• Title/Summary/Keyword: Extraction of dye

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Extraction Methods for Recovering Malachite Green and Leucomalachite Green (추출방법들에 의한 Malachite Green과 Leucomalachite Green 회수율)

  • Bae, Jin-Han;Yun, Young-Soo;Yoon, Sung-Ho;Choi, Kwang-Jin;Lee, Jeong-Seon;Lim, Chi-Won;Kim, Yeon-Kye;Park, Hee-Yeon
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.41 no.1
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    • pp.13-19
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    • 2008
  • Malachite green (MG), a triphenylmethane dye, is carcinogenic, mutagenic, teratogenic, a respiratory toxin, and causes chromosomal fractures. It is not permitted for use as an aquaculture veterinary drug in a number of countries. Sensitive extraction methods for MG and leucomalachite green (LMG), which have long residence times in fish tissues, were developed. For LMG, the average recovery of liquid extraction (LE) ranged from 41.71 (yellowtail) to 71.60% (snakehead); the recovery of liquid-liquid extraction (LLE) was between 67.68 (yellowtail) and 83.68% (snakehead); and the average recovery of solid-phase extraction (SPE) ranged from 84.16 (yellowtail) to 92.92% (shrimp). The recovery of MG was less than 30% with SPE. However, the dye is found primarily as the colorless reduced leuco form in fish tissues.

Efficiency of Dyes Extraction and Dyeing of Safflower according to pH Condition (pH에 따른 홍화(紅花)의 색소(色素) 추출(抽出)과 염색(染色)의 효율성(效率性)``)

  • Kim, Kyung-Sun;Jeon, Dong-Won;Oh, Ha-Na;Lee, Hye-Yeon
    • Journal of Fashion Business
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    • v.11 no.2
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    • pp.102-112
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    • 2007
  • Effect of the pH condition was examined on extraction and dyeing of the yellow and red dyes of safflower. Absorption of dye solution extracted from safflower was changed by pH of solvent. In the case of yellow dyes, cotton and ramie weren't dyed regardless of pH of dye bath, but silks were significantly dyed at pH4. Raw silk showed better dyeability than refined silk. In the case of red dyes, cotton and ramie absorbed red dyes selectively, but silks absorbed yellow dyes more significantly than red dyes. Efficiency of extraction and dyeing of yellow dyes in acidic range were find out higher than that in neutral range. Red dyes was effectively extracted at pH11 and dyed at pH6.

Dyeing Property and Antimicrobial activity of Protein Fiber Using Terminalia chebula Retzius Extract (가자열매 추출물을 이용한 단백질 섬유의 염색과 항균효과)

  • Nam, Ki Yeon;Lee, Jung Soon
    • Fashion & Textile Research Journal
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    • v.16 no.3
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    • pp.476-484
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    • 2014
  • The purpose of this study was to investigate the dyeing properties and anti-microbial ability of silk and wool fabrics dyed with Terminalia chebula Retzius(TCR) extract using two extraction solvent, hot water and methanol. Dyeing properties of fabrics were studied by investigating the characteristics of colorant, changes in dye uptake under different dyeing conditions, and by investigating color change when mordants were applied. Also, color fastness, and antimicrobial activity of dyed fabrics were estimated. Regardless of extraction solvent type, colorant showed maximum absorption wavelength at 280 nm and 578 nm, which implied that tannin was the major pigment component of TCR. Also, through FT-IR spectrum result, it was confirmed that tannin of TCR methanol extract was hydrolysable tannin. But for the hot water extract, it was only assumed that its tannin was condenced tannin. Fabric dyed with hot water solvent extract showed higher dye uptake than fabric dyed with methanol solvent extract, dye uptake increasing by higher concentration of the dye, longer dyeing time and higher dyeing temperature. And the absorption curve between TCR extract and protein fiber was shaped in the form of Langmuir adsorption isotherm. Fabric dyed without mordant was yellow in color, and when dyed with mordant, fabric showed various colors depending on mordant types except Sn. Color fastness to washing was generally fine and color fastness to light was moderate. But color fastness to rubbing and dry cleaning was outstanding. Lastly, dyed fabrics showed very good antimicrobial activity of 99.9% against Staphylococcus aureus and Kiebsiella pneumoniae.

