• Title/Summary/Keyword: Exfoliation

Search Result 396, Processing Time 0.033 seconds

Investigation and Assessment of the Deterioration on Aging Large Water Mains (대형 상수관로 노후상태 조사 및 평가에 관한 연구)

  • Kim, Ju-Hwan;Bae, Chul-Ho;Kim, Jung-Hyun;Hong, Sung-Ho;Lee, Kyung-Jae
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.20 no.4
    • /
    • pp.545-558
    • /
    • 2006
  • The current conditions of large water mains are evaluated by deteriorations and the causes of deterioration are investigated through visual assessments in the field, mechanical tests and analysis of chemical compositions in laboratory for each pipe material, unlined cast iron pipes (CIPs), ductile iron pipes (DCIPs) and steel pipes (SPs) Tubercles and scales from internal and external corrosion of unlined cast iron pipes were identified as the causes of functional performance limitations in large water mains. It is investigated that main causes of internal and external corrosion of water pipes are from lots of depositions of organic and inorganic substances on pipe surface, concentrated pitting, and uniform corrosion by local or global exfoliation or detachment of lining and coatings of DCIPs and SPs. Internal and external corrosion depths of CIPs were higher than those of DCIPs and SPs. Consequently, total corrosion rate summed internal and external corrosion rates of CIPs also were shown to be higher than those of DCIPs and SPs. The failure time from hole generation of CIPs by total corrosion rate was predicted to be taken sixteen years, and DCIPs and SPs were twenty-six years and one hundred and fifty three years. And longitudinal deflection of investigated water mains were not happened and mechanical strengths such as tensile strength, elongation, and hardness also were mostly suited to Korea Standards. It was thought that the weakness of tensile strength of one sample(S-11) was, however, due to higher carbon contents(%) in CIPs. Pipe deterioration score of S-46 was 55.2 and was preferentially assessed to be rehabilitated.

Pneumonia due to tooth-like foreign body aspiration in a child with seizure disorder (경련성 질환을 가진 장애 아동에서 치아로 추정되는 이물질 흡인에 의한 폐렴)

  • Park, Minji;Lee, Ko-Eun;Lee, Jae-Ho
    • The Journal of Korea Assosiation for Disability and Oral Health
    • /
    • v.14 no.1
    • /
    • pp.26-30
    • /
    • 2018
  • Aspiration of tooth can occur not only during dental treatment, but also due to factors like trauma or physiologic exfoliation of primary tooth. If this occurs, complications such as fever, cough, dyspnea, pain, and bronchitis can be appeared. 9 years-old girl with Lennox-Gastau syndrome visited the dental clinic for regular checkups. Calcified tooth-like material was observed in the chest PA x-ray, and maxillary left primary first molar was not observed in the patient's oral cavity. She had a history of hospitalization for pneumonia two months ago. Because it was considered that the tooth was likely to be aspirated and caused pneumonia, the extraction of remaining primary teeth with mobility was performed. It is necessary to reduce the risk of aspiration in patient with disabilities by performing active treatment such as removal of primary tooth with mobility or ill-fitting restorations.

TREATMENT OF CLASS Ⅲ MALOCCLUSION WITH HORSESHOE APPLIANCE : CASE REPORT (Horseshoe Appliance를 이용한 Ⅲ급 부정교합의 치험례)

  • Hong, Han-Young;Park, Jae-Hong;Choi, Yeong-Chul;Kim, Kwang-Chul
    • Journal of the korean academy of Pediatric Dentistry
    • /
    • v.35 no.2
    • /
    • pp.376-381
    • /
    • 2008
  • In mixed dentition there exists many empty spaces in the arch due to eruption of permanent teeth and exfoliation of primary teeth. The empty spaces makes it difficult to apply fixed orthodontic appliances. Horseshoe Appliance can be used effectively at this stage, holding the whole dentition in one piece. It covers every surface of erupted teeth and prevents extrusion and rotation of single tooth. By using intermaxillary elastic force, remodeling of the alveolar bone is opposite in each arch. In patients who were treated with horseshoe appliance, forward growth of maxilla, labioversion of maxillary incisors and linguoversion of mandibular incisors were obtained. Minimum downward and clockwise rotation of mandible was shown, so increasing anterior facial height was minimized.

