• 제목/요약/키워드: Explosion Limit

검색결과 186건 처리시간 0.03초

n-Hexadecane의 폭발하한계 예측 (The Prediction of Lower Explosion Limit of n-Hexadecane)

  • 하동명;박상훈
    • 한국화재소방학회:학술대회논문집
    • /
    • 한국화재소방학회 2013년도 춘계학술대회 초록집
    • /
    • pp.163-163
    • /
    • 2013
  • 최근의 수많은 산업 현장에서 취급하고 있는 각종 화학물질은 잠재적 위험성이 크므로 보관, 수송 및 취급할 때 특별한 주의가 필요하다. 공정 설계 시 정확하지 않은 폭발한계를 사용함으로서 사고가 유발되는 경우가 많다. 따라서 사업장에서 사용되고 있는 화학물질의 화재 및 폭발 특성치인 인화점, 폭발한계 등을 정확히 파악하는 것은 중요하다. 인화점은 하부인화점과 상부인화점으로 나누고 있고 있으며, 인화점은 가연성 액체의 화재 위험성을 나타내는 지표로써, 가연성액체의 액면 가까이서 인화할 때 필요한 증기를 발산하는 액체의 최저온도 또는 점화원 존재시 인화가 일어날 수 있는 최저온도, 그리고 가연성증기의 포화증기압이 공기와 혼합기체의 폭발한계 하한농도와 같게 되는 온도로 정의한다. 폭발한계는 발화원이 존재할 때 가연성가스와 공기가 혼합하여 일정 농도범위 내에서만 연소가 이루어지는 혼합범위를 말한다. 본 연구에서는 실제 공정에서 사용되고 있는 n-Hexadecane의 인화점을 측정하여 이를 기존 문헌값과 비교 하였고, 측정된 인화점을 이용하여 폭발한계를 예측하였다. 예측된 폭발한계를 여러 문헌에 제시된 자료과 비교하여 공정안전에 타당한 자료를 제시하였다. 본 연구는 n-Hexadecane을 취급하는 공정에서 안전 확보의 중요한 지침 마련과 MSDS D/B의 최신화에 유용한 정보를 제공하는데 목적이 있다.

  • PDF

연속 레이저 흡수에 의한 증발제거 과정의 관련 인자 영향 고찰 (Effect of Parameters in Evaporative Removal Process by Absorption of a CW Laser)

  • 김진윤;송태호
    • 대한의용생체공학회:의공학회지
    • /
    • 제16권1호
    • /
    • pp.67-76
    • /
    • 1995
  • Explosive evaporative removal process of biological tissue by absorption of a CW laser has been simulated by using gelatin and a multimode Nd: YAG laser. Because the point of maximun temperature of laser-irradiated gelatin exists below the surface due to surface cooling, evaporation at the boiling temperature is made explosively from below the surface. The important parameters of this process are the conduction loss to laser power absorption (defined as the conduction-to-laser power parameter, Nk), the convection heat transfer at the surface to conduction loss (defined as Bi), dimensionless extinction coefficient (defined as BrJ, and dimensionless irradiation time (defined as Fo). Dependence of Fo on Nk and Bi has been observed by experiment, and the results have been compared with the numerical results obtained by solving a 2-dimensional conduction equation. Fo and explosion depth (from the surface to the point of maximun temperature) are increased when Nk and Bi are increased. To find out the minimum laser power for explosive evaporative removal process, steady state analysis has been also made. The limit of Nk to induce evaporative removal, which is proportional to the inverse of the laser power, has been obtained.

  • PDF

LPG 판매업소의 위험성 제어계획 (Planning for Safety Control on LPG Distribution Depot)

  • 노삼규;전성우;강태희;서영민
    • 한국화재소방학회논문지
    • /
    • 제12권4호
    • /
    • pp.21-30
    • /
    • 1998
  • LPG 판매업소의 용기보관창고는 보관량이나 위해 상황을 충분히 고려하지 않은 상태로 단순히 방폭벽 구조에 의한 안전규제에 의존해 왔다 따라서 LPG폭발로 인한 보관창고 의 안전규정은 안전완충거리를 충분히 확보하고 있는지 확인할 필요가 있다. 기존의 안전 규제는 그러한 보관창고로부터 사고시 인근에 위치한 구조물과 연간 활동에 미치는 잠재 적 초과압력이나 방출열의 정도를 고려하고 있는지 그 확인이 요구된다. 본 연구는 P PHAST와 IAEA의 위험성 평가와 우선 순위 선정수법, 일본의 LPG 판매소 안전규정 등 을 통하여 안전거리를 산출하였다. 이 결과에 의하면 기존의 LPG판매소의 방폭벽은 추가 적인 안전거리가 요구된다.