The Dyeability and Antimicrobial Activity of Methanol Extracted in Artemisia princeps (쑥 메탄올 추출물의 염색성 및 항균성)

  • Kim, Byung-Hee;Song, Wha-Soon
    • Fashion & Textile Research Journal
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    • v.1 no.4
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    • pp.363-369
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    • 1999
  • Artemisia princeps was used for the natural dye stuff extraction and concentration to produce the condensed dye liquid. Using this liquid, the silk and the cotton fabrics were dyed. And then the K/S value, color difference were measured in order to determine the dyeability and the antimicrobial activity. The K/S value of silk were much higher than those of cotton. In terms of the silk fabric, the premordanting method was most efficient of the mordanting method. The various surface colors on the dyed fabric were resulted according to used mordants and mordanting methods. The dye fastness was significantly improved when mordants were added. Among them, Cr-mordant improved more than 1 level. The Cu-mordant showed the greatest antimicrobial activity on both of mordant treated silk and cotton.

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Dyeing of Cellulose Fabric with C. I. Direct Blue 15 by Redox System (직접 염료 Direct Sky Blue 5B(C. I. Direct Blue 15)의 면에 대한 레독스계에서의 염색)

  • 김광오;김정구;이영희;김경환
    • Textile Coloration and Finishing
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    • v.5 no.3
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    • pp.173-181
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    • 1993
  • Dyeing cotton fabric with direct dye (C. I. Direct Blue 15) by redox sytem of ammonium persulfate as an oxidant and glucose as reductant was studied. It was found that covalent bond between dye and cellulose molecule can be formed by free radical produced by the redox system in the dye bath, which enhanced significantly the color strength. The retained color strength after DMF extraction was much better in the presence than in the absence of the redox sytem. The optimum dyeing condition was 0.028 mol/$\ell$(APS/Glucose each) of redox concentration, 65$^{\circle}C$ of dyeing temperature and 60min of dyeing time. The color variation on the dyed sample had not been observed as a result of fixed ${\lambda}_max$.

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The Dyeability and Antimicrobial Activity of Saururus Chinensis(I) (삼백초의 염색성 및 항균성(I))

  • 김병희;송화순
    • Journal of the Korean Home Economics Association
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    • v.38 no.3
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    • pp.1-9
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    • 2000
  • Saururus-chinensis was used for the natural due stuff extraction and concentration to produce the condensed dye liquid. Using this liquid, the silk and the cotton fabrics were dyed. And then the K/S value, color difference were measured in order to determine the dye ability and the antimicrobial activity. The K/S values of silk were much higher than those of cotton. In terms of the silk fabric, the Al, Cr-premordanting and Fe, Cu-simmordanting method was most efficient of the mordanting method. The various suface colors on the dyed fabric were resulted according to used mordants and mordanting methods. The dye fastness was significantly improved when mordants were added. Among them, Al-mordant improved more than 1 level. The Cu, Fe-mordants showed the greatest antimicrobial activity on both of mordant treat silk and cotton.

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The Dyeability of Natural dye Extracted from Chesnut Shell (밤껍질에서 추출되는 천연염료의 염색성 연구)

  • 정영옥
    • Korean Journal of Rural Living Science
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    • v.8 no.2
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    • pp.83-91
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    • 1997
  • In this study, the dyeability of natural dye extracted from chesnut shell was investigated in order to explore the using of discarded chesnut shell in natural dyeing. Dyeing experiments were done in various dyeing conditions which were different in dyeing temperature, concentration of dyebath, dyeing time, repitition of dyeing. pH of dyebath and mordant with 3 kinds of experimental fabrics silk, nylon and cotton. Color and color difference ($\Delta$ E) of every dyed fabrics were measured and color fastness to drycleaning, washing, perspiration and light were measured. The results were as follows ; 1. The dyebath became thicker with time and temperature of extraction and the characteristics of dyebath prepared chesnut shell 1g : distilled water 30㏄ after 3 hrs-boiling were 32,400ppm and 3.7pH. 2. The dyeabilities of silk and nylon fabrics were good and color difference was increased with dyeing temperature, concentration of dyebath, dyeing time, number of repitition and acidity of dyebath. But the dyeability of cotton was very poor compared to silk and nylon. 3. Without the treatment of mordant, the dyeability of silk was little lower than that of nylon, but after the treatment of mordants it became higher than nylon. After the treatment of mordant Cu and Fe, the dyeability of cotton was increased although the natural dye from the chesnut shell was hardly absorved in cotton without mordant. 4. On the whole, the colorfastness of dyed silk and nylon were very good except the colorfastness to washing in silk and the colorfastness to light in nylon.

