• Journal of the Korean Wood Science and Technology
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• v.20 no.2
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• pp.73-80
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• 1992

The effect of presteaming on native oak specimens(Quercus serrata) of 2.5cm thick were investigated by measuring specific gravities, internal moisture gradients, residual extractives, and transport rates of free and bound water. The specific gravities and internal moisture gradients of the presteamed samples did not much deviate from those of the controls, but after presteaming discrepancy in moisture content between specimens lessened. The amount of residual hot-water extractives of the presteamed samples were less than those of the controls by 25%. The transport rates of bound water were determined by measuring steady-state diffusion coefficients with a vapormeter cup. After presteaming the diffusion coefficients in radial direction increased by 35%, but decreased those in the tangential direction.

• Journal of the Korean Wood Science and Technology
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• v.26 no.4
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• pp.56-60
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• 1998

The bark of Fraxinus rhynchophylla, one of ash trees grown in domestic, was collected, extracted with acetone-$H_2O$(7:3, v/v) and freeze dried to give 50g of ethylacetate soluble powder. A portion of the freeze dried powder was chromatographed on a Sephadex LH-20 and a TSK 40F column using a series of aqueous methanol and ethanol-hexane mixture as eluents. The extractives contained a large amount of coumarin derivatives in addition to a small amount of ester compounds such as ligstroside and oleuropein which have not been isolated from this tree species yet. Some spectrometric analyses such as NMR and FAB-MS including TLC were performed to identify the structures of the isolated ester compounds.

• Journal of the Korean Wood Science and Technology
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• v.26 no.4
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• pp.71-77
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• 1998

To elucidate chemical structure of the wood extractive, wood meal of Larix leptolepis Gorden was extracted with 95% ethanol for 72 hours. The extract was fractionated with organic solvents such as n-hexane, chloroform, diethylether, and ethyl acetate. From the hexane somble fraction of the extractives, a new diterpene compound was isolated and identified as 6-acetoxymanool or 13-hydroxy-8(17), 14-labddienyl-6-acetate by IR, $^1H(^{13}C)$-NMR and Mass spectrometry.

• Journal of the Korean Wood Science and Technology
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• v.31 no.6
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• pp.8-14
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• 2003

This study was carried out identify extractives of Amorpha fruticosa. In this study, one flavonoid glycoside, one ester and two rotenoids were isolated from fruits of A. fruticosa. The structures were determined as: kaempferol 7-O-α-L-rhamnopyranoside (I), methyl 3, 4, 5-trihydroxybenzoate (methyl gallate, II), tephrosin (III) and dalbinol (IV), respectively, on the basis of spectroscopic data.

• Proceedings of the Korea Forestry Energy Research Society Conference
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• 1999.04a
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• pp.41-42
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• 1999

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.37 no.3
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• pp.66-73
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• 2005

This study was performed to understand the changes in wood extractives, mainly acetone extracts, in pine woods (Pinus densiflora and Pinus rigida) treated by three blue stain fungi (BSF) such as native BSF in Korea, Leptographium sp., screened Albino strain(BSFcs-1) and commercial Cartapip and fungicide, Wood guard. In addition their pulping and bleaching properties were investigated. BSF treatment has significantly reduced acetone extracts, $25.1{\sim}30.4%$ decreasing in red pine and $22.9{\sim}28.1%$ in pitch pine. Three week aging treatment showed about 20% decreasing in red pine and 19.3% in pitch pine. There were not so significant differences in extracts reduction among native BSF and Albino-type strains (Albino strain, BSFcs-1, and commercial Cartapip). But fungicide, Wood guard, treated wood showed relatively lower decreasing rates of extractives, 14% in red pine and 10.1% in pitch pine. Therefore it is understandable that the fungicide could protect the wood from blue stain fungi attack, but has no effect on its extractive reduction. Concerned to pulping properties of BSF and fungicide treated woods, red pine and pitch pine, optimum pulping condition was 20% active alkali, wood to liquor ratio 1 to 6, $170^{\circ}C$, and 2.5 hr. In the case of BSF woods, optimum pulping condition was same as the sound wood, $43.5{\sim}45%$ of pulp yields and $1.3{\sim}1.45%$ of rejects. Screened pulp yield of fungicide treated wood was lower than those of BSF treated woods. Rejects in pulps were higher in fungicide-treated wood than BSF treated woods. Bleaching pulp yields were ranged of 92 to 93.5%. BSF, Cartapip and fungicide treated woods resulted in lower brightness of $55{\sim}58%$, but Albino-type strain(BSFcs-1) $61.3{\sim}62.3%$, very similar to untreated one. Therefore bleaching chemicals could be saved in the processing of chemical pulping.

