Journal of Korean Society for Atmospheric Environment (한국대기환경학회지)

Korean Society for Atmospheric Environment (한국대기환경학회)
권호 표지

Determination of Metallic Elements in Urban Particulate Matter (SRM 1648) by ICP-MS and AAS

ICP-MS와 AAS를 이용한 대기 입자상 표준물질 (SRM 1648) 금속성분의 정량에 관한 연구

  • Yoo Su-Young (Department of Environmental Engineering, Dong-A University) ;
  • Choi Kum-Chan (Department of Environmental Engineering, Dong-A University) ;
  • Kim Ki-Hyun (Department of Earth & Environmental Science, Sejong University)
  • Published : 2005.08.01
Download PDF
⟨ Previous Next ⟩

Abstract

This study was investigated with sample digestion techniques and a reliability of the analytical results for a quantitative analysis of a standard reference material ('urban particulate matter', SRM 1648). The metallic elements were analyzed by inductively coupled plasma mass spectrometry (ICP-MS) with closed vessel microwave acid digestion method and atomic absorption spectroscopy (AAS). Quality control of the overall analytical procedures for metallic element determinations of standard reference material were estimated by analysis of a SRM 1648. Three digestion solutions $(type\;1:\;HNO_3,\;type\;2:\;HNO_3\;and\;H2O_2(4'1)\;mixture,\;type\;3:5.55\%\; HNO_3\;and\;16.75\%\;HCI\;mixture)$ were applied to SRM 1648. As a result, three digestion solutions used in this study are completely unable to digest Cr of SRM 1648. Reliability of Cr and As showed some errors in the digestion with digestion solution type (3) due to the influence of chlorides. Type (3) digestion solutions are sufficient to fulfill the digestion of As as well as Se in SRM 1648. ICP-MS results showed the improvement in accurate and precise determination of some trace elements like Cd, V and Pb in SRM 1648. It is important to use the proper digestion solution for each element to qualify analytical precision.

Keywords

References

  1. 김기현, 이강웅, 김조천, 서영화, 이종해, 허귀석(1999) 대기오염측정에 대한 정도 관리의 필요성, 한국대기환경학회지, 15(1), 63-69
  2. 대기환경연구회(1996) 환경 분석을 위한 대기환경시험법, 동화기술, 13pp
  3. 일본환경청(1997) 유해 대기오염물질 측정방법 메뉴얼, 일본환경청 대기보전국, 140pp
  4. 정용삼, 문종화, 정영주, 박광원, 이길용, 윤윤열, 심상권, 조경행, 한명섭, 이종해(1999) INAA, ICP, AAS를 이용한 대기먼지(PM10)의 다원소분석, 한국대기환경학회지, 15(4), 495-503
  5. Becker S.J. and H. Dietze (2000) Inorganic mass spectrometric methods for trace, ultratrace, isotope, and surface analysis, International Journal of Mass Spectrometry, 197, 1-35 https://doi.org/10.1016/S1387-3806(99)00246-8
  6. Bhandari S.A. and D. Amarasiriwardena (2000) Closed-vessel microwave acid digestion of commercial maple syrup for the determination of lead and seven other trace elements by ICP-MS, Microchemical Journal, 64,73-84 https://doi.org/10.1016/S0026-265X(99)00017-X
  7. Curdova E. and L. Vavruskova (2004) ICP-MS determination of heavy metals in submerged cultures of wood-rotting fungi, Talanta, 62(3), 483-487 https://doi.org/10.1016/j.talanta.2003.08.030
  8. Kawaguchi H., T. Tanaka, T. Nakamura, M. Morishita, and A. Mizuike (1987) Matrix Effects in Inductively Coupled Plasma Mass Spectrometry, Anaytical Sciences, 3(4), 305-308 https://doi.org/10.2116/analsci.3.305
  9. Rodushkin I., T. Ruth, and A. Huhtasaari (1999) Comparison of two digestion method for elemental determina-tion in plant material by lCPS techniques, Analytica Chimica Acta, 378, 191 -200 https://doi.org/10.1016/S0003-2670(98)00635-7
  10. Saitoh K., K. Sera, T. Gotoh, and M. Nakamura (2002) Comparison of elemental quantity by PIXE and ICPMS and/or ICP-AES for NIST standards, Nuclear Instruments and Methods in Physics Research, B 189,86-93 https://doi.org/10.1016/S0168-583X(01)01012-6
  11. US EPA (2003) The Particle Pollution Report, Current Understanding of Air Quality and Emissions through 2003, EPA 454-04-002
  12. US EPA (1999) Compendium of methods for the determination of inorganic compounds in ambient air, Center for Environmental Research Information, Office of Research and Development, IO-3.1, EPA/625/R-96/010a
  13. Wang C.F., C.J. Chin, S.K. Luo, and L.C. Men (1999) Determination of chromium in airbome particulate matter by high resolution and laser ablation inductively coupled plasma mass spectrometry, Analytica Chimica Acta, 389, 257-266 https://doi.org/10.1016/S0003-2670(99)00162-2
  14. Wang C.F., C.Y. Chang, C.J. Chin, and L.C. Men (1999) Determination of arsenic and vanadium in airbome related reference materials by inductively coupled plasma mass spectrometry, Analytica Chimica Acta, 392, 299-306 https://doi.org/10.1016/S0003-2670(99)00242-1