• Title/Summary/Keyword: Exchange flow

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Characterization of Commercial Membranes for Non-aqueous Vanadium Redox Flow Battery (비수계 바나듐 레독스 흐름 전지를 위한 상용 멤브레인의 특성분석)

  • Sung, Ki-Won;Shin, Sung-Hee;Moon, Seung-Hyeon
    • Korean Chemical Engineering Research
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    • v.51 no.5
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    • pp.615-621
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    • 2013
  • Membrane characterization methods for aqueous redox flow batteries aqueous RFBs were modified for non-aqueous RFBs. The modified characterization methods, such as ion exchange capacity, transport number, permeability and single cell test, were carried out to evaluate commercial membranes in non-aqueous electrolyte. It was found that columbic efficiency and energy efficiency in a single cell test were dependent on the ion selectivity of commercial anion exchange membranes. Neosepta AHA anion exchange membrane showed the anion transport number of 0.81, which is a relatively low ion selectivity in non-aqueous electrolyte, however, exhibited 92% of coulombic efficiency and 86% of energy efficiency in a single cell test. It was also found that a porous membrane without ion selectivity is suitable for a non-aqueous redox flow battery at a high current density.

Study on the Vanadium Redox Flow Battery using Cation Exchange Membrane and Ammonium Metavanadate (메타바나듐산암모늄과 양이온교환막을 활용한 바나듐 레독스 흐름전지에 관한 연구)

  • Jung, Bo-Young;Ryu, Cheol-Hwi;Hwang, Gab-Jin
    • Membrane Journal
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    • v.31 no.4
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    • pp.262-267
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    • 2021
  • The electrochemical performance of all vanadium redox flow battery (VRFB) using an electrolyte prepared from ammonium metavanadate and a cation exchange membrane (Nafion117) was evaluated. The electrochemical performance of VRFB was measured at a current density of 60 mA/cm2. The average current efficiency of VRFB using the electrolyte prepared from ammonium metavanadate was 94.9%, the average voltage efficiency was 82.2%, and the average energy efficiency was 78.0%. In addition, it was confirmed that the efficiencies of VRFB using the electrolyte prepared from ammonium metavanadate had almost the same value as the efficiencies of VRFB using the electrolyte prepared with vanadyl sulfate (VOSO4).

Evaluation of Tidal Flow around the Pile-supported Pier Structures (잔교식 항만구조물 주변에서 해수유동의 평가)

  • Park Il Heum
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.7 no.2
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    • pp.82-88
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    • 2004
  • To evaluate the tidal flow around the transmission type harbour structures, the numerical models considering hydraulic resistance are used. The traditional governing equations of depth-integratef hydrodynamics are modified by using of the drag force term. As a numerical model to evaluate the rate of tidal exchange, the Random-walk method is used. The models are applied in a design of the pile-supported pier structures in Busan harbour site, Korea, where the flow speed and the tidal exchange are more promotive than the case of non-transmission structure. The developed model will be applied usefully to design the transmission type structure in the ocean space.

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The Impact of Operating Cash Flows on Financial Stability of Commercial Banks: Evidence from Pakistan

  • ELAHI, Mustahsan;AHMAD, Habib;SHAMAS UL HAQ, Muhammad;SALEEM, Ali
    • The Journal of Asian Finance, Economics and Business
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    • v.8 no.11
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    • pp.223-234
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    • 2021
  • This study aims to examine whether operating cash flows influence banks' financial stability in Pakistan. The study employed annual panel data collected from annual reports of 20 commercial banks listed on the Pakistan Stock Exchange for the year 2011 to 2019. Free cash flow yield was taken as the dependent variable while cash flow ratio was selected as the independent variable, and net interest margin, income diversification, asset quality, financial leverage, the cost to income ratio, advance net of provisions to total assets ratio, capital ratio, financial performance, breakup value per share and bank size were taken as control variables. The study performed ordinary least square technique, random and fixed effects models, Hausman test, Lagrange multiplier test, descriptive and correlation analysis. Results showed that operating cash flows and net interest margin significantly and positively influenced banks' financial stability while the cost to income ratio and advances net of provisions to total assets ratio significantly and negatively associated with banks' financial stability. To improve financial stability, banks should become more cost-effective and enhance their liquidity levels by lowering lending activities. In the future, it would be useful to compare commercial and investment banks, also Islamic and conventional banks in the same research setting.

Numerical Analysis of Flow Pattern by Outflow Gates with Manifold Channel (다기수로를 가진 수중 유출구에 의한 유동패턴에 관한 수치해석)

  • Kim, Nam-Hyeong;Lee, Chang-Lym;Ku, Bon-Soo;Song, Man-Soon
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.23 no.1
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    • pp.43-49
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    • 2011
  • For the improvement of water quality in a harbor, several studies have been carried out on SEB (Seawater Exchange Breakwater) in recent years, but a problem has been shown whereby the water on the inside area far from the SEB cannot be easily exchanged. In order to solve the problem of the SEB, the Manifold channel, a new concept of the SEB, is introduced in this paper. By using the manifold channel, it is possible to exchange the water of the inside area for seawater from the outside. Here, to assess the outflow gates of the manifold channel governing flow behavior, a virtual manifold channel controlled the location, width and direction of outflow gates applied to the Jumunjin fishery port, where the SEB has been established. In addition, the desirable flow pattern of the port by utilizing the two layer current model is identified, and five general cases of the manifold channel are described in this paper. The model is verified by comparing with observation of the SEB model, and the results are in general agreement. From the results of the manifold channel, in the case of the Jumunjin fishery port, the small circulation of counter clockwise is necessary for the water exchange on the inside area, but it should be controlled by the outflow gates for other areas. Using the two layer current model, the desirable flow pattern of the port can be predicted, and the water exchange for the upper and lower layer can be examined. For the practical use of the manifold channel, further studies on the manifold channel will be necessary, and it may then be used broadly for the design of breakwater in the future.

