• Title/Summary/Keyword: Ex-situ

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Effect of Hydroxyl Ethyl Cellulose Concentration in Colloidal Silica Slurry on Surface Roughness for Poly-Si Chemical Mechanical Polishing

  • Hwang, Hee-Sub;Cui, Hao;Park, Jin-Hyung;Paik, Ungyu;Park, Jea-Gun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.545-545
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    • 2008
  • Poly-Si is an essential material for floating gate in NAND Flash memory. To fabricate this material within region of floating gate, chemical mechanical polishing (CMP) is commonly used process for manufacturing NAND flash memory. We use colloidal silica abrasive with alkaline agent, polymeric additive and organic surfactant to obtain high Poly-Si to SiO2 film selectivity and reduce surface defect in Poly-Si CMP. We already studied about the effects of alkaline agent and polymeric additive. But the effect of organic surfactant in Poly-Si CMP is not clearly defined. So we will examine the function of organic surfactant in Poly-Si CMP with concentration separation test. We expect that surface roughness will be improved with the addition of organic surfactant as the case of wafering CMP. Poly-Si wafer are deposited by low pressure chemical vapor deposition (LPCVD) and oxide film are prepared by the method of plasma-enhanced tetra ethyl ortho silicate (PETEOS). The polishing test will be performed by a Strasbaugh 6EC polisher with an IC1000/Suba IV stacked pad and the pad will be conditioned by ex situ diamond disk. And the thickness difference of wafer between before and after polishing test will be measured by Ellipsometer and Nanospec. The roughness of Poly-Si film will be analyzed by atomic force microscope.

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Conservation of an Endangered Corylopsis coreana Uyeki in and ex situ and Development of Cooperative Model within Local Community - III. Populational Comparison Between Natural Groups and Deforestation Groups of Corylopsis coreana UYEKI (보호종인 히어리의 자생지내외 보전과 지역사회 협력 모델 개발 - III. 몇 개의 히어리 자연집단과 벌채집단 간 개체군 비교)

  • Lim Dong-Ok;Hwang In-Chon;Choung Heung-Lak
    • Korean Journal of Environment and Ecology
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    • v.20 no.2
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    • pp.227-234
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    • 2006
  • The comparison of Corylopsis coreana populations between natural groups and deforestation groups is carried in five regions such as Seungju, Woldeung, Hwangjeon in Suncheon, Myeongseok in Jinju and Mt. Baegun in Pocheon. The number of sprouting per both $100m^2$ and each individual stump were appeared more in deforestation than in natural groups. In contrast, the height and the diameter of individuals by the number of sprouting are higher and larger in the natural groups. The relationship between the floristic composition and vegetation in the two groups of C. coreana populations was not appeared. Corylopsis coreana are propagated sprouting as well as seedling in deforestation groups located an opening area. Because of the powerful environmental adaptability through growth of the sprouting and the seedling in deforestation groups, the population of C. coreana are not extinction of species oneself, and on the contrary are showed expansion of C. coreana population after temporary disturbance.

Experimental Investigation of the Water Droplet Dynamics inside the Simulated PEMFC Single Flow Channel with GDL (GDL을 고려한 고분자전해질형 연료전지 모사 단위 유로 채널에서의 물방울 유동 특성에 대한 실험적인 고찰)

  • Kim, Han-Sang;Ji, Yong-Whi;In, Ji-Hyun;An, Ji-Yong
    • Journal of Hydrogen and New Energy
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    • v.24 no.1
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    • pp.76-83
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    • 2013
  • Polymer electrolyte membrane fuel cells (PEMFCs) are regarded as a promising alternative to replace the existing automotive power sources. To get high performance and long-term durability for PEMFC systems, novel water management is essential. To this end, a comprehensive understanding of dynamics of the liquid water droplets within an operating PEMFC plays an important role. In this work, direct visualization of dynamic behaviors of the water droplet in the ex situ unit flow channel of a PEMFC including gas diffusion layer (GDL) is carried out as one of the fundamental studies for novel water management. Water droplet dynamics such as the movement and growth of liquid water droplets are mainly presented. Effects of GDL characteristics and inlet air flow rate on the water droplet transport and its removal from the flow channel are also discussed. The data obtained in this study can contribute to build up the fundamental operating strategy including balanced water removal capacity for automotive PEMFC systems.

