• Title/Summary/Keyword: F/C ratio

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A Characteristic of Nitrogen and Phosphorus Removal in Anoxic/Oxic Basins combined with Iron Electrolysis (철 전기분해장치와 무산소/호기공정을 결합한 질소, 인제거 특성에 관한 연구)

  • Kim, Young-Gyu
    • Journal of Environmental Health Sciences
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    • v.43 no.6
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    • pp.525-531
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    • 2017
  • Objectives: The purpose of this experiment is to better understand the nitrogen and phosphorus removal ratio according to operating conditions in an iron electrolysis system consisting of an anoxic basin, aerobic basin, and iron precipitation apparatus. Methods: Iron electrolysis consists of an iron precipitation reactor composed of iron plates in oxic and anoxic basins. We studied the interrelation coefficient between T-N and T-P removal rates and F/M ratio, and the C/N ratio and BOD removal rate. Results: The F/M ratio and the T-N and T-P removal rate per unit area have interrelation coefficients of 0.362 and 0.603, respectively. The removal rate per MLVSS and the T-N and T-P removal rate per unit area have respective interrelation coefficients of 0.49 and 0.59. Conclusions: The removal rate of T-N and T-P increased with the increasing F/M ratio in the influent, and they also linearly increased in proportion to the C/N ratio of influent and BOD removal rate of the reactor.

The Characteristics of Residual Films on Silicon Surface $CHF_3/C_2F_6$ Reactive Ion Etching ($CHF_3/C_2F_6$ 플라즈마에 의한 실리콘 표면 잔류막의 특성)

  • 권광호;박형호;이수민;강성준;권오준;김보우;성영권
    • Journal of the Korean Vacuum Society
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    • v.1 no.1
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    • pp.145-152
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    • 1992
  • Si surfaces exposed to CHF3/C2F6 gas plasmas ih reactive ion etching (RIE) have been characterized by X-ray photoelectron spectroscopy (XPS). CHF3/C2F6 gas plasma exposure of Si surface leads to the deposition of residual film containing carbon and fluorine. The narrow scan spectra of C 1s show various bonding states of carbon as C-Si, C-F/H, C-CFx(x $\leq$ 3), C-F, C-F2, and C-F3. The chemical bonding states of fluorine are described with F-Si, F-C and F-O. And the oxygen and silicon are also detected. The effects of parameters for reactive ion etching as CHF3/C2F6 gas ratio, RF power, and pressure are investigated.

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The Study on Earlier Evaluation of Concrete Strength Using Electric Resistance Method (전기 저항법을 이용한 콘크리트 조기 강도 판정에 관한 연구)

  • 김화중;이도현;윤상천;박정민;최신호
    • Proceedings of the Korea Concrete Institute Conference
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    • 1995.04a
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    • pp.130-135
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    • 1995
  • We can consider that the study on early evaluation of strength of concrete is useful to raise safety of building and utility of quality control of concrete is useful to raise safety of building and utility of quality control of concrete. In this paper, was proposed to method early to predict strength of concrete with key parameters, such as Water/Cement(W/C) ratio and Sand / Aggregate(S/A) ratio. Through a series of experiment, the obtained results are summarized as follow. $\circled1$ The ratio of resistance was decteased as the increase of W/C ratio. $\circled2$ The maximum value for the ratio of resistance and compressive strength was presented in the case of 40% S/A ratio. $\circled3$ The relationship. of the ratio of resistance and compressive strength on 28days according to the change of W/C and S/A ratio is to be: $F_{28}=-0.00104R^2 + 2.263R - 935.5$ (W/C Ratio) $F_{28} = 0.007R^2 - 10.693R - 4269.1$ (S/A Ratio)

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Study on the Changes in Saponins from Ginseng Callus by Tissue Culture -Part 1. Comparison of Saponins from Callus Tissue and from the Root of Ginseng Plant- (조직배양(組織培養)에 의한 인삼성분(人蔘成分)의 변화(變化) -제1보(第一報) Callus와 인삼성분(人蔘成分)의 비교(比較)-)