Experimental study on water exchange between crack and clay matrix

  • Song, Lei;Li, Jinhui;Garg, Ankit;Mei, Guoxiong
    • Geomechanics and Engineering
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    • v.14 no.3
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    • pp.283-291
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    • 2018
  • Cracks in soil provide significant preferential pathways for contaminant transport and rainfall infiltration. Water exchange between the soil matrix and crack is crucial to characterize the preferential flow, which is often quantitatively described by a water exchange ratio. The water exchange ratio is defined as the amount of water flowing from the crack into the clay matrix per unit time. Most of the previous studies on the water exchange ratio mainly focused on cracked sandy soils. The water exchange between cracks and clay matrix were rarely studied mainly due to two reasons: (1) Cracks open upon drying and close upon wetting. The deformable cracks lead to a dynamic change in the water exchange ratio. (2) The aperture of desiccation crack in clay is narrow (generally 0.5 mm to 5 mm) which is difficult to model in experiments. This study will investigate the water exchange between a deformable crack and the clay matrix using a newly developed experimental apparatus. An artificial crack with small aperture was first fabricated in clay without disturbing the clay matrix. Water content sensors and suction sensors were instrumented at different places of the cracked clay to monitor the water content and suction changes. Results showed that the water exchange ratio was relatively large at the initial stage and decreased with the increasing water content in clay matrix. The water exchange ratio increased with increasing crack apertures and approached the largest value when the clay was compacted at the water content to the optimal water content. The effective hydraulic conductivity of the crack-clay matrix interface was about one order of magnitude larger than that of saturated soil matrix.

Influence of Operating Conditions on the Performances of a Continuous Electrodeionizatioin with Cation Exchange Textile (CEDI-CET)

  • Song, Jung-Hoon;Lee, Jin-Woo;Lee, Hong-Joo;Moon, Seung-Hyeon
    • Korean Membrane Journal
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    • v.9 no.1
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    • pp.18-26
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    • 2007
  • The transport and removal characteristics of cobalt ions were investigated in a continuous electrodeionization with cation exchange textile (CEDI-CET). It was shown that the removal properties of cobalt ions are strongly dependent on the operating parameters such as temperature, flow velocity, and the solution pH. The transport and removal of cobalt ions was mainly related to the sorption on the surface and the convection and electro-migration through the ion exchange medium. In this study, the CEDI-CET showed good process performance for the removal of metal ions compared with the conventional CEDI with resins.

A feasibility study of interconnection between ROK and Russia (남한-러시아 국가간 계통연계를 위한 예비 타당성 검토)

  • Kim, Jong-Yul;Lee, Seong-Ryul;Yoon, Jae-Young
    • Proceedings of the KIEE Conference
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    • 2005.11b
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    • pp.356-358
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    • 2005
  • This paper evaluates minimum and maximum power exchange considering economic and technical characteristics between Russia and ROK. First, we evaluate minimum power exchange to assure the economic feasibility by comparison with the total cost and benefit of the interconnected line. For evaluating maximum exchange power, system constraints are considered, which are examined through load flow and dynamic analysis by using the PSS/E program. As a result of these evaluations, we suggest the reasonable range of power exchange between ROK and Russia considering economic and technical constraints with the interconnection scenario that power system interconnection between ROK and Russia will be realized in the year 2010.

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An Application of the Optimal Routing Algorithm for Radial Power System using Improved Branch Exchange Technique (개선된 선로교환 기법을 이용한 방사상 전력계통의 최적 라우팅 알고리즘의 적용)

  • Kim, Byeong-Seop;Sin, Jung-Rin;Park, Jong-Bae
    • The Transactions of the Korean Institute of Electrical Engineers A
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    • v.51 no.6
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    • pp.302-310
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    • 2002
  • This paper presents an application of a improved branch exchange (IBE) algorithm with a tie branch power (TBP) flow equation to solve the Optimal Routing problem for operation of a radial Power system including power distribution system. The main objective of the Optimal Routing problem usually is to minimize the network real power loss and to improve the voltage profile in the network. The new BE algorithm adopts newly designed methods which are composed by decision method of maximum loss reduction and new index of loss exchange in loop network Thus, the proposed algorithm in this paper can search the optimal topological structures of distribution feeders by changing the open/closed states of the sectionalizing and tie switches. The proposed algorithm has been evaluated with the practical IEEE 32, 69 bus test systems and KEPCO 148 bus test system to show favorable performance gained.

Decolorization of Aqueous Caprolactam Solution by Anion-exchange Resins

  • Yuan Zhen;Yu Ping;Luo Yunbai
    • Fibers and Polymers
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    • v.7 no.2
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    • pp.112-116
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    • 2006
  • Caprolactam is the most important raw material for making Nylon 6 fibers and its quality directly determines the quality of Nylon. So it is necessary to study the techniques and methods to remove the colorful impurities from caprolactam. In this paper, the decolorization of caprolactam aqueous solution by anion exchange resins was studied and the decoloring abilities of five commercial resins were investigated. The regeneration of the resins was also studied, too. This study shows that the resin AMTX202 have excellent decoloring ability in the column experiment and that the decoloring efficiency is correlated with the volume of resins packed and is slightly affected by the flow rate and regenerating times. The fact that the resins can be regenerated and reused without affecting the efficiency of decolorization will decrease the cost of the treatment and operation in the industry. The adsorption of colored compounds with anion exchange resins in the packed columns seems to be technically feasible.