• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.96.1-96.1
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• 2011

Solid oxide fuel cells(SOFCs) can convert the chemical energy of fuel into electricity directly. With the rising fuel prices and stricter emission requirement, SOFCs have been widely recognized as a promising technology in the near future. In this study, lean premixed flame using the orifice swirl burner was analyzed numerically and experimentally. We used the program CHEMKIN and the GRI 3.0 chemical reaction mechanism for the calculation of burning velocity and adiabatic flame temperature to investigate the effects of equivalence ratio on the adiabatic flame temperature and burning velocity respectively. Burning velocity of hydrogen was calculated by CHEMKIN simulation was 325cm/s, which was faster than that of methane having 42 cm/s at the same equivalence ratio. Also Ansys Fluent was used so as to analysis the performance with alteration of swirl structure and orifice mixer structure. This experimental study focused on stability and emission characteristics and the influence of swirl and orifice mixer in Solid Oxide Fuel Cell Systme burner. The results show that the stable blue flame with different equivalence ratio. NOx was measured below 20 ppm from equivalence ratios 0.72 to 0.84 and CO which is a very important emission index in combustor was observed below 160 ppm under the same equivalence region.

• Journal of the Korean Society of Combustion
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• v.15 no.3
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• pp.8-14
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• 2010

Fuel processing systems which convert fuel into rich gas (such as stream reforming, partial oxidation, autothermal reforming) need high temperature environment ($600{\sim}1,000^{\circ}$). Generally, anode-off gas or mixture of anode-off gas and LNG is used as input gas of fuel reformer. In order to make efficient and low emission burner system for fuel reformer, it is necessary to elucidate the combustion and emission characteristic of fuel reformer burner. The purpose of this study is to develop a porous premixed flat ceramic burner that can be used for 1~5 kW fuel cell reformer. Ceramic burner experiments using natural gas, hydrogen gas, anode off gas, mixture of natural gas & anode off gas were carried out respectively to investigate the flame characteristics by heating capacity and equivalence ratio. Results show that the stable flat flames can be established for natural gas, hydrogen gas, anode off gas and mixture of natural gas & anode off gas as reformer fuel in the porous ceramic burner. For all of fuels, their burning velocities become smaller as the equivalence ratio goes to the lean mixture ratio, and a lift-off occurs at lean limit. Flame length in hydrogen and anode off gas became longer with increasing the heat capacity. In particular, the blue surface flame is found to be very stable at a very lean equivalence ratio at heat capacity and different fuels. The exhausted NOx and CO measurement shows that the blue surface flame represents the lowest NOx and CO emissions since it remains very stable at a lean equivalence ratio.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.29 no.2 s.233
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• pp.263-270
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• 2005

An experimental study was performed to investigate the effects of partially premixing, varying the equivalence ratios from $0.79{\sim}{\infty}$, on NOx emissions and chemiluminescence of excited $OH^{\ast},\;CH^{ast}\;C_2^{\ast}$ radicals in laminar partially premixed flames. the signal from the electronically excited state of $OH^{\ast},\;CH^{ast}\;C_2^{\ast}$ was detected through a band pass filter with a photo multiplier tube, which are processed to the intensity ratio ($C_2^{\ast}/CH^{\ast},\;C_2^{\ast}/OH^{\ast},\;and\;CH^{\ast}/OH^{\ast}$) to reveal the correlation with local equivalence ratio. And measurements of NOx emission were made to investigate the relationship between visible flame appearance, chemiluminescence, and EINOX. The results demonstrated that (1) the flames at ${\phi}<1.59$ exhibited classical double flame structure, at ${\phi}>4.76$, the flames exhibited diffusion flame structure, and the intermediate flames at $1.59<{\phi}<4.76$ was a merged flame, (2) the $OH^{\ast}$ peak was located inside the $CH^{\ast}\;and\;C_2^{\ast}$ radical for all measured conditions and the emission intensity ratio of $C_2^{\ast}/CH^{\ast}\;and\;C_2^{\ast}/OH^{\ast}$ were identified as good marker for local equivalence ratio over a range of ${\phi}=0.79{\sim}1.2\;and\;CH^{\ast}/OH^{\ast}\;is\;0.79<{\phi}<1.9$. However, it was difficult to predict the equivalence ratio in partially premixed flames using this system for ${\phi}>2.38$, (3) the minimum NOX emission index (EINOx) is obtained for a equivalence ratio of 3.19 in the intermediate flames.

• Journal of the Korean Society of Propulsion Engineers
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• v.26 no.6
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• pp.34-42
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• 2022

A correlation between propellant supply condition and chamber pressure in GCH₄-LOx small rocket engine was explored and hot-firing tests were conducted to analyze the engine performance characteristics according to the equivalence ratio variation at a constant chamber pressure. Correlation studies have shown that chamber pressure is linearly proportional to oxidizer supply pressure. As a result of the test, the thrust, specific impulse and characteristic velocity that are the main performance parameters of a rocket engine, were found to be enhanced as the equivalence ratio starting from a fuel-lean condition approached the stoichiometric ratio, but the efficiencies of characteristic velocity and specific impulse were on the contrary, in their dependency on the equivalence ratio.

