• 한국전산유체공학회:학술대회논문집
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• 2008.10a
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• pp.268-275
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• 2008

The prediction of hydrate pellet decomposition characteristics is required to design the regasification process of GTS (gas to solid) technology, which is considered as an economic alternative for LNG technology to transport natural gas produced from small and stranded gas wells. Mathematical model based on the conservation principles, the phase equilibrium relation, equation of gas state and phase change kinetics was set up and numerical solution procedure employing volume averaged fixed grid formulation and extended enthalpy method are implemented. Initially, porous methane hydrate pellet is at uniform temperature and pressure within hydrate stable region. The pressure starts to decrease with a fixed rate down to the final pressure and is kept constant afterwards while the bounding surface of pellet is heated by convection. The predicted convective heat and mass transfer accompanied by the decomposed gas flow through hydrate/ice solid matrix is reported focused on the comparison of spherical and cylindrical pellets having the same effective radius.

• Bulletin of the Korean Chemical Society
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• v.34 no.7
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• pp.2148-2154
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• 2013

Three push-pull organic semiconductors, TPA-$Th_3$-MMN (1), TPA-ThTT-MMN (2), and TPA-ThDTT-MMN (3), comprising a triphenylamine donor and a methylene malononitrile acceptor linked by various ${\pi}$-conjugated thiophene units were synthesized, and the effects of the ${\pi}$-conjugated bridging unit on the photovoltaic characteristics of solution-processed small-molecule organic solar cells based on these semiconductors were investigated. Planar bridging units with extended ${\pi}$-conjugation effectively facilitated intermolecular ${\pi}-{\pi}$ packing interactions in the solid state, resulting in enhanced $J_{sc}$ values of the SMOSCs fabricated with bulk heterojunction films.

• Korean Chemical Engineering Research
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• v.43 no.2
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• pp.187-201
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• 2005

Bioprocessing technologies utilizing 'biorecognition' between a solid matrix and a protein is being widely experimented as a means to replacing the conventional, solution-based technology. Frequently the matrices are chromatographic resins with specific functional groups exposed outside. Since the reactions of and interactions with the proteins occur as they are attached to the solid matrix, this 'solid-phase' processing has distinct advantages over the solution-phase technology. Solid-phase refolding of inclusion body proteins uses ion exchange resins to adsorb denaturant-dissolved inclusion body. As the denaturant is slowly removed from the micromoiety around the protein, it is refolded into a native, three-dimensional structure. Once the refolding is complete, the folded protein can be eluted by a conventional elution technique such as the salt-gradient. This concept was successfully extended to 'EBA (expanded bed adsorption)-mediated refolding,' in which the denaturant-dissolved inclusion body in whole cell homogenate is adsorbed to a Streamline resin while cell debris and other impurity proteins are removed by the EBA action. The adsorbed protein follows the same refolding steps. This solid-phase refolding process shows the potential to improve the refolding yield, reduce the number of processing steps and the processing volume and time, and thus improve the overall process economics significantly. In this paper, the experimental results of the solid-phase refolding technology applied to several biopharmaceutical proteins of various types are presented.

• Transactions of the Society of Information Storage Systems
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• v.6 no.2
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• pp.79-82
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• 2010

In optical imaging systems, such as microscopes, high resolution exposure systems, and optical storage devices, higher optical resolution is a requirement. One of the promising technologies that is able to satisfy this requirement with relatively simple construction and reliable performance are, solid immersion lens (SIL)-based near-field (NF) optical systems. High NA optical systems using annular apertures have been investigated as one solution to achieve higher resolutions and an extended focal depth. By applying an optimized annular aperture to convention SIL optical head resolution can be increased by approximately 20%. This novel SIL-based near-field optics will be verified through experiments such as measuring focused beam spot profiles and observing the topology of a measurement sample. The studied SIL-based near-field optics can be applicable to not only next generation optical storage device but also high resolution microscopy and pattering technologies.

• Transactions of the Korean Society of Automotive Engineers
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• v.11 no.6
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• pp.93-100
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• 2003

This paper describes the thermoelastic instability arising from friction heat generation in braking and proposes the finite element methods to predict the variation of temperature and thermal deformation. In a conventional disc brake analysis, heat generation is only related with wheel speed and friction material and the interface pressure between disc and pad is assumed constant. But under dynamic braking conditions, the frictional heat causes the thermoelastic distortion that leads to more concentrated contact pressure distribution and hence more and more non-uniform temperature. In this paper, to complete the solution of the thermomechanically coupled problem, the linear relation model between pressure and temperature is proposed and demonstrated in examples of a simple two dimensional contact problem. And the two dimensional model has been extended to an annular three dimensional disc model in order to consider more realistic geometry and to provide a more accurate critical speed for automotive brake systems.

