• Journal of the Korean Society of Combustion
• /
• v.15 no.4
• /
• pp.9-14
• /
• 2010

Numerical simulations of freely propagating fuel-rich $CH_4/CH_3Cl$ premixed flames were performed at atmospheric pressure in order to understand the effect of the oxygen enrichment on the production of PAH. A chemical kinetic mechanism was used, which involved 157 gas-phase species and 1693 forward reactions. The calculated flame speeds were compared with the experiments for the flames established on the equivalence ratios of 1~1.6, the results of which were in good agreement. As the level of oxygen enrichment was increased, the concentrations of one or four ring aromatic hydrocarbons were decreased. This might cause the fact that the contribution of PAH species to soot was weakened.

• 한국연소학회:학술대회논문집
• /
• 2007.05a
• /
• pp.37-44
• /
• 2007

A nickel foam, one of metal foams was seleced as a catalyst support instead of conventional ceramic materials. $Al_2O_3$ was coated on the surface of nickel foam to increase the surface area. $Al_2O_3$ coating process was based on sol-gel process. SEM image was obtained and $Al_2O_3$ coverage was confirmed. Combustion experiments were carried out using SUS combustor and $H_2$/air mixture. Temperatures were measured with different equivalence ratios and $H_2$ flow rates. $H_2$ conversion rates were calculated by the analysis of product gas using gas chromatography. Catalytic combustion of $H_2$ was complete and stable with Pt/$Al_2O_3$ coated nickel foam and influences of water vapor were confirmed during the beginning of combustion.

• 한국연소학회:학술대회논문집
• /
• 2012.11a
• /
• pp.211-214
• /
• 2012

A short reaction mechanism was developed in order to predict the flame phenomena in premixed Dimethyl Ether-Air flame with the methods of SEM-CM(Simulation Error Minimization Connectivity Method), sensitivity analysis, and the rate of production analysis. It consisted of 31 species including nitrogen as inert gas and 177 elementary reactions. The flame structures obtained using a detailed reaction mechanism and the short reaction mechanism were compared with various equivalence ratios and pressure, and the results were in good agreement. Therefore, the short reaction mechanism would be used to aim at studying the development of a reduced reaction mechanism.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2003.10a
• /
• pp.191-194
• /
• 2003

A series of computational simulations have been carried out for non-reacting and reacting flows in a supersonic combustor configuration with and without a cavity. Transverse injection of hydrogen, a simplest form of fuel supply, is considered in the present study with the injection pressure of 0.5 and 1.0 ㎫. The corresponding equivalence ratios are 0.17 and 0.33. The work features detailed resolution of the flow and flame dynamics in the combustor, which was not typically available in most of the previous studies. In particular, oscillatory flow characteristics are captured at a scale sufficient to identify the underlying physical mechanisms. Much of the flow unsteadiness is related not only to the cavity, but also to the intrinsic unsteadiness in the flowfield. The interactions between the unsteady flow and flame evolution may cause a large excursion of flow oscillation. The role of the cavity, injection pressure, and amount of heat addition are examined systematically.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2009.11a
• /
• pp.191-196
• /
• 2009

Experiments were conducted in a constant pressure combustion chamber using schlieren system to investigate the effects of carbon dioxide/nitrogen/helium diluents on cellular instabilities of syngas-air premixed flames at room temperature and elevated pressures. Laminar burning velocities and Markstein lengths were calculated by analyzing high-speed schlieren images at various diluent concentrations and equivalence ratios. Experimental results showed substantial reduction of the laminar burning velocities and of the Markstein lengths with the diluent additions in the fuel blends. Effective Lewis numbers of helium-diluted syngas-air flames increased but those of carbon dioxide- and nitrogen-diluted syngas-air flames decreased in increase of diluents in the reactant mixtures. With helium diluent, the propensity for cells formation was significantly diminished, whereas the cellular instabilities for carbon dioxide-diluted and nitrogen-diluted syngas-air flames were not suppressed.

