• Title/Summary/Keyword: Environmental capacity

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High capacity polymer for nickel determination in environmental samples

  • Panahi, Homayon Ahmad;Feizbakhsh, Alireza;Dadjoo, Fatemeh;Moniri, Elham
    • Advances in environmental research
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    • v.2 no.4
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    • pp.309-321
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    • 2013
  • High AA new high capacity sorbent for preconcentration and determination of nickel in environmental samples was synthesized. The sorbent was synthesized by copolymerization of allyl glaycidyl ether / imminodiacetic acid with N,N-dimethylacrylamide as functional monomers in the presence of N,N-bismethylenacryl amid as cross linker and characterized by Fourier transform infra red spectroscopy, elemental analysis, thermogravimetric analysis and scanning electron microscopy. A recovery of 93.6% was obtained for the metal ion with 0.1 M, sulfuric acid as the eluting agent. The sorption capacity of the functionalized sorbent was 55.9 $mgg^{-1}$. The equilibrium sorption data of Ni(II) on polymeric sorbent were analyzed using Langmuir, Freundlich, Temkin and Redlich.Peterson models. Based on equilibrium adsorption data the Langmuir, Freundlich and Temkin constants were determined 0.87 (L mg-1), 25.87 ($mgg^{-1}$) $(Lmg^{-1})^{1/n}$ and 171.4 ($Jmol^{-1}$) respectively at pH 4.5 and $20^{\circ}C$.

The Study on Assessment of Protective Capacity of the Reinforced Concrete Box-type Artillery Positions (철근콘크리트조 박스형 포상의 방호성능 평가)

  • Baek, Jonghyuk;Kim, Suk Bong;Son, Kiyoung;Park, Young Jun
    • Journal of the Korea Institute of Military Science and Technology
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    • v.17 no.2
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    • pp.275-281
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    • 2014
  • Although self-propelled artilleries are mobile equipment, they need their own covered-positions for survival against preemptive strikes. The most important military requirement is enough protective capacity against blast pressure caused by explosion. This paper aims to assess the protective capacity of the newly-placed concrete box-type artillery positions using accurate structural geometric models as well as soil-structure interaction analysis. The commercial program is used to model the structural geometry of the positions. In order to describe the correct wave propagation in the backfill along with soil-structure interaction, used parameters in shock equation of state are selected based on the related studies as well as theories and then their final results are verified with the ones calculated with empirical equations in the US Unified Facility Criteria. In sum, it could be concluded that the protective capacity of the newly-built positions satisfies the protective structural requirement.

Evaluation of Allowable Bearing Capacity of 600 mm Diameter Preboring PHC Piles Using Dynamic Load Test (직경 600mm PHC 매입말뚝의 동재하시험을 통한 허용 지지력 평가)

  • Woo, Gyu-Seong;Park, Jong-Bae;Seo, Mi-Jeong;Lee, Jong-Sub
    • Journal of the Korean Geotechnical Society
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    • v.32 no.11
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    • pp.61-72
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    • 2016
  • For the construction of high-rise structures and the optimized foundation design, the use of the large-diameter PHC pile has increased. Especially, the use of the 600 mm diameter PHC pile has significantly increased. In this study, for the evaluation of the suitability of the current design practice, the 46 dynamic pile load tests, which were carried out in the 600 mm diameter preboring PHC pile, are analyzed. The end bearing capacity is obtained from the end of initial driving test and the shaft capacity is estimated from the restrike test. The allowable capacities estimated by the dynamic load test are compared with those based on the current design practice. The analyses show that the allowable end bearing capacity evaluated by the dynamic pile load test is greater than the design practice in most piles. The allowable shaft capacity, however, is smaller than the design practice in many piles. The higher end bearing capacity and the smaller shaft capacity may result from the improvement of the drilling equipment and the increase in the penetration depth. Thus, the portion of the end bearing capacity in the total capacity increases.

A Study on the Estimation of Ecological Footprint in Gyeongsangbuk-do for Comparison of Environmental Capacity of Each Local Government (자치단체별 환경용량 비교를 위한 경상북도지역 생태발자국 추정연구)

