• Journal of the Korean Institute of Gas
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• v.28 no.2
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• pp.76-83
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• 2024

In the semiconductor manufacturing process, the Diffusion process generates various reactive by-products. These by-products are deposited inside the pipes of post-processing and exhaust treatment systems, posing a potential risk of substantial dust explosions. In this study, three methods material verification, selection of analysis samples, and risk analysis were employed to address the substances produced during the Diffusion process. Among the materials handled in the Diffusion process, ZrO₂, TEOD, and E-DEOS were identified as raw material capable of generating by-product dust. Test for Minimum Ignition Energy and dust explosion were conducted on the by-products collected from each processing facility. The results indicated that, in the case of MIE, none of the by-products ignited. However, the dust explosion test revealed that ZrO₂ exhibited a maximum pressure of 7.6 bar and K_st value of 73.3 bar·m/s, its explosive hazard. Consequently, to mitigate such risks in semiconductor processes, it is excessive buildup.

• Journal of the Korean Institute of Gas
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• v.16 no.6
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• pp.87-101
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• 2012

In gas industries, the potential risks of serious accidents have been increased due to high technology application and process complexities. Especially, in case of gas-related accidents, the extent of demage is out of control since gas plants handle and produce combustible, flammable, explosive and toxic materials in large amounts. The characteristics of this kind of disaster is that accident frequency is low, while the impact of damage is high, extending to the neighboring residents, environment and related industries as well as employees involved. The hydrogen gases treated important things and it used the basic material of chemical plants and industries. Since 2000, this gas stood in the spotlight the substitution energy for reduction of the global warming in particular however it need to compress high pressure(more than 150 bar.g) and store by using the special cylinders due to their low molecular weight. And this gas led to many times the fire and explosion due to leak of it. To reduce these kinds of risks and accidents, it is necessary to improve the new safety management system through a risk management after technically evaluating potential hazards in this process. This study is to carry out the quantitative risk assesment for hydrogen filling plant which are very dangerous(fire and explosive) and using a basic materials of general industries. As a results of this risk assessment, identified the elements important for safety(EIS) and suggested the practical management tools and verified the reliability of this risk assessment model through case study of accident.

• Tunnel and Underground Space
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• v.21 no.4
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• pp.320-327
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• 2011

In this study, for stemming effect in blast of the mortar block body, the crushed granite sand as fine aggregate, which is waste rock obtained at the ○○ limestone mine, was investigated to compare with stemming materials such as sea sand, river sand, clayed soil and water can be acquired easily at the field. The mortar block body was manufactured with the dimensions of 50 cm width, 50 cm length and 70 cm height. The direct shear and sieve separator test were performed, and the properties of friction resistance were analyzed by the extrusion test for five stemming materials. Axial strain of steel bar and ejection velocity of stemming materials due to the explosive shock pressure in blasthole with the stemming length of 10 cm and 20 cm in the mortar blast test were measured by the dynamic data acquisition system. Among stemming materials, axial strain showed the largest value at the crushed granite sand as fine aggregate, and the ejection velocity was the smallest value at the stemming of water. The results has shown correlate with harden unit weight in blasthole, particle size distribution, shear resistance, and extrusion strength of stemming materials. The ejection velocity of stemming material at the mouth of blasthole and the axial strain of steel bar in the inside of blasthole tend to be inversely proportional to each other, represent exponentially.

• Journal of the Korean Geotechnical Society
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• v.37 no.10
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• pp.13-25
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• 2021

The most widely used method for determining the blast effects of explosives is the Trauzl test. This test is used to measure the explosive power (strength) of a substance by determining volume increase, which is produced by the detonation of a tested explosive charge in the cavity of a lead block with defined quality and size. In this paper, Trauzl lead block test and High speed 3D-DIC (Digital Image Correlation) system were conducted to evaluate the stemming effect of the blast hole. The effects of stemming materials can be expressed as the expansion of the cavity in a standard lead block through explosion of the explosives. The blasting experiment was conducted with emulsion explosives. The stemming material in the blast hole of lead block, which was adopted in this study, were using sand and stone chips. Results of blasting experiment and numerical analysis showed that the expansion rates of lead block were most affected by stone chips followed by sand. Also, as result of dynamic strain measurement on the lead block surface of High speed 3D-DIC system, the displacement and surface strain on the block were the highest in the experiment case of stone chips stemming.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.4
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• pp.95-102
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• 2012