  • PDF

폭발.연소 에너지의 개발 방향에 관한 연구 (A Study on the Development Trend of Explosion and Combustion Energy)

  • 신창용;안명석;조명찬
    • 화약ㆍ발파
    • /
    • 제27권2호
    • /
    • pp.56-60
    • /
    • 2009
  • 물리학적 측면에서 에너지의 개념은 일하는 능력으로 정의된다. 기존의 석탄 석유등 화석연료를 대체하기 위해 1980년 이후부터 천연가스 원자력 등의 사용이 증가하였으나 환경오염문제로 태양열 풍력 조력 지열 등 대체에너지로의 전환을 촉진하고 있다. 그러나 에너지 이용효율 측면에서는 원자력 에너지와 화약 가스 등 화학에너지와는 비교가 되지 않는다. 본 논문에서는 환경(대체)에너지의 한계점을 뛰어 넘을 수 있는 방안을 연구하기 위하여 그린에너지의 현황을 조사하였으며, 고효율 에너지원에 대한 청정화와 응용 및 개발방향에 대해 검토, 연구 하였다.

행렬구조 메모리 참조표를 사용한 페트리네트 제어기의 하드웨어 구현 (Hardware implementation of Petri net-based controller with matrix-based look-up tables)

  • 장래혁;정승권;권욱현
    • 제어로봇시스템학회논문지
    • /
    • 제4권2호
    • /
    • pp.194-202
    • /
    • 1998
  • This paper describes a hardware implementation method of a Petri Net-based controller. A flexible and systematic implementation method, based on look-up tables, is suggested, which enables to build high speed Petri net-based controllers. The suggested method overcomes the inherent speed limit that arises from the microprocessors by using of matrix-based look-up tables. Based on the matrix framework, this paper suggests various specific data path structures as well as a basic data path structure, accompanied by evolution algorithms, for sub-class Petri nets. A new sub-class Petri net, named Biarced Petri Net, resolves memory explosion problem that usually comes with matrix-based look-up tables. The suggested matrix-based method based on the Biarced Petri net has as good efficiency and expendability as the list-based methods. This paper shows the usefulness of the suggested method, evaluating the size of the look-up tables and introducing an architecture of the signal processing unit of a programmable controller. The suggested implementation method is supported by an automatic design support program.

  • PDF

마이크로파가 인가된 화염에서의 화염안정성 및 오염물질 배출특성 (Characteristics of the Microwave Induced Flames on the Stability and Pollutant Emissions)

  • 전영훈;이의주
    • 한국안전학회지
    • /
    • 제29권4호
    • /
    • pp.23-27
    • /
    • 2014
  • The use of electromagnetic energy and non-equilibrium plasma for enhancing ignition and combustion stability is receiving increased attention recently. The conventional technologies have adapted the electrical devices to make the electromagnetic field, which resulted in various safety issues such as high-maintenance, additional high-cost system, electric shock and explosion. Therefore, an electrodeless microwave technology has an advantage for economic and reliability compared with conventional one because of no oxidation. However, the application of microwave has been still limited because of lack of interaction mechanism between flame and microwave. In this study, an experiment was performed with jet diffusion flames induced by microwaves to clarify the effect of microwave on the combustion stability and pollutant emissions. The results show that microwave induced flames enhanced the flame stability and blowout limit because of abundance of radical pool. However, NOx emission was increased monotonically with microwave intensity except 0.2 kW, and soot emission was reduced at the post flame region.