• 한국연소학회:학술대회논문집
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• 2006.10a
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• pp.79-85
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• 2006

Radiative heat transfer is very important in many combustion systems since they are operated in high temperature. Fluid flows in most of the combustion systems are turbulent to promote fast mixing of the hydrocarbon fuel and oxidant. Major combustion products are $CO_2$ and $H_2O$. The turbulent flow is modeled by using the standard ${\kappa}-{\epsilon}$ model and the radiation transfer is modeled by using the discrete ordinates method where the radiative gas properties are calculated by using the weighted sum of gray gases model with a gray gas regrouping(WSGGM-RG). Effect of the radiation on the combustion characteristics in a three-dimensional rectangular enclosure is studied by changing the equivalence ratio. Results show that the radiation plays a significant role on the heat transfer in the combustion systems by resulting in a temperature drop of 16% as compared to that obtained without radiation. The equivalence ratio also affects the combustion by different contribution of the radiative transfer with different gas compositions.

• Transactions of the Korean Society of Automotive Engineers
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• v.3 no.1
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• pp.65-75
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• 1995

The present study was investigated combustion characteristics of methane-air mixtures at stratified charge in a constant volume combustion chamber. The results indicated that even the vety lean mixture, which is normally not flammable in single chamber type, could be burned within. a comparatively short time by using sub-chamber with stratified charge method. And the lean inflammability limit of mixture in a main chamber was about ($\phi_m$cr=O.46, when the equivalence ratio of a sub-chamber was $\phi_s$= 1.0. Initial time of pressure increase and total burning times were decreased and maximum combustion pressure. was increased as the equivalence ratio of both sub and main chamber approached unity. Specifically, initial time of pressure increase and total burning times were greatly affected rather by. the equivalence ratio of sub-chamber than that of main chamber. The maximum combustion pressure was little affected if the total equivalence ratio lies in the same range.

• Journal of the Korean Society of Combustion
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• v.15 no.3
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• pp.32-39
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• 2010

An experimental study was conducted to investigate the relationship between global equivalence ratio(GER) and fire characteristics in an ISO 9705 room. Heptane fuel was burned with different fuel flow rates and doorway widths in order to force the room to be placed in different GER conditions. It was observed that after the onset of under-ventilated fire conditions, temperature and unburned fuel components such as CO and soot increased with increasing heat release rate (HRR), regardless of the doorway width. From the analysis of local mixture fraction, it was reconfirmed that the inclusion of soot production in the product composition was very important to predict accurately the chemical conditions inside the compartment, particularly for the under-ventilated fire conditions. In addition, the local equivalence ratio (LER) was directly proportional to the GER with a unit gradient regardless of doorway width when the soot production was included in the chemical products. This finding provided an important potential that the GER could be used to correlate the local thermal and chemical environment measured at the upper layer of a full-scale enclosure when soot was included.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.31 no.5
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• pp.405-415
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• 2007

The effects of recirculated exhaust gas on exhaust emissions under four kinds of nozzle tip with the different fuel consumption rates are experimentally investigated by using an once-through boiler with a FGR system. The purpose of this study is to develop the FGR control system for reducing $NO_x$ emissions in boilers. Intake and exhaust oxygen concentrations, and equivalence ratio are considered to figure out the effect of FGR rate on exhaust emissions at various fuel consumption rates. It is found that $NO_x$ emissions are markedly decreased, while soot emissions are increased owing to the drop of intake and exhaust oxygen concentrations, and the rise of equivalence ratio as FGR rates are elevated. One can also conclude that the reduction in $NO_x$ emissions is more considerably influenced by the variation of equivalence ratio due to the FGR rate than the fuel consumption rate.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.20 no.2
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• pp.659-669
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• 1996

To clarify the effects of equivalence ratio, initial pressure and temperature on the flame propagation and radicals characteristics, a series of the experimental study were conducted in a quiescent methane-air premixture using a constant volume chamber. The development of the flame was visualized following the start of ignition using high speed schlieren photo and radical images by intensified CCD camera. Combustion pressure and ion current were recorded simultaneously according to the experimental conditions which were equivalence ratio with 0.7 to 1.2, initial pressure with 0.08 MPa to 0.40 MPa and initial premixture temperature with 3l3.2K to 403.2K. The results showed that the flame speed by ion current and mass fraction burned by combustion pressure characterized the effects of flame propagation very well. And increased combustion duration due to lean combustion condition that was below equivalence ratio, 0.8 caused cycle variation and decreasing the power of engine.

• Journal of the Korean Society of Combustion
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• v.8 no.3
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• pp.38-48
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• 2003

OH, CH and NO radical distributions have been measured and compared with the numerical analysis results in methane/air partially premixed laminar flames using 2-D LIF technique. The pick intensity of OH LIF signal is insensitive to fuel equivalence ratio: however, CH LIF intensity decreases as equivalence ratio increases and the NO concentration increases with equivalence ratio. The contribution of the prompt NO, formed near premixed reaction zone, to the total NO formation is evident from the OH, CH, and NO PLIF images in which the dilution effect of nitrogen is minimal for the highest equivalence ratio. Measured OH and NO LIF signals in counterflow flames agree with the computed concentration distributions. Both numerical and experimental results indicate that the structural change in a flame alters the NO formation characteristics of a partially premixed counterflow flame. The nitrogen dilution also changes flame structure, temperature and OH radical distributions and results in the decreased NO concentrations in a flame. The levels of decrease in NO concentrations, however, depends on the premixedness(${\alpha}$) of a flame. The larger change in the flame structure and NO concentrations have been observed in a premixed flame(${\alpha}=1.0$), which implies that the premixedness is likely to be a factor in the dilution effect on NO formation of a flame.