• Title/Summary/Keyword: Excess viscosity

Search Result 43, Processing Time 0.03 seconds

3-Dimensional Consolidation Analysis Considering Viscosity on Soft Clay Ground improved by Plastic Board Drain (점성을 고려한 PBD 타설 연약점토지반의 3차원 압밀해석)

  • You, Seung-Kyong;Han, Jung-Gun;Jo, Sung-Min;Kim, Ji-Yong
    • Journal of the Korean Geosynthetics Society
    • /
    • v.4 no.4
    • /
    • pp.39-46
    • /
    • 2005
  • A series of numerical analyses on soft clay ground improved by plastic board drain(PBD) were carried out, in order to investigate the consolidation behavior considering viscosity of the improved ground. The applicability of numerical analyses, in which an elasto-viscoplastic three-dimensional consolidation finite element method is applied in this study, was confirmed through comparison between experimental and analytical results. As the analytical results, consolidation behavior of both settlement and excess pore pressure and effective stress in clay were elucidated. Then secondary consolidation characteristics of improved ground were estimated through compare with results of typical one-dimensional consolidation analysis.

  • PDF

Processability Enhancement in Melt Processing of Poly(ethylene naphthalate) (폴리(에틸렌 나프탈레이트)의 가공 특성 향상 연구)

  • Kim Hyogap;Kang Ho-Jong
    • Polymer(Korea)
    • /
    • v.29 no.5
    • /
    • pp.475-480
    • /
    • 2005
  • The lowering of melt viscosity has been investigated to achieve the processability enhancement in poly(ethylene naphthalate) (PEN) melt processing by the reactive melt blending with poly(ethylene terephthalate) (PET) and introducing lubricant as well. CaST lubricant resulted in the lowering of PEN melt viscosity but noticeable mechanical property drop was found in PEN with more than $2wt\%$ of lubricant due to the acceleration of thermal degradation by excess lubricant. PEN/PET (90/10) blend has less melt viscosity than PEN and transesterification between two polymers caused the additional viscosity depression. further viscosity lowering was found in PEN/PET blend with CaST since CaST is acting as the catalyst of transesterification as well as a lubricant in PEN/PET blend.

Conformational Transition of Form II to Form Ⅰ PoLy(L-proline) and the Aggregation of Form Ⅰ in the Transition: Water-Propanol Solvent System

  • 김현돈
    • Bulletin of the Korean Chemical Society
    • /
    • v.18 no.9
    • /
    • pp.922-928
    • /
    • 1997
  • The conformational transition of poly(L-proline) (PLP), Form Ⅱ → Form Ⅰ and the intermolecular aggregation of the product, Form Ⅰ, during and after the transition in water-propanol (1:7, 1:9, 1:15.7, and 1:29 v/v) were studied. For the study, the viscosity change and excess light scattering intensity were measured in the course of the transition which was determined by the Form Ⅰ fraction, fI of the sample solution. For the PLP sample of molecular weight Mv=31,000 the experimental results show that the reaction course is roughly divided into three regions: in the first region [fI=0.27 to 0.40 (- [α]D=400 to 330)], the conformational change of Form Ⅱ → Form Ⅰ occurs with decrease of viscosity, in the second region [fI=0.40 to 0.80 (- [α]D=330 to 120)], a partial side-by-side (p-S-S) type aggregation in which Form Ⅰ blocks interact with each other, which induces the increase of viscosity, starts to occur, and in the third region [fI=0.80 to 1.00 (- [α]D=120 to 15)], a side-by-side type (raft like) aggregation of Form Ⅰ or an end-to-end (E-E) type aggregation occurs according to the solvent situation, i.e., in a water-rich medium [water-propanol (1:9 or 1:7 v/v)], the (S-S) type aggregation with a gross decrease in viscosity occurs while in a water-poor medium [water-propanol (1:29 or 1:15.7 v/v), the (E-E) type aggregation with a large increase in viscosity occurs. The (S-S) type aggregation was promoted at high temperatures. Based on the structure of PLP, a reasonable mechanism for the (p-S-S) and (S-S) aggregation which occurs with the transition of Form Ⅱ → Form Ⅰ is considered. The suggested mechanism was also supported by the result of chain length effect of PLP for the aggregation.