  • Kang, Kee-Rae;Kim, Hee-Chae;Kim, Dong-Pil;Oh, Hyun-Kyung;Cho, Kwang-Jin;Shin, Young-Ho
    • Korean Journal of Environment and Ecology
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    • v.28 no.6
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    • pp.769-778
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    • 2014
  • The rapid urbanization and increase in population due to industrialization have led to the extension of cities and the reduction in naturality as a necessity. Now, it is the biggest threat to virtuous circle of ecosystem. With the expansion of common recognition that this ecological crisis would be accompanied by the crisis of mankind, many countries all around the world are conducting researches to indicate the optimum consumption level of individual as an index in addition to cross-national environmental indicators such as ESI, EPI and SDI, by measuring environmental consumption of state, local government or individual, and comparing each region. Based on this background, this research was carried out to estimate the environmental capacity of 23 local government in Gyeongsangbuk-do. The result of EF estimation showed that EF value necessary for life per head in Gyeongsangbuk-do was 0.9534, and it showed an ecological deficit of 25.3 percent when analyzing it in consideration of the ecological capacity. Also, among the local governments in Gyeongsangbuk-do, Youngduk-gun displayed the highest EF, and Ulleung-gun displayed the lowest EF. But when analyzing the ecological deficit in consideration of the ecological capacity of each region, Gumi-city showed the greatest ecological deficit, and Youngyang-gun showed the biggest ecological capacity. The environmental capacity estimated in this study is to digitize the ecological capacity and ecological deficit of each local government in Gyeongsangbuk-do. The estimated optimum environmental capacity of each local government suggests the scale of environmental preservation and proper development and furthermore, could be used as fundamental data for persuading members of each local government when selecting a location of development facility or preservation area.

Research on improvement of water purification efficiency by porous concrete using bio-film (생물막을 이용한 다공성 콘크리트의 수질정화 효율 개선에 대한 연구)

  • Kim, Tae-Hoon;Li, Feng-Qi;Ahn, Tae-Woong;Choi, I-Song;Oh, Jong-Min
    • Journal of Environmental Impact Assessment
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    • v.20 no.6
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    • pp.815-821
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    • 2011
  • This study aims to estimate the biological decomposition capacity of MPC(Microorganism Porous-Concrete). MPC has specific surface area formed by inside pores, and bio compound was added to those pores to reduce pollutants loading. To evaluate the water purification capacity of MPC, we carried out the comparative studies using different media types [GPC(General Porous-concrete), CPC(Compound porous-concrete), LPC(Lightweight aggregate porous-concrete)] under the condition of CFSTR, and different retention times (30, 60 and 120 min). We also estimated the purification capacity of MPC under different concentrations of pollutant loadings. The MPC showed higher efficiency in water purification function than other conventional porous concretes with efficient decrease rates of SS, BOD, COD, and nutrient concentrations. In the comparison experiment for different retention times, MPC showed the highest removal efficiency for all tested pollutants in the longest retention time(120 min). In the long period test, the removal efficiencies of MPC concrete were high until 100 days after the set up of the operation, but began to decrease. Outflow flux was invariable compared with inflow flux so that extra detention time for media fouling such as back washing is not needed. But the results suggested that appropriate management is necessary for long-term operation of MPC. As the final outcome, MPC using bio organisms is considered to be efficient for stream water purification when they used as substrates for artificial river structure.

Cu and Cd Sorption of the Biochar Derived from Coffee Sludge (커피 슬러지 바이오차의 Cu와 Cd 흡착제거 특성 연구)

  • Kim, Byung-Moon;Kang, Chang-Hwan;Yang, Jae-Kyu;Na, Jung-Kyun;Jung, Jong-Am;Jung, Hyung-Jin;Lim, Jin-Hwan;Ko, Kyung-Min;Kim, Wan-Hee;Chang, Yoon-Young
    • Journal of Soil and Groundwater Environment
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    • v.17 no.2
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    • pp.47-53
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    • 2012
  • In this study, the adsorption of $Cu^{2+}$ and $Cd^{2+}$ from aqueous solution on the biochar derived from used coffee grounds at different pyrolysis temperatures has been investigated as a potential low-cost treatment method for heavy metal-containing waters. Three biochar samples prepared by heating coffee sludge at temperature of $300^{\circ}C$ (B300), $500^{\circ}C$ (B500), and $700^{\circ}C$ (B700) were tested for the adsorption capacity and kinetics of Cd and Cu. Also the influencing factor of heavy metal removal by ion exchange in terms of cation exchange capacity (CEC) of each biochar was measured. Adsorption of Ca and Cu by biochar produced at higher pyrolysis temperature showed higher adsorption capacity but the optimal pyrolysis temperature based on performance and economy was known as $500^{\circ}C$. Sorption of Cu and Cd by biochar followed a Langmuir model at pH 6~6.5, attributing mainly to surface sorption. The biochar was more effective in Cu and Cd sorption than activated carbon (AC), with BC 500 being the most effective, which indicates that sorption of Cd and Cu by coffee sludge biochar is partly influenced by chemical sorption on surface functional group as well as physical sorption.