• Journal of Powder Materials
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• v.17 no.1
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• pp.59-64
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• 2010

8 mol% Y-doped $SrTiO_3$ powder was synthesized by Pechini method from titanium isopropoxide, strontium nitrate, yttrium nitrate, citric acid and ethylene glycol. A $Y_2Ti_2O_7$ pyrochlore phase-free perovskite powder was obtained by calcining a polymeric resin, which was prepared from a precursor solution, at $500^{\circ}C$ in an air atmosphere. Low temperature calcination could lead to a fine-grained microstructure. In the case of a solid-state reaction, an extended heat-treatment at high temperature in a reduced atmosphere needed to obtain a single phase perovskite $SrTiO_3$.

• Nuclear Engineering and Technology
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• v.50 no.3
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• pp.432-438
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• 2018

The occurrence of saturation in the CR-39 detector reduces and limits its detection dynamic range; nevertheless, this range could be extended using spectroscopic techniques and by measuring the net bulk rate of the saturated CR-39 detector surface. CR-39 detectors were irradiated by 1.5 MeV high alpha-particle fluence varying from $0.06{\times}10^8$ to $7.36{\times}10^8\;alphas/cm^2$ from Am-241 source; thereafter, they were etched in a 6.25N NaOH solution at a temperature of $70^{\circ}C$ for different durations. Net bulk etch rate measurement of the 1.5 MeV alpha-irradiated CR-39 detector surface revealed that rate increases with increasing etching time and reaches its maximum value at the end of the alpha-particle range. It is also correlated with the alpha-particle fluence. The measurements of UV-Visible (UV-Vis) absorbance at 500 and 600 nm reveal that the absorbance is linearly correlated with the fluence of alpha particles at the etching times of 2 and 4 hour. For extended etching times of 6, 10, and 14.5 hour, the absorbance is saturated for fluence values of $4.05{\times}10^8$, $5.30{\times}10^8$, and $7.36{\times}10^8\;alphas/cm^2$. These new methods pave the way to extend the dynamic range of polymer-based solid state nuclear track detectors (SSNTDs) in measurement of high fluence of heavy ions as well as in radiation dosimetry.

• Structural Engineering and Mechanics
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• v.72 no.3
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• pp.329-338
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• 2019

In this paper, the magnetic field influence on the wave propagation characteristics of graphene nanosheets is examined within the frame work of a two-variable plate theory. The small-scale effect is taken into consideration based on the nonlocal strain gradient theory. For more accurate analysis of graphene sheets, the proposed theory contains two scale parameters related to the nonlocal and strain gradient effects. A derivation of the differential equation is conducted, employing extended principle of Hamilton and solved my means of analytical solution. A refined trigonometric two-variable plate theory is employed in Kinematic relations. The scattering relation of wave propagation in solid bodies which captures the relation of wave number and the resultant frequency is also investigated. According to the numerical results, it is revealed that the proposed modeling can provide accurate wave dispersion results of the graphene nanosheets as compared to some cases in the literature. It is shown that the wave dispersion characteristics of graphene sheets are influenced by magnetic field, elastic foundation and nonlocal parameters. Numerical results are presented to serve as benchmarks for future analyses of graphene nanosheets.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.20 no.4
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• pp.501-507
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• 2007

In the first part of this study, the moving least squares finite difference method for solving solid mechanics problems was formulated. This second part verified the accuracy, robustness and effectiveness of the developed method through several numerical examples. It was shown that the method gives excellent convergence rate for elasticity problem. The solution process of elastic crack problems showed the easiness in discontinuity modeling and demonstrates the accuracy and efficiency in finding singular stress solution based on adaptive node distribution. The applicability to the engineering problem with abrupt change in displacement and stresses gradient fields is verified through a localization band problem. The developed method is expected to be extended to the various special engineering problems.

• Journal of the Korean Magnetics Society
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• v.12 no.5
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• pp.179-183
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• 2002

Fe-Si-C alloy system has been made by mechancial alloying process. The structural and magnetic properties were analysed as a function of processing times. The structural properties were investigated by X-ray diffraction and EXAFS experiments. The magnetic properties were measured by vibrating sample magnetometer and M ssbauer spectroscopy. As processing time increases, Si and C atoms diffuse into a ${\alpha}$-Fe structure and then bcc solid solution is formed after 12 hours of the processing time. The magnetization and the hyper fine field decreased steeply up to 4 hours and then it changed slowly. After 12 hours of the processing time, it almost saturated. These results were agreed with the structural variation.