containerized Seedlings in Chionanthus retusus

  • Choi, Chung Ho
    • Korean Journal of Plant Resources
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    • v.33 no.6
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    • pp.586-596
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    • 2020
  • Chionanthus retusus has been used for landscaping and gardening trees, foods and medicines. This study was carried out to analyze the effect of fertilization on the growth performance of container seedlings (1-year-old) in C. retusus. We used multifeed 19 (MF) as a fertilizer, and measured the height, root collar diameter (RCD), biomass, seedling quality index (SQI) chlorophyll contents and chlorophyll fluorescence of the seedlings. The findings of this paper showed that the height, RCD, H/D ratio, T/R ratio and the fresh and dry weight of seedlings increased after fertilization. The moisture content of the stem and root did not show any significant difference among fertilizations, except in the case of the leaf. Production distribution such as the dry weight ratio of leaves and the stem dry weight ratio of fertilized seedlings had a higher value than that of non-treatment. SQI was the highest in MF 1,000 mg/L and 2,000 mg/L treatment. Chlorophyll contents (SPAD value) also increased with the increase in fertilization concentrations. Chlorophyll fluorescence (Fv/Fm) showed the highest value of 0.8 in MF 2,000 mg/L treatment.