• Title/Summary/Keyword: Environmental sieve

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Effects of Water and Silica Gel on Enzyme Agglomeration in Organic Solvents

  • Keehoon Won;Lee, Sun-Bik
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.6 no.2
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    • pp.150-155
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    • 2001
  • It has been observed that water, which is absolutely essential for enzyme activity, can induce the agglomeration of enzyme particles in organic media. Although enzyme agglomeration is significant in that it usually reduces enzyme activity and stability, little attention has been paid to the quantitative analysis of enzyme agglomeration behavior in nonaqueous biocatalytic systems. In this study, the effect of water and silica gel on enzyme agglomeration were investigated using Candida rugosa lipase and cyclohexane as a model enzyme and an organic medium. The extent of enzyme agglomeration was quantified by sieve analysis of freeze-dried agglomerates. Increasing the water content of the medium increased the size of the enzyme agglomerates, and it was found that water produced during the esterification reaction could also promote the agglomeration of enzyme particles suspended in organic media. On the other hand, the size of the enzyme agglomerates was remarkably reduced in the presence of silica gel at the same water content. We also show that this increase in the size of enzyme agglomerates results in lower reaction rates in organic solvents.

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The Construction Work Method of Mixed Coal Ash in Ash Pond to Recycle as a Horizontal Drain Material (수평배수재로 재활용하는 회사장 혼합석탄재의 시공 방안)

  • Koh, Yongil
    • Journal of the Korean GEO-environmental Society
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    • v.14 no.4
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    • pp.53-58
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    • 2013
  • The design for horizontal drain layer on soft ground starts from the decision that the material could be used or not, by verifying material condition in permeability of horizontal drain material according to the weight percent of the dry soil retained on #200 sieve. In the next step of the design, we estimate the thickness of horizontal drain layer to confirm trafficability of heavy machinery in construction work. Successively, the long-term functionality for good drainage of horizontal drain layer is checked and if needed, some means are considered. In this study, the system to recycle mixed coal ash in ash pond successfully as a horizontal drain material on soft ground is presented through the process and the result of its practical construction work. Namely, the pact is confirmed that mixed coal ash in ash pond should be sorted out by sieve screen to a certain extent and the remainders of this mixed coal ash on sieve openings be recycled, because the amount of finer particles than $75{\mu}m$ contained in mixed coal ash in ash pond is quite massive and irregular depending on the coal power plant or the location in same ash pond. In order to sort at large scale in situ, the dimension of a sieve squre hole and the sort-out method, etc. should be decided before the sort-out process. And, it is described that we need to manufacture classifier to sort out mixed coal ash in ash pond, too.

Determination of Metals of Coal and Respirable Coal Dust in Gangneung and Taebaek Coal Mines (강릉·태백지역 석탄광산의 탄 및 호흡성 탄분진중 금속 농도 비교에 관한 연구)

  • Kim, Hae Jeong;Choi, Ho Chun;Chung, Ho Keun
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.1 no.1
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    • pp.82-88
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    • 1991
  • Determination of Cu, Fe, Ni, Pb, and Zn concentrations in coal and respirable coal dust were performed by atomic absorption spectrophotometry. The coal samples of 18 coal mines in Gangneung area were collected and 25 coal mines in Taebaek area. Crushed coal samples were divided into three mesh sizes. The results were as follows : 1. Metal concentrations of coals in Gangneung area by sieve sizes( -100/+200 mesh, -200/+325 mesh, -325 mesh) were as follows: Cu ; 20, 18, 19, Fe ; 1,830, 1,765, 1,107, Pb ; 6, 8, 14, Ni ; 17, 17, 14, Zn ; 4, 2, $4{\mu}g/g$, respectively. Metal concentrations in coals in Taebaek area by sieve sizes(-100/+200 mesh, -200/+325 mesh, -325 mesh) were as follows: Cu ; 30, 32, 26, Fe ; 1,741, 1,822, 1,773, Pb ; 8, 9, 7, Ni ; 13, 13, 13, Zn ; 8, 5, $4{\mu}g/g$, respectively. There were not significant differences of Cu, Fe, Ni, Pb, and Zn concentrations of coals statistically in Gangneung and Taebaek area by sieve size. 2. Metal concentrations of coals in Gangneung and Taeback area were as follows : Cu ; 19, 30, Fe ; 1,514, 1,778, Pb ; 9, 8, Ni ; 16, 13, Zn ; 3, $6{\mu}g/g$, respectively. Differences of copper and zinc concentrations of coal samples were significant between Gangneung and Taebaek area, but those of iron, nickel and lead concentrations were not significant. 3. Copper, iron, lead, nickel and zinc concentrations of coals and respirable coal dust were as follows : Cu ; 30, 6, Fe ; 1,779, 5,075, Pb ; 8, 7,814, Ni ; 13, 5,681, Zn ; 5, $134{\mu}g/g$, respectively. Differences of nickel, lead and zinc concentrations were significant between coals and respirable coal dust but those of copper and iron concentrations were not significant.

