• Title/Summary/Keyword: Erosion/Corrosion

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Effect of Solution Temperature on the Cavitation Degradation Properties of Epoxy Coatings for Seawater Piping

  • Jeon, J.M.;Yoo, Y.R.;Jeong, M.J.;Kim, Y.C.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.20 no.6
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    • pp.335-346
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    • 2021
  • Since epoxy resin coating shows excellent properties in formability, adhesion, and corrosion resistance, they have been extensively used in many industries. However, various types of damages in the epoxy coated tube within a relative short time have been reported due to cavitation erosion, liquid impingement, variation of temperature and pressure. Nevertheless, there has been little research on the effect of temperature on the cavitation degradation of epoxy coatings. Therefore, this work used an ultrasonic cavitation tester to focus on the effect of solution temperature on the cavitation properties of 3 kinds of epoxy coatings in 3.5% NaCl. The cavitation properties were discussed basis on the material properties and environmental aspects. As the solution temperature increased, even though with large fluctuation, the cavitation degradation rates of A and B coatings were reduced rapidly, but the rate of C coating was decreased gradually. In addition to the cushioning effect, the reason that the cavitation degradation rate reduced with solution temperature was partly related to the brittle fracture and water absorptivity of the epoxy coatings, and the water density, but was little related to the shape and composition of the compound in the coatings or the phase transition of the epoxy coating.

Numerical Simulations on the Thermal Flow and Particle Behaviors in the Gas Reversal Chamber of a Syngas Cooler for IGCC (IGCC 합성가스 냉각기 GRC의 열유동 및 입자거동 특성에 대한 전산해석 연구)

  • Park, Sangbin;Ye, Insoo;Ryu, Changkook;Kim, Bongkeun
    • Journal of the Korean Society of Combustion
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    • v.18 no.1
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    • pp.21-26
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    • 2013
  • In the Shell coal gasification process, the syngas produced in a gasifier passes through a syngas cooler for steam production and temperature control for gas cleaning. Fly slag present in the syngas may cause major operational problems such as erosion, slagging, and corrosion, especially in the upper part of the syngas cooler (gas reversal chamber, GRC). This study investigates the flow, heat transfer and particle behaviors in the GRC for a 300 MWe IGCC process using computational fluid dynamics. Three operational loads of 100%, 75% and 50% were considered. The gas and particle flows directly impinged on the wall opposite to the syngas inlet, which may lead to erosion of the membrane wall. The heat transfer to the wall was mainly by convection which was larger on the side wall at the inlet level due to the expansion of the cross-section. In the evaporator below the GRC, the particles were concentrated more on the outer channels, which needs to be considered for alleviation of fouling and blockage.

Study on Design Change of a Pipe Affected by Liquid Droplet Impingement Erosion (액적충돌침식 영향 배관의 설계변경에 관한 연구)

  • Hwang, Kyeong-Mo;Lee, Chan-Gyu;Bhang, Keug-Jin;Yim, Young-Sig
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.10
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    • pp.1097-1103
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    • 2011
  • Liquid droplet impingement erosion (LDIE) is caused by the impact of high-velocity droplets entrained in steam or air on metal. The degradation caused by the LDIE has been experienced in steam turbine internals and high-velocity airplane components (particularly canopies). Recently, LDIE has also been observed in the pipelines of nuclear plants. LDIE among the pipelines occurs when two-phase steam experiences a high pressure drop (e.g., across an orifice in a line to the condenser). In 2011, a nuclear power plant in Korea experienced a steam leak caused by LDIE in a pipe through which a two-phase fluid was flowing. This paper describes a study on the design change of a pipe affected by LDIE in order to mitigate the damage. The design change has been reviewed in terms of fluid dynamics by using the FLUENT code.