• Journal of Environmental Science International
• /
• v.29 no.8
• /
• pp.847-855
• /
• 2020

This study presented problems and improvements in the quality control of an air monitoring network, using Gyeongnam as an example. 1) The effective utilization rate of the air monitoring was 95%, which showed good management, but the maximum of 2% was indicated by zero or detection limit among measurement data. 2) In the equivalence evaluation of PM_2.5, the slope and intercept satisfy the evaluation criteria; however, 1% of the PM_2.5/PM₁₀ ratios were outliers. 3) All air monitoring stations meet the quality control standards; however, the management status is added to the quality inspection, management system is unified and the related budget is expanded, and systematic commission management is required.

• Proceedings of the KSME Conference
• /
• 2003.04a
• /
• pp.1372-1377
• /
• 2003

The stabilization of propane/air lean premixed flames by a heated cylindrical rod is investigated experimentally. The flame stability limits, heat flux, surface temperatures, equivalence ratios, and mixture velocities are measured in order to understand the role of heat flux or surface temperature on the flame stabilization of lean premixed flames. The flame stability limits are lowered by a heated cylindrical rod and extended even below the flammability limit of propane/air mixture when sufficient heat flux is provided. The flame stability limit decreases with the increase of heat flux or surface temperature and decreases with the higher mixture velocity. The diameter of cylindrical rod, however, dose not significantly affect the flame stability limit. The laminar flame speed has been measured for ultra lean propane/air premixed flames. The flame stabilization by a heated cylindrical rod provides the useful tool for the measurement of flame speed under very fuel-lean conditions.

• Proceedings of the KSME Conference
• /
• 2003.04a
• /
• pp.2180-2185
• /
• 2003

Numerical simulations of freely propagating flames burning $H_2/HCl/Air$ mixtures are performed at atmospheric pressure in order to understand the effect of HCl on the NOx reduction. A chemical kinetic mechanism is developed, which involves 26 gas-phase species and 99 reactions. Under several equivalence ratios the flame speeds are calculated and compared with those obtained from the experiments, the results of which is in good agreement. As HCl is added into $H_2/Air$ flame as additive, its chemical effect causes the reduction of radicals (H, OH, and O), and then the decrease of the net rate of NO production. It is found that the chemical effect of additive has much more influence on the reduction of EINO than its physical effect.

• Journal of Mechanical Science and Technology
• /
• v.18 no.2
• /
• pp.325-334
• /
• 2004

Computational experiments on fundamental un stretched laminar burning velocities and flame response to stretch (represented by the Markstein number) of hydrogen-air flames at high temperatures and pressures were conducted in order to understand the dynamics of the flames including hydrogen as an attractive energy carrier in conditions encountered in practical applications such as internal combustion engines. Outwardly propagating spherical premixed flames were considered for a fuel-equivalence ratio of 0.6, pressures of 5 to 50 atm, and temperatures of 298 to 1000 K. For these conditions, ratios of unstretched-to-stretched laminar burning velocities varied linearly with flame stretch (represented by the Karlovitz number), similar to the flames at normal temperature and normal to moderately elevated pressures, implying that the "local conditions" hypothesis can be extended to the practical conditions. Increasing temperatures tended to reduce tendencies toward preferential-diffusion instability behavior (increasing the Markstein number) whereas increasing pressures tended to increase tendencies toward preferential-diffusion instability behavior (decreasing the Markstein number).

• Proceedings of the KSME Conference
• /
• 2000.04b
• /
• pp.422-427
• /
• 2000

Propagation characteristics of tribrachial flames have been investigated experimentally in both two-dimensional and axisymmetric counterflows. Mixture fraction gradient at stoichiometric location is controlled by varying equivalence ratios at the two nozzles, one of which maintains rich while the other lean premixture. Tribrachial flames propagating through these mixtures are investigated. The propagation speed of tribrachial flames in two-dimensional counterflow decreases with fuel concentration gradient and has much higher speed than the maximum speed predicted previously in two-dimensional mixing layers. From an analogy with premixed flame propagation, this excessively large propagation speed can be attributed to the tribrachial flame propagating with respect to burnt gas. Corresponding maximum speed in the limit of small mixture fraction gradient is estimated and extrapolated experimental results substantiate this limiting speed. As mixture fraction gradient approaches zero, a transition in propagation characteristics occurs, such that the propagation speed of tribrachial flame approaches stoichiometric laminar burning velocity with respect to burnt gas. Similar behavior has been obtained for tribrachial flames propagating in axisymmetric counterflow.