The serious issue of tall building is to ensure the fire resistance of high strength concrete. Therefore, Solving methods are required to control the explosive spalling. The fire resistant finishing method is installed by applying a fire resistant material as a light-weight material to structural steel and concrete surface. This method can reduce the temperature increase of the reinforcement embedded in structural steel and concrete at high temperature due to the installation thickness control. This study is interested in identifying the effectiveness of light-weight fire protection material compounds including the inorganic admixture such as fly ash, meta-kaolin and light-weight aggregate as the fire resistant finishing materials through the analysis of fire resistance and components properties at high temperature. Also, this paper is concerned with change in microstructure and dehydration of the light-weight fire protection materials at high temperatures. The testing methods of fire protection materials in high temperature properties are make use of SEM and XRD. The study results show that the light-weight fire resistant finishing material composed of fly ash, meta-kaolin and light-weight aggregate has the thermal stability of the slight decrease of compressive strength at high temperature. These thermal stability is caused by the ceramic binding capacity induced by alkali activation reaction by the reason of the thermal analysis result not showing the decomposition of calcium hydrate. Developed light-weight fire protection materials showed good stability in high Temperatures. Thus, the results indicate that it is possible to fireproof panels, fire protection of materials.

• Korean Journal of Materials Research
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• v.22 no.5
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• pp.253-258
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• 2012

Activated magnetite ($Fe_3O_{4-{\delta}}$) was applied to reducing $CO_2$ gas emissions to avoid greenhouse effects. Wet and dry methods were developed as a $CO_2$ removal process. One of the typical dry methods is $CO_2$ decomposition using activated magnetite ($Fe_3O_{4-{\delta}}$). Generally, $Fe_3O_{4-{\delta}}$ is manufactured by reduction of $Fe_3O_4$ by $H_2$ gas. This process has an explosion risk. Therefore, a non-explosive process to make $Fe_3O_{4-{\delta}}$ was studied using $FeC_2O_4{\cdot}2H_2O$ and $N_2$. $FeSO_4{\cdot}7H_2O$ and $(NH_4)_2C_2O_4{\cdot}H_2O$ were used as starting materials. So, ${\alpha}-FeC_2O_4{\cdot}2H_2O$ was synthesized by precipitation method. During the calcination process, $FeC_2O_4{\cdot}2H_2O$ was decomposed to $Fe_3O_4$, CO, and $CO_2$. The specific surface area of the activated magnetite varied with the calcination temperature from 15.43 $m^2/g$ to 9.32 $m^2/g$. The densities of $FeC_2O_4{\cdot}2H_2O$ and $Fe_3O_4$ were 2.28 g/$cm^3$ and 5.2 g/$cm^3$, respectively. Also, the $Fe_3O_4$ was reduced to $Fe_3O_{4-{\delta}}$ by CO. From the TGA results in air of the specimen that was calcined at $450^{\circ}C$ for three hours in $N_2$ atmosphere, the ${\delta}$-value of $Fe_3O_{4-{\delta}}$ was estimated. The ${\delta}$-value of $Fe_3O_{4-{\delta}}$ was 0.3170 when the sample was heat treated at $400^{\circ}C$ for 3 hours and 0.6583 when the sample was heat treated at $450^{\circ}C$ for 3 hours. $Fe_3O_{4-{\delta}}$ was oxidized to $Fe_3O_4$ when $Fe_3O_{4-{\delta}}$ was reacted with $CO_2$ because $CO_2$ is decomposed to C and $O_2$.

• Journal of the Korea Concrete Institute
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• v.22 no.1
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• pp.93-102
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• 2010

Recently, FRP usage for strengthening RC structures in civil engineering has been increasing. Especially, the use of FRP to strengthen structures against blast loading is growing rapidly. To estimate FRP retrofitting effect under blast loading, blast tests with nine $1,000{\times}1,000{\times}150\;mm$ RC panel specimens, which were retrofitted with carbon fiber reinforced polymer (CFRP), Polyurea, CFRP with Poly-urea and basalt fiber reinforced polymer (BFRP) have been carried out. The applied blast load was generated by the detonation of 15.88 kg ANFO explosive charge at 1.5 m standoff distance. The data acquisitions not only included blast waves of incident pressure, reflected pressure, and impulse, but also included central deflection and strains at steel, concrete, and FRP surfaces. The failure mode of each specimen was observed and compared with a control specimen. From the test results, the blast resistance of each retrofit material was determined. The test results of each retrofit material will provide the basic information for preliminary selection of retrofit material to achieve the target retrofit performance and protection level.

