• 한국결정성장학회:학술대회논문집
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• 한국결정성장학회 1999년도 PROCEEDINGS OF 99 INTERNATIONAL CONFERENCE OF THE KACG AND 6TH KOREA·JAPAN EMG SYMPOSIUM (ELECTRONIC MATERIALS GROWTH SYMPOSIUM), HANYANG UNIVERSITY, SEOUL, 06월 09일 JUNE 1999
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• pp.403-418
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• 1999

Fiber growth of Al2O3/R-Al-O(R=Y, Gd, Dy, Ho, Er) eutectic by the micro-pulling down methods is described. The thermal stability and strength at elevated temperature of each material is evaluated in relation to the microstructure. PACS: 81.05 Mh, 81.10 Fq, 81.30-t.

• Nuclear Engineering and Technology
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• 제54권2호
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• pp.653-660
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• 2022

The interaction between UN and CdCl₂ in the LiCl-KCl molten eutectic was studied at 1023 K. The chlorination was monitored by sampling and recording the redox potential of the medium. At 1023 K the chlorination of UN with cadmium chloride in the molten LiCl-KCl eutectic proceeds completely and results in the formation of uranium chlorides. The melts of the LiCl-KCl-UCl₃ or LiCl-KCl-UCl₄ compositions can be obtained by the end of experiment depending on the presence of metallic cadmium in the reaction zone. The higher the concentration of the chlorinating agent, the faster the reaction rate. At [CdCl₂]/[UN] = 1.65 (10% excess) the reaction proceeds to completion in about 7.5 h. At [CdCl₂]/[UN] = 7 the complete chlorination takes 2.5-3 h.

• Journal of Electrochemical Science and Technology
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• 제11권3호
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• pp.291-309
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• 2020

Chromium was electrodeposited from deep eutectic solvents-based Cr³⁺ electrolytes on HB-pencil graphite electrode. Factors influencing the electrochemical behavior and the processes of Cr nucleation and growth were explored using cyclic voltammetry and chronoamperometry techniques, respectively. Cr³⁺ reduction was found to occur through an irreversible diffusion-controlled step followed by another irreversible one of impure diffusional behaviour. The reduction behavior was found to be greatly affected by Cr³⁺ concentration, temperature, and type of hydrogen bond donor used in deep eutectic solvents (DESs) preparation. A more comprehensive model was suggested and successfully applied to extract a consistent data relevant to Cr nucleation kinetics from the experimental current density transients. The potential, the temperature, and the hydrogen bond donor type were estimated to be critical factors controlling Cr nucleation. The nucleation and growth processes of Cr from either choline chloride/ethylene glycol (EG-DES) or choline chloride/urea (U-DES) deep eutectic solvents were evaluated at 70℃ to be three-dimensional (3D) instantaneous and diffusion-controlled, respectively. However, the kinetics of Cr nucleation from EG-DES was found to be faster than that from U-DES. Cr nucleation was tending to be instantaneous at higher temperature, potential, and Cr³⁺ concentration. Cr nuclei electrodeposited from EG-DES were characterized at different conditions using scanning electron microscope (SEM). SEM images show that high number density of fine spherical nuclei of almost same sizes was nearly obtained at higher temperature and more negative potential. Energy dispersive spectroscopy (EDS) analysis confirms that Cr deposits were obtained.

• 한국재료학회지
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• 제5권1호
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• pp.123-131
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• 1995

