• 한국가스학회지
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• 제11권1호
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• pp.1-8
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• 2007

본 논문에서는 메탈화이버를 이용한 난류예혼합 플랫버너를 제작하여 다양한 연소조건하에서 화염의 안정화범위를 확인하였으며, 연료유량과 공기유량의 변화에 따른 균일가열 능력과 배기가스 특성에 관한 실험을 실시하였다. 그리고 화염의 안정성 평가를 위한 실험을 통해 화염을 공기유량 변화에 따라 청녹염, 복사염, 청염 영역으로 나눌 수 있었고, 이들 영역은 청염>복사염>청녹염 영역 순으로 연소상태가 양호하였다. 공기비에 따른 영향을 살펴보면, 본 실험에서는 연료유량 1과 4l/min에서는 공기비 ${\alpha}=1.5$가 적합하였으며 연료유량 2l/min에서는 ${\alpha}=2.0$이 적합한 것으로 나타났다. 한편 연료유량과 관계없이 공기비 ${\alpha}=1.3{\sim}2.1$범위에서는 연소소음이 발생했다.

• 대한화학회지
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• 제59권6호
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• pp.488-492
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• 2015

본 연구에서는 칼슘채널 차단제로서 항고혈압 작용을 가진 (S)-(+)-pranidipine의 광학 분할에 의한 효과적인 제조방법을 제시하였다. (±)-Pranidipine을 가수분해시켜 얻은 monocarboxylic acid 5의 라세미 혼합물에 광학 활성이 있는 quinidine을 첨가하여 염을 형성한 다음 불용성 부분입체이성질체 염을 여과하고 염기와 산으로 처리하여 (R)-(-)-carboxylic acid 7을 분리하였고 이 carboxylic acid를 cinnamyl alcohol과의 에스터화 반응에 의해 (S)-(+)-pranidipine을 합성하였다. 이 화합물의 거울상 초과량(enantiomeric excess, ee)을 카이랄 HPLC로 분석한 결과 100% ee 값이 얻어졌고, 합성 과정에서 강염기 사용과 무수 조건 및 초저온 조건을 배제하였는바 이는 산업상 매우 유용한 개량방법이라 하겠다.

• Journal of Advanced Marine Engineering and Technology
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• 제38권10호
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• pp.1244-1250
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• 2014

The temperature of the main engine cabin of commercial vessel is very high. The material SS-316L undergoes creep damage at temperatures exceeding $450^{\circ}C$. It is essential to maintain the highly stressed engine cabin below the creep regime. Hence, seawater is employed in this kind of maritime vehicles as cooling liquid. It obtains the thermal energy at the cooling pipe line after passing through main engine cooling system. To harness the energy in the seawater, a turbine can be installed to absorb the energy in the seawater before being released into the sea. In this study, a cooling pipe line is selected to apply the tubular type hydro turbine for transferring the energy. Numerical analysis for investigating the performance and the internal flow characteristics of the tubular turbine is conducted. The results show that the maximum efficiency of 85.8% is achieved although the efficiency drops rapidly at partial flow rate condition. The efficiency descends slowly at the condition of excess flow rate. There is a relatively wide operating range of flow rate of this turbine to keep high efficiency at the excess flow rate condition. For the internal flow of the turbine, there is uniform streamline on the suction and pressure sides of the blade at the design point. However, the secondary flow appears at the suction and pressure sidesat the excess flow rate.In addition, it appears only at pressure side at the partial flow rate condition.

