• Title/Summary/Keyword: Ether-Ether-Ester

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Volatile Flavor Components in Various Edible Portions of Capsella bursa-pastoris (냉이의 식용부위별 휘발성 향기성분)

  • Lee, Mie-Soon;Choi, Hyang-Sook
    • Korean Journal of Food Science and Technology
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    • v.28 no.5
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    • pp.822-826
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    • 1996
  • Volatile flavor components from various edible portions of Capsella bursa-pastoris were collected by simultaneous steam distillation-extraction (SDE) method using diethyl ether as solvent. Essential oils were analyzed by gas chromatography (GC) and combined gas chromatography-mass spectrometry (GC-MS). Thirty four volatile flavor components, including 12 hydrocarbons, 2 aldehydes, 2 ketones, 5 alcohols, 1 ester, 10 acids and 2 miscellaneous ones were confirmed in whole samples. Thirty one components, including 11 hydrocarbons, 5 aldehydes, 4 ketones, 5 alcohols, 1 esters and 5 miscellaneous ones were confirmed in leaves. Twenty four components, including 5 hydrocarbons, 1 aldehyde, 2 ketones, 6 alcohols, 2 esters, 1 acid and 7 miscellaneous ones were confirmed in roots. The kinds and amounts of volatile flavor components revealed different patterns depending upon various edible portions. Relatively greater numbers of volatile flavor components were identified in leaves compared with roots of these wild plants. The characteristic aroma of Capsella bursa-pastoris appeared to be due to combination of C6 alcohol and acids, terpene alcohol and sulfur containing compounds.

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Effect of Salinity on Lignin and Hydroxycinnamic Acid Contents in Rice

  • Wi Seung Gon;Kim Jae-Sung;Kim Jin-Hong;Baek Myung Hwa;Yang Dae-Hwa;Lee Myung Chul;Chung Byung Yeoup
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.49 no.5
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    • pp.368-372
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    • 2004
  • The lignin contents between IR-29 and Pokkali were not significantly different in the absence of NaCl, but they were slightly increased at 40 mM NaCl. Although lignin contents were not relatively significantly different between salt treated and control plants, the total yields of alkaline nitrobenzene oxidation ranged from 17.4-20.0 mg/g of cell wall residue at 40 mM NaCl were significantly different compared with control plants (11.8-12.2 mg/g). The total amounts of ester-linked hydroxycin-namic acids in IR-29 were decreased from 14.5 to 9.9mg/g, while Pokkali is almost same levels (14.9-15.0 mg/g) under treated and control with 40 mM NaCl. In contrast, the total amounts of ether-linked hydroxycinnamic acids were increased from 9.4 to 13.9 mg/g together with an opposite trend in Pokkali as a decrease 10.9 to 8.8 mg/g under treated and control with 40 mM NaCl. These results revealed that IR-29 is more sensitive in response to 40 mM NaCl in terms of hydroxycinnamic acids than Pokkali.

Synthesis and Cholesteric Mesophase Properties of (Hydroxypropyl)celluloses, Their Ester and Ether Derivatives ((Hydroxypropyl)celluloses와 에스테르 및 에테르 유도체들의 합성과 Cholesteric 상의 특성)

  • ;;;Yoshinobu Tsujii
    • Polymer(Korea)
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    • v.25 no.2
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    • pp.279-292
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    • 2001
  • Two kinds of (hydroxypropyl)cellulose(HPCs) with different molar substitution (MS) and three types of derivatives based on the HPCs: (acetoxypropyl)celluloses, (ethoxypropyl)celluloses, and (cyanoethoxyprofyl)celluloses were synthesized, and their thermal and mesomorphic properties were investigated. All samples, which exhibit cholesteric reflection colours at room temperature, formed right-handed helicoidal structures whose optical pitches (λ$_{ms}$ ) increase with temperature. However, the isotropization ($T_{i}$) and glass temperatures, the magnitude of λ$_{m}$ of the mesophase at the same temperature, and the temperature dependence of λ$_{m}$ of the investigated derivatives highly depended on MS and the length and structure of the side chain introduced in HPC. The results were discussed in terms of the difference in the polarity and flexibility of the substituents and the distance between the main chains. For all derivatives, Am values approached infinity at temperatures above the $T_{i}$, of the mesophase, and no reversal in the sense of the pitch with temperature was detected.

