• 제목/요약/키워드: Environmental solutions

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제초제 스크리닝을 위한 계면활성제-아세톤 수용액의 용매성, 전착성 및 약해 (Solubilizability, foliar wettability and phytotoxicity of nonionic surfactant-acetone aqueous solutions for the herbicide screening)

  • 유주현;조광연
    • 한국환경농학회지
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    • 제14권3호
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    • pp.296-301
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    • 1995
  • 약제, 계면활성제, 수용성 유기용매, 증류수의 조성을 가지는 농약스크리닝용 약제용액중에서 각 성분들의 역할을 명확히 이해하는 동시에 약제용액에 보다 우수한 성질을 부여할 수 있는 계면활성제를 선발하기 위하여 Tween 20을 포함한 6종의 비이온성 계면활성제 수용액의 제초제 원제 18종에 대한 용매성, 벼와 콩에 대한 전착력 및 약해를 시험하고 평가하였다. 제초제 원제에 대한 계면활성제-아세톤 수용액의 용매성은 아세톤의 첨가비에 의존하였으며, 이에 대한 비이온 계면활성제의 역할은 미미하였다. 시험한 계면활성제중 polyoxyethylene nonylphenyl ether HLB 16.0(NP-16.0)을 함유하는 아세톤 수용액이 약간 더 양호한 용매성을 보였다. 콩잎에 대한 전착력은 모든 계면활성제 수용액이 고르게 양호하였으나, 벼에 대한 전착력은 polyoxyethylene lauryl ether HLB 13.6(LE-13.6)를 함유하는 아세톤 수용액만이 양호하였다. 대부분의 계면활성제 수용액이 벼에 대해서는 약해를 유발하지 않았으나, 콩잎에 대해서는 Tween 20 0.1%, LE-13.6 0.01% 및 NP-16.0 0.01% 수용액만이 약해를 유발하지 않았다. 약제에 대한 유화성, 식물체에 대한 전착력 및 약해 안전성을 모두 만족시킬 수 있는 계면활성제는 찾지 못하였으나 시험한 계면활성제중에서는 LE-13.6이 가장 적당하였다.

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고온환경에 있어서 면양의 제일위내 VFA 조성비율이 일반임상소견 및 Insulin 분필반응에 미치는 영향 - VFA-TG 인공영양사육법의 응용 - (Combined Effects of VFA Composition of Rumen Fluid and Heat Exposure on General Clinical View and Insulin Secretion Response in Sheep)

  • 홍경선;정태영;좌야굉명;지하농랑;중와방야;안보계일
    • 한국축산시설환경학회지
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    • 제3권1호
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    • pp.1-12
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    • 1997
  • This study was conducted to investigate the combined effects of VFA composition of rumen fluid and heat exposure (30${\pm}$2$^{\circ}C$) on the general clinical view and insulin secretory response to glucose in sheep. The total infusion of nutrients was examined in sheep via the technique of continuous alimentation. Four adult Suffolk sheep fitted with a permanent ruminal cannula and a simple T-shaped duodenal cannula were used. A peristaltic pump was used to infuse the solutions of volatile fatty acid triglycerides (VFA-TG) consisting of 70 triacetin : 20 tripropionin : 10 tributyrin (low propionin division: LP) and 50 triacetin : 40 tripropionin : 10 tributyrin (high propionin division: HP) on the basis of energy and minerals into the rumen, and casein solution into the duodenum. The effects of heat exposure and type of the levels of VFA-TG solutions on the insulin secretory response to glucose in sheep were investigated by using hyperglycemic clamp (HGC) technique. The results obtained are summarized as follows: 1. During the heat exposure (latter half of the infusion period), respiration rate, heart rate and rectal temperature increased (P<0.01, P<0.01, P<0.05), but the levels of VFA-TG solutions (LP and HP division) did not affect the general clinical view except for the heart rate. 2. In the HGC technique, glucose infusion rate (GIR) and mean plasma insulin increments (MPII) tended to be ower in the heat exposure than in the thermoneutral environment, but no significant difference was found among the treatments. GIR and MPII remained unchanged between the levels of VFA-TG solutions. 3. In the HGC technique, ratio of MPII to GIR (MPII/GIR) which represents pancreatic ${\beta}$-cell response to glucose stimulation remained unchanged among the treatments.

