• Title/Summary/Keyword: Equivalent Mass

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Electrochemical Properties of Polypyrrole/Polyfuran Polymer Composite Electrode (피롤/퓨란 고분자 복합체 전극의 전기화학적 성질)

  • Cha, Seong Keuck
    • Journal of the Korean Chemical Society
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    • v.42 no.6
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    • pp.664-671
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    • 1998
  • Poly pyrrole polymer(ppy) has an excellent electrical conductivity and can be easily polymerized on anode to give various morophology according to doped anion on electroactive sites. To improve the properties of brittleness, ageing and hydrophobisity, poly furan polymer(pfu) having a high initiation potential was anodically implanted in this porous ppy film matrix to get the Pt/ppy/pfu(x)type of polymer composite electrode. Cyclic voltammetry and electrochemical impedance methods were used to these electrode, where $PF_6^-,\; BF_4^-$, and $ClO_4^-$ ions were employed as dopants. The composition of the pfu(x) at the electrode was changed from 0 to 1.10, but the range was useful only at 0.1 to 0.2 as the redox electrode. The polymer composite electrode doped with $PF_6^-$ was better in charge transfer resistance by a factor of 40 times and in double layer capacitance by a factor of 20 times than others. The charge transfer in the polymer film of the electrode was influenced on frequency change and equivalent circuit of this electrode had Warburg impedance including mass transfer.

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Development and Its Application of a Discrete Fracture Flow Model for the Analysis of Gas-Water Transient Flow in Fractured Rock Masses Around Storage Cavern (지하저장공동 주변 불연속 암반에서의 가스-물 천이유동해석을 위한 개별균열 유동모델의 개발 및 응용)

  • 나승훈;성원모
    • Proceedings of the Korean Geotechical Society Conference
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    • 2000.11a
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    • pp.705-712
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    • 2000
  • The fluid generally flows through fractures in crystalline rocks where most of underground storage facilities are constructed because of their low hydraulic conductivities. The fractured rock is better to be conceptualized with a discrete fracture concept, rather continuum approach. In the aspect of fluid flow in underground, the simultaneous flow of groundwater and gas should be considered in the cases of generation and leakage of gas in nuclear waste disposal facilities, air sparging process and soil vapor extraction for eliminating contaminants in soil or rock pore, and pneumatic fracturing for the improvement of permeability of rock mass. For the purpose of appropriate analysis of groundwater-gas flow, this study presents an unsteady-state multi-phase FEM fracture network simulator. Numerical simulation has been also conducted to investigate the hydraulic head distribution and air tightness around Ulsan LPG storage cavern. The recorded hydraulic head at the observation well Y was -5 to -10 m. From the results obtained by the developed model, it shows that the discrete fracture model yielded hydraulic head of -10 m, whereas great discrepancy with the field data was observed in the case of equivalent continuum modeling. The air tightness of individual fractures around cavern was examined according to two different operating pressures and as a result, only several numbers of fractures neighboring the cavern did not satisfy the criteria of air tightness at 882 kPa of cavern pressure. In the meantime, when operating pressure is 710.5 kPa, the most areas did not satisfy air tightness criteria. Finally, in the case of gas leaking from cavern to the surrounding rocks, the resulted hydraulic head and flowing pattern was changed and, therefore, gas was leaked out from the cavern ceiling and groundwater was flowed into the cavern through the walls.

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Ring-Shaped Inductive Sensor Design and Application to Pressure Sensing (환형 인덕티브 센서의 설계 및 압력센서로의 적용)

  • Noh, Myounggyu;Kim, Sunyoung;Baek, Seongki;Park, Young-Woo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.10
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    • pp.995-999
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    • 2015
  • Inductive sensors are versatile and economical devices that are widely used to measure a wide variety of physical variables, such as displacement, force, and pressure. In this paper, we propose a simple inductive sensor consisting of a thin partial ring and a coil set. The self-inductance of the sensor was estimated using magnetic circuit analysis and validated through finite element analysis (FEA). The natural frequency of the ring was estimated using Castigliano's theorem and the method of equivalent mass. The estimation was validated through experiments and FEA. A prototype sensor with a signal processing circuit is built and applied to noninvasively sense the pressure inside a flexible tube. The obtained sensor outputs show quadratic behavior with respect to the pressure. When fitted to a quadratic equation, the least-square measurement error was less than 2%. The results confirm the feasibility of pressure sensing using the proposed inductive sensor.