Failure Assessment and Strength of Steam Generator Tubes with Wall Thinning (증기발생기 전열관 감육부의 강도 및 손상평가)

  • Seong, Ki-Yong;Ahn, Seok-Hwan;Yoon, Ja-Moon;Nam, Ki-Woo
    • Journal of Ocean Engineering and Technology
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    • v.21 no.2 s.75
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    • pp.50-59
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    • 2007
  • Steam generator tubes are degraded from wear, stress corrosion cracking, rupture and fatigue and so on. Therefore, the failure assessment of steam generator tube is very important for the integrity of energy plants. In the steam generator tubes, sometimes, the local wall thinning may result from severe degradations such as erosion-corrosion damage and wear due to vibration. In this paper, the elasto-plastic analysis was performed by FE code ANSYS on steam generator tubes with wall thinning. Also, the four-point bending tests were performed on the wall thinned specimens, and then it was compared with the analysis results. We evaluated the failure mode, fracture strength and fracture behavior from the experiment and FE analysis. Also, it was possible to predict the crack initiation point by estimating true fracture ductility under multi-axial stress conditions at the center of the thinned area from FE analysis.

A Feasibility Study on the Brazing of Zircaloy-4 with Zr-Be Binary Amorphous Filler Metals (비정질 이원계 합금 Zr-Be 용가재를 이용한 지르칼로이-4의 브레이징 타당성 검토)

  • 고진현;박춘호;김수성
    • Journal of Welding and Joining
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    • v.17 no.4
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    • pp.26-31
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    • 1999
  • An attempt was made in this study to investigate the brazing characteristics of Zr-Be binary amorphous alloys for the development of a new brazing filler metal for joining Zircaloy-4 nuclear fuel cladding tubes. This study was also aimed at the feasibility study of rapidly solidified amorphous alloys to substitute the conventional physical vapor-deposited(PVD) metallic beryllium. The $Zr_{1-x}Be_{x}$($0.3\leq$x$\leq0.5$) binary amorphous alloys were produced in the ribbon form by the melt-spinning method. It was confirmed by x-ray diffraction that the ribbons were amorphous. The amorphous. the amorphous alloys were used to join bearing pads on Zircaloy-4 nuclear fuel cladding tubes. Using Zr-Be amorphous alloys as filler metals, it was found that the reduction in the tube wall thickness caused by erosion was prevented. Especially, in the case of using $Zr_{0.65}Be_{0.35}$ and $Zr_{0.7}Be_{0.3}$ amorphousalloys, the smooth and spherical primary $\alpha$-Zr particles appeared in the brazed layer, which was the most desirable microstructure from the corrosion-resistance standpoint.

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Electrochmical Characteristics by Water Cavitation Peening of Cu Alloy (워터캐비테이션피닝된 동합금의 전기화학적 특성평가)

  • Kim, Seong-Jong;Han, Min-Su;Kim, Min-Sung
    • Journal of Advanced Marine Engineering and Technology
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    • v.36 no.8
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    • pp.1083-1090
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    • 2012
  • Copper alloys are widely used for casting materials including ship's propellers and pump impellers as they provide high corrosion resistance. In addition, the demand for these alloys is increasing with rapid growth of offshore structures and exploitation of various substitute energy sources. However, they require regular maintenance because of erosion and cavitation damages induced by exposure to marine environment at high speed flows for a long period of time. Water cavitation peening have received attention as one of surface modifications for durability improvement of the copper alloys. This is a environment friendly technology without influence of heat and easily applicable to casting materials. In this research, water cavitation peening was employed in distilled water for copper alloy castings as a function of time and evaluation of corrosion resistance was followed in seawater for the modified surface by using electrochemical methods. The result suggests that the water cavitation peening for 2 minutes was found to be the optimal peening parameter in terms of durability and corrosion resistance.

