• Clean Technology
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• v.26 no.3
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• pp.161-167
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• 2020

For the design of the prevention and mitigation measures in process industries involving flammable substances, reliable safety data are required. An important property used to estimate the risk of fire and explosion for a flammable liquid is the flash point. Flammability is an important factor to consider when developing safe methods for storing and handling solids and liquids. In this study, the flash point data were measured for the binary systems {2-butanol + 2,2,4-trimethylpentane}, {2-butanol + methylcyclohexane} and {2-butanol + toluene} at 101.3 kPa. Experiments were performed according to the standard test method (ASTM D 3278) using a Stanhope-Seta closed cup flash point tester. A minimum flash point behavior was observed in the binary systems as in the many cases for the hydrocarbon and alcohol mixture that were observed. The measured flash points were compared with the predicted values calculated via the following activity coefficient (GE) models: Wilson, Non-Random Two-Liquid (NRTL), and UNIversal QUAsiChemical (UNIQUAC) models. The predicted data were only adequate for the data determined by the closed-cup test method and may not be appropriate for the data obtained from the open-cup test method because of its deviation from the vapor liquid equilibrium. The predicted results of this work can be used to design safe petrochemical processes, such as the identification of safe storage conditions for non-ideal solutions containing flammable components.

• Fire Science and Engineering
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• v.28 no.4
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• pp.1-7
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• 2014

Several complex devices and equipments are installed in the car's engine room, including various kind of oils or other flammable materials. So re-ignition is very likely to take place in it. In addition, it is restrictive for the driver or the occupant to open the bonnet and to spray the fire extinguisher in the engine room due to the high possibility of explosion. Therefore, a fire extinguishing system, which can detect a fire and inject the fire extinguishing agent to extinguish it, and fire extinguishing agents including HFC-227ea, which can stand the high temperature within the engine room and hold the viscosity sufficient to keep it in the kind of foam, were developed and tested. And the suffocation effect and the cooling effect come from the fire extinguishing principle of the foam fire extinguishing agent and the inhibiter catalyst effect come from the one of HFC-227ea was led simultaneously, and fire extinguishing agents without the secondary damage caused by residuals after the fire extinguishment like a case of the powder fire extinguishing agent, were developed. And experiments using a vehicle collision after the discharge is complete, foreign material can be removed without extinguishing the advantage that experimental results obtained.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.36 no.5
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• pp.891-901
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• 2016

By comparing test blasting data experimented in three layered-structure polymorphic grounds to a geological profile, influence of blast vibration with respect to uncontrollable ground characteristics was analyzed. Inefficient blast have been performed without sufficient verifications or confirmations because insufficiencies with regard to experiments and data of blasting engineering on the layered structures to be irregularly repeated clinker layer consisted of volcanic clastic zones. It is difficult to quantify N values of clinkers within test blasting region because they have diverse ranges, or coverages. An absolute value of attenuation coefficient N in a field, estimated by blasting vibration predictive equation (SRSD), are lesser than criteria of a design instruction, meaning that vibrations caused by blast can spread far away, and the vibrational characteristics of blasting test No.1, indicating relatively small values, inferred by the geological profile, pressures of gas by the explosion may be lost into a widely distributed clinker layers by penetrating holes resulted from blast into vicinity of clinker layers located in bottom of soft rock layers at the moment of blast. As a result, amounts of spalling rocks are decreased by almost half. Also, ranges of primary frequencies in the fields are identified as similar to those of natural frequency of typical structures.

• Fire Science and Engineering
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• v.15 no.1
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• pp.16-22
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• 2001

Thermal properties of PP and LLDPE dusts from chemical plant and their risks of coexisting with oxidizer were investigated by a pressure vessel. The thermal decomposition of PP and LLDPE dusts with temperature using DSC and the weight loss with temperature using TGA were also investigated to find the thermal hazard of PP and LLDPE dusts. Using the pressure vessel which can estimate ignition and explosion of PP and LLDPE dusts coexisting with oxidizer, a series of bursting of a rupture disc, experiments has been conducted by varying the orifice diameters the weight ratio of the sample coexisting with oxidizers and the species of oxidizer. And fire gases was measured by gas analyser ($ECOM-A^+$). According to the results of the thermal analysis of PP and LLDPE dusts, the decomposition temperature range of PP and LLDPE dusts was 200 to 350 and 300 to $500^{\circ}c$, respectively. The risk of PP and LLDPE dusts coexisting with oxidizer was increased as the orifice diameter was decreased. On the other hand, it was increased as the weight ratio of the sample to the oxidizer were increased. In addition, the risk of PP and LLDPE dusts coexisting with oxidizer was affected by the decomposition temperature of the sample and oxidizer. It is found that the risk of fire becomes high when the decomposition temperature of the sample is about same as that of oxidizer. Also, the fire gases was occurred carbon monoxide and carbon dioxide. The amount of carbon monoxide generated was found to be much higher in PP decomposition than in LLDPE due to incomplete combustion of PP which has high content of carbon in chemical compound.

• Korean Journal of Optics and Photonics
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• v.29 no.3
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• pp.119-125
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• 2018

Hydrogen gas is an important and promising energy resource that has no emissions of pollutants during power generation. However, hydrogen gas is very dangerous because it is colorless, odorless, highly flammable, and explosive at low concentration. Conventional techniques for hydrogen gas detection are very difficult for measuring the hydrogen gas distribution at long distances, because they sample the gas to measure its concentration. Raman lidar is one of the techniques for remotely detecting hydrogen gas and measuring the range of the hydrogen gas distribution. A Raman lidar system with an on-axis optical receiver was developed to improve the range of hydrogen gas detection at long distance. To verify the accuracy and improvement in the range of detecting the hydrogen gas, experiments measuring the hydrogen gas concentration are carried out using the developed on-axis Raman lidar system and a gas chamber, to prevent explosion of the hydrogen gas. As a result, our developed on-axis Raman lidar system can measure a minimum hydrogen gas concentration of 0.66 volume percent at a distance of 50 m.