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Effect of Soil Grinding on Total Concentrations of As and Pb in Soil Determined by aqua regia Method (토양시료의 분쇄가 왕수분해법을 이용한 비소와 납의 전함량 분석 결과에 미치는 영향)

  • An, Jinsung;Yu, Gihyeon;Nam, Kyoungphile
    • Journal of Soil and Groundwater Environment
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    • v.23 no.1
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    • pp.25-29
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    • 2018
  • The effect of soil grinding on total As and Pb concentrations determined by aqua regia method was examined. Among six field-collected, air-dried soil samples tested, soils A, B, C, and E were directly sieved through a $150-{\mu}m$ sieve without grinding and showed 2.18 to 3.03 times higher total As concentrations and 2.62 to 3.45 times higher total Pb concentrations than those of the soil samples prepared to allow all soil particles to pass through the $150-{\mu}m$ sieve by grinding. The reason can be ascribed to the fact that those soils contain fine particles (i.e., < $150{\mu}m$ in diameter) only 4.6 to 6.8% of the total soil weights. On the other hand, for D and F soils, fine particles smaller than $150{\mu}m$ accounted for 57 and 46%, respectively, so that the effect of grinding on As and Pb concentrations were relatively low (As: 1.15 and 1.23 times, Pb: 1.36 and 1.49 times, respectively). The result demonstrates that grinding prior to $150-{\mu}m$ sieving is necessary to ensure the homogeneity of soil samples and hence to obtain more accurate heavy metal concentrations in soils. This is especially true for soil samples with less fine soil particles and/or microaggregates (i.e., below $150{\mu}m$).

An Efficient Method for Zircon Separation Using the Gold Pan (선광팬을 이용한 효과적인 저어콘 분리법)

  • Cheong, Wonseok;Cho, Moonsup;Kim, Yoonsup
    • The Journal of the Petrological Society of Korea
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    • v.22 no.1
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    • pp.63-70
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    • 2013
  • We report an easy and efficient method for separating zircon grains using a gold pan and disposable sieve together with the tap water. Samples powdered to less than $230{\mu}m$ in grain size are placed on the water-filled pan tilted at about $10^{\circ}$. The outflowing water flooded with low-density particles is screened by a ${\sim}70{\mu}m$ sieve. The most efficient rate of water outflow is estimated to be 0.1 L/sec, when the distance between the tap and the surface of water-filled pan is kept at 20-25 cm. After 20-30 minutes of water outflow, heavy mineral fractions are ready for zircon collection using a hand magnet (and heavy liquid when necessary) or simply hand-picking. This procedure is most likely applicable for the separation of other heavy minerals including monazite.

Adsorption of CO2 on Monoethanol Amine-Impregnated ZSM5 and MS13X (Monoethanolamine을 함침한 ZSM5와 MS13X의 CO2 흡착특성 비교)

  • Choi, Sung-Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.6
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    • pp.325-331
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    • 2017
  • Adsorption experiments of carbon dioxide were performed on ZSM5 and Molecular Sieve 13X (MS13X) impregnated with Monoethanol Amine (MEA). Adsorption efficiency of $CO_2$ was investigated in a U type packed column with GC/TCD. The adsorption capacities of adsorbents are estimated in the temperature range of $30-80^{\circ}C$. The modified adsorbents was characterized by BET surface area, $N_2$ adsorption/desorption isotherms, X-ray diffraction and FT-IR. Surface analysis results showed that the impregnation method did not affect the crystallinity of any adsorbents. BET surface area of the MS13X impregnated amine decreased to $19.945m^2/g$ from $718.335m^2/g$. These reults showed that amine molecules were filled with the pore volume in MS13X, as a results restricting access of nitrogen into the pores. The MEA modified MS13X showed improvement in $CO_2$ adsorption capacity over the ZSM5 impregnated with MEA. The MS13X-MEA showed the highest adsorption capacity due to physical adsorption and chemical adsorption by amino-group content. This results also showed that adsorption capacity of MS13X-MEA increases with the temperature range of $60-80^{\circ}C$ compared with pristine MS13X.

