• Journal of the Korean Chemical Society
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• v.66 no.4
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• pp.269-277
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• 2022

In recent years, carbon-based catalysts have become a research hotspot in environmental governance applications. Carbon-based catalysts have large surface areas, porous structures, multi-surface functional groups and excellent electron transfer capabilities, and can synergistically exhibit adsorption and catalytic performance. This article reviews the research progress of carbon-based catalysts in environmental governance, mainly including its application in wastewater treatment, exhaust gas purification and soil remediation. In view of the current difficulties in the research of carbon-based catalysts, the development prospects are proposed. We hope that this review will provide convenience for new entrants and researchers intending to employ carbon-based catalysts for the remediation of contaminated environment.

• Structural Engineering and Mechanics
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• v.84 no.6
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• pp.831-849
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• 2022

One of the most prevalent causes of reinforced concrete (RC) structural deterioration is chloride-induced corrosion. This paper aims to provide a comprehensive insight into the environmental effect of RC's chloride ingress process. The first step is to investigate how relative humidity, temperature, and wind influence chloride ingress into concrete. The probability of initiation time of chloride-induced corrosion is predicted using a probabilistic model that considers these aspects. Parametric analysis is conducted on several factors impacting the corrosion process, including the depth of concrete cover, surface chloride concentration, relative humidity, and temperature to expose environmental features. According to the findings, environmental factors such as surface chloride concentration, relative humidity and temperature substantially impact on the time to corrosion initiation. The long- and short-distance impacts are also examined. The meteorological data from the National Meteorological Center of China are collected and used to analyze the environmental characteristics of the chloride ingress issue for structures along China's coastline. Finally, various recommendations are made for improving durability design against chloride attacks.

• Journal of Korean Society on Water Environment
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• v.29 no.2
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• pp.247-258
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• 2013

A grid-based configuration of Land Surface Models (LSMs) coupled with a climate model can be advantageous in impact assessment of climate change for a large scale area. We assessed the applicability of Common Land Model (CoLM) to runoff and land surface temperature (LST) simulations at the domain that encompasses the Nakdong river basin. To establish a high resolution model configuration of a $1km{\times}1km$ grid size, both surface boundary condition and atmospheric inputs from the observed weather data in 2009 were adjusted to the same resolution. The Leaf Area Index (LAI) was collected from MODerate esolution Imaging Spectroradiometer (MODIS) and the downward short wave flux was produced by a nonstationary multi-site weather state model. Compared with the observed runoffs at the stations on Nakdong river, simulated runoffs properly responded to rainfall. The spatial features and the seasonal variations of the domain fairly well were captured in the simulated LSTs as well. The monthly and seasonal trend of LST were described well compared to the observations, however, the monthly averaged simulated LST exceeded the observed up to $2^{\circ}C$ at the 24 stations. From the results of our study, it is shown that high resolution LSMs can be used to evaluate not only quantity but also quality of water resources as it can capture the geographical features of the area of interest and its rainfall-runoff response.

• Membrane and Water Treatment
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• v.11 no.3
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• pp.231-235
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• 2020

Industrialization and modern developments have led to an influx of toxic heavy metals into the aquatic environment, and the accumulation of heavy metals has serious adverse effects on humans. Among the various heavy metal treatment methods, adsorption is very useful and frequently used. Plastic materials, such as polypropylene and polyethylene, have been widely used as filter media due to their mechanical and chemical stability. However, the surface of plastic material is inert and therefore the adsorption capability of heavy metals is very limited. In this study, granular media and fiber media composed of polypropylene and polyethylene are used, and the surface modification was conducted in order to increase adsorption capability toward heavy metals. Oxygen plasma generated hydroxyl groups on the surface of the media to activate the surface, and then acrylic acid was synthesized on the surface. The grafted carboxyl group was confirmed by FT-IR and SEM. Heavy metal adsorption capability of pristine and surface modified adsorbents was also evaluated. Overall, heavy metal adsorption capability was increased by surface modification due to electrostatic interaction between the carboxyl groups and heavy metal ions. Fibrous PP/PE showed lower improvement compared to granular PP media because pore blockage occurred by the surface modification step, thereby inhibiting mass transfer.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2018.10a
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• pp.179-179
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• 2018

• Korean Journal of Remote Sensing
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• v.36 no.4
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• pp.609-626
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• 2020