대용량 이차전지 보호 시스템용 전류 감지 동작형 보호소자의 저융점 금속 가용체 설계 (Design of Low-Melting Metal Fuse Elements of Current Sensing Type Protection Device for Large Capacity Secondary Battery Protection System)

  • 김은민;강창룡
    • 한국전기전자재료학회논문지
    • /
    • 제31권6호
    • /
    • pp.427-432
    • /
    • 2018
  • High-capacity secondary batteries can cause explosion hazards owing to microcurrent variations or current surges that occur in short circuits. Consequently, complete safety cannot be achieved with general protection that is limited to a mere current fuse. Hence, in the case of secondary batteries, it is necessary for the protector to limit the inrush current in a short circuit, and to detect the current during microcurrent variations. To serve this purpose, a fuse can be employed for the secondary battery protection circuit with current detection. This study aims at designing a protection device that can stably operate in the hazardous circumstances associated with high-capacity secondary batteries. To achieve the said objective, a detecting fuse was designed from an alloy of low melting point elements for securing stability in abnormal current states. Experimental results show that the operating I-T and V-T characteristic constraints can be satisfied by employing the proposed current detecting self-contained low melting point fuse, and through the resistance of the heating resistor. These results thus verify that the proposed protection device can prevent the hazards of short circuit current surges and microcurrent variations of secondary batteries.

가연성물질의 폭발한계에 관한 연구 - 용액열역학 및 MRSM 모델에 의한 3성분계 폭발한계 - (A Study on Explosive Limits of Flammable Materials - Explosive Limits of Ternary System by Means of Solution Thermodynamics and MRSM Model -)

  • 하동명
    • 한국안전학회지
    • /
    • 제20권3호
    • /
    • pp.91-97
    • /
    • 2005
  • The research on the explosive limits is one of fundamental fields of combustion process, and information on the explosive limits of mixture of fuel and oxidant, with or without additives, is very important for the prevention in industrial fire and explosion accidents. Explosive limits of all compounds and solvent mixtures can be calculated with the appropriate use of the fundamental laws of Raoult, Batten, Le Chatelier and MRSM(modified response surface methodology) model. In this study, the reference values of lower explosive limits(LEL) of the ethanol+toluene+ethylacetate system were compared with the calculated values by using the solution thermodynamics and the MRSM model, respectively. The values calculated by the proposed equations were a good agreement with literature data within a few percent. By means of this methodology, it is possible to evaluate reliability of experimental data of the lower explosive limits of the flammable mixtures. Also, from given results, it is possible to predict explosive limits of the other flammable liquid mixtures used in the chemical process by the use of the proposed equations.

휴대용 이차전지 보호 시스템용 전류 감지 동작형 보호소자의 퓨즈 가용체 설계 (Design of Fuse Elements of Current Sensing Type Protection Device for Portable Secondary Battery Protection System)

  • 강창룡;김은민
    • 전기학회논문지
    • /
    • 제67권12호
    • /
    • pp.1619-1625
    • /
    • 2018
  • Portable electronic devices secondary batteries can cause fire and explosion due to micro-current change in addition to the situation of short-circuit inrush current, safety can not be secured with a general operation limited current fuse. Therefore, in secondary battery, it is necessary for the protector to satisfy both the limit current type operation in the open-short-circuit inrush current and the current detection operation characteristic in the micro current change situation and for this operation, a fuse for the current detection type secondary battery protection circuit can be applied. The purpose of this study is to design a protection device that operates stably in the hazardous situation of small capacity secondary battery for portable electronic devices through the design of low melting fuse elements alloy of sensing type fuse and secures stability in abnormal current state. As a result of the experiment, I-T and V-T operation characteristics are satisfied in a the design of the alloy of the current sensing type self-contained low melting point fuse and the resistance of the heating resistor. It is confirmed that it can prevent accidents of short circuit over-current and micro current change of secondary battery.

국내 철도 위험물 운송 시 격리차 운영기준 안전성 검증 (Verification on Separation Distance Criteria when Transporting Dangerous Goods in Korea Railroad)

  • 이병우;박다성;강태선;정승호
    • 한국안전학회지
    • /
    • 제34권2호
    • /
    • pp.28-33
    • /
    • 2019
  • After the Tianjin Port explosion on 2015, it is highlighted that securing safety for dangerous goods in Korea and try to establish safety standards for railroad dangerous substances transport. In Korea, the regulation for the transport of dangerous goods is stipulated to need 3 buffer cars. However, It is inefficient that 3 buffer cars. because 3 buffer cars, increase transportation too much costs in transit and it is too strict compared to other country rules. The purpose of this study was to improve transportation efficiency by mitigating the criteria for isolated railroads through rational safety assessment. In order to verify this, we used a risk assessment software which is PHAST 7.2 developed by DNV GL. We calculated safety distances that could prevent ignitions setting up scenarios when relief system work installed on a train loaded with propylene, nonane. As a result, we confirmed that buffer cars can be reduced from three to one. This result would be implemented in the application of Korail.