Utilization of an Instructional Centrifuge Test for Teaching in Geotechnical Engineering (Focus on Retaining Wall Model) (지반공학 분야에서 교육용 도구로서의 원심모형실험 활용법 (옹벽 모델의 예를 중심으로))

  • Kim, Tae-Hyung;Lee, Kang-Il;Kim, Tae-Hoon;Lee, Sung-Chul;Hwang, Joong-Ho
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.03a
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    • pp.1254-1259
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    • 2008
  • Recently, centrifuge tests have been widely used as tools in geotechnical engineering researches in domestic and foreign. However, the size of these centrifuge facilities is very large and thus the tests require for long time, high expense, and many labors. In this study, therefore, a small capacity(2g ton) of instructional centrifuge, which can conduct tests in a short period of time effectively, was introduced. The results of centrifuge tests conducted on the retaining wall both passive and active cases was used. Medium size of sand was used with sieve off fines in sand using #40 sieve. Based on the test results, this centrifuge facility introduced in here can be enough used for geotechnical engineering education for graduate and undergraduate students.

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A Study on the Quality of the Domestic Fly Ash as an Additive for Concrete (콘크리트용 혼화재(混和材)로서 국산 플라이애쉬의 품질에 관한 실험적 연구)

  • Moon, Han Young;Seo, Joung Woo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.7 no.3
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    • pp.213-221
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    • 1987
  • To use fly ash as an additive for concrete, authors collected 15 kinds of domestic fly ashes and tested the chemical compositions and physical properties of the fly ashes. Fluidity of the fly ash paste was also investigated. The result shows that the chemical compositions of the fly ashes were in the range of regulation of Korean Industrial Standards except ignition loss and the following relationships in fly ash were studied; specific surface and residue in standard sieve, specific surface and unit weight, residue in standard sieve and ignition loss. For the given flow properties, fly ash paste required higher water-binder ratio than cement paste.

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Comparative Study on the Sampling Methods of Benthic Macroinvertebrates in the Fine Sediments of Freshwater (담수의 세립질 퇴적물 내 저서성 대형무척추동물 채집방법 비교 연구)

  • Kim, PilJae;Kim, Ah Reum;Kwon, Yongju;Min, Jeong Ki;Huh, In Ae;Kong, Dongsoo
    • Journal of Korean Society on Water Environment
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    • v.34 no.1
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    • pp.84-95
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    • 2018
  • The community structure of benthic macroinvertebrates in the fine sediments of freshwater was analyzed according to various sampling tools and methods. The sediment core with the inner diameter of 7.5 cm was more effective in cost and labor in comparison to that of ${\Phi}5cm$ or ${\Phi}10cm$. The number of species increased with the increase in sample size (replicates). When it was collected five times with the ${\Phi}7.5cm$ sediment core, Shannon-Weaver's diversity and McNaughton's dominance of the sample reached about the 80 % level of the community estimates. Most species appeared in the sediment layer of 0-4 cm, and there were no newly recruited species below the depth of 4 cm. Individual abundance of benthic macroinvertebrates decreased exponentially along with the increase in sediment depth. Compared with the individual abundance of the 0-15 cm sediment layer, the abundance was 60 % in the 0-2 cm layer, 25 % in the 2-4 cm layer, 10 % in the 4-6 cm layer and 95 % in the 0-6 cm layer. Compared with organisms collected with the sieve of 0.2 mm pore, the number of species and the individual abundance sifted through the sieve with pore of 1 mm were 36 % and 88 %, and those with pore of 0.5 mm were 5 % and 55 %, respectively.

Molecular Sieve Properties for $CH_4/CO_2$ of Activated Carbon Fibers Prepared by Benzene Deposition (벤젠 증착에 의해 제조된 활성탄소섬유의 $CH_4/CO_2$ 분자체 성질)

  • Moon, Seung-Hyun;Shim, Jae-Woon
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.6
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    • pp.614-619
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    • 2005
  • The activated carbon fibers of different surface area and pore structures were modified by carbon deposition from the pyrolysis of benzene, in an attempt to obtain carbon molecular sieves of high adsorption capacity and selectivity for the separation of $CO_2/CH_4$ gas mixtures. The ACFs molecular sieves prepared from different temperature and time were tested by the static adsorption of $CO_2$ and $CH_4$ gas, and their pore structures were characterized by the $N_2$ adsorption isotherms. We are able to prepare ACF molecular sieve with good selectivity for $CO_2/CH_4$ separation and showing acceptable adsorption capacities from the change of porosity by carbon deposition of pyrolyzed benzene.