• Structural Engineering and Mechanics
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• 제21권3호
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• pp.255-273
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• 2005

Based on the random vibration theory, a response spectrum method is developed for seismic response analysis of linear, multi-degree-of-freedom structures under multi-support excitations is developed. Various response quantities, including the mean and variance of the peak response, the response mean frequency, are obtained from proposed combination rules in terms of the mean response spectrum. This method makes it possible to apply the response spectrum to the seismic reliability analysis of structures subjected to multi-support excitations. Considering that the tedious numerical integration is required to compute the spectral parameters and correlation coefficients in above combination rules, this paper further offers simplified procedures for their computation, which enhance dramatically the computational efficiency of the suggested method. The proposed procedure is demonstrated for tow numerical examples: (1) two-span continuous beam; (2) two-tower cabled-stayed bridge by using Monte Carlo simulation (MC). For this purpose, this paper also presents an approach to simulation of ground motions, which can take into account both mean and variation properties of response spectrum. Computed results based on the response spectrum method are in good agreement with Monte Carlo simulation results. And compared with the MSRS method, a well-developed multi-support response spectrum method, the proposed method has an incomparable computational efficiency.

• 대한기계학회논문집B
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• 제24권10호
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• pp.1326-1334
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• 2000

The oscillatory excitation with a Strouhal number of 2.65 ncar the stagnation zone of hemispherical nose model was employed to control the laminar separation bubble and the transition to turbulence. The effects of oscillatory excitation upon the separation bubble and the transition were addressed in terms of kurtosis/skewness and time-frequency analyses. The measured noise spectrum of radiated sound from the turbulent boundary layer on the axi-symmetric infinite cylinder is compared with that by Sevik's wave-number white approximations. The noise sources in TBL on axi-symmetric cylinder and the caling of their far-field sound are also discussed.

• Journal of Photoscience
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• 제7권1호
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• pp.21-26
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• 2000

The photoemission and excitation spectra of cis-[Cr(cyclam)F$_2$]ClO$_4$ (cyclam = 1,4,8,11-tetraazacy-clotetradecane) taken at 77 K are reported. The 298 K mid- and far-infrared spectra are also measured. The vibrational intervals of the electronic ground state are extracted from the far-infrared and emission spectra. The ten electronic bands due to spin-allowed and spin-forbidden transitions are assigned. The zero-phonon line In the excitation spectrum splits into two components by 169 cm$^{1}$, and the large $^2$E$_{g}$ splitting can be reproduced by the ligand field theory. According to the ligand field analysis, we can confirm that nitrogen atoms of the cyclam ligand have a strong c-donor character, and fluoride ligand also has strong $\sigma$- and $\pi$-donor properties toward chromium(III) ion.n.

• Bulletin of the Korean Chemical Society
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• 제14권1호
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• pp.118-122
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• 1993

The 77 K luminescence and excitation spectra, room-temperature FT-infrared and visible absorption spectra of a newly prepared complex cis-[Cr(cyclam)(pn)]$(ClO_4)_3$, where cyclam and pn represent 1,4,8,11-tetraazacyclotetradecane and 1,2-propanediamine respectively, have been measured. Absorption maximum of the first spin-allowed transition in the electronic absorption spectra of cis-[Cr(cyclam)(pn)]$^{3+}$ and cis-[Cr(cyclam)(en)]$^{3+}$ appears at nearly the same position. The two spin-allowed and six spin-forbidden electronic transitions are assigned from the visible absorption and excitation spectra. It is also shown that the zero phonon line in the excitation spectrum splits into two components by 50 cm$^{-1}$.

• Bulletin of the Korean Chemical Society
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• 제33권10호
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• pp.3391-3396
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• 2012

Two-dimensional infrared (2D-IR) spectroscopy can probe the fast structural evolution of molecules under thermal equilibrium. Vibrational frequency fluctuation caused by structural evolution produced the time-dependent line shape change in 2D-IR spectrum. A variety of methods has been used to connect the evolution of 2D-IR spectrum with Frequency-Frequency Correlation Function (FFCF), which connects the experimental observables to a molecular level description. Here, a new method to extract FFCF from 2D-IR spectra is described. The experimental observable is the time-dependent frequency shift of maximum peak position in the slice spectrum of 2D-IR, which is taken along the excitation frequency axis. The direct relation between the 2D-IR peak shift and FFCF is proved analytically. Observing the 2D-IR peak shift does not need the full 2D-IR spectrum which covers 0-1 and 1-2 bands. Thus data collection time to determine FFCF can be reduced significantly, which helps the detection of transient species.

• 한국결정성장학회지
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• 제14권1호
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• pp.21-26
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• 2004

HPHT(고온고압) 처리된 type IIa 다이아몬드의 분광분석 결과를 나타내었다. 그리고 HPHT 처리된 다이아몬드 spectrum의 특성을 이와 유사한 color와 type을 가진 처리되지 않은 다이아몬드와 비교하였다. 325nm 에서 여기된 He/Cd laser로는 HPHT 처리된 다이아몬드와 처리되지 않은 다이아몬드에 현저한 변화가 있음을 알 수 있었는데 이는 HPHT 처리된 다이아몬드의 spectrum에서 H3, H4에 관련된 peak가 제거되고 N3 system에 관련된 peak의 emission이 증가함을 보여 주었다. 또한 514nm에서 여기된 Ar-ion laser로 측정된 spectrum은 575nm와 637.1 nm에서 Nitrogen과 vacancy가 관련되어있는 N-V center가 발견 되었는데 이러한 center가 존재하고 있을 경우 637.1 nm의 FWHM의 값은 HPHT 처리된 다이아몬드와 처리되지 않은 다이아몬드를 구분할 수 있음을 보여주었다. 본 실험에서 측정된 HPHT 처리된 다이아몬드의 637.1nm $(N-V)^-$의 FWHM 값은 $19.8{\textrm}{cm}^{-1}$에서$32.1{\textrm}{cm}^{-1}$였다.

• Bulletin of the Korean Chemical Society
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• 제25권4호
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• pp.445-446
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• 2004

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2012년도 추계학술대회 논문집
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• pp.651-652
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• 2012

• 한국음향학회지
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• 제29권1호
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• pp.82-90
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• 2010

본 논문에서는 HMM기반 음성합성시스템에서 합성음의 음질 개선을 위한 방법으로 스펙트럼 정보에 기반한 여기신호 추출방법을 제안한다. 제안된 방법은 스펙트럼 정보와 여기신호를 함께 통계적 모델로 만든 후에 합성 과정에서 스펙트럼 정보를 기반으로 여기신호를 추출해 냄으로써 스펙트럼 파라메터에 가장 적합한 여기신호를 사용할 수 있다. 제안된 방법으로 합성음의 음질을 MUSHRA 테스트 및 WB-FESQ점수를 통해 확인해 본 결과, 비슷한 조건에서 기존에 사용되는 STRAIGHT 방법을 이용한 합성음보다 좋은 음질을 얻을 수 있었다.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2007년도 추계학술대회논문집
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• pp.589-594
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• 2007

In this paper, the optimal command input is considered in order to minimize the residual vibrations of a flexible cantilever beam when the beam simply changes its position by translation or rotation. Although a cantilever beam has many modes of vibration, it is shown that the consideration of the first mode is sufficient in this case. Thus, the problem becomes a singledegree-of-freedom system subjected to a ground excitation. Two simple methods are proposed to find the optimal command input based on the Shock Response Spectrum (SRS). The first method is the simplest and can be applied to lightly damped cases, and the second method is applicable to more general problems. The second method gives almost the same results as the input shaping method. However the proposed method gives a easier and clearer control strategy.