Satellite-based land surface temperature (LST) has been used as one of the major parameters in various climate and environmental models. Especially, Moderate Resolution Imaging Spectroradiometer (MODIS) LST is the most widely used satellite-based LST product due to its spatiotemporal coverage (1 km spatial and sub-daily temporal resolutions) and longevity (> 20 years). However, there is an increasing demand for LST products with finer spatial resolution (e.g., 10-250 m) over regions such as urban areas. Therefore, various methods have been proposed to produce high-resolution MODIS-like LST less than 250 m (e.g., 100 m). The purpose of this review is to provide a comprehensive overview of recent research trends and challenges for the downscaling of MODIS LST. Based on the recent literature survey for the past decade, the downscaling techniques classified into three groups-kernel-driven, fusion-based, and the combination of kernel-driven and fusion-based methods-were reviewed with their pros and cons. Then, five open issues and challenges were discussed: uncertainty in LST retrievals, low thermal contrast, the nonlinearity of LST temporal change, cloud contamination, and model generalization. Future research directions of LST downscaling were finally provided.

• Bulletin of the Korean Chemical Society
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• v.32 no.3
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• pp.809-814
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• 2011

A method based on the TMS derivatives and acidic hydrolysis was developed for the simultaneous determination of free and conjugated steroidal hormones in surface water. A silylation of five natural and two synthetic steroidal hormones was achieved with N-methyl-N-(trimethylsilyl) trifluoroacetamide/$NH_4I$ (1000:3) under catalysis of dithioerythritol for 60 min at $80^{\circ}C$. TMS derivatives of the steroid hormones containing multifunctional groups offer a single derivative product under this condition. The accuracy of the analytes was in the range of 87 to 110% at a concentration of 20 and 50 ng/L with relative standard deviations of less than 10%. The method detection limit was in the range of 0.01 to 0.02 ng/L for surface water. Natural steroidal hormones were detected in a concentration range of 0 to 1.03 ng/L in free form and 0 to 14.6 ng/L in conjugated form, respectively. We found that most of the natural hormonal steroids exist in conjugate forms (43 to 100%) in river water.

• Journal of the Korean Ceramic Society
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• v.49 no.6
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• pp.535-541
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• 2012

ALC was fabricated using cement, lime, quartzite and a foaming agent via a hydrothermal reaction. ALC has various hydrothermal reaction products and many pores. The properties and colors of ALC surfaces were changed by various factors during ALC fabrication process. This study tested various staying times to analyze these phenomena. It was found that the staying time of green body influenced the properties of hydrothermal products and color of ALC surface. The longer staying time of green body, the lower tobermorite content and cumulative loss weight. An increase in holding time changed color and decreased whiteness of ALC surface. The relationship between whiteness and cumulative loss weight was very high (Coefficient, r = 0.95). It was surmised that tobermorite content was an important factor for enhancement of whiteness However, ettringite and quartzite did not contribute to whiteness.

• Korean Journal of Remote Sensing
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• v.37 no.4
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• pp.665-685
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• 2021

This study focused on the a 20-year evaluation of the dynamism of critical thermal anomalies in Busan metropolitan area prompted by unusual infrastructural development and demographic growth rate. Archived Landsat thermal data derived-LST was the major input for UTFVI and hot spot analysis (Getis-Ord Gi^*). Results revealed that the surface urban heat island-affected area has gradually expanded overtime from 23.32% to 32.36%; while the critical positive thermal anomalies (level-3 hotspots) have also spatially increased from 19.88% in 2000 to 23.56% in 2020, recording a net LST difference of > 5℃ between the maximum level-3 hotspot and minimum level-3 coldspot each year. It is been observed that thermal conditions of Busan have gradually deteriorated with time, which is potentially inherent in the rate of urban expansion. Thus, this work serves as an eye-opener to powers that be, to think and act constructively towards a sustainable thermal conform for city dwellers.

• Journal of Climate Change Research
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• v.34 no.22
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• pp.8813-8828
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• 2021

Stomatal closure is a major physiological response to the increasing atmospheric carbon dioxide (CO₂), which can lead to surface warming by regulating surface energy fluxes-a phenomenon known as CO₂ physiological forcing. The magnitude of land surface warming caused by physiological forcing is substantial and varies across models. Here we assess the continental warming response to CO₂ physiological forcing and quantify the resultant climate feedback using carbon-climate simulations from phases 5 and 6 of the Coupled Model Intercomparison Project, with a focus on identifying the cause of intermodel spread. It is demonstrated that the continental (40°-70°N) warming response to the physiological forcing in summer (~0.55 K) is amplified primarily due to cloud feedback (~1.05 K), whereas the other climate feedbacks, ranging from -0.57 to 0.20 K, show relatively minor contributions. In addition, the strength of cloud feedback varies considerably across models, which plays a primary role in leading large diversity of the continental warming response to the physiological forcing.