Interaction analysis of three storeyed building frame supported on pile foundation

  • Rasal, S.A.;Chore, H.S.;Sawant, V.A.
    • Coupled systems mechanics
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    • v.7 no.4
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    • pp.455-483
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    • 2018
  • The study deals with physical modeling of a typical three storeyed building frame supported by a pile group of four piles ($2{\times}2$) embedded in cohesive soil mass using three dimensional finite element analysis. For the purpose of modeling, the elements such as beams, slabs and columns, of the superstructure frame; and that of the pile foundation such as pile and pile cap are descretized using twenty noded isoparametric continuum elements. The interface between the pile and the soil is idealized using sixteen node isoparametric surface element. The soil elements are modeled using eight nodes, nine nodes and twelve node continuum elements. The present study considers the linear elastic behaviour of the elements of superstructure and substructure (i.e., foundation). The soil is assumed to behave non-linear. The parametric study is carried out for studying the effect of soil- structure interaction on response of the frame on the premise of sub-structure approach. The frame is analyzed initially without considering the effect of the foundation (non-interaction analysis) and then, the pile foundation is evaluated independently to obtain the equivalent stiffness; and these values are used in the interaction analysis. The spacing between the piles in a group is varied to evaluate its effect on the interactive behaviour of frame in the context of two embedment depth ratios. The response of the frame included the horizontal displacement at the level of each storey, shear force in beams, axial force in columns along with the bending moments in beams and columns. The effect of the soil- structure interaction is observed to be significant for the configuration of the pile groups and in the context of non-linear behaviour of soil.

A Novel z-axis Accelerometer Fabricated on a Single Silicon Substrate Using the Extended SBM Process (Extended SBM 공정을 이용하여 단일 실리콘 기판상에 제작된 새로운 z 축 가속도계)

  • Ko, Hyoung-Ho;Kim, Jong-Pal;Park, Sang-Jun;Kwak, Dong-Hun;Song, Tae-Yong;Cho, Dong-Il;Huh, Kun-Soo;Park, Jahng-Hyon
    • Journal of Sensor Science and Technology
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    • v.13 no.2
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    • pp.101-109
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    • 2004
  • This paper presents a novel z-axis accelerometer with perfectly aligned vertical combs fabricated using the extended sacrificial bulk micromachining (extended SBM) process. The z-axis accelerometer is fabricated using only one (111) SOI wafer and two photo masks without wafer bonding or CMP processes as used by other research efforts that involve vertical combs. In our process, there is no misalignment in lateral gap between the upper and lower comb electrodes, because all critical dimensions including lateral gaps are defined using only one mask. The fabricated accelerometer has the structure thickness of $30{\mu}m$, the vertical offset of $12{\mu}m$, and lateral gap between electrodes of $4{\mu}m$. Torsional springs and asymmetric proof mass produce a vertical displacement when an external z-axis acceleration is applied, and capacitance change due to the vertical displacement of the comb is detected by charge-to-voltage converter. The signal-to-noise ratio of the modulated and demodulated output signal is 80 dB and 76.5 dB, respectively. The noise equivalent input acceleration resolution of the modulated and demodulated output signal is calculated to be $500{\mu}g$ and $748{\mu}g$. The scale factor and linearity of the accelerometer are measured to be 1.1 mV/g and 1.18% FSO, respectively.

Study on Sasang Constitutional Characteristics using Sasang Personality Questionnaire and Sasang Digestive Function Inventory in Clinical Level (의원급 임상에서 SPQ와 SDFI를 이용한 사상체질별 특징 연구)

  • Lee, Myoung Eun;Seo, Han Gil;Kim, Pan Jun;Chae, Han;Kwon, Young Kyu
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.30 no.6
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    • pp.426-431
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    • 2016
  • Sasang Digestive Function Inventory (SDFI) and Sasang Personality Questionnaire (SPQ) were developed on the basis of clinical experiences of Korean medicine hospital and previous studies have used these for analyzing Sasang constitutional characteristics mainly in hospital level. The purpose of this study is to analyze Sasang constitutional characteristics using SDFI and SPQ in clinical level. The SPQ, SDFI, height and weight were measured with 79 patients over 18-years-old from Jan. 2015 to Apr. 2016 in the clinic, Daegu, Korea that specializes in tinnitus and performs Sasang constitution diagnosis. We used ANOVA in analyzing the differences of the scores of SPQ, SDFI, BMI and PI in each Sasang types (Tae-Yang, So-Yang, Tae-Eum), and Bonferroni test or Dunnett's T3 for post verification. The SDFI-T(F=3.215) and SDFI-D(F=4.347) scores were significantly different(p<0.05) and SPQ score was not different in each Sasang types(p>0.05). And Weight(F=4.294), BMI(F=12.386) and PI(F=14.490) were significantly different in each Sasang types(p<0.001). We found that SDFI(SDFI-D) and BMI PI can explain the Sasang constitutional characteristics, that is equivalent to previous studies and might be used for clinical index in making objective questionnaire for Sasnag constitutional diagnosis in clinical level.

Mathematical Modelling and Chaotic Behavior Analysis of Cyber Addiction (사이버 중독의 수학적 모델링과 비선형 거동 해석)

  • Kim, Myung-Mi;Bae, Young-Chul
    • Journal of the Korean Institute of Intelligent Systems
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    • v.24 no.3
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    • pp.245-250
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    • 2014
  • Addiction can be largely divided into two categories. One is called medium addiction in which medium itself causes an addiction. Another is called cause addiction that brings addiction through combination of sensitive self and latent personal action. The medium addiction involves addiction phenomena directly caused by illegal drugs, alcohol and various other chemicals. The cause addiction is dependent on personal sensitivities as a sensitive problem of personal and includes cyber addictions such as shopping, work, game, internet, TV, and gambling. In this paper we propose two-dimensional addiction model that are equivalent to using an R-L-C series circuit of Electrical circuit and a Spring-Damper-mass of mechanical system. We also organize a Duffing equation that is added a nonlinear term in the proposed two-dimensional addiction model. We represent periodic motion and chaotic motion as time series and phase portrait according to parameter's variation. We confirm that among parameters chaotic motion had addicted state and periodic motion caused by change in control coefficient had pre-addiction state.