  • PDF

Quantitative Distribution of Created Voids by Applying General Flame and DC Short-circuit Current to 2.5 mm2 HIV (2.5 mm2 HIV에 일반화염 및 DC 단락 전류를 인가하여 생성된 기공의 정량적 분포 해석)

  • Kim, Seung-Sam;Choi, Chung-Seog
    • Journal of the Korean Society of Safety
    • /
    • v.28 no.4
    • /
    • pp.38-42
    • /
    • 2013
  • This study performed the quantitative distribution analysis of created voids to an insulator when applying general flame and DC short-circuit current to 2.5 $mm^2$ HIV (600 V Grade Heat-Resistant Polyvinyl Chloride Insulated Wires). The diameter of cross-section of HIV normal product and the radius of conductor were measured to be 3.3 mm and 1.8 mm. The exterior of HIV exposed to general flame showed severe carbonization and its interior exhibited voids created by dechlorination reaction. This study observed the characteristics that, when the shortcircuit current applied for 2 seconds from a DC 12 V lead battery, the conductor and neighboring insulator were melted, causing the insulator adhering to the conductor. On average, 87 voids were created on 10 mm of the HIV. The average diameter of voids was 0.25 mm. In addition, it was found that, when the short-circuit current applied for 4 seconds, the interior of insulator in contact with conductor severely carbonized and showed exfoliation phenomenon. On average, 47 voids were created, with more voids at the bottom. The average diameter of voids was 0.20 mm. When the short-circuit current for 6 seconds, most parts of upper part of conductor was carbonized, 20 voids were created. The average diameter of voids was measured to be 0.24 mm. It could be seen that the created voids received little influence by the type of energy source and the number of created voids was reduced as the energy supply time increased.

Thermal Chemical Vapor Deposition법으로 성장된 MoS2 박막의 물리적 특성 분석

  • Chu, Dong-Il;Lee, Dong-Uk;Kim, Eun-Gyu
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2014.02a
    • /
    • pp.376.1-376.1
    • /
    • 2014
  • 그래핀은 차세대 2차원 물질로서 지금까지 활발히 연구되어 왔으나 밴드갭이 없기 때문에 전자소자로서의 응용이 매우 제한적이다. 최근에 그래핀을 대체할 수 있는 물질로서 Transition Metal Dichalcogenides (TMDs)가 주목을 받고 있다. 특히, TMDs 중에서 $MoS_2$는 bulk일 때 indirect한 1.2 eV인 밴드 갭을 갖고 있으나, layer가 줄어들면서 direct한 1.8 eV인 밴드갭을 가진다. 국내외 여러 연구 그룹에서 $MoS_2$를 이용하여 제작한 Field Effect Transistor (FET)는 high-$\small{K}$ gate가 산입되지 않은 경우에 on-off ratio와 mobility가 각각 $10^6$와 약 $3cm^2/Vs$로 나타나고 있다. 이와 같이 아주 우수한 전기적, 광학적 특성을 갖는 소자 응용성을 가지고 있다. 최근까지의 연구결과들은 대부분 mechanical exfoliation method (MEM) 로 제작된 $MoS_2$ monolayer를 이용하였으나, 이 방법은 large scale 및 layer controllable에는 적합하지 않다. 본 연구에서는 대면적의 집적회로 응용에 적합한 chemical vapor deposition법을 이용하여 $MoS_2$를 성장하였다. 높은 결정성을 위해 sulphur (powder purity 99.99%)와 molybdenum trioxide(powder purity 99.9%)를 이용하고, Ar 가스 분위기에서 sulphur powder 및 molybdenum trioxide powder를 각각 $130^{\circ}C$$1000^{\circ}C$로 유지하며 $MoS_2$ 박막을 성장하였다. 성장된 $MoS_2$ 박막은 Atomic force Microscopy (AFM)을 통해 박막의 단차와 roughness을 확인하였다. 또한, X-ray Diffraction (XRD) pattern 분석으로 박막의 결정성을 확인하였으며, Raman Spectroscopy, X-ray Photoelectron Spectroscopy (XPS), Photoluminescence (PL) 측정으로 광학적 특성을 분석하였다.