An Evaluation of Atmospheric Environmental Capacity in Daegu (대구지역 대기환경용량 산정에 관한 연구)

  • Park, Myung-Hee;Choi, Geun-Sik;Jung, Woo-Sik;Kim, Hae-Dong;Lee, Joon-Soo
    • Journal of Environmental Science International
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    • v.19 no.10
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    • pp.1271-1281
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    • 2010
  • This study aims to implement the modeling of selected substances for the evaluation of Atmospheric Environmental Capacity by means of the data of 2006 atmospheric pollution substance emissions. As a result, it turned out that the substance with the concentration higher than Atmospheric Environmental standard concentration was NO2, and 17.6% of the total regions researched turned out to exceed the standard concentration. In addition, set was the targeted amount to be reduced in the areas where the upper limit of emission per unit lattice was exceeded, and the model was adopted accordingly. As a result, it turned out that about 80% of the actual emission should be reduced to meet the 2006 Atmospheric Environmental standard over the Daegu. In reality, it is impossible to reduce 80% of the actual emission. Thus, the same ratio of reduction was applied in all of the Daegu regions, and the modeling was applied. The results are as follows: When 30% was reduced, the level went down to 50 ppb, which is as high as 2006 Atmospheric Environmental standard; when 50% was reduced, the level went down to 30 ppb, which is as high as 2007 Atmospheric Environmental standard.

Predicting the axial compressive capacity of circular concrete filled steel tube columns using an artificial neural network

  • Nguyen, Mai-Suong T.;Thai, Duc-Kien;Kim, Seung-Eock
    • Steel and Composite Structures
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    • v.35 no.3
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    • pp.415-437
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    • 2020
  • Circular concrete filled steel tube (CFST) columns have an advantage over all other sections when they are used in compression members. This paper proposes a new approach for deriving a new empirical equation to predict the axial compressive capacity of circular CFST columns using the Artificial Neural Network (ANN). The developed ANN model uses 5 input parameters that include the diameter of circular steel tube, the length of the column, the thickness of steel tube, the steel yield strength and the compressive strength of concrete. The only output parameter is the axial compressive capacity. Training and testing the developed ANN model was carried out using 219 available sets of data collected from the experimental results in the literature. An empirical equation is then proposed as an important result of this study, which is practically used to predict the axial compressive capacity of a circular CFST column. To evaluate the performance of the developed ANN model and the proposed equation, the predicted results are compared with those of the empirical equations stated in the current design codes and other models. It is shown that the proposed equation can predict the axial compressive capacity of circular CFST columns more accurately than other methods. This is confirmed by the high accuracy of a large number of existing test results. Finally, the parametric study result is analyzed for the proposed ANN equation to consider the effect of the input parameters on axial compressive strength.

Predicting shear capacity of NSC and HSC slender beams without stirrups using artificial intelligence

  • El-Chabib, H.;Nehdi, M.;Said, A.
    • Computers and Concrete
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    • v.2 no.1
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    • pp.79-96
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    • 2005
  • The use of high-strength concrete (HSC) has significantly increased over the last decade, especially in offshore structures, long-span bridges, and tall buildings. The behavior of such concrete is noticeably different from that of normal-strength concrete (NSC) due to its different microstructure and mode of failure. In particular, the shear capacity of structural members made of HSC is a concern and must be carefully evaluated. The shear fracture surface in HSC members is usually trans-granular (propagates across coarse aggregates) and is therefore smoother than that in NSC members, which reduces the effect of shear transfer mechanisms through aggregate interlock across cracks, thus reducing the ultimate shear strength. Current code provisions for shear design are mainly based on experimental results obtained on NSC members having compressive strength of up to 50MPa. The validity of such methods to calculate the shear strength of HSC members is still questionable. In this study, a new approach based on artificial neural networks (ANNs) was used to predict the shear capacity of NSC and HSC beams without shear reinforcement. Shear capacities predicted by the ANN model were compared to those of five other methods commonly used in shear investigations: the ACI method, the CSA simplified method, Response 2000, Eurocode-2, and Zsutty's method. A sensitivity analysis was conducted to evaluate the ability of ANNs to capture the effect of main shear design parameters (concrete compressive strength, amount of longitudinal reinforcement, beam size, and shear span to depth ratio) on the shear capacity of reinforced NSC and HSC beams. It was found that the ANN model outperformed all other considered methods, providing more accurate results of shear capacity, and better capturing the effect of basic shear design parameters. Therefore, it offers an efficient alternative to evaluate the shear capacity of NSC and HSC members without stirrups.