Effects of Walking Exercise on Metabolic Syndrome Risk Factors and Body Composition in Obese Middle School Girls (걷기운동이 비만여중생의 대사증후군 위험인자와 신체구성에 미치는 효과)

  • Kim Young-Hae;Yang Young-Ok
    • Journal of Korean Academy of Nursing
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    • v.35 no.5
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    • pp.858-867
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    • 2005
  • Purpose: This study was done to determine the effects of walking exercise training(WET) on metabolic syndrome risk factors and body composition in obese middle school girls. Method: A non-equivalent pretest-posttest experimental design was used. Twenty seven subjects participated in this study from one women's middle school in Busan. The participants were purposely allocated to an experimental group (n=14) and a control group (n=13). The experimental group participated in 30-60 minutes of WET with 55 to $75\%$ of a maximal heart rate six days a week for 12 weeks. Results: The prevalence of individual risk factors on metabolic syndrome were improved in the experimental group after the intervention. The high waist circumference(WC), high triglyceride(TG), low high density lipoprotein cholesterol(HDL-C), high blood pressure(BP) and high fasting glucose(FG) were 21.4, 21.4, 14.3, 28.6 and $7.2\%$, respectively. There were significant differences in WC (F=22.24, p<.001), TG (F=5.34, p=0.30), body weight(F=21.99, p<.001), fat mass(F=19.17, p<.001), and $\%$ body fat(F=17.93, p<.001) between the experimental and control group after the intervention. However, there were no significant differences in HDL-C, FG and BP between the experimental and control group after the intervention. Conclusion: These results indicate that WET is effective in decreasing risk factors of the metabolic syndrome and body composition components in obese middle school girls. These findings suggest that WET can be useful as a nursing intervention in the prevention of obesity-related disorders in obese adolescents.

Moment Analysis (MA) of Lysozyme in Cation Exchange High Performance Liquid Chromatography (HPLC) (양이온교환 고성능액체크로마토그래피에서 라이소자임의 모멘트 분석)

  • Ko, Kwan Young;Kim, In Ho
    • Korean Chemical Engineering Research
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    • v.54 no.4
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    • pp.487-493
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    • 2016
  • The moment analysis of lysozyme was implemented using chromatograms that were obtained from weak cation exchange column in high performance liquid chromatography system. Three elution sodium phosphate buffers containing 1.0, 0.75, 0.5M sodium chloride were used. Experiments were conducted by varying flow rate, elution sodium chloride concentration, and lysozyme solute concentration. The general rate (GR) model was employed to calculate the first moment and the second moment. By plotting $L/u_0$ vs. $({\mu}_1-t_0)/(1-{\varepsilon}_e)(1-{\varepsilon}_i)$] equilibrium constants (K) were obtained from first moment analysis. Intra-particle diffusivity was obtained from theoretical plate number data. Based on the results of moment analysis, van Deemter plots were drawn in order to investigate the contributions of $H_{ax}$, $H_f$, and $H_d$ to total Height Equivalent to a Theoretical Plate (HETP, $H_{total}$). The effect of intra-particle diffusion ($H_d$) was the most dominant factor contributing to HETP while external mass transfer ($H_f$) was negligible factor.

Study of Stay Vanes Vortex-Induced Vibrations with different Trailing-Edge Profiles Using CFD

  • Neto, Alexandre D'Agostini;Saltara, Fabio
    • International Journal of Fluid Machinery and Systems
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    • v.2 no.4
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    • pp.363-374
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    • 2009
  • The 2D flow around 13 similar stay-vane profiles with different trailing edge geometries is investigated to determinate the main characteristics of the excitation forces for each one of them and their respective dynamic behaviors when modeled as a free-oscillating system. The main goal is avoid problems with cracks of hydraulic turbines components. A stay vane profile with a history of cracks was selected as the basis for this work. The commercial finite-volume code $FLUENT^{(R)}$ was employed in the simulations of the stationary profiles and, then, modified to take into account the transversal motion of elastically mounted profiles with equivalent structural stiffness and damping. The k-$\omega$ SST turbulence model is employed in all simulations and a deforming mesh technique used for models with profile motion. The static-model simulations were carried out for each one of the 13 geometries using a constant far field flow velocity value in order to determine the lift force oscillating frequency and amplitude as a function of the geometry. The free-oscillating stay-vane simulations were run with a low mass-damping parameter ($m^*{\xi}=0.0072$) and a single mean flow velocity value (5m/s). The structural bending stiffness of the stay-vane is defined by the Reduced Velocity parameter (Vr). The dynamic analyses were divided into two sets. The first set of simulations was carried out only for one profile with $2{\leq}Vr{\leq}12$. The second set of simulations focused on determining the behavior of each one of the 13 profiles in resonance.