  • PDF

Synthesis and Characterization of Large-Area and Highly Crystalline Molybdenum Disulphide Atomic Layer by Chemical Vapor Deposition

  • Park, Seung-Ho;Kim, Yooseok;Kim, Ji Sun;Lee, Su-Il;Cha, Myoung-Jun;Park, Chong-Yun
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2014.02a
    • /
    • pp.356.1-356.1
    • /
    • 2014
  • The Isolation of few-layered transition metal dichalcogenides has mainly been performed by mechanical and chemical exfoliation with very low yields. in particular, the two-dimensional layer of molybdenum disulfide (MoS2) has recently attracted much interest due to its direct-gap property and potential application in optoelectronics and energy harvesting. However, the synthetic approach to obtain high-quality and large-area MoS2 atomic thin layers is still rare. In this account, a controlled thermal reduction-sulfurization method is used to synthesize large-MoOx thin films are first deposited on Si/SiO2 substrates, which are then sulfurized (under vacuum) at high temperatures. Samples with different thicknesses have been analyzed by Raman spectroscopy and TEM, and their photoluminescence properties have been evaluated. We demonstrated the presence of mono-, bi-, and few-layered MoS2 on as-grown samples. It is well known that the electronic structure of these materials is very sensitive to the number of layer, ranging from indirect band gap semiconductor in the bulk phase to direct band gap semiconductor in monolayers. This synthetic approach is simple, scalable, and applicable to other transition metal dichalcogenides. Meanwhile, the obtained MoS2 films are transferable to arbitrary substrates, providing great opportunities to make layered composites by stacking various atomically thin layers.

  • PDF

Fabrication of Two-dimensional MoS2 Films-based Field Effect Transistor for High Mobility Electronic Device Application

  • Joung, DaeHwa;Park, Hyeji;Mun, Jihun;Park, Jonghoo;Kang, Sang-Woo;Kim, TaeWan
    • Applied Science and Convergence Technology
    • /
    • v.26 no.5
    • /
    • pp.110-113
    • /
    • 2017
  • The two-dimensional layered $MoS_2$ has high mobility and excellent optical properties, and there has been much research on the methods for using this for next generation electronics. $MoS_2$ is similar to graphene in that there is comparatively weak bonding through Van der Waals covalent bonding in the substrate-$MoS_2$ and $MoS_2-MoS_2$ heteromaterial as well in the layer-by-layer structure. So, on the monatomic level, $MoS_2$ can easily be exfoliated physically or chemically. During the $MoS_2$ field-effect transistor fabrication process of photolithography, when using water, the water infiltrates into the substrate-$MoS_2$ gap, and leads to the problem of a rapid decline in the material's yield. To solve this problem, an epoxy-based, as opposed to a water-based photoresist, was used in the photolithography process. In this research, a hydrophobic $MoS_2$ field effect transistor (FET) was fabricated on a hydrophilic $SiO_2$ substrate via chemical vapor deposition CVD. To solve the problem of $MoS_2$ exfoliation that occurs in water-based photolithography, a PPMA sacrificial layer and SU-8 2002 were used, and a $MoS_2$ film FET was successfully created. To minimize Ohmic contact resistance, rapid thermal annealing was used, and then electronic properties were measured.