비공정조성 공정복합재료의 일방향응고시 나타나는 액상내의 자연대류가 응고후 공정복합재료의 조성에 미치는 영향을 조사하였다. 이를 위해 Al-Cu합금을 선택하여 액상내에서 발생되는 애류의 형태를 변화시키기 위하여 상향 및 하향 일방향응고를 실시하여 각 응고조건에 따른 공정복합재료의 Cu 용질농도를 측정하였으며, 일방향응고 중에 급냉응고하여 고액계면 전방의 용질농도분포와 열분석을 통해 온도분포를 실측하였다. 그 결과로 비공정조성 공정복합재료의 일방향응고시 나타나는 대류는 공정복합재료의 용질편석에 커다란 영향을 주었으며, 고액계면 전방에서 thermal convection과 solutal convection이 모두 발생하는 하향 일방향응고된 아공정 Al-Cu합금에서 용질편석이 가장 크게 나타났다. 과공정 Al-Cu합금에서 상향 일방향응고한 경우가 하향 일방향응고한 경우보다도 용질편석이 증가한 것으로 나타났다. 이것은 본 연구조건에서는 solutal convection이 thermal convection보다 용질편석에 더 커다란 영향을 주는 것으로 생각되었다. 공정복합조직으로 성장시 고액계면은 평활계면으로 성장하였으며, 고액계면에서 액상 쪽의 용질농도는 아공정이나 과공정합금에 관계없이 공정조성의 용질농도를 가지며, 고액계면에서의 온도는 커다란 과냉도 없이 거의 공정온도 부근이었다.

• 연구논문집
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• 통권25호
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• pp.163-168
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• 1995

The intermetallic compound $Ni_3Al$ causes a peritectic reaction at the composition and temperature very close to the eutectic reaction in Ni-Al system. Although the phase diagram accepted for this system by ASM Handbook has the eutectic forming between the $\gamma$ and $\gamma$ phases, directional solidification study has shown that the eutectic occurs between $\beta$ and $\gamma$. This work examines the liquidus region using quenched, directional solidification experiments that preserve the microstructrues formed at the solidification front. It is also shown that under certain composition and growth conditions a metastable eutectic between the $\beta$ and $\gamma$ phases forms in this system. Finding of the metastable eutectic provided an important information to understand the phase equilibria near the $Ni_3Al$ composition.

• 한국주조공학회지
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• 제35권6호
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• pp.147-154
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• 2015

The effects of Sc and Sr elements on the modification of the eutectic $Mg_2Si$ phase and the castability were investigated in the Al-4wt%Mg-0.9wt%Si-0.3wt%Mn-0.15wt%Fe alloy. Measurements of the cooling curve and microstructure observations were performed to analyze the additional effects of Sc and Sr minor elements during the solidification process. A prominent effect found on the modification of the eutectic $Mg_2Si$ phase with additions of the Sr and Sc elements. Here, a fine eutectic $Mg_2Si$ phase and a decrease in the growth temperature of the eutectic $Mg_2Si$ phase were evident with an addition of Sc element up to 0.2 wt%. The growth temperature of the eutectic $Mg_2Si$ phase decreased and the effect on the modification of the eutectic $Mg_2Si$ phase increased with the addition of Sr element up to 0.02 wt%. The addition of 0.02wt%Sr had the strongest effect on the modification of the eutectic $Mg_2Si$ phase, and the resulting microstructure of the eutectic $Mg_2Si$ phase was found to have a fibrous morphology with a decreased aspect ratio and an increased modification ratio. Fluidity and shrinkage tests were conducted to evaluate the castability of the alloy. The addition of 0.02wt%Sr effectively increased the fluidity of the alloy, while an addition of Sc did not show any effect compared to when nothing was added. The maximum filling length was recorded for 0.01wt%TiB-0.02wt%Sr owing to the effect of the fine ${\alpha}$-Al grains. The macro-shrinkage ratio decreased, while the micro-shrinkage ratio increased with the addition of various eutectic modifiers. The highest ratio of micro-shrinkage was recorded for the 0.02wt%Sr condition. However, the total shrinkage ratio was nearly identical regardless of the amounts added in this study.