• Journal of the Korean Wood Science and Technology
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• v.16 no.2
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• pp.90-97
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• 1988

The rate of utilization of the oak cork (bark of Quercus variabilis Blume) ranges only 40-50%. Therefore, this study was carried out to investigate the chemical properties of the oak cork for increasing the utility. 1) The contents of alkali extractives, organic solvent extractives and ash in the oak cork are similar to those of other barks, but hot and cold water extractives and lignin contents are lower than those of the wood. The carbohydrate (cellulose and hemicellulose) content of the oak cork is similar to that of other barks. The suberin contents in the first and the second bark of the oak cork are 34.8 and 32.2% respectively, in the dry weight. 2) Inorganic component contents of the first bark are similar to those of the second. The pH of the first and the second bark are 3.9 and 4.2%. The caloric values of the first and second bark are 6,263 Kcal/kg, and 5,828 Kcal/kg, respectively, and these caloric values are higher than those of other barks. The sclerencymatous cell content of the first bark which is related to the quality of the oak cork is lower than that of second bark, the contents of the sclerenchymatous cell and lignin show the positive correlation. 3) In the dimension of the cross sectioned cork cell, the first bark is bigger than that of the second. The shape of the cork cell is globular shape in the early bark and discoid shape in the late bark. The cross and the radial section are the same shape, but the tangential section shows difference from the other section.

• Journal of Korea Foresty Energy
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• v.20 no.2
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• pp.1-8
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• 2001

The 90% methanol extracts of eight magnoliaceae plants were collected and tested the cytotoxicity against SK-OV-3 and SiHa cells. Also six pure compounds such as magnonol, honokiol, dihydroxybiphenyl ether, linodenine, anonaine, asimilobine which were previously isolated from Magnolia obovata Thunb. were evaluated the cytotoxicities and their mechanism study using the Lactate dehydrogenase assay(LDH) and FACScan analysis system. Of the tested six compounds, magnonol, honokiol, dihydroxybiphenyl ether showed high cytotoxicities against human cancer cell lines, SK-OV-3 and SiHa cells. In addition, one of the plausible mechanisms of their antitumor activities suggested that they could induce the early stage of apoptosis. For the quantitative analysis, the methanol extractives were fractionated with chloroform, ethylacetate, $H_2O$ and then the ethylacetate fraction was chromatographed on silica gel using n-Hexane ; Acetone(4:1, v/v) as eluent. This fraction was subjected for the quantitative analysis in the HPLC system. The result suggested that the methanol extractives of Magnolia obovata Thunb. contained with magnonol, honokiol, dihydroxybiphenyl ether, 0.9%, 0.3% and 0.24%, respectively.

• Journal of Korean Society of Forest Science
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• v.99 no.2
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• pp.226-234
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• 2010

This study was conducted to examine the effects of pruning season on the compartmentalization of pruning wounds in Acer palmatum and Pinus strobus. A total of eighty five field-grown trees for each species were allocated to five different seasons, early- and late-winter, mid-spring, mid- and late-summer, for pruning treatments. Wound closure rate (WCR) of the two species for one year after treatment, area of discolored stem tissue on the medial longitudinal surface and cambial dieback length under the pruning wound of A. palmatum were measured. Changes of total phenols and variations of extractives, holocellulose and lignin at the treated branch unions were examined. In WCR of A. palmatum, late-winter (March, 39.8%) and mid-spring (May, 39.7%) were higher than any other seasons, while early-winter (November, 28.4%) was significantly lower than late-winter and mid-spring. P. strobus showed similar results with A. palmatum. The WCR of early-winter (57.2%) was the lowest significantly among the five seasons, and mid-spring (73.5%) and late-winter (71.4%) showed higher a WCR than other seasons. In the discolored/wound area ratio of A. palmatum, early-winter (73.2%) was the highest by far, and mid- (July) and latesummer (September, 36.7%, respectively) were the lowest among the five seasons. In the length of cambial dieback, two dormant seasons, early- and late-winter were longer than any other seasons. Phenol contents at the treated branch union were changed in line with the seasonal fluctuation of the tree. Total phenols in the below core of the treated union were higher than those of the branch union with living branch, while little differences were seen in the above core. At the branch core of the treated union, phenols of A. palmatum decreased one month after the treatments, but P. strobus maintained similar to or a little higher than those at the controls. The major changes in chemical composition at pruning wounds were extractives and lignin increased by less than 20% in A. palmatum, while extractives in P. strobus remarkably increased by 70%.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.43 no.3
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• pp.43-51
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• 2011

Chemical composition and contents of carbohydrates, lignin, and extractives in Moso(Phyllostachys pubescens Mazel), Henon(Phyllostachys nigra var. henonis Stapf ex. Rendle), and Timber bamboo(Phyllostachys bambusoides Sieb. et Zucc.) known as economically valuable bamboo species in Korea were analyzed as a function of ages. All of tested bamboo species were composed of fucose, arabinose, rhamnose, galactose, glucose, xylose, and mannose. Glucose was the sugar which showed the highest content followed by xylose. The contents of others were below 3%. Sugar contents of bamboo shoots showed the lowest among the tested bamboo samples, and the constant rates were shown after 50 days of growth. Lignin content increased by the growth of one year, and the increasing rates tended to be constant after the growth of three years. Bamboo shoots have the highest contents of acid-soluble lignin, which turned into insoluble lignin after the growth of 50 days. Bamboo shoots showed the highest content of extractives and tend to be decreased by the growth of 50 days and then the content increased slowly in proportion to the period of bamboo growth. No relationship was found between species and chemical composition of bamboo. However, there were significant difference in chemical composition between bamboo shoots and 50-day old bamboo.