• Korean Chemical Engineering Research
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• 제43권3호
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• pp.387-392
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• 2005

Dimethyl carbonate(DMC)는 낮은 독성과 빠른 생분해성으로 인해 MTBE(methyl tert-butyl ether)를 대체할 수 있는 무연가솔린의 첨가제로 주목받는 물질로, 주로 methanol의 carbonylation에 의해 합성되고, 원가절감을 위해 methanol을 출발물질로 한 새로운 DMC 제조공정의 개발이 진행 중에 있다. 이에 필요한 다양한 조건하의 DMC 관련 혼합계의 상평형 자료 및 물성은 Dortmund Data Bank(DDB)검색 결과, 매우 부족하며 무한희석 활동도계수에 대한 자료는 전무한 것으로 나타났다. 이 글에서는 methanol+DMC계의 333.15 K에서의 이성분계 등온 기-액 평형과, 혼합물성으로써 methanol+DMC계의 과잉부피 및 점도편차를 298.15 K에서 측정하였다. 또한, 무한희석상태에서 DMC 용매에서의 methanol의 무한희석 활동도계수를 303.15, 313.15, 323.15 K에서 각각 측정하였으며, 측정값은 modified UNIFAC(Dortmund)식에 의한 계산 값과도 비교하였다.

• 한국재료학회지
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• 제22권10호
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• pp.508-512
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• 2012

ZnO thin films were grown on a sapphire substrate by RF magnetron sputtering. The characteristics of the thin films were investigated by ellipsometry, X-ray diffraction (XRD), atomic force microscopy (AFM), photoluminescence (PL), and Hall effect. The substrate temperature and growth time were kept constant at $200^{\circ}C$ at 30 minutes, respectively. The RF power was varied within the range of 200 to 500 W. ZnO thin films on sapphire substrate were grown with a preferred C-axis orientation along the (0002) plan; X-ray diffraction peak shifted to low angles and PL emission peak was red-shifted with increasing RF power. In addition, the electrical characteristics of the carrier density and mobility decreased and the resistivity increased. In the electrical and optical properties of ZnO thin films under variation of RF power, the crystallinity improved and the roughness increased with increasing RF power due to decreased oxygen vacancies and the presence of excess zinc above the optimal range of RF power. Consequently, the crystallinity of the ZnO thin films grown on sapphire substrate was improved with RF sputtering power; however, excess Zn resulted because of the structural, electrical, and optical properties of the ZnO thin films. Thus, excess RF power will act as a factor that degrades the device characteristics.

• Journal of Magnetics
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• 제14권1호
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• pp.7-10
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• 2009

In this work, we studied the effects of Sn addition on the ordering temperature of FePt thin film. The coercivity of FePtSn film was about 1000 Oe greater than the coercivity of FePt film for an annealing temperature of $600^{\circ}C$. Therefore, Sn addition was effective in promoting the $L1_0$ ordering and in reducing the ordering temperature of the FePt film. From our X-ray diffraction results, we found that in the as-deposited film, the addition of Sn induced a lattice expansion in disordered FePt thin films. After the annealing process, the excess Sn diffuses out from the ordered FePt thin film because of the difference in the solid solubility of Sn between the disordered and ordered phases. The existence of precipitates of Sn from the FePt lattice was deduced by Curie temperature measurements of the FePt and FePtSn films. Therefore, the key role played by the addition of Sn to the FePt film can be explained by a reduction in the activation energy for the $L1_0$ order-disorder transformation of FePt which originates from the high internal stress in the disordered phase induced by the supersaturated Sn atoms.

• 한국수소및신에너지학회논문집
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• 제23권5호
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• pp.521-529
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• 2012

Since the energy demand for refrigeration and air-conditioning has greatly increased all over the world, thermally activated refrigeration cycle has attracted much attention. This study carries out a performance analysis of a vapor compression cycle (VCC) driven by organic Rankine cycle (ORC) utilizing low-temperature heat source in the form of sensible heat. The ORC is assumed to produce minimum net work which is required to drive the VCC without generating an excess electricity. Effects of important system parameters such as turbine inlet pressure, condensing temperature, and evaporating temperature on the system variables such as mass flow ratio, net work production, and coefficient of performance (COP) are thoroughly investigated. The effect of choice of working fluid on COP is also considered. Results show that net work production and COP increase with increasing turbine inlet pressure or decreasing condensing temperature. Out of the five kinds of organic fluids considered $C_4H_{10}$ gives a relatively high COP in the range of low turbine inlet pressure.