Development of the Water-borne Separation Media Polymer for a Moving Historic Sites (자기분산형 수용성 에폭시를 이용한 유구 이전용 박리제의 개발)

  • Han, Won-Sik;Hong, Tae-Kee;Lim, Sung-Jin;Wi, Koang-Chul
    • Journal of Conservation Science
    • /
    • v.25 no.2
    • /
    • pp.171-178
    • /
    • 2009
  • When we considered the superior ability of the semi-water soluble urethane 1st transcription and final epoxy products, the stability for moving historic sites depend on physical properties and the peel off state of separation media. In this paper, we synthesised three type of water-borne epoxy solution without using a surfactant, and investigated the peel off state, physical properties, and the state between urethane surface and epoxy surface after exfoliation. The life time of water-borne separation media is over the 60 days. When it is used the 30% solution of water-borne separation media, it made good separation of urethane pre-products surface and epoxy final product surface and no color change. The separation tension pressure is about 15~50 kg/$cm^2$ and there is no surface whitewash phenomenon. We suggest that this water-borne epoxy will be best material as separation media of low viscosity type.

  • PDF

Nondestructive Deterioration Diagnosis for Wooden Ksitigarbha Triad Statues of Shinhungsa Temple in Sokcho, Korea (속초 신흥사 목조지장보살삼존상의 비파괴 손상도 진단)

  • Han, Na Ra;Lee, Chan Hee;Yi, Jeong Eun
    • Journal of Conservation Science
    • /
    • v.29 no.2
    • /
    • pp.93-102
    • /
    • 2013
  • The wooden Ksitigarbha Triad Statues (Treasure No. 1749) of Shinhungsa temple in Sokcho are enshrined in the inside of the Myeonbujeon Hall. The Statues are highly damaged physical weathering which are crack and exfoliation. Also, the Statues were deteriorated by chemical and biological weathering. This study carried out nondestructive method as deterioration map, ultrasonic measurement, X-ray and endoscopy survey for deterioration evaluation and conservation plan. As a result, Ksitigarbha Statue coated by dust and various pollutants. And gold-gilt of Statue's surface has peeled off. Head part of Mudokguiwang Statue was discolored from water leak in Myeongbujeon Hall. Domyeongjonja Statue is highly damaged by insects. Result of endoscopy, there were bee hives in the inside of the Statue. Therefore, we suggest that these Statues have need to do conservation treatment on the basis of diagnostic results.

Effects of Nitrogen Contents on the Nitriding Characteristics of the Micro-Pulse Plasma and Post Oxidation Treated SCM440 Steel (SCM440강의 마이크로 펄스 플라즈마 질화 및 후산화처리시 질소농도에 따른 특성변화)

  • Lee, S.K.;Chung, I.S.;Lee, J.S.
    • Journal of the Korean Society for Heat Treatment
    • /
    • v.12 no.2
    • /
    • pp.117-128
    • /
    • 1999
  • This study was carried out to investigate the surface characteristics of SCM440 steel nitrided with various nitrogen contents for 7 hours at $520^{\circ}C$ by using micro-pulse plasma nitriding apparatus of hot wall type. The effects of oxidation treatment was also investigated on plasma nitrided in 30% nitrogen and post oxidized SCM440 steel at $500^{\circ}C$ in $H_2O$ atmosphere. The ${\gamma}^{\prime}-Fe_4N$ and ${\varepsilon}-Fe_{2-3}N$ phases were detected in compound layer of the nitrided steel. As the content of nitrogen in plasma gas increased with 30, 50, 70% on the micro-pulse plasma nitriding for SCM440 steel, the thickness of compound, diffusion layer and the surface hardness were increased. From the wear test results, the best wear resistance was appeared in the condition of ductile ${\gamma}^{\prime}-Fe_4N$ phase formed specimen at 30% nitrogen, whereas that of the treated with 50% and 70% nitrogen decreased owing to the exfoliation of brittle ${\varepsilon}-Fe_{2-3}N$ phase in the compound layer. On the nitrided and subsequently oxidized SCM440 steel, the surface layer consisted of $Fe_3O_4$, ${\gamma}^{\prime}-Fe_4N$, and ${\varepsilon}-Fe_{2-3}N$ phases. In these treatments, the dissolution of nitrides affect hardness and hardening depth in compound and diffusion layers. For the nitrided in 30% nitrogen and post oxidized specimen at $500^{\circ}C$ for 1 hour, the wear resistance was lower than that of the only nitrided one in 30% nitrogen but higher than those of the nitrided ones in 50 and 70% nitrogen.

  • PDF