칼슘 및 칼륨 용액을 이용한 원자력발전소 주변 스트론튬과 세슘 오염토양 세척기술 연구 (Soil Washing Technology for Sr and Cs-contaminated Soil Near Nuclear Power Plants using Calcium and Potassium Based Solutions)

  • 송호재;남경필
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제27권2호
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    • pp.76-86
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    • 2022
  • Calcium (Ca) and potassium (K) were introduced to remove Sr and Cs in soil, respectively. Four factor and three level Box-Bhenken design was employed to determine the optimal washing condition of Ca- and K-based solutions, and the ranges tested were 0.1 to 1 M of Ca or K, L/S ratio of 5 to 20, washing time of 0.5 to 2 h, and pH of 2 to 7. The optimal washing condition determined was 1 M of Ca or K, L/S ratio of 20, washing time of 1 h, and pH of 2, and Ca-based and K-based solutions showed 68 and 81% removal efficiency for Sr and Cs, respectively in soil. For comparison, widely used conventional washing agents such as 0.075 M EDTA, 0.01 M citric acid, 0.01 M oxalic acid, and 0.05 M phosphoric acid were tested, and they showed 25 to 30% of Sr and Cs removal efficiency. Tessier sequential extraction was employed to identify the changes in chemical forms of Sr and Cs during the washing. In contrast to the conventional washing agents, Ca-based and K-based solutions were able to release relatively strongly bound forms of Sr and Cs such as Fe/Mn-oxide and organic matter bound forms, suggesting the involvement of direct substitution mechanism, probably due to the physicochemical similarities between Sr-Ca and Cs-K.

Geomechanical and hydrogeological validation of hydro-mechanical two-way sequential coupling in TOUGH2-FLAC3D linking algorithm with insights into the Mandel, Noordbergum, and Rhade effects

  • Lee, Sungho;Park, Jai-Yong;Kihm, Jung-Hwi;Kim, Jun-Mo
    • Geomechanics and Engineering
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    • 제28권5호
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    • pp.437-454
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    • 2022
  • The hydro-mechanical (HM) two-way sequential coupling in the TOUGH2-FLAC3D linking algorithm is validated completely and successfully in both M to H and H to M directions, which are initiated by mechanical surface loading for geomechanical validation and hydrological groundwater pumping for hydrogeological validation, respectively. For such complete and successful validation, a TOUGH2-FLAC3D linked numerical model is developed first by adopting the TOUGH2-FLAC3D linking algorithm, which uses the two-way (fixed-stress split) sequential coupling scheme and the implicit backward time stepping method. Two geomechanical and two hydrogeological validation problems are then simulated using the linked numerical model together with basic validation strategies and prerequisites. The second geomechanical and second hydrogeological validation problems are also associated with the Mandel effect and the Noordbergum and Rhade effects, respectively, which are three phenomenally well-known but numerically challenging HM effects. Finally, sequentially coupled numerical solutions are compared with either analytical solutions (verification) or fully coupled numerical solutions (benchmarking). In all the four validation problems, they show almost perfect to extremely or very good agreement. In addition, the second geomechanical validation problem clearly displays the Mandel effect and suggests a proper or minimum geometrical ratio of the height to the width for the rectangular domain to maximize agreement between the numerical and analytical solutions. In the meantime, the second hydrogeological validation problem clearly displays the Noordbergum and Rhade effects and implies that the HM two-way sequential coupling scheme used in the linked numerical model is as rigorous as the HM two-way full coupling scheme used in a fully coupled numerical model.

환경보전의식 및 환경보전행동과 삶의 질의 관계에 대한 연구 - 서울시 주부를 중심으로- (The Relationship between Environmental Conservation Consiousness, Environmental Conservation Behavior and Qualify of Life - Centered on Seoul City Housewives-)

  • 최남숙;이소영
    • 가족자원경영과 정책
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    • 제6권1호
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    • pp.135-147
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    • 2002
  • The purpose of this study was to achieve regarding the environmental problem due to excessive economic development for human being's continous life and to try to enhance the quality of life. The major findings of this study are as followings: 1) Environmental consciousness and activity are closely correlated and also postively related to quality of life. Accordingly, environmental consciousness should be inspired and the environmental activities performed successfully to enhance the quality of life so that we can lead higher quality of life. 2) Income takes the highest position in the life-influncing factor with the following sequence of environmental consciousness, preservation acitivity, housekeeper's education level and age. So, earlier and steady education are important in raising the education level to have people equipped with environmental consciousness and activity. Moreover, we should be able to create income through education to enhance the quality of life. Accordingly, we should take a positive measure for enhancing environmental preservation and quality of life to meet two solutions, such as mankind's continuous development and value-oriented life.

