• The Korean Journal of Ceramics
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• v.1 no.4
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• pp.179-184
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• 1995

Sodium superionic conductor (NASICON) compounds were prepared. The effects of sintering temperature and cooling rate on the formation and the distribution of crystalline NASICON and $ZrO_3$ second phase were investigated. In the von Alpen-type composition, the $ZrO_2$ second phase is in thermal equilibrium with the crystalline NASICON above $1320^{\circ}C$, but when cooled through 1260-$1320^{\circ}C$ crystalline NASICON was formed by reaction between $ZrO_2$ and liquid phase. Very slow cooling ($1^{\circ}C$/hr) to $1260^{\circ}C$ from sintering temperature decreased the amount of sodium which prevents the formation of the crystalline NASICON resulted high number of $ZrO_2$ grains near the surface of some sintered bodies. Maximum electrical conductivity of 0.200 ohm-1cm-1 was obtained at $300^{\circ}C$ for well-sintered samples with little $ZrO_3$. On the other hand, low conductivities were obtained for rapid-cooled samples which have less dense microstructure.

• Transactions on Electrical and Electronic Materials
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• v.7 no.6
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• pp.283-292
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• 2006

So that high-strength and electrical properties apply by excellent high voltage insulator electricity material, ATH content and platinum-based flame retardant that influence in flame retardant and tracking characteristic among composite of silicone rubber studied mechanical strength and influence getting to electrical properties. Composition of ${\alpha}$, ${\omega}-vinyl$ poly (dimethyl-methylphenyl) siloxane(VPMPS) of a polymer quantity made doing mole of D4, $D3^{Me,Ph}$ and VMS by 1000:15:0.2 mole ratio and uses basic catalyst tetramethylammonium silanolate(TMAS) and do opening equilibrium polymerization to be used to main polymer for high voltage insulation insulator. Control ATH content and content of platinum-based flame retardant and made high voltage insulation silicone rubber. Measured mechanical strength of making silicone rubber using UTM, and tracking characteristic according to standard of IEC 60587, flame retardant test studied effect that flame retardant characteristic gets in tracking characteristic, measuring according to UL94V method of test.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.1036-1037
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• 2017

This study investigated the aging reactions of three kinds of igniters(BKNO3, THPP, ZPP). The life-time of igniter depends on oxygen and moisture in the air. For example, Magnesium contained in the $BKNO_3$ reacts with oxygen and water to form oxide and hydrate. This reaction has an adverse effect on ignition reaction and could be information to analyze aging. Thermodynamic calculation could interpret the aging reaction by calculating flame temperature applying several variables(initial temperature, composition, etc.). If combustion is not completed because of aging igniters, flame temperature will be formed at a low range. The result of this research is expected to support the analysis of igniters aging reactions.

• Journal of the Mineralogical Society of Korea
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• v.4 no.2
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• pp.119-128
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• 1991

In the southern limb of the Hambaek geosyncline belt, large-scaled skarn deposits are developed in the Cambro-Ordovician sedimentary rocks of the Chosun Supergroup. They are the Sangdong tungsten deposit, Geodo iron-copper deposit, Yeonhwa I and II lead-zinc deposits, and Ulchin zinc-lead deposit, all of which are associated with various skarn minerals. Though different occurrences and paragenesis are found in different deposits, most skarn deposits always have skarns of garnet (andradite-grossular series) and clinopyroxene(heden-bergite-diopside series). Andradite and hedenbergite are Fe-dominant members, but show different oxidation states, that is, Fe3+ for andradite and Fe2+ for hedenbergite. According to iron chemistry and log([Fe/Al]gd/[Fe/Mg]cpx) derived from equilibrium reactions, the diopside-andradite and hedenbergite-grossular pairs suggest the oxidized state (dian type) and reduced state (hegro type), respectively. Among skarn deposits developed in the Hambaek geosynline, it can be classified that the Geodo and Yeonhwa I skarns are of dian type, while the Sangdong, Yeonhwa II, and Ulchin deposits are of hegro type. This classification is not applicable to all kinds of skarn deposits, but may be applicable to such deposits as are more controlled by oxygen fugacity than composition of skarn fluid.

• Transactions of the Korean hydrogen and new energy society
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• v.23 no.5
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• pp.448-454
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• 2012

In this paper, a three-dimensional hydrogen absorption model is applied to a thin double-layered annulus ZrCo hydride bed and validated against the temperature evolution data measured by Kang et al. The present model reasonably captures the bed temperature evolution behavior and the 99% hydrogen charging time. The equilibrium pressure expression for hydrogen absorption on ZrCo is derived as a function of temperature and the H/M atomic ratio based on the pressure-composition isotherm data given by Konishi et al. In addition, this present model provides multi-dimensional contours such as temperature and H/M atomic ratio in the thin doublelayered annulus metal hydride region. This numerical study provides fundamental understanding during hydrogen absorption process and indicates that efficient design of the metal hydride bed is critical to achieve rapid hydrogen charging performance. The present three-dimensional hydrogen absorption model is a useful tool for the optimization of bed design and operating conditions.

• Textile Coloration and Finishing
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• v.8 no.5
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• pp.68-75
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• 1996

Even if fibers are practically identical with respect to chemical composition and denier, the dyeabilities are freqently a little different in an industrial processing. It is difficult to interpret the numerical values of dye diffusion coefficients from a dye solution into fibers. The main reasons are the multicomponent nature of the diffusion process and the inhomogeneities of the substrate, so-called, various kinds of ordered and disordered regions of polymers, void and pores. The equilibrium dye adsorptions and dyeing rates of a disperse dye into the several PET fibers having the same denier were determined at various temperatures. The dyeability of examined samples was divided into two groups, that is, lower dye adsorption fiber and higher ones at the lower temperatures. This result was discussed with the degree of crystallinity, DSC diagram, X-ray diffractometry and Porosimetry of the PET fiber, and an appropriate model for fine structure of PET fiber was proposed.

• Korean Journal of Metals and Materials
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• v.46 no.10
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• pp.662-671
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• 2008

The behavior of hydrogen in the steel making process was investigated. The relation between the composition of ladle slag and hydrogen concentration in molten steel was considered. The hydrogen distribution ratio between ladle slag and molten steel was increased with increasing basicity of the slag; it was about 20 when the basicity of slag was 15. Hydroxyl capacity measured from the hydrogen distribution ratio between slag and the molten steel was comparatively corresponding to the value of hydroxyl capacity measured by the equilibrium reaction of slag and $H_2O$ gas. However, it is considerably different from the value calculated by regular solution model. The influence of hydrogen on a sticking type breakout is considered. The effect of hydrogen and $H_2O$ gas on the crystallization behavior of mold powder was investigated by DHTT (Dual hot thermocouple technique). As a result, it was proved that mold powder could be crystallized by $H_2O$ gas in the atmosphere. Therefore, it is concluded that $H_2O$ gas in the atmosphere can be a possible cause of the sticking type breakout that occasionally occurs in the continuous casting process.

• Steel and Composite Structures
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• v.49 no.2
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• pp.125-141
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• 2023

Firstly, a new kind of prismatic tensegrity structures with redundant cables is defined, the topology, geometry and forming conditions of which are introduced further. The development of its mechanical properties including self-stress states and structural stiffness with the increment of the twist angle is also investigated carefully. Combined with the topology of this kind of structures, a reasonable erection scheme is proposed, in which some temporary lifting points need to be set and two groups of vertical cables are tensioned in batches. Then, a simplified dynamic relaxation method is employed to track the erection process inversely, which aims to predict each intermediate equilibrium state during the construction, and give the key structural parameters that can effectively guide the construction. The removal of the active cables, the relaxation or tension of the passive cables are simulated by controlling their axial stiffness, so that the structural composition as well as the serial numbers of the elements always keep invariant regardless of the withdrawal of the slack cables. The whole analysis process is clear in concept, simple to implement and easy to popularize. Finally, several examples are given to verify the practicability and effectiveness of the proposed method further.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.13 no.1
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• pp.83-88
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• 2008

Using micromill, discrete carbonate powders from the otolith of Argyrosomus argentatus were sampled along the growth band, and high-resolution stable isotope profiles were obtained. The ${\delta}^{18}O$ and ${\delta}^{13}C$ values are increasing gradually from the core to the margin. However, such increases do not seem to be attributed to the environmental property changes during the growth, but to the dominant effect of metabolic carbons during the early growth, and then, the isotopic composition seems to be equilibrium to the environmental condition. This paper allows the diverse applicability of high-resolution isotope research to the fish otoliths in the future.

• Korean Journal of Food Science and Technology
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• v.15 no.1
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• pp.19-26
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• 1983

A study was designed to investigate the sorption characteristics of binary mixtures of NaCl and sucrose or glucose stored at various relative humidities ranging from 46% to 92%. At low relative humidity below RH 65%, the sorption equilibrium was easily achieved, whereas at higher relative humidity values over 73%, all of the mixtures tended to cintinously absorb moisture with increase in storage time. A linear equation of log $({\frac{dw}{dt}})$ = a log(t) + log(b) was found to be valid between the sorption rate and storage time with respect to storage humidities. In sucrose-NaCl mixture, the slope showed a increasing tendency as the percentage of NaCl increased in the mixture, while that of glucose-NaCl mixture failed to show a definite trend. Plateaus were obtained when the amount of water absorbed was plotted on the X axis and the percent composition of mixture on the Y axis at different storage time. The shape of plateau was varied with respect to the kind of sugar-NaCl mixture, composition of the mixture and relative humidities. A linearity was found between log(1-Aw) and the amount of water absorbed over the Aw range 0.73-0.92 and the slope was affected by the kind and composition of sugar-NaCl mixtures.