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Volatile Flavor Components in Various Edible Portions of Calystegia japonica $(T_{HUNB})\;C_{HOIS}$. (메꽃의 식용부위별 휘발성 풍미성분)

  • Lee, Mie-Soon;Choi, Hyang-Sook
    • Korean Journal of Food Science and Technology
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    • v.26 no.4
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    • pp.359-364
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    • 1994
  • Volatile flavor components from various edible portions of Calystegia japonica $(T_{HUNB})\;C_{HOIS}$ were collected by simultaneous steam distillation-extraction(SDE) method using diethyl ether as solvent. Essential oils were analyzed by gas chromatography(GC) and combined gas chromatography-mass spectrometry(GC-MS). Thirty nine volatile flavor components, including 21 hydrocarbons, 1 aldehyde, 4 ketones, 7 alcohols, 4 esters, 1 acid and 1 miscellaneous one were confirmed in leaves. Twenty six components, including 16 hydrocarbons, 2 aldehydes, 3 ketones and 5 alcohols were confirmed in stems, and 52 components, including 26 hydrocarbons, 2 aldehydes, 5 ketones, 13 alcohols, 1 ester, 1 acid and 4 miscellaneous ones were confirmed in roots. The kinds and amounts of volatile flavor components revealed different patterns depending upon various edible portions. Relatively greater numbers of volatile flavor components were identified in roots compared with other portions of this wild plant.

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Effect of chemical input during wet air oxidation pretreatment of rice straw in reducing biomass recalcitrance and enhancing cellulose accessibility

  • Morone, Amruta;Chakrabarti, Tapan;Pandey, R.A.
    • Korean Journal of Chemical Engineering
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    • v.35 no.12
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    • pp.2403-2412
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    • 2018
  • The present study was aimed at evaluating the effect of variable sodium carbonate ($Na_2CO_3$) loading during wet air oxidation (WAO) pretreatment of rice straw in reducing biomass recalcitrance. The research study was intended to increase the cellulose recovery, hemicellulose solubilization, lignin removal in the solid fraction and limiting the generation of inhibitors in the liquid fraction while reducing the chemical input. The operating condition of $169^{\circ}C$, 4 bar, 18 min and 6.5 g/L $Na_2CO_3$ loading resulted in maximum cellulose recovery of 82.07% and hemicellulose solubilization and lignin removal of 85.43% and 65.42%, respectively, with a total phenolic content of 0.36 g/L in the liquid fraction. The crystallinity index increased from 47.69 to 51.25 along with enzymatic digestibility with an increase in $Na_2CO_3$ loading from 0 to 6.5 g/L as a result of removal of barriers for saccharification via effective cleavage of ether and ester bonds cross-linking the carbohydrates and lignin as indicated by FT-IR spectroscopy. A further increase in the $Na_2CO_3$ loading to 9.5 g/L did not significantly increase the sugar release. Thus, it was concluded that 6.5 g/L $Na_2CO_3$ during WAO is sufficient to increase the delignification and deacetylation, leading to significant changes in apparent cellulose crystallinity inter alia improvement in cellulose accessibility and digestibility of rice straw.

