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http://dx.doi.org/10.12989/aer.2013.2.4.309

High capacity polymer for nickel determination in environmental samples  

Panahi, Homayon Ahmad (Department of Chemistry, Islamic Azad University)
Feizbakhsh, Alireza (Department of Chemistry, Islamic Azad University)
Dadjoo, Fatemeh (Department of Chemistry, Islamic Azad University)
Moniri, Elham (Department of Chemistry, Islamic Azad University)
Publication Information
Advances in environmental research / v.2, no.4, 2013 , pp. 309-321 More about this Journal
Abstract
High AA new high capacity sorbent for preconcentration and determination of nickel in environmental samples was synthesized. The sorbent was synthesized by copolymerization of allyl glaycidyl ether / imminodiacetic acid with N,N-dimethylacrylamide as functional monomers in the presence of N,N-bismethylenacryl amid as cross linker and characterized by Fourier transform infