• 제목/요약/키워드: Equilibrium constant

검색결과 545건 처리시간 0.032초

Unsteady Electroosmotic Channel Flows with the Nonoverlapped and Overlapped Electric Double Layers

  • Kang, Sang-Mo;Suh, Yong-Kweon
    • Journal of Mechanical Science and Technology
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    • 제20권12호
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    • pp.2250-2264
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    • 2006
  • In micro- and nanoflows, the Boltzmann distribution is valid only when the electric double layers (EDL's) are not overlapped and the ionic distributions establish an equilibrium state. The present study has numerically investigated unsteady two-dimensional fully-developed electroosmotic flows between two parallel flat plates in the nonoverlapped and overlapped EDL cases, without any assumption of the Boltzmann distribution. For the study, two kinds of unsteady flows are considered: one is the impulsive application of a constant electric field and the other is the application of a sinusoidally oscillating electric field. For the numerical simulations, the ionic-species and electric-field equations as well as the continuity and momentum ones are solved. Numerical simulations are successful in accurately predicting unsteady electroosmotic flows and ionic distributions. Results show that the nonoverlapped and overlapped cases are totally different in their basic characteristics. This study would contribute to further understanding unsteady electroosmotic flows in micro- and nanofluidic devices.

폐석고 침전제를 이용한 불소폐수 처리특성 (Treatment Characteristics of Fluoride Wastewater by Waste Gypsum as a Precipitant)

  • 김성준;전용태;원찬희
    • 한국물환경학회지
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    • 제26권6호
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    • pp.919-925
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    • 2010
  • The features of precipitating reaction of fluoride have been examined by employing waste gypsum as a precipitant. The major component of waste gypsum was examined to be CaO with minor components of $SO_3$, $SiO_2$. In the experimental condition, the precipitating reaction of fluoride progressed rapidly within a few minutes after the reaction started and reached its equilibrium in 10 minutes. Kinetic analysis showed that the precipitating reaction of fluoride generally followed a first Oder and second Oder with decreasing rate constant with the initial dosage of precipitant. XRD analysis showed that the crystalline structure of precipitate was mainly $CaF_2$ with partly $Ca_5(PO_4)_3(OH)$.

다이아프램 정량펌프의 맥동감쇄 장치 (Pulsation Dampener for Diaphragm Metering Pump)

  • 윤승원
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2004년도 추계학술대회 논문집
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    • pp.1143-1147
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    • 2004
  • A mechanical type pulsation dampener for the diaphragm metering pump has been developed. The pulsation pressure is an inevitable phenomenon for the positive displacement pump such as cam operated or solenoid operated metering pump. The pulsation pressure of the metering pump could be the noise source and would be harmful for the piping system which delivers hydraulic fluid. Developed pulsation dampener consists of three coil springs which have different spring constant and height each other. Depending on pressure magnitude of the piping system, total hydraulic pressure on damping diaphragm which compresses coil springs will be varied. Force equilibrium of the pulsation dampener will be set by manual by adjusting the compressed coil spring height. During the discharge stroke, pulsation dampener stores potential energy that is released as the pumping diaphragm back to an initial position during the suction stroke.

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정적 연소실내에서 화염 전파 과정에 대한 실험적 연구 (The Experimental study on the Flame Propagation Process of a Constant Volume Combustion Chamber)

  • 김춘중;강경구
    • 한국산업융합학회 논문집
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    • 제2권1호
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    • pp.121-130
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    • 1999
  • It is necessary to measure pressure, temperature, chemical equilibrium and the shape of flame in order to understand the combustion process in a combustion chamber. In particular, the flame formulation and combustion process of divided combustion chamber are different from those of a single chamber, And the variable diameter of a jet hole can effect not only physical properties like ejection velocity, temperature and time of combustion but also a chemical property like the reaction mechanism. Accordingly temperature is one of the most important factors which influence the combustion mechanism. This paper observed shape of flame by using the schlieren photographs and measured the pressure in a combustion chamber and the reaching time of the flame by ion probe By doing these, we investigation the formulation of the flame and the process of propagation. These measurement methods can be advanced in understanding the combustion process and process and propagation of flame.

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활성탄으로 코팅된 집진전극의 BTEX 흡착특성 (Adsorption Characteristics of BTEX on Dust Collecting Electrode Coated with Activated Carbon)

  • 남상철;김현정;김광수
    • 한국대기환경학회지
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    • 제29권6호
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    • pp.773-779
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    • 2013
  • This study was performed to provide the basic data for the function of BTEX removal for compact electrostatic precipitator which are applicable to indoor environment (or closed spaces). For this purpose, the adsorption equilibrium test was conducted for BTEX of activated carbon sheet (ACS) and activated carbon (AC), and the adsorption characteristics of AC and ACS were evaluated using the Langmuir constant which was obtained from the adsorption characteristics, adsorption capacity and regression calculation. The surface area and adsorption pore volume of ACS reduced by 70% and 86%, respectively, as compared to those of AC, and the adsorption capacities of BTEX also showed a similar level. Thus, it is considered that ACS applied electrostatic precipitator is able to remove dust and BTEX simultaneously.

Effects of Surface Geometry on Polyelectrolyte Adsorption

  • Park, Young-G.;Kim, Key-Seek;Sung, Ki-Chun
    • 한국응용과학기술학회지
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    • 제17권2호
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    • pp.149-156
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    • 2000
  • For the adsorption of polyelectrolyte at the surface of polyacrylamide gel particle, preferential adsorption of the large polyelectrolyte such as DNA is governed by the surface area of an adsorbent. The adsorption equilibrium constant can be varied by surface geometry of porous polymer, and it can be described as a function of ionic strength and surface area. Physical parameters affecting the adsorption were estimated using the theoretical governing equation of polyelectrolyte which electrophoretically moved along the column, and geometrical surface area was estimated by Waldman-Mayer's physical model. The separation of polyelectrolytes was studied using the physical parameters estimated by ionic strength and surface geometry.

Chua다이오드의 비선형제어 (Nonlinear Control of Chua's Diode)

  • 임소영;이호진;이정국;김성열;이금원;이준모
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2006년 학술대회 논문집 정보 및 제어부문
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    • pp.285-287
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    • 2006
  • The paper treats the nonlinear robust control of Chua's circuit having Chuar's diode as an element based on the internal model principle. The Chua's diode has unknown nonlinear parameters and the circuits parameters are alos assumend unknown. Nonlinear regulator equations are established to obtain 3-fold equilibrium equations on which the output error is zero. Also an internal model of the 3-fold exosystem is constructed for obtaining the control law. Pole Placement method is used for obtaining the feeback control law. Simulation results are presented for tracking the sinusoidal and constant reference input signal. Asymptotic trajectory control and the suppression of chaotic motion in spite of uncertainties in the system are accomplished.

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Taylor-Lei Series에 의한 지연이 있는 비선형 시스템의 시간 이산화 (Time-Discretization of Nonlinear control systems with State-delay via Taylor-Lie Series)

  • 장위옌리앙;이의동;정길도
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2005년도 심포지엄 논문집 정보 및 제어부문
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    • pp.125-127
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    • 2005
  • In this paper, we propose a new scheme for the discretization of nonlinear systems using Taylor series expansion and the zero-order hold assumption. This scheme is applied to the sample-data representation of a nonlinear system with constant state tine-delay. The mathematical expressions of the discretization scheme are presented and the effect of the time-discretization method on key properties of nonlinear control system with state tine-delay, such as equilibrium properties and asymptotic ability, is examined. The proposed scheme provides a finite-dimensional representation for nonlinear systems with state time-delay enabling existing controller design techniques to be applied to then. The performance of the proposed discretization procedure is evaluated using a nonlinear system. For this nonlinear system, various sampling rates and time-delay values are considered.

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Voltammetric Studies of Cu-Adriblastina Complex and its Effect on ssDNA-Adriblastina Interaction at In Situ Mercury Film Electrode

  • D.Abd El Hady;M.Ibrahim Abdel Hamid;M.Mahmoud Sellem;N.Abo E Maali
    • Archives of Pharmacal Research
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    • 제27권11호
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    • pp.1161-1167
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    • 2004
  • Adriblastina, a cancerostatic anthracycline antibiotic, causes considerable oxidative damage to DNA molecules. The interaction of this compound with DNA was investigated using Osteryoung square wave stripping voltammetry (OSWSV) and cyclic voltammetry (CV) at an in situ mercury film electrode. It was found that the equilibrium constant of the bonded oxidized form of the drug was 63 times bigger more important than that of the bonded reduced form. Copper forms 1 metal: 2 drug stoichiometry complex which is highly stable compared to ssDNA-drug interaction and consequently inhibited the drug biochemical damaging effects. Copper complex offered sub-nanogram determination of adriblastina in aqueous and urine media.

Aspergillus oryzae로부터 분리한 chitosan복합체에 의한 카드뮴 제거 효율에 관한 연구 (A Study on Removal Efficiency of Cd by using Chitosan Complex isolated from Aspergillus oryzae)

  • 장재선;이제만;김용희
    • 환경위생공학
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    • 제19권1호
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    • pp.37-41
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    • 2004
  • The removal efficiency of cadmium by chitosan complex isolated from Aspersillus oryzae was investigated through laboratory experiments. The results of the study are as follows. The adsorption kinetics of cadmium was reached the adsorption equilibrium in approximately 20 minutes and the removal efficiency was showed 95.8%. The effect of temperature on cadmium adsorption by chitosan complex shows that as the temperature increased, the amount of cadmium adsorption per unit weight of chitosan complex increased. The correlation between amount of cadmium adsorption per unit weight of chitosan complex and temperature was obtained through the coefficient of determination($R^2$). $R^2$ values was 0.854(p<0.05). A linearized Freundlich equation was used to fit the acquired experimental data. As a result, Freundlich constant, the adsorption intensity(1/n) was 0.550, and the measure of adsorption(k) was 2.181. So, it was concluded that adsorption of cadmium by chitosan complex is effective.