Development and Fabrication of Heating and Water Sparging Remediation System (HWSRS) for DNAPL-contaminated Groundwater Treatment

  • Lee, Ju-Won;Park, Won-Seok;Gong, Hyo-Young;Lee, Ae-Ri;Kim, Da-Eun;Baek, Seung-Chon;Lee, Jong-Yeol
    • Journal of Soil and Groundwater Environment
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    • v.18 no.6
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    • pp.32-37
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    • 2013
  • The scope of this study was to develop, design, and build an ex-situ remediation system of using the heating and water sparging treatment for the highly volatile DNAPL (Dense Non-Aqueous Phase Liquid) contaminated groundwater, and to conduct pilot testing at the site contaminated with DNAPL. The TCE (Trichloroethylene) removal was at the highest rate of 94.6% with the water sparging at $70^{\circ}C$ in the lab-scale test. The pilot-scale remediation system was developed, designed, and fabricated based on the results of the lab-scale test conducted. During the pilot-scale testing, DNAPL-contaminated groundwater was detained at heat exchanger for the certain period of time for pre-heating through the heat exchanger using the thermal energy supplied from the heater. The heating system supplies thermal energy to the preheated DNAPL-contaminated groundwater directly and its highly volatile TCE, $CCl_4$ (Carbontetrachloride), Chloroform are vaporized, and its vaporized and treated water is return edback to the heat exchanger. In the pilot testing the optimum condition of the HWSRS was when the water temperature at the $40^{\circ}C$ and operated with water sparging concurrently, and its TCE removal rate was 90%. The efficiency of the optimized HWSRS has been confirmed through the long-term performance evaluation process.

Optical properties of epitaxial $Gd_2$O_3:EU^{3+}$luminescent thin films depending on crystallinity ($Gd_2$O_3:EU^{3+}$ 형광체 박막의 결정성에 따른 발광특성 연구)

  • 장문형;최윤기;정권범;황보상우;장홍규;노명근;조만호;손기선;김창해
    • Journal of the Korean Vacuum Society
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    • v.12 no.4
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    • pp.275-280
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    • 2003
  • Epitaxial Gd$_2O_3:Eu^{3+}$luminescent thin films have been grout on Si(III) substrates using ionized Cluster Beam Deposition (ICBD). After the film growing, they were implanted and post annealed to change the crystal structure. The initial growth stage was monitored by using in-situ Reflection High Energy Electron Diffraction (RHEED). The formed crystal structure was identified with X-ray diffraction (XRD) technique and Fourier transform infrared (FT-R) spectroscopy. The electronic states variations were investigated by Near Edge X-ray Absorption Fine Structure (NEXAFS). Photoluminescence (PL), Cathodoluminescence (CL). and Vacuum ultraviolet (VUV) spectrum were used for examining the optical properties. We report the optical property changes depending on crystal structure and the electronic states.

Analysis of Soot Particle Morphology Using Rayleigh Debye Gans Scattering Theory (RDG 산란 이론을 이용한 그을음 탄소 입자의 형상 분석)

  • Seo, Hyoungseock;Kim, Kibum
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.9
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    • pp.641-646
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    • 2016
  • Soot particles generated by fossil fuel combustion normally have fractal morphology with aggregates consisting of small spherical particles. Thus, Rayleigh or Mie elastic light scattering theory is not feasible for determining the fractal properties of soot aggregates. This paper describes a detailed process for applying Rayleigh-Debye Gans (RDG) scattering theory to effectively extract the morphological properties of any nano-scale particles. The fractal geometry of soot aggregates produced from an isooctane diffusion flame was observed using ex situ transmission electron microscopy (TEM) after thermophoretic sampling. RDG scattering theory was then used to analyze their fractal morphology, and various properties were calculated, such as the diameter of individual soot particles, number density, and volume fraction. The results show indiscernible changes during the soot growth process, but a distinct decreasing trend was observed in the soot oxidation process. The fractal dimension of the soot aggregates was determined to be around 1.82, which is in good agreement with that produced for other types of fuel. Thus, it can be concluded that the value of the fractal dimension is independent of the fuel type.

Coloring Quality of Prunus mume and Prunus armeniaca var. ansu - Plant Genetic Resource of ex situ Conservation in Yesan - (매실나무와 살구나무 열매의 착색 특성 - 예산지역 이식의 현지외보전 식물자원 -)

  • Kang, Hee Kyoung;Yi, Ja Yeon;Kang, Hye Rin;Oh, Chan Sik;Song, Hong Seon
    • Proceedings of the Plant Resources Society of Korea Conference
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    • 2019.04a
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    • pp.48-48
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    • 2019
  • 본 연구는 대한민국 매실나무 (207점)와 살구나무 (7점) 열매의 특성평가를 위하여 개체별 과피 및 과육의 착색정도를 조사하였다. 매실나무 열매의 착색상태는 아주 약함이 65점 (31.4%)으로 가장 많았으며, 다음으로 약함 (57점, 27.5%), 아주 짙음 (56점, 27.1%), 중간 (19점, 9.2%), 짙음 (10점, 4.8%)이었다. 살구나무 열매의 착색상태는 아주 짙음이 3점(42.8%)으로 가장 많았고, 다음으로 아주 약함 (2점, 28.6%), 약함과 짙음 (각각 1점, 14.3%)이었다. 매실나무 열매의 착색부위는 적음이 105점 (50.7%)으로 가장 많았으며, 다음으로 중간 (65점, 31.4%), 아주 적음(32점, 15.5%), 많음 (5점, 2.4%)이었다. 살구나무 열매의 착색부위는 아주 많음이 5점 (71.4%)으로 가장 많았고, 다음으로 중간 및 많음 (각각 1점, 14.3%)이었다. 매실나무 과육의 빛깔은 백록색이 103점 (49.8%)으로 가장 많았으며, 다음으로 연등색 (77점, 37.2%), 등색 (25점, 12.0%), 유백색 및 암등색 (각각 1점, 0.5%)이었다. 살구나무 과육의 빛깔은 등색이 4점 (57.1%)으로 가장 많았고, 다음으로 연등색 (2점, 28.6%), 백록색 (1점, 14.3%)이었다.