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Wastewater treatment using a hybrid process coupling adsorption on marl and microfiltration

  • Maimoun, Bakhta;Djafer, Abderrahmane;Djafer, Lahcene;Marin-Ayral, Rose-Marie;Ayral, Andre
    • Membrane and Water Treatment
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    • v.11 no.4
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    • pp.275-282
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    • 2020
  • Hranfa's marl, a local natural mineral, is selected for the decontamination by adsorption of aqueous effluents in textile industry. Its physicochemical characterization is first performed. It is composed mainly of Calcite, Quartz, Ankerite and Muscovite. Its specific surface area is 40 ㎡ g-1. Its adsorption performance is then tested in batch conditions using an industrial organic dye, Bemacid Red E-TL, as a model pollutant. The measured adsorption capacity of Hranfa's marl is 16 mg g-1 which is comparable to that of other types of natural adsorbents. A hybrid process is tested coupling adsorption of the dye on marl in suspension and microfiltration. An adsorption reactor is inserted into the circulation loop of a microfiltration pilot using ceramic membranes. This makes possible a continuous extraction of the treated water provided that a periodic replacement of the saturated adsorbent is done. The breakthrough curve obtained by analyzing the dye concentration in the permeate is close to the ideal one considering that no dye will cross the membrane as long as the adsorbent load is not saturated. These first experimental data provide proof of concept for such a hybrid process.

Dyeing of Silk and Ramie Fabric with Natural Dye(1) - The traditional dyeing method of safflower - (천연 염료에 의한 견 및 모시 염색(1) - 전통 방법에 의한 홍화 염색 -)

  • 정인모;우순옥
    • Journal of Sericultural and Entomological Science
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    • v.37 no.2
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    • pp.161-166
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    • 1995
  • Safflower is natural red dye largely used for dyeing on protein and cellulose fabric. It contains safflower yellow and carthamin red. Safflower yellow is water-soluble dye, while carthamin red is soluble in alkaline condition. Therefore the former was extracted by cold water. Cartamon obtained by adding acidic solution to carthamin red shows the original hue of safflower. In this study, the condition of extraction with bean stem ash solution and dyeing behavior of carthamon in safflower were examined by using the traditional dyeing method. The relationship between the dye-uptake(K/S) of silk and ramie fabric and the various extractions and dyeing conditions was investigated.

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Separation of Chromophoric Substance from Sappanwood under Different Extraction Conditions (염료 추출조건에 따른 소목의 색소성분 분리 거동)

  • Ahn, Cheun-Soon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.31 no.12
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    • pp.1653-1661
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    • 2007
  • The research aimed to establish the standard extraction procedure for examining brazilin, the major chromophoric substance of Sappanwood, using GC-MS with the ultimate goal of identifying the sappanwood dye in severely faded archaeological textiles. The amount of brazilin represented by the GC abundance was the largest when acetone was used as the extraction medium, followed by methanol. Shaking plate operated at room temperature was more effective than the waterbath shaker which was operated at $30^{\circ}C$. In both cases, the extraction method which incorporated one hour pre-soaking before the 12 hours of actual extraction resulted in a larger amount of brazilin detection than the extraction procedure without the one hour pre-soaking. In case of water extraction, pH 5 resulted in the most effective pH level for the extraction of brazilin, The best GC-MS parameter for detecting brazilin was to set the column temperature initially at $50^{\circ}C$. gradually increase to $210^{\circ}C$ at a $23^{\circ}C/min$ rate, finally increase to $305^{\circ}C$ at $30^{\circ}C/min$ rate, and hold for 14 minutes, and the MSD scan range at $75{\sim}400m/z$.