• The Journal of Engineering Geology
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• v.6 no.3
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• pp.137-153
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• 1996

The purpose of this study is to investigate the possibilities of identifying and detecting underground cavities using seismic waves recorded by the fixed and mobile stations. During 18 months of field work we recorded chemical explosions near the Bongdarn station. Seismic Stations were installed on the free surface and underground inside the Samba mine. The seismograms at the fixed(lorg-term) seismic station show abrupt change of polarization characteristics which can he associated with the appearance of P-to-S converted phase(PS) at 150 ~ 200 msec after the first P arrival. This result indicates that converted phases are generated very near to the Bongdarn station at a depth of 190m. Shear-wave splitting phenomena have also been observeci The time delay between fast shear(fS) and slow shear(sS) waves ranges between 30 and 60 msec(average is 42 msec). However, exact time delay between the fast and the slow shear waves can not be accurately measured because of the very short time delay and limitation of sampling rate. Chemical explosion experiments were recorded at stations along various paths to contrast the seismic response of areas with and without cavities. The seismograms recorded at the stations installed at cavity areas show an abrupt change of polarization characteristics but not on the other stations. Seismic waves propagating through the cavity are characterized by the attenuation of high frequency waves and predominantly low frequency seismic waves after the S wave arrivals.

• Journal of the Korea Institute of Information Security & Cryptology
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• v.29 no.5
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• pp.1039-1048
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• 2019

Symbolic execution, an automatic search method for vulnerability verification, has been technically improved over the last few years. However, it is still not practical to analyze the program using only the symbolic execution itself. One of the biggest reasons is that because of the path explosion problem that occurs during program analysis, there is not enough memory, and you can not find the solution of all paths in the program using symbolic execution. Thus, it is practical for the analyst to construct a path for symbolic execution to a target with vulnerability rather than solving all paths. In this paper, we propose a static analysis - based backward CFG(Control Flow Graph) generation technique that can be used in symbolic execution for program analysis. With the creation of a backward CFG, an analyst can select potential vulnerable points, and the backward path generated from that point can be used for future symbolic execution. We conducted experiments with Linux binaries(x86), and indeed showed that potential vulnerability selection and backward CFG path generation were possible in a variety of binary situations.

• Journal of the Korean Electrochemical Society
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• v.22 no.4
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• pp.139-147
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• 2019

Lithium-ion battery (LiB) with high energy density and efficiency has been utilized for the electric vehicle (EV) and energy storage system (ESS) as well as portable devices. However, as explosion accidents have frequently happened till lately, all-solid-state lithium secondary battery (ALSB) began to get in a spotlight because it can secure a very high safety and energy density by substituting flammable organic liquid electrolyte to nonflammable inorganic solid electrolyte. In spite of ALSB's certain merits, it has shown much poorer performance of cells than one of LiB due to some challenges, which have been small or never dealt with in the LiB system. Hence, although plenty of studies made progress to solve them, an approach about design of all-solid-state electrode (ASSE) has been limited on account of difficulty of ALSB's experiments. That is why the virtual 3D structure of an all-solid-state electrode has to be built and used for the prediction of cell performance. In this study, we elucidate how to form the 3D ASSE structure and what to be needed for the simulation of characteristics on ALSB. Furthermore, the ultimate orientation of 3D modeling and simulation for the study of ALSB are briefly suggested.

• Journal of Conservation Science
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• v.37 no.6
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• pp.821-830
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• 2021

The weapons excavated from the de-militarized zones (DMZ) of Korea are vulnerable to corrosion due to the immediate and drastic environmental change. Especially, the chloride ions (Cl^-) in iron weapons cause active corrosion and require removal. In this study, conservation treatment and de-salination was performed for the discovered weapons from excavation sites of soldiers killed in action during the Korean War. Furthermore, an attempt was made to prepare the most stable plan for conservation treatment through the comparative study of soaking weapons in distilled water without chemicals and in a solution of sodium (SSC) at different temperatures. In the preliminarily experiments, the comparison of the eluted Cl^- ions according to different conditions of de-salination showed that the highest number of ions were detected from the de-salination with SSC at a temperature of 100℃, and its duration was much smaller, i.e., 1~2 weeks. Accordingly, for the parts from the guns and rifles amongst other objects, a six-time de-salination was conducted in the SSC solution for 8 hours at 100℃ and subsequently, for 16 hours at room temperature during which the distilled water and SSC were exchanged every week. However, in the case of a loaded rifle, the de-salination was not conducted, considering the risk that the high temperature and pressure by impregnation in vacuum could cause an explosion

• Journal of the Computational Structural Engineering Institute of Korea
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• v.36 no.6
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• pp.355-364
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• 2023

The arbitrary Lagrangian-Eulerian (ALE) method has been extensively researched owing to its capability to accurately predict the propagation of blast shock waves. Although the use of the ALE method for dynamic analysis can produce unreliable results depending on the mesh size of the finite element, few studies have explored the relationship between the mesh size for the air domain and the accuracy of numerical analysis. In this study, we propose a procedure to calculate the optimal mesh size based on the mean squared error between the maximum blast pressure values obtained from numerical simulations and experiments. Furthermore, we analyze the relationship between the weight of explosive material (TNT) and the optimal mesh size of the air domain. The findings from this study can contribute to estimating the optimal mesh size in blast simulations with various explosion weights and promote the development of advanced blast numerical analysis models.