• 열처리공학회지
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• 제31권6호
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• pp.300-306
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• 2018

In the present study we proposed new equations to predict the liquidus temperature curve for hypoeutectic Al-Si-Cu-Mg alloy. A thermodynamic simulation was carried out to calculate the liquidus temperature, eutectic temperature and eutectic Si concentration with different Si, Cu, and Mg contents in hypoeutectic Al-Si alloys. Regressed equations were derived using the thermodynamic simulation results by multiple regression analysis. The proposed equations were compared with the equations reported previously by other researchers and agreed better with the experimental data. The addition of Cu and Mg lowered the eutectic temperature. The eutectic Si concentration was decreased by adding Cu whereas that was increased by adding Mg. Al-Si binary phase diagram was successfully predicted with a consideration of the effect of Cu and Mg addition by using the proposed equations.

• 한국재료학회지
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• 제13권6호
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• pp.381-388
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• 2003

Directional solidification experiments were carried out at 0.5-150 $\mu\textrm{m}$/s in the Co-base superalloy ECY 768. As increasing solidification rate, the dendrite length increased and it reached the maximum at 150 $\mu\textrm{m}$/s, where the tip temperature is close to the liquidus. The liquidus and eutectic temperatures could be estimated by comparing the dendrite lengths and the temperature gradients at the solid/liquid interface and those were estimated as $1424.6^{\circ}C$ and $1343^{\circ}C$ respectively. Between the dendrites just below final freezing temperature, MC carbide and $M_{23}$$C_{6}$ carbide were found. It was confirmed that the script or blocky shape was Ta or W-rich MC carbide, and the lamellar shape was Cr-rich eutectic carbide. The solid/liquid interface morphology clearly showed that the Cr-rich eutectic carbide formed just after the script type MC carbide.

• 한국주조공학회지
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• 제38권6호
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• pp.121-131
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• 2018

The effect of additives on the castability of the AC2BS aluminum alloy, which contains 35% recycled scrap, was investigated. For the wide utilization of the recycled scrap AC2BS aluminum alloy, the research results were compared to those with the AC2B virgin alloy, which is typical Al-Si-Cu alloy system. It was confirmed that the addition of Al-5%Ti-1%B increased the ${\alpha}$-Al nucleation temperature during solidification and decreased the grain size through cooling curve and microstructural observations of the recycled alloy. It was also found that an addition of Al-10%Sr decreased the eutectic Si growth temperature during the solidification process and modified the shape of the eutectic Si of the recycled alloy. The characteristics of fluidity, shrinkage and solidification crack strength were evaluated. For the AC2BS aluminum alloy containing 35% recycled scrap, both ${\alpha}$-Al grain refinement due to Ti-B and eutectic Si modifications due to Sr contributed to the improvement of the fluidity. The macro- shrinkage ratio increased with additions of both Al-10%Sr and Al-5%Ti-1%B and the micro-shrinkage ratio increased with the addition of Al-10%Sr but decreased with the addition of Al-5%Ti-1%B. The casting characteristics of TiB and Sr-treated AC2BS aluminum alloy containing 35% recycled scrap are similar to those of AC2B virgin alloy. The improvement of the solidification crack strength of the AC2BS aluminum alloy was possible by the reduction of the grain boundary the stress concentration through the enhancement by both ${\bullet}{\cdot}$-Al refinement and eutectic Si modification. More extensive use of the AC2BS aluminum alloy containing 35% recycled scrap can be expected in the future.

• 한국주조공학회지
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• 제32권6호
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• pp.261-268
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• 2012

The effects of thickness, base element and additive to inoculant on the number of eutectic cells and chill depth of thin-section gray cast iron were investigated. Meanwhile the number of eutectic cells increased by inoculation, chill depth decreased. The former decreased and the latter increased by holding the melt at the temperature range between 1,450 and $1,500^{\circ}C$. The former was more for the thinner casting with the thickness of 5 mm than the other. The result of thermal analysis coincided well with the change of macrostructure. The former increased and the latter decreased with the increased contents of carbon, silicon and the silicon content by inoculation. The former decreased and the latter increased with increased manganese content. The number of eutectic cells decreased as the amounts of rare earth and the bismuth added to this inoculant increased. With the addition of sulfur of 0.10 wt% of the weight of this inoculant, the maximum number of eutectic cells was obtained.