• Journal of the Korean Society for Precision Engineering
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• v.25 no.6
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• pp.108-115
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• 2008

The wear on engine valve and seat insert is one of the most important factors affecting engine performance. The engine valve and seat insert must be able to withstand the severe environment that is created by: high temperature exhaust gases generated while the engine is running, rapid movement of the valve spring, high pressure generated in the explosive process. In order to study such problems, a simulator has been developed to generate and control high temperatures and various speeds during motion. The wear simulator is considered to be a valid simulation of the engine valve and seat insert wear process with various speeds during engine activity. This work focused on the test of various degrees of wear on four different exhaust valve materials such as HRV40, HRV40-FNV (face nitrided valve), STL #32, STL #6,. Throughout all tests performed in this study, the outer surface temperature of the seat insert was controlled at $350^{\circ}C$, the cycle number was $4.0{\times}10^6$, the test load was 6860 N, the fuel was LPG the test speed was 20 Hz (2400 RPM) and the seat insert material was HVS1-2. The mean (standard deviation) maximum roughness of the exhaust valve and seat insert was $25.44\;(3.16)\;{\mu}m$ and $27.53\;(3.60)\;{\mu}m$ at the HRV40, $21.58\;(2.38)\;{\mu}m$ and $25.94\;(3.07)\;{\mu}m$ at the HRV40-FNV, $36.73\;(8.98)\;{\mu}m$ and $61.38\;(7.84)\;{\mu}m$ at the STL #32, $73.64\;(23.80)\;{\mu}m$ and $60.80\;(13.49)\;{\mu}m$ at the STL #6, respectively. It was discovered that the maximum roughness of exhaust valve was lower as the high temperature hardness of the valve material was higher under the same test conditions such as temperature, test speed, cycle number, test load and seat insert material. The set of the HRV40-FNV exhaust valve and the HVS1-2 seat insert showed the best wear resistance.

• Journal of the Korean Society of Safety
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• v.34 no.4
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• pp.22-31
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• 2019

The flammable liquid conductivity is an important factor in determining the generation of electrostatic in fire and explosion hazardous areas, so it is necessary to study the physical properties of flammable liquids. In particular, the relevant liquid conductivity in the process of handling flammable liquids in relation to the risk assessment and risk control in fire and explosion hazard areas, such as chemical plants, is classified as a main evaluation item according to the IEC standard, and it is necessary to have flammable liquid conductivity measuring devices and related data are required depending on the handling conditions of the material, such as temperature and mixing ratio for preventing the fire and explosion related to electrostatic. In addition, IEC 60079-32-2 [Explosive Atmospheres-Part 32-2 (Electrostatic hazards-Tests)] refers to the measuring device standard and the conductivity of a single substance. It was concluded that there is no measurement data according to the handling conditions such as mixing ratio of flammable liquid and temperature together with the use and measurement examples. We have developed the measurement reliability by improving the structure, material and measurement method of measuring device by referring to the IEC standard. We have developed a measurement device that is developed and manufactured by itself. The test results of flammable liquid conductivity measurement and the data of the NFPA 77 (Recommended Practice on Static Electricity) Annex B Table B.2 Static Electric Characteristic of Liquids were compared and verified by conducting the conductivity measurement of the flammable liquid handled in the fire and explosion hazardous place by using Measuring / Data Acquisition / Processing / PC Communication. It will contribute to the prevention of static electricity related disaster by taking preliminary measures for fire and explosion prevention by providing technical guidance for static electricity risk assessment and risk control through flammable liquid conductivity measurement experiment. In addition, based on the experimental results, it is possible to create a big data base by constructing electrostatic physical characteristic data of flammable liquids by process and material. Also, it is analyzed that it will contribute to the foundation composition for adding the specific information of conductivity of flammable liquid to the physical and chemical characteristics of MSDS.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.24 no.6
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• pp.699-705
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• 2011

High-maneuver missile is a projectile which demands a strong momentum at short time. To produce a necessary thrust for the flight, the gas of high temperature and pressure is generated through explosive combustion of solid propellant, and a great thrust can be obtained by expanding this high temperature and pressure gas. Although the operating time of a rocket motor is less than a few seconds, a failure of part or ablation near the throat of nozzle may take place during the expansion of high temperature and pressure gas for great thrust. In other words, for the precise control of a missile an exact stress analysis considering both, the thermal stress caused by the heat transfer between combustion gas and wall, and the mechanical stress caused by the pressure change in the flow, should be considered first. In this connection, this study investigated the safety, as a point of view of stress and melting point of the material, of the pre-designed thrust generating structure which is subjected to high temperature and pressure as a function of motor operating time.