• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.381.1-381.1
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• 2014

In this study, we investigated the deposition behavior and the etch resistivity of plasma polymerized carbon hardmask (ppCHM) film with the variation of process temperature. The etch resistivity of deposited ppCHM film was analyzed by thickness measurement before and after direct contact reactive ion etching process. The physical and chemical properties of films were characterized on the Fourier transform infrared (FT-IR) spectroscope, Raman spectroscope, stress gauge, and ellipsometry. The deposition behavior of ppCHM process with the variation of temperature was correlated refractive index (n), extinction coefficient (k), intrinsic stress (MPa), and deposition rate (A/s) with the hydrocarbon concentration, graphite (G) and disordered (D) peak by analyzing the Raman and FT-IR spectrum. From this experiment we knew an optimal deposition condition for structure of carbon hardmask with the higher etch selectivity to oxide. It was shown the density of ppCHM film had 1.6~1.9 g/cm3 and its refractive index was 1.8~1.9 at process temperature, $300{\sim}600^{\circ}C$. The etch selectivity of ppCHM film was shown about 1:4~1:8 to undoped siliconoxide (USG) film (etch rate, 1300 A/min).

• Publications of The Korean Astronomical Society
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• v.30 no.2
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• pp.443-445
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• 2015

We provide results of near-infrared (NIR) spectroscopic observations of 83 nearby (0.002< z <0.48) and bright (K <14 mag) type 1 active galactic nuclei (AGNs). For the observations, we used the Infrared Camera (IRC) on AKARI allowing us to obtain the spectrum in the rarely studied spectral range of $2.5-5.0{\mu}m$. The $2.5-5.0{\mu}m$ spectral region suffers less dust extinction than ultra violet (UV) or optical wavelength ranges, and contains several important emission lines such as $Br{\beta}$ ($2.63{\mu}m$), $Br{\alpha}$ ($4.05{\mu}m$), and polycyclic aromatic hydrocarbon (PAH; $3.3{\mu}m$). The sample is selected from the bright quasar surveys of Palomar Green and SNUQSO, and AGNs with black hole (BH) masses estimated from reverberation mapping method. We measure the Brackett line properties for 11 AGNs, which enable us to derive BH mass estimators and investigate circum-nuclear environments. Moreover, we perform spectral modeling to fit the hot and warm dust components by adding photometric data from SDSS, 2MASS, WISE, and ISO to the AKARI spectra, and estimate hot and warm dust temperatures of ~1100K and ~220 K, respectively.

• Korean Journal of Optics and Photonics
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• v.22 no.3
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• pp.122-128
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• 2011

The AWG-filtering effect was investigated on a bidirectional 100-GHz-channel-spacing WDM-PON link using spectrum-sliced and RSOA-amplified light sources for downstream signals and a wavelength reuse technique for upstream signals. Signal performances of three different filtering AWGs, including Gaussian, trapezoidal, and rectangular types, were compared on link transmission with fiber nonlinear effects. As an extinction ratio of a downstream signal varied, the effect for both directional signals was analyzed and optimized. It was found that there was an optimal pass bandwidth of an AWG for the balance between relative intensity noise decrement and cross phase modulation noise increment as the bandwidth got wider.

• Korean Journal of Agricultural Science
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• v.22 no.2
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• pp.151-155
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• 1995

Two types of modified celluloses which contain trinitrophenyl groups as chromophore were synthesized from carboxymethyl cellulose Whatman CM 70 and CM 32. Diaminoethyl groups were added to the CM 70 and CM 32 to make DAE-CM celluloses and then the DAE-CM groups were substituted by 2,4,6-trinitrophenyl groups to produce TNP-celluloses. Average particle size of the TNP-cellulose from CM 32 was $44.6{\pm}9.6{\mu}m$ in diameter and $127.9{\pm}22.5{\mu}m$ in length, which was much smaller than those from CM 70, however its TNP-moiety per gram determined by using the molar extinction coefficient $1.33{\times}10^4$ of ${\varepsilon}$-TNP-lysine at 345 nm, was 0.68 millimoles, which was 5.6-fold greater than those from CM 70. The absorption spectrum of TNP-oligosaccharides which were the soluble products of TNP-celluloses by a cellulase preparation Onozuka R-10, showed a maximal peak at 344 nm. Increases in the absorbance during hydrolysis were linear with the enzyme concentration, and the differences of slope values between two types of TNP-celluloses that the more semsitive assay could be achieved by using those from CM 32 as substrate at the low range of the enzyme concentration.