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한국의 친환경농업을 위한 농업환경계정 구축에 관한 연구 (Research about Agriculture Environment Account Construction for Korea of Environment-friendly Agriculture)

  • 윤성이
    • 한국유기농업학회지
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    • 제10권2호
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    • pp.51-66
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    • 2002
  • It is almost impossible to aggregate environment-related information, simply because it is vast. Therefore, Recently, the development of an environmental index is attracting the attention in Korea and other nations, since it is taken to be useful for legislating environmental policies. When it comes to the development of an environmental index, the first necessary step is to organize environmental information by using an accounting framework that manifests outstanding consistency and inclusiveness. And then, this organized environmental information should be appropriately used, whenever required. Compared to these movements, it is necessary to point out that the environmental accounts in the agricultural section still suffer from numerous problems that need to be solved. According1y, this dissertation suggests and considers at least the following three matters. First of all, an integrated index evaluation method should be developed, taking domestic and foreign movements into consideration at the time of conducting the environmental evaluation. Secondly, a master plan for the environmental accounts should be developed for the agricultural sector. And thirdly and finally, problems and solutions incurred during the process of performing the aforementioned tasks need to be examined in detail.

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제약조건 처리기법에 따른 하모니써치 알고리즘의 효율성 평가 : 관로 최소비용설계 문제의 적용 (Efficiency Evaluation of Harmony Search Algorithm according to Constraint Handling Techniques : Application to Optimal Pipe Size Design Problem)

  • 유도근;이호민;이의훈;김중훈
    • 한국산학기술학회논문지
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    • 제16권7호
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    • pp.4999-5008
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    • 2015
  • 제약조건이 있는 공학 최적화 문제에서 보다 좋은 결과를 얻기 위해서는 효율적인 제약조건 처리기법의 적용은 필수적이다. 본 연구에서는 네 가지의 제약조건 처리기법을 적용하여 메타휴리스틱 최적화 기법으로 널리 사용되고 있는 Harmony Search 알고리즘의 최적화 효율성을 평가하였다. 평가를 위해 대표적인 이산형 최적화 문제 중 하나인 상수관로 최소비용설계 문제를 적용하였다. 적용결과 전통적인 제약조건 처리방법으로 사용되던 벌칙함수에 비해 제안된 제약조건 처리기법의 결과가 효율적임을 확인하였다. 특히, ${\varepsilon}$-Constrained Method의 경우 기존방법에 비하여 효율적이고 안정적인 결과를 도출하였다. 제안된 방법은 새로운 최적화 알고리즘의 개발 필요 없이 HS의 성능을 증가시킬 수 있다는 점에서 의의가 있다고 판단된다. 또한 400개 이상의 결정변수를 가지는 대규모 문제의 적용을 통하여, 제안된 방법이 대규모 공학 최적화 문제에서도 활용이 가능함을 확인하였다.

Degradation of energetic compounds using an integrated zero-valent iron-Fenton process