Effects of Mold Temperatures on Physical Properites of Injection Molded Thermoplastic Polyurethanes (사출성형 열가소성 폴리우레탄의 물리적 성질에 미치는 금형 온도 영향)

  • Lee, Dai-Soo;Kim, Seong-Geun;Nguyen, Vinh-Khanh;Lee, Wing-Ji;Pang, Su-Jin
    • Elastomers and Composites
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    • v.39 no.4
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    • pp.286-293
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    • 2004
  • Ester- and ether-based thermoplastic polyurethanes of different hardness were injection molded at different mold temperatures and effects of mold temperature on the physical properties of TPUs were investigated. Glass transition temperatures of soft segments of TPUs were hardly changed by mold temperatures. The phase separation of soft and hard segments of injection molded TPUs were affected little by mold temperatures. However, crystallinity of hard segments, temperature range of rubbery plateau, and tensile strength of injection molded TPUs decreased with increasing mold temperatures for TPUs of high hardness. However, injection molded TPUs of low hardness showed increases of crystallinity of hard segments, temperature range of rubbery plateau, and tensile strength with increasing mold temperatures. Different physical properties of injection molded TPUs depending on mold temperatures were attributed to different crystallization and physical crosslinking effects of hard segments.

Coated Wire Lead(Ⅱ) Ion-Selective Electrodes based on Crown Ethers (Crown Ether를 이용한 탐침형 납 이온선택성 전극)

  • Jang, Mi Kyeong;Ha, Kwang Soo;Seo, Moo Lyong
    • Journal of the Korean Chemical Society
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    • v.41 no.7
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    • pp.337-342
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    • 1997
  • Acryloylmethylbenzo-15-crown-5 was prepared from the reaction of 4'-hydroxymethylbenzo-15-crown-5 with acryloyl chloride. And, poly(acryloylmethylbenzo-15-crown-5) [poly(AMB15C5)] was synthesized by radical polymerization using AIBN as initiator in benzene. Coated wire lead(II) ion-selective electrodes ($Pb^{2+}$-CWISEs) using either poly(AMB15C5) or B15C5 as neutral carrier were prepared, respectively. $Pb^{2+}$-CWISEs gave linear responses with slopes of 28$\pm$ 1mV per decade within the concentration range of $10^{-5} M{\sim}10^{-1}$ M, respectively. Also, the detection limits were $10^{-6}$ M and response times were either 3 or 5 min. for B15C5 and poly(AMB15C5), respectively. $Pb^{2+}$-CWISE base on B15C5 was rather unstable than poly(AMB15C5)'s due to solubility of the B15C5 in water. The selectivity coefficients of a variety of interfering ions such as $Mg^{2+},\; Ca^{2+},\; Co^{2+},\; Ni^{2+},\; Cu^{2+},\; Zn^{2+}$ and $Cd^{2+}$ were small ($10^{-4}{\sim}10^{-5}$), while those of $Na^+$ and $K^+$ were large (0.1∼0.01). In addition, the electrode responses depended upon the pH of test solution and the composition of the membrane. In the range pH 3∼6 of test solution, potentials of Pb2+-CWISEs were hardly changed. The optimal contents of B15C5 and poly(AMB15C5) were 7.7 wt% and 13.1 wt%, respectively.

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Preparation and Properties of DMF-Based Polyurethanes Containing Bio-Polyol/Ester-Polyol for Wet-Type Polyurethane Artificial Leather (습식 인조피혁용 바이오 폴리올/폴리에스터 폴리올을 함유한 DMF 기반 폴리우레탄의 제조 및 물성)

  • Sur, Suk-Hun;Choi, Pil-Jun;Ko, Jae-Wang;Park, Ji-Hyeon;Lee, Jae-Yeon;Lee, Young-Hee;Kim, Han-Do
    • Clean Technology
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    • v.25 no.1
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    • pp.7-13
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    • 2019
  • Recently, attention has been paid to obtaining bio-polyols from renewable resources. Successful use of these natural ingredients successfully produced in the industry for the synthesis of various polyurethanes is a very important task. In this study, a series of dimethylformamide (DMF) based polyurethanes were synthesized from methylene diphenyl diisocyanate (MDI)/1, 4-butanediol and bio-polyol (polytrimethylene ether glycol based on 1, 3-propanediol : B-POL)/polyester polyol (polyadipate diol based on 1,4-butandiol : H-PET). The effect of different ratio of bio-polyol (B-POL)/polyester polyol (H-PET) on the physical properties of polyurethane was investigated. As the B-POL content in B-POL/H-PET mixture increased, the glass transition of soft segment (Tgs) and tensile strength of polyurethane decreased, however, the elongation at break and tear strength increased. On the other hand, artificial leather was produced by wet process using synthesized DMF-based polyurethanes. It was found that there was almost no difference in the effect of the B-POL/H-PET composition on the average size and density (the number of cells per unit volume) of the porous cells formed in artificial leather. These results show that there is no problem in using bio-polyol (B-POL) based polyurethane for artificial leather produced by wet process.