• Journal of the Korean Society of Marine Environment & Safety
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• v.28 no.6
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• pp.843-852
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• 2022

To determine the composition of benthic species on the southwest coast, a macrobenthos study was conducted at 18 sites on the islands of Wando and Jodo for seven summers (2014-2021) from June to September. Two hundred and twenty species(645 ind./m²) were collected on the rocky shores of Wando and Jodo. A similar number of species was observed in Wando (165 species) and Jodo (167 species). The mean density was higher in Wando (726 ind./m²) than in Jodo (564 ind./m²). The number of species was the highest at Site 15 (116 species), and the density was highest at Site 7 (1,664 ind/m²). The dominant species were Nodilittorina radiata with 175 ind./m² (27.1%), Littorina brevicula with 97 ind./m² (15.1%), and Heminerita japonica with 41 ind./m² (6.3%). The climate change indicator species, Tetraclita japonca, appeared in 15 sites, and the endemic species, Ptilohyale bisaeta, appeared in some sites. Fusinus spectrum, which appears on the Red List as a Near Threatened (NT) species, the lowest level of extinction risk, appeared in Jodo. The macrobenthos of Wando and Jodo demonstrated the general characteristics of rocky shores in Korea. Based on the tides and substrate, the rocky shores revealed a vertical distribution trend where Nodilittorina radiata, Littorina brevicula, Chthamalus challengeri, and Reishia clavigera were dominant. Wando and Jodo exhibited similar habitat distribution patterns.

• Journal of Information Display
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• v.3 no.1
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• pp.6-10
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• 2002

We have synthesized a new green Ir(III) complex fac-tris-(3-methyl-2-phenyl pyridine)iridium(III) $Ir(mpp)_3$ and fabricated phosphorescent polymer light-emitting device using it as a triplet emissive dopant in PVK. $Ir(mpp)_3$ showed absorption centered at 388 nm corresponding to the $^1MLCT$ transition as .evidenced by its extinction coefficient of the order of $10^3{\cdot}$ From the PL and EL spectra of the $Ir(mpp)_3$ doped PVK film, the emission maximum was observed at 523 nm, due to the radiative decay from the $^3MLCT$ state to the ground state, confirming a complete energy transfer from PVK to $Ir(mpp)_3$. The methyl substitution has probably caused a red shift in the absorption and emission spectrum compared to $Ir(mpp)_3$. The device consisting of a 2 % doped PVK furnished 4.5 % external quantum efficiency at 72 $cd/m^2$ (current density of 0.45 $mA/cm^2$ and drive voltage of 13.9 V) and a peak luminance of 25,000 $cd/m^2$ at 23.4 V (494 $mA/cm^2$). This work demonstrates the impact of the presence of a methyl substituent at the 3-position of the pyridyl ring of 2-phenylpyridine on the photophysical and electroluminescence properties.

• The Bulletin of The Korean Astronomical Society
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• v.42 no.1
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• pp.54.1-54.1
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• 2017

The UKIRT Wide-field Infrared survey for Fe+(UWIFE) is an unbiased survey of the first Galactic quadrant, with narrow-band filter centered on $1.644{\mu}m$. This survey covers $7^{\circ}$ < l < $62^{\circ}$ and |b| < $1.5^{\circ}$, where active interaction of stars and interstellar medium is expected. With median seeing of 0.8 arcsec, 5 - sigma detection limit of 18.7 mag and surface brightness limit of $8.1{\times}10^{-20}W\;m^{-2}arcsec^{-2}$, this survey gives an opportunity to statistically study Galactic [Fe II] - emitting sources for the first time. In order to identify Ionized Fe Objects (IFOs) in survey area systematically, we conducted visual inspection and automatic detection simultaneously. Total of ~300 extended IFOs are identified, most of them are found out to be part of supernova remnants (SNRs), young stellar objects, HII regions and planetary nebulae. The majority of IFOs are new discoveries which reveal shocked structures in high-extinction region. Spatial distribution of IFOs suggest that they trace Galactic structure. As a part of spectroscopic follow-up, we observed SNR candidate IFO J183740.829-061452.41 with IGRINS (Immersion Grating Infrared Spectrograph, Yuk+2010), mounted on 2.7m Harlan Smith telescope. This unknown arc-like, 6'-long IFO is coincident with inner part of radio continuum loop G25.8+0.2, which has been known as HII region. However, interior of this radio shell is filled with diffuse soft X-ray emission, and possible association of hard X-ray pulsar / pulsar wind nebula makes the nature of the IFO unclear. The H and K-band 2D spectrum shows shock-ionized [Fe II] filaments, which is apart from photoionized HII filaments. In this presentation we present basic statistics of newly identified IFOs, as well as the follow-up study of IFO J183740.829-061452.41.