• Electronic Materials Letters
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• 제14권6호
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• pp.766-773
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• 2018

In this paper, temperature dependence of the excitonic bands in a mechanically exfoliated tungsten diselenide ($WSe_2$) monolayer is studied using photoluminescence and circular dichroic photoluminescence (PL) in the temperature range between 8 and 300 K. The peak energies associated with the neutral exciton (A), charged exciton (trion) and localized excitons are extracted from the PL spectra revealing a trion binding energy of around 30 meV. The circular dichroic PL measured at 8 K shows about 45% valley polarisation that sharply reduces with increasing temperature to 5% at 300 K with photoexcitation energy of 1.96 eV. A detailed analysis of the emission line-width suggests that the rapid decrease of valley polarisation with the increase of temperature is caused by the strong exciton-phonon interactions which efficiently scatter the excitons into different excitonic states that are easily accessible due to the supply of excess photoexcitation energy. The emission line-width broadening with the increase of temperature indicate residual exciton dephasing lifetime < 100 fs, that correlates with the observed rapid valley depolarisation.

• 한국가스학회지
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• 제22권2호
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• pp.59-66
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• 2018

최근 무인기에 대한 관심과 수요가 높아지고 있는 가운데, 가동범위가 넓고 전략적으로 활용이 많은 고고도장기체공 무인기의 동력원개발이 연구 목표로 검토되었다. 기존 왕복동 엔진에 수소 연료를 적용하는 기술은 현행으로써 적용성이 용이하고 경제적이다. 수소는 중량당 에너지 밀도가 높아서 한 번 충전으로 장시간 운항을 지속할 수 있고 환경적인 측면에서도 무공해 연료라는 긍정적인 부분이 존재하기 때문에 적합하다고 평가된다. 하지만 현재 수소연료를 왕복동 엔진에 적용한 개발사례가 적은 편이라 향후 기술적으로 많은 연구가 필요한 것으로 판단된다. 항공기는 운항고도에 따라 공기밀도 저감으로 인한 냉각성능 저하 또는 복사열 감소에 의한 주변온도 강하로 과냉각이 될 수 있는 요인들이 존재한다. 따라서 본 실험은 냉각수온을 변화시켜서 이러한 주변온도 변화가 수소연료 엔진에 미치는 연소특성에 대해 살펴보았다. 역화에 의한 안정적인 운전 영역의 제한은 냉각수 온도변화에 의한 영향보다 공기과잉률에 의한 영향이 지배적으로 나타났으며, 냉각수 온도가 증가할 경우 충진효율이 감소하여 토크가 감소하고 냉각수 온도가 감소할 경우 열손실이 증가하여 열효율이 감소하였다.

• Environmental Analysis Health and Toxicology
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• 제26권
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• pp.9.1-9.9
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• 2011

Objectives: In order to evaluate which temperature index is the best predictor for the health impact assessment of heat stress in Korea, several indexes were compared. Methods: We adopted temperature, perceived temperature (PT), and apparent temperature (AT), as a heat stress index, and changes in the risk of death for Seoul and Daegu were estimated with $^1{\circ}C$ increases in those temperature indexes using generalized additive model (GAM) adjusted for the non-temperature related factors: time trends, seasonality, and air pollution. The estimated excess mortality and Akaike's Information Criterion (AIC) due to the increased temperature indexes for the $75^{th}$ percentile in the summers from 2001 to 2008 were compared and analyzed to define the best predictor. Results: For Seoul, all-cause mortality presented the highest percent increase (2.99% [95% CI, 2.43 to 3.54%]) in maximum temperature while AIC showed the lowest value when the all-cause daily death counts were fitted with the maximum PT for the $75^{th}$ percentile of summer. For Daegu, all-cause mortality presented the greatest percent increase (3.52% [95% CI, 2.23 to 4.80%]) in minimum temperature and AIC showed the lowest value in maximum temperature. No lag effect was found in the association between temperature and mortality for Seoul, whereas for Daegu one-day lag effect was noted. Conclusions: There was no one temperature measure that was superior to the others in summer. To adopt an appropriate temperature index, regional meteorological characteristics and the disease status of population should be considered.