Effect of Solvent Mixture on the Properties of LTCC Slurry and Green Sheets (LTCC 슬러리 및 그린시트의 물성 변화에 미치는 혼합용매 조성의 영향)

  • Cho, Beom-Joon;Park, Eun-Tae
    • Korean Journal of Materials Research
    • /
    • v.16 no.9
    • /
    • pp.533-537
    • /
    • 2006
  • The effects of binary solvent mixtures with various ratios of toluene and ethanol on the properties of slurries and green sheets were investigated. Viscosity of slurry was changed by varying the ratio of solvent mixture which affected the solubility of binder. The relative solvency behavior of a solvent mixture could be predicted with the Hildebrand solubility parameter(${\delta}$) and hydrogen bonding index( ${\gamma}$). The minimum viscosity, the best dispersion of binder, was reached at the composition of toluene:ethanol=4:6, which corresponded to our forecast. The mechanical properties of green sheets related to evaporation of solvents were influenced by the composition of the solvent mixture. At the azeotrope the skin was formed on a drying cast during the drying process because of fast evaporation. At a range of concentrations over 50wt% toluene, green sheets could not be fully dried at low temperature due to excessive toluene. The mechanical properties of green sheets were excellent at the azeotrope-like composition of toluene:ethanol=4:6 which has a little excess of toluene over the azeotrope.

A Study on the Coating Thickness of Surface Modified Aggregate by Using the Excess Paste Theory and Rheology Value (잉여 페이스트 이론과 레올로지 정수를 이용한 표면 개질골재의 피막두께 평가에 관한 연구)

  • Choi, Hee-Sup;Choi, Hyeong-Gil
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.23 no.5
    • /
    • pp.23-29
    • /
    • 2019
  • This study applies to the surface modification technique by coating the surface of aggregates using the modified paste such as cementitious materials in order to develop completely recycling technology of coarse aggregate. In this case, coating thickness of modified aggregate can be considered that the decision is dependent on the viscosity and tenacity of modified paste. In this study identify the flow properties of the fresh modified paste, and examined for the coating thickness of modified aggregate. As a result, it was possible to design a quantitative coating thickness of modified paste assuming that a modified paste to a Bingham Fluid and consider by excess paste theory and rheology constant (yield value). Accordingly, it is considered that the quantitative mix design of concrete using by surface modified aggregates will be possible.

Correlation of morphological changes of rice starch granules with rheological properties during heating In excess water (가열 조리시 쌀 전분 입자들의 형태학적 변화와 리올로지 특성과의 관계)

  • Lee, Young-Eun;Osman, Elizabeth M.
    • Applied Biological Chemistry
    • /
    • v.34 no.4
    • /
    • pp.379-385
    • /
    • 1991
  • Morphological changes of starch granules from 12 different varieties of rice were examined by scanning electron microscopy during heating at 2.5% (w/v) concentration. Rice starch granules proceeded through a similar pattern of progressive morphological changes daring heating, regardless of variety. Rice starch granules began to swell radially in the initial stage of gelatinization and then undergo radial contraction and random tangential expansion to form complex structures in the latter stage of gelatinization temperature range. At higher temperatures, starch granules softened and melted into thin flat discs, and then stretched into thin filaments to form three-dimensional networks. These progressive morphological changes were reflected in the changes of swelling power, solubility and amylograph viscosity of starch. During the transition of melting or softening, swelling power, solubility and amylograph viscosity increased rapidly. The time of loss of granular structure of starch depended on gelatinization temperature range. The ratio of amylose to amylopectin was largely responsible fur the rate of melting or softening and the fineness of a three-dimensional filamentous network above the gelatinization temperature range. Therefore, both the gelatinization temperature range and amylose content of starch affect the rate of cooking, and amylose content of starch affects the final texture of cooked starch paste.

  • PDF

Association between air conduction hearing threshold and blood viscosity in normal adult males (정상 성인남자에 있어서 기도청력역치와 혈액점도와의 연관성에 관한 연구)

  • Kim, Sang-Woo;Lee, Jong-Young;Park, Wan-Seup;Woo, Kuck-Hyeun
    • Journal of Preventive Medicine and Public Health
    • /
    • v.30 no.3 s.58
    • /
    • pp.623-629
    • /
    • 1997
  • This is cross-sectional study to evaluate a potential relationship between air conduction hearing threshold and blood viscosity in normal adult males(n=1677). We measured hearing threshold in frequency level at 500, 1000, 2000, 4000Hz by pure-tone audiometry and RBC profiles containing red cell number, hemoglobin, hematocrit. Blood viscosity are replaced by hematocrit that are one major factor of influencing blood viscosity. PTAs(pure-tone averages) are measured by hearing threshold averages level at 500Hz, 1000Hz, 2000Hz. Grades of PTAs(pure-tone averages) are divided three groups that are less then 10.0dB group, between 10.0-19.9dB group and excess 20.0dB. The results shows significant association among hematocrit, red cell number and hearing loss(age adjust by ANACOVA).