  • Oh Seok-Young;Kim Byung J.;Chiu Pei C.;Cha Daniel K.
    • 한국지구물리탐사학회:학술대회논문집
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    • 한국지구물리탐사학회 2003년도 Proceedings of the international symposium on the fusion technology
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    • pp.493-500
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    • 2003
  • The effect of reductive treatment with elemental iron on the extent of mineralization by Fenton oxidation was studied for the explosive 2,4,6-trinitrotoluene (TNT) and hexahydro-l,3,5-trinitro-l,3,5-triazine (RDX) using a completely-stirred tank reactor (CSTR). The results support the hypothesis that TNT and RDX are reduced with elemental iron to products that are oxidized more rapidly and completely by Fenton's reagent. Iron pretreatment enhanced the extent of TOC removal by approximately $20\%\;and\;60\%$ for TNT and RDX, respectively. Complete TOC removal was achieved for TNT and RDX solutions with iron pretreatment under optimal conditions. On the other hand, without iron pretreatment, complete mineralization of TNT and RDX solutions were not achieved even with much higher $H_2O_2$ and $Fe^{2+}$ concentrations. The bench-scale iron treatment-Fenton oxidation integrated system showed more than $95\%$ TOC removal for TNT and RDX solutions under optimal conditions. The proposed zero-valent iron-Fenton process was evaluated with pink water from the Iowa Army ammunition plant. Results from batch and column experiments show that TNT, RDX, and octahydro-l,3,5,7-tetranitro-l,3,5,7-tetrazocine (HMX) were completely removed from the pink water and that triaminotoluene (TAT) and ${NH_4}^+$ were recovered as products in reduction with zero-valent iron. By using an integrated system, $83.3\pm4.2\%$ of TOC was removed in a CSTR with 10 mM of $Fe^{2+}$ and 50 mM of $H_2O_2$. These results suggest that the reduction products of TNT and RDX are more rapidly and completely mineralized by Fenton oxidation and that a sequential iron treatment-Fenton oxidation process may be a viable technology for pink water treatment.

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전기방사에 의한 셀룰로오스 아세테이트 극세 섬유 웹의 제조 (Preparation of Ultrafine Fiber Web from Cellulose Acetate by Electrospinning)

  • 이인화;설명수;박주영;윤석진
    • 공업화학
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    • 제17권3호
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    • pp.255-259
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    • 2006
  • 전기방사에 의해 셀룰로오스 아세테이트 약 800 nm 지름 극세 섬유를 농도, 전압, 방사거리 변화에 따라 제조하였다. 아세톤 용매를 이용해 7.5 wt%~15.0 wt% 셀룰로오스 고분자용액을 만든 후 다양한 조건에서 전기방사를 실시하였다. 농도별 셀룰로오스 고분자용액은 인가전압, 토출 유속, 그리고 팁과 집적판 사이의 거리의 변화와 함께 적용되었다. 섬유 직경은 전기방사 시 고분자용액의 점도에 의존하였다. 섬유의 직경은 점도에 의존하며, 12.0 cp 이하의 고분자용액에서는 형성되지 못하였다. 셀룰로오스 고분자용액의 농도가 12.5 wt%, 인가전압 12 kV, 토출 유속 $100{\mu}L/min$ 그리고 팁과 집적판의 거리 가 7.5 cm에서 단섬유의 직경이 800 nm의 극세 섬유를 제조할 수 있다.

ICP-MS와 AAS를 이용한 대기 입자상 표준물질 (SRM 1648) 금속성분의 정량에 관한 연구 (Determination of Metallic Elements in Urban Particulate Matter (SRM 1648) by ICP-MS and AAS)

  • 유수영;최금찬;김기현
    • 한국대기환경학회지
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    • 제21권4호
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    • pp.423-430
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    • 2005
  • This study was investigated with sample digestion techniques and a reliability of the analytical results for a quantitative analysis of a standard reference material ('urban particulate matter', SRM 1648). The metallic elements were analyzed by inductively coupled plasma mass spectrometry (ICP-MS) with closed vessel microwave acid digestion method and atomic absorption spectroscopy (AAS). Quality control of the overall analytical procedures for metallic element determinations of standard reference material were estimated by analysis of a SRM 1648. Three digestion solutions $(type\;1:\;HNO_3,\;type\;2:\;HNO_3\;and\;H2O_2(4'1)\;mixture,\;type\;3:5.55\%\; HNO_3\;and\;16.75\%\;HCI\;mixture)$ were applied to SRM 1648. As a result, three digestion solutions used in this study are completely unable to digest Cr of SRM 1648. Reliability of Cr and As showed some errors in the digestion with digestion solution type (3) due to the influence of chlorides. Type (3) digestion solutions are sufficient to fulfill the digestion of As as well as Se in SRM 1648. ICP-MS results showed the improvement in accurate and precise determination of some trace elements like Cd, V and Pb in SRM 1648. It is important to use the proper digestion solution for each element to qualify analytical precision.