• Korean Journal of Materials Research
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• v.24 no.8
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• pp.417-422
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• 2014

In this study, we investigated localized surface plasmon resonance and the related coupling phenomena with respect to various geometric parameters of Ag nanoparticles, including the size and inter-particle distance. The plasmon resonances of Ag nanoparticles were studied using three-dimensional finite difference time domain(FDTD) calculations. From the FDTD calculations, we discovered the existence of a symmetric and an anti-symmetric plasmon coupling modes in the coupled Ag nanoparticles. The dependence of the resonance wavelength with respect to the inter-particle distance was also investigated, revealing that the anti-symmetric mode is more closely correlated with the inter-particle distance of the Ag nanoparticles than the symmetric mode. We also found that higher order resonance modes are appeared in the extinction spectrum for closely spaced Ag nanoparticles. Plasmon resonance calculations for the Ag particles coated with a $SiO_2$ layer showed enhanced plasmon coupling due to the strengthened plasmon resonance, suggesting that the inter-particle distance of the Ag nanoparticles can be estimated by measuring the transmission and absorption spectra with the plasmon resonance of symmetric and anti-symmetric localized surface plasmons.

• Bulletin of the Korean Chemical Society
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• v.31 no.12
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• pp.3771-3776
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• 2010

The dynamics of the $CN^-$-ligated ferric cytochrome c (CytcCN) in $D_2O$ at 283 K following Q-band photoexcitation at 575 nm was observed using femtosecond time-resolved vibrational spectroscopy. The equilibrium vibrational spectrum of the CN stretching mode of CytcCN shows two overlapping bands: one main band (82%) at $2122\;cm^{-1}$ with $23\;cm^{-1}$ full width at half maximum (fwhm) and the other band (18%) at $2116\;cm^{-1}$ with $7\;cm^{-1}$ fwhm. The time-resolved spectra show bleaching of the CN fundamental mode of CytcCN and two absorption features at lower energies. The bleach signal and both absorption features are all formed within the time resolution of the experiment (< 200 fs) and decay with a life time of 1.9 ps. One transient absorption feature, appearing immediately red to the bleach signal, results from the thermal excitation of low-frequency modes of the heme that anharmonically couple to the CN fundamental mode, thereby shifting the CN mode to lower energies. The shift of the CN mode decays with a lifetime of 2 ps, equivalent to the time scale for vibrational cooling of the low-frequency heme modes. The other transient absorption feature, which is 3.3 times weaker than the bleach signal and shifted $27\;cm^{-1}$ toward lower energies, is attributed to the CN mode in an electronically excited state where the CN bond is weakened with a lowered extinction coefficient. These observations suggest that photoexcited CytcCN mainly undergoes ultrafast radiationless relaxation, causing photo-deligation of $CN^-$ from CytcCN highly inefficient. As also observed in $CN^-$-ligated myoglobin, inefficient ligand photodissociation might be a general property of $CN^-$-ligated ferric hemes.

• The Bulletin of The Korean Astronomical Society
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• v.36 no.1
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• pp.88.2-88.2
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• 2011

The far-ultraviolet (FUV) continuum and spectral images of C IV and H2 emission lines for the region of Orion-Eridanus Superbubble (OES) are hereby presented and compared with the maps obtained in other wavelengths. While the region shows complex structures, consisting of hot gases and cold dust, a close examination reveals that the FUV emission in this region can be understood reasonably as the result of their interactions. We confirm the origin of most diffuse FUV continuum to be starlight scattered by dust, but we also find that the ionized gas also contributes 50-70% of the total FUV intensity in the regions of H_alpha arcs. We note the bright diffuse FUV continuum in the eastern part of the northern dust-rich region, and attribute it to the bright early-type stars more abundant in this region than in the west as the amount of dust itself does not seem to be much different across 'arc A' that separates the two regions. In addition, two P Cygni-type stars are identified in this eastern region and their peculiar spectral profiles around the C IV emission line are anifested in the scattered diffuse spectrum. Besides this, the C IV emission is generally enhanced at the boundaries of the hot X-ray cavities where thin dust regions are located, confirming the thermal interface nature of the origin of this cooling emission line. The morphology of the H2 emission shows a general correlation with dust extinction features but its intensity peaks are rather located in thin dust areas, off the peak dust regions. Furthermore, H2 emission is seen to be weak in the arc A region though the arc passes through the center of the dust-rich area. Hence, the H2 emission and dust features, together with those of X-ray and ion lines emissions, show stratified structure of arc A quite well, again confirming its thermal interface nature.