Thermotropic Liquid Crystalline Behavior of α,ω-Bis(4-nitroazobenzene-4'-carbonyloxy)alkanes (α,ω-비스(4-니트로아조벤젠-4'-카보닐옥시)알칸들의 열방성 액정 거동)

  • Jeong, Seung Yong;Hwang, Dong Jun;Ma, Yung Dae
    • Applied Chemistry for Engineering
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    • v.21 no.2
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    • pp.230-237
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    • 2010
  • A homologous series of linear liquid crystal dimers, ${\alpha},{\omega}$-bis(4-nitroazobenzene-4'-carbonyloxy)alkanes (NATWESn, n = 2~8, 10, the number of methylene units in the spacer) have been synthesized, and the thermal behavior of the series has been investigated. All the dimers formed enantiotropic nematic phases. The nematic-isotropic transition temperatures of the dimers and their entropy variation at the phase transition showed a large odd-even effect as a function of n. This behavior was rationalized in terms of the change in the average shape of the spacer on varing the parity of the spacer. The thermal stability and degree of order in the nematic phase and the magnitude of the odd-even effect of NATWESn were very similar to those of the corresponding ether compounds, while they were significantly different from those of the monomesogenic compounds, 4-{4'-(nitrophenylazo)phenoxy}alkanoyl chlorides and the side-chain liquid-crystalline polymers, the poly[1-{4-(4'-nitrophenylazo) phenoxycarbonylalkanoyloxy}ethylene]s. The results were discussed in terms of the 'irtual trimer model'by Imrie.

Synthesis and Property of Modified PMMA Resin Using Polyurethane and Polyurethane Dimethacrylate (Polyurethane과 polyurethane dimethacrylate를 이용한 내충격성 PMMA수지의 합성과 그 물성)

  • Kim, Dong-Hyun;Kim, Ju-Young;Seo, Kyung-Do
    • Applied Chemistry for Engineering
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    • v.4 no.3
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    • pp.616-626
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    • 1993
  • Polyurethane(PU) have an excellent flexibility and toughness so that it has been widely used as an elastomer. PMMA was blended with PU to improve the impact property. Five types of PU, having different molecular weight and different polyol types, were prepared and blended with PMMA in order to investigate the effect of molecular weight and polyol type of PU on property of PU-PMMA blend. Tensile strength of PU-PMMA blend was determined by Inston. Differential Scanning Calorymetry(DSC) and Scanning. Elctron Microscopy(SEM) were used to observe morphology change and glass transition temperature changes of PU-PMMA blends. Transparency of PU-PMMA blends was determined by haze meter. But, owing to intrinsic incompatability of PU-PMMA, Low impact strength of PMMA wasn't improved through PU-PMMA blend. therefore, polyurethane dimethacrylate(PUD), having similiar chemical structure to PU and two vinyl group at both ends, was prepared and reacted with methyl methacrylate(MMA) to form crosslinked copolymer Mechanical property of this crosslinked polymer, such as impact strength and transparency, was investigated by Instron, Izod type (Cantilever beam) impact tester and haze meter. Results of these measurements showed that crosslinked copolymer of PUD-MMA was better impact resistance than PMMA and maintained similar transparency to PMMA.

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