  • PDF

Effect of associating polymer on the dispersion stability and rheology of suspensions

  • Otsubo, Yasufumi;Horigome, Misao
    • Korea-Australia Rheology Journal
    • /
    • v.15 no.1
    • /
    • pp.27-33
    • /
    • 2003
  • Associating polymers are hydrophilic long-chain molecules to which a small amount of hydrophobic groups (hydrophobes) is incorporated. In aqueous solution, the association interactions result in the formation of three-dimensional network through flowerlike micelles at high concentrations. In colloidal suspensions, the associating polymers act as flocculated by bridging mechanism. The rheological properties of suspensions flocculated by associating polymers end-capped with hydrophobes are studied in relation to the bridging conformation. At low polymer concentrations, the polymer chains effectively form bridges between particles by multichain association. The suspensions are highly flocculated and show typical viscoelastic responses. When the polymer concentration is increased above the absorbance at saturation, the excess polymer chains remaining in the solution phase build up three-dimensional network by associating interactions. Since the presence of particles does not significantly influence the network structures in the medium, the relative viscosity, which gives a measure of the degree of flocculation is decreased with increasing polymer concentration. The bridging conformation and flocculation level vary strongly depending on the polymer concentrations.

EVELOPMENT OF AXISYMMETRIC MULTI-SPECIES GH EQUATION FOR HYPERSONIC RAREFIED FLOW ANALYSES (극초음속 희박유동 해석을 위한 축대칭 다화학종 GH 방정식의 개발)

  • Ahn, J.W.;Kim, C.
    • 한국전산유체공학회:학술대회논문집
    • /
    • 2008.03a
    • /
    • pp.84-91
    • /
    • 2008
  • Generalized hydrodynamic (GH) theory for multi-species gas and the computational models are developed for the numerical simulation of hypersonic rarefied gas flow on the basis of Eu's GH theory. The rotational non-equilibrium effect of diatomic molecules is taken into account by introducing excess normal stress associated with the bulk viscosity. The numerical model for the diatomic GH theory is developed and tested. Moreover, with the experience of developing the dia-tomic GH computational model, the GH theory is extended to a multi-species gas including 5 species; O$_2$, N$_2$, NO, O, N. The multi-species GH model includes diffusion relation due to the molecular collision and thermal phenomena. Two kinds of GH models are developed for an axisymmetric flow solver. By compar-ing the computed results of diatomic and multi-species GH theories with those of the Navier-Stokes equations and the DSMC results, the accuracy and physical consistency of the GH computational models are examined.

  • PDF

EVELOPMENT OF AXISYMMETRIC MULTI-SPECIES GH EQUATION FOR HYPERSONIC RAREFIED FLOW ANALYSES (극초음속 희박유동 해석을 위한 축대칭 다화학종 GH 방정식의 개발)

  • Ahn, J.W.;Kim, C.
    • 한국전산유체공학회:학술대회논문집
    • /
    • 2008.10a
    • /
    • pp.84-91
    • /
    • 2008
  • Generalized hydrodynamic (GH) theory for multi-species gas and the computational models are developed for the numerical simulation of hypersonic rarefied gas flow on the basis of Eu's GH theory. The rotational non-equilibrium effect of diatomic molecules is taken into account by introducing excess normal stress associated with the bulk viscosity. The numerical model for the diatomic GH theory is developed and tested. Moreover, with the experience of developing the dia-tomic GH computational model, the GH theory is extended to a multi-species gas including 5 species; $O_2,\;N_2$, NO, O, N. The multi-species GH model includes diffusion relation due to the molecular collision and thermal phenomena. Two kinds of GH models are developed for an axisymmetric flow solver. By compar-ing the computed results of diatomic and multi-species GH theories with those of the Navier-Stokes equations and the DSMC results, the accuracy and physical consistency of the GH computational models are examined.

  • PDF