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Plant Regeneration of Iris koreana Nakai through Organogenesis for Ex-situ Conservation

  • Bae, Kee-Hwa;Yun, I-Seul;Jung, Ji-Sun;Kim, Chan-Beom;Kim, Hye-Won;Hong, Yong-Sik;Oak, Min-Kyeong;Kim, Hak-Koo;Lee, Ju-Hui
    • Journal of Forest and Environmental Science
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    • v.37 no.4
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    • pp.304-308
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    • 2021
  • Iris koreana (Iridaceae) is an endangered plant native to Korea. In order to develop an in vitro propagation method, we investigated the effect of 2,4-dichlorophenoxy acetic acid (2,4-D) and a-naphthalene acetic acid (NAA) on callus induction in different I. koreana tissues. In addition, we also investigated the effect of 2,4-D and Benzyl aminopurine (BA) treatments on adventitious shoot induction in viable calli and the effect of indole-3-butyric acid (IBA) on root formation in viable shoots. We found that callus production was highest with 1.0 mg/L NAA (94.4% cultured rhizome explants), and adding low concentrations of 2,4-D to BA containing media significantly increased the frequency of shoot primordial formation. The best rooting results were obtained with 1.0 mg/L IBA, on which 98% of regenerated shoots developed roots and produced an average of 7.4 roots within 45 days. This in vitro propagation protocol will be useful for conservation, as well as for mass propagation.

Formation of Al2O2 supported Ni2P based 3D catalyst for atmospheric deoxygenation of rubberwood sawdust

  • Pranshu Shrivastava
    • Advances in Energy Research
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    • v.8 no.4
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    • pp.223-231
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    • 2022
  • An ex-situ gravitational fixed bed pyrolysis reactor was used over Al2O3 supported Ni2P based catalyst with various Ni/P molar ratios (0.5-2.0) and constant nickel loading of 5.37 mmol/g Al2O3 to determine the hydrodeoxygenation of rubberwood sawdust (RWS) at atmospheric pressure. The 3D catalysts formed were characterized structurally as well as acidic properties were determined by hydrogen-temperature programmed reduction (TPR). The Ni2P phase formed completely on Al2O3 for 1.5 Ni/P ratio, although lesser crystallite sizes of Ni2P were seen at Ni/P ratios less than 1.5. Additionally, it was shown that when nickel loading level increased, acidity increased and specific surface area dropped, probably because nickel phosphate is not easily converted to Ni2P. When Ni/P ratio was 1.5, Ni2P phase fully formed on Al2O3. The catalytic activity was explained in terms of impacts of reaction temperature and Ni/P molar ratio. At relatively high temperature of 450℃, the high-value deoxygenated produce was predominantly composed of n-alkanes. Based on the findings, it was suggested that hydrogenolysis, hydrodeoxygenation, dehydration, decarbonylation, and hydrogenation are all part of mechanism underlying hydrotreatment of RWS. In conclusion, the synthesized Ni2P/ Al2O3 catalyst was capable of deoxygenating RWS with ease at atmospheric pressure, primarily resulting in long chained (C9-C24) hydrocarbons and acetic acid.

Hydrogen Embrittlement Properties of SA-723 steel via controlling Gaseous Hydrogen Pre-charging Condition (가스 수소 장입 조건 제어를 통한 SA-723 강의 수소 취화 특성 평가)

  • Kangjin Lee;Jeonghwan Kim;Hwayoung Lee;Dohoon Kim;Soonjik Hong;Gian Song
    • Journal of the Korean Society for Heat Treatment
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    • v.36 no.6
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    • pp.382-388
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    • 2023
  • In this study, hydrogen embrittlement (HE) behavior of a SA-723 steel via controlling gaseous hydrogen pre-charging condition has been analyzed. The gaseous hydrogen charging of the SA-723 steel was performed under a constant pressure of 20 MPa of gaseous H2 at 150℃ and 300℃ for 2 and 6h, and TDS, SSRT and Charpy tests were conducted to analyze the hydrogen embrittlement (HE) behavior of the SA-723 steel. Furthermore, prior to commencing the test, these specimens were coated with Zn to prevent hydrogen from diffusing out of a specimen during the tests. The TDS results showed that the 300℃-6h and 150℃-6h charged steels contain larger amounts of hydrogen than 300℃-2h and 150℃-2h charged steel. The SSRT and Charpy test results also showed the similar trends that the mechanical properties of the steels deteriorate as the amount of hydrogen charged in the steel increases. Therefore, this study suggests that, for SA-723 steel, the charging time parameter is more effective to charge more amount of hydrogen into SA-723 steel, rather than the charging temperature.