  • Yang, R.;Choi, Y.C.;Kim, H.J.;Lee, S.C.;Park, S.H.
    • Korean Journal of Food Science and Technology
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    • v.10 no.2
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    • pp.181-188
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    • 1978
  • To study on the changes in saponins from callus mass by tissue culture, the callus was derived from the petiole of Korean Ginseng (Panax Ginseng C.A. Meyer) and cultivated on Murashige and Skoog's agar medium supplemented with 2.4-dichlorophenoxyacetic acid and kinetin for 8 months. Then, well-grown callus was analyzed for its components estimation. The results obtained are as follows: (1) When saponins isolated from callus mass were chromatographed on a silca gel plate, and determined by the thinchrograph TFG-10, the ratio of Rb, c to Rg(f) in saponins was 2.16 to 1 and Rb, c, d to Re, g (f) was 1 to 1.63, while in the case of saponins from the root of Panax Ginseng grown by soil culture, the ratio of Rb, c to Rg(f) was 1.03 to 1 and the ratio of Rb, c,d to Re, g(f) was 1 to 1.17. (2) Sapogenins were obtained from the hydrolysates of saponins, and determined by thinchrograph TFG-10. The ratio of panaxadiol to panaxatriol in sapogenins from callus saponins was 2.66 to 1, while the ratio of panaxadiol to panaxatriol in sapogenins from ginseng root saponins was 1.86 to 1. From the results above mentioned, we concluded that the relative contents of sapogenins in saponins from callus mass by tissue culture were different from those in saponins from ginseng root by soil culture.

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Effects of F/M ratio on the EPS production and fouling at MBR (MBR에서 F/M비가 EPS 생성 및 fouling에 미치는 영향)

  • Kim, Yun-Ji;Choi, Yun-Jeong;Hwang, Sun-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.35 no.3
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    • pp.197-204
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    • 2021
  • In MBR, extracellular polymeric substance (EPS) is known as an important factor of fouling; soluble EPS (sEPS) affects internal contamination of membrane, and bound EPS (bEPS) affects the formation of the cake layer. The production of EPS changes according to the composition of influent, which affects fouling characteristics. Therefore, in this study, the effects of the F/M ratio on the sEPS concentration, bEPS content, and fouling were evaluated. The effects of F/M ratio on the amount and composition of EPS were confirmed by setting conditions that were very low or higher than the general F/M ratio of MBR, and the fouling occurrence characteristics were evaluated by filtration resistance distribution. As a result, it was found that the sEPS increased significantly with the increase of the F/M ratio. When the substrate was depleted, bEPS content decreased because bEPS was hydrolyzed into BAP and seemed to be used as a substrate. In contrast, when the substrate is sufficient, UAP (utilization-associated products) was rapidly generated in proportion with the consumption of the substrate. UAP has a relatively higher Protein/Carbohydrate ratio (P/C ratio) than BAP, and this means, it has a higher adhesive force to the membrane surface. As a result, UAP seems like causing fouling rather than BAP (biomass-associated products). Therefore, Rf (Resistance of internal contamination) increased rapidly with the increase of UAP, and Rc (Resistance of cake layer) increased with the accumulation of bEPS in proportion, and as a result, the fouling interval was shortened. According to this study, a high F/M ratio leads to an increment in UAP generation and accumulation of bEPS, and by these UAP and bEPS, membrane fouling is promoted.

Study for combustion characteristic according to the O/F ratio of low thrust rocket engine using green propellant (친환경 추진제를 사용하는 저추력 엑체로켓엔진의 혼합비에 따른 연소 특성)

  • Jeon, Jun-Su;Kim, Young-Mun;Hwang, O-Sik;Ko, Young-Sung;Kim, Yoo;Kim, Sun-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.134-137
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    • 2009
  • Combustion tests of a low thrust rocket engine was performed to get combustion characteristics, which used a high concentrated hydrogen peroxide and kerosene as the oxidizer and fuel. The engine consisted of multi injector(six coaxial swirl injectors), chamber, nozzle and catalyst ignition system. The test was carried out by changing O/F ratio from 3.8 to 11.0. The experimental results showed that combustion efficiency was highest at O/F ratio from 5 to 6 and pressure fluctuations of all the range were lower than 5%.

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Evaluation Technique of Linearity of Ratio Error and Phase Angle Error of Voltage Transformer Comparison Measurement System Using Capacitor Burden (전기용량 부담을 이용한 전압변성기 비교 측정 시스템의 비오차 및 위상각 오차의 직선성 평가기술)

  • Jung Jae Kap;Kim Han Jun;Kwon Sung Won;Kim Myung Soo
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.6
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    • pp.274-278
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    • 2005
  • Voltage transformer(VT) comparison measurement system is usually used for measurements of ratio error and phase angle error of VT made in industry. Both ratio error and phase angle error in VT are critically influenced by values of burden of VT used. External burden effects on both ratio error and phase angle error in VT are theoretically calculated. From the theoretical calculation, a method of evaluation for linearity of ratio error and phase angle error in VT measurement system have been developed using the standard capacitive burdens, with negligible dissipation factor less than 10$^{-4}$. These burden consists of five standard capacitors, with nominal capacitance of 1.1 $\mu$F, 1 $\mu$F, 0.1 $\mu$F, 0.01 $\mu$F, 0.001 $\mu$F. The developed method has been applied in VT measurement system of industry, showing in good consistency and linearity within 0.001 $\%$ between theoretical and measured values.