DEPENDENCY OF SINGLE-PHASE FAC OF CARBON AND LOW-ALLOY STEELS FOR NPP SYSTEM PIPING ON PH, ORIFICE DISTANCE AND MATERIAL

  • Moon, Jeong-Ho;Chung, Hung-Ho;Sung, Ki-Woung;Kim, Uh-Chul;Rho, Jae-Seong
    • Nuclear Engineering and Technology
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    • v.37 no.4
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    • pp.375-384
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    • 2005
  • To investigate the flow-accelerated corrosion (FAC) dependency of carbon steel (A106 Gr. B) and low-alloy steels (1Cr-1/2Mo, 21/4Cr-1Mo) on pH, orifice distance, and material, experiments were carried out. These experiments were performed using a flow velocity of 4 m/sec (partly 9 m/sec) at pH $8.0\~10.0$ in an oxygen-free aqueous solution re-circulated in an Erosion-Corrosion Test Loop at $130^{\circ}\;{\ldots}$ for 500 hours. The weight loss of the carbon steel specimens appeared to be positively dependent on the flow velocity. That of the carbon and low-alloy steel specimens also showed to be distinguishably dependent on the pH. At pH levels of $8.0\~9.5$ it decreased, but increased from 9.5 to 10.0. Utility water chemistry personnel should carefully consider this kind of pH dependency to control the water system pH to mitigate FAC of the piping system material. The weight loss of the specimens located further from the orifice in the distance range of $6.8\~27.2$ mm was shown to be greater, except for 21/4Cr-1Mo, which showed no orifice distance dependency. Low alloy steel specimens exhibited a factor of two times better resistance to FAC than that of the carbon steel. Based on this kind of FAC dependency of the carbon and low-alloy steels on the orifice distance and material, we conclude that it is necessary to alternate the composition of the secondary piping system material of NPPs, using low-alloy steels, such as 21/4Cr-1Mo, particularly when the system piping has to be replaced.

Ultrasonic Cavitation Behavior and its Degradation Mechanism of Epoxy Coatings in 3.5 % NaCl at 15 ℃

  • Jang, I.J.;Jeon, J.M.;Kim, K.T.;Yoo, Y.R.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.20 no.1
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    • pp.26-36
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    • 2021
  • Pipes operating in the seawater environment faces cavitation degradation and corrosion of the metallic component, as well as a negative synergistic effect. Cavitation degradation shows the mechanism by which materials deteriorate by causing rapid change of pressure or high-frequency vibration in the solution, and introducing the formation and explosion of bubbles. In order to rate the cavitation resistance of materials, constant conditions have been used. However, while a dynamic cavitation condition can be generated in a real system, there has been little reported on the effect of ultrasonic amplitude on the cavitation resistance and mechanism of composites. In this work, 3 kinds of epoxy coatings were used, and the cavitation resistance of the epoxy coatings was evaluated in 3.5% NaCl at 15 ℃ using an indirect ultrasonic cavitation method. Eleven kinds of mechanical properties were obtained, namely compressive strength, flexural strength and modulus, tensile strength and elongation, Shore D hardness, water absorptivity, impact test, wear test for coating only and pull-off strength for epoxy coating/carbon steel or epoxy coating/rubber/carbon steel. The cavitation erosion mechanism of epoxy coatings was discussed on the basis of the mechanical properties and the effect of ultrasonic amplitude on the degradation of coatings.

Fracture Behavior Evaluation of Wall Thinned pipes by Finite Element Analysis (감육배관의 요한요소해석에 의한 파괴거동 평가)

  • AHN SEOK-HWAN;NAM KI-Woo;KIM JIN-WOOK;LEE SOO-SIG;YOON JA-MUN
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2004.05a
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    • pp.320-325
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    • 2004
  • Fracture behaviors and strength of pipes with local wall thinning are very important Jar the integrity of energy plants. In pipes of energy plants, sometimes, the local wall thinning may result from severe erosion-corrosion damage. Recently, the effects of local wall thinning on strength and fracture behaviors of piping system have been well studied. In this paper, the elasto-plastic analysis is performed by FE code ANSIS. We evaluated the failure mode, fracture strength and fracture behavior from FE analysis.

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A Fundamental Study on Sulfate Resistance of Inorganic Binder with High Acid Resistance (고내산성 무기바인더의 내황산성에 관한 기초적 특성 연구)

  • Choi, Jung-Gu;Lee, Gun-Cheol;Lee, Gun-Young;Ko, Dong-Guen;Gao, Shan
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.11a
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    • pp.11-12
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    • 2015
  • This study analyzed sulfate resistance of strongly acid-resistant inorganic binder based on industrial byproducts. According to the study experiment, compared to OPC mixture, the mixture of high acid-resistant inorganic binder had excellent chemical resistance against 10% H2SO4 solution. In the case of ordinary portland cement, its sample with 28 days of immersion had severe corrosion on its mortar erosion part, and thus external appearance was damaged greatly, and compression strength decreased by around 57% and more.

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