Infrared Multiphoton Dissociation of $CHCl_2F$: Reaction Mechanisms and Product Ratio Dependence on Pressure and Laser Pulse Energy

  • Song, Nam-Woong;Lee, Won-Chul;Kim, Hyong-Ha
    • Journal of Photoscience
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    • v.12 no.2
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    • pp.101-107
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    • 2005
  • Infrared multiphoton dissociation of $CHCl_2F$ was studied using $CO_2$ laser excitation. Three products, $C_2Cl_2F_2$, $C_2ClF_3$, and $C_2HClF_2$, were identified by the analysis of the gas mixture from the photoreaction of $CHCl_2F$. The dependence of the reaction probability on added Ar gas pressure and excitation laser pulse energy was investigated. At low pressure (< 10 torr), the reaction probability increased as Ar pressure increased due to the rotational hole-filling effect, while it diminished with the increase of Ar pressure at high pressure (> > 20 torr) due to the collisional deactivation. The ratio of two products $(C_2ClF_3/C_2Cl_2F_2)$ decreased at low pressure (< 10 torr) and increased at high pressure (> 20 torr) with the increase of Ar pressure. The log-log plot of the reaction probability vs. laser pulse energy (${\\phi}$) was found to have a linear relationship, and its slope decreased as the added Ar pressure was increased. The reaction mechanisms for product formation have been suggested and validated by experimental evidences and considering the energetics. Fluorine-chlorine exchange reaction in the intermediate complex has been suggested to explain the formation of $C_2ClF_3$.

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Influences of Water to Cement Ratio and Chemical Admixtures on the Quality of Inter-Locking Block (인터로킹 블록의 품질에 미치는 물시멘트비와 화학혼화제의 영향)

  • 이상태;김기철;신병철;김진선;한천구
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.10c
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    • pp.157-160
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    • 1998
  • KS F 4419, which is dealt with the Inter-Locking block, states that water to cement ratio for manufacturing inter-locking block should be less than 25% and in KS F4419, the use of admixture is shown to be reluctant to recommend. In this paper, reinvestigation of some regulations in KS F 4419 are carried out. According to the experimental results, as W/C increases, flexural strength and compressive strength are tended to decrease, whereas they increases within certain range, Flexural strength and compressive strength have higher values in 1:2(W/C=35%), 1:4(W/C=45%) and 1:6(W/C=55%) of mix proportions. Moreover they have rather higher values with the containment of high range AE water-reducing agent. The absorption ratios decrease with the increase of W/C and the containment of high range AE water-reducing agent. Therefore, the regulations on the W/C and admixture in KS F 4419 reguire revision.

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A Study on The Improvement of Profile Tilting or Bottom Distortion in HARC (높은 A/R의 콘택 산화막 에칭에서 바닥모양 변형 개선에 관한 연구)

  • Hwang, Won-Tae;Kim, Gli-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.5
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    • pp.389-395
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    • 2005
  • The etching technology of the high aspect ratio contact(HARC) is necessary at the critical contact processes of semiconductor devices. Etching the $SiO_{2}$ contact hole with the sub-micron design rule in manufacturing VLSI devices, the unexpected phenomenon of 'profile tilting' or 'bottom distortion' is often observed. This makes a short circuit between neighboring contact holes, which causes to drop seriously the device yield. As the aspect ratio of contact holes increases, the high C/F ratio gases, $C_{4}F_{6}$, $C_{4}F_{8}$ and $C_{5}F_{8}$, become widely used in order to minimize the mask layer loss during the etching process. These gases provide abundant fluorocarbon polymer as well as high selectivity to the mask layer, and the polymer with high sticking yield accumulates at the top-wall of the contact hole. During the etch process, many electrons are accumulated around the asymmetric hole mouth to distort the electric field, and this distorts the ion trajectory arriving at the hole bottom. These ions with the distorted trajectory induce the deformation of the hole bottom, which is called 'profile tilting' or 'bottom distortion'. To prevent this phenomenon, three methods are suggested here. 1) Using lower C/F ratio gases, $CF_{4}$ or $C_{3}F_{8}$, the amount of the Polymer at the hole mouth is reduced to minimize the asymmetry of the hole top. 2) The number of the neighboring holes with equal distance is maximized to get the more symmetry of the oxygen distribution around the hole. 3) The dual frequency plasma source is used to release the excessive charge build-up at the hole mouth. From the suggested methods, we have obtained the nearly circular hole bottom, which Implies that the ion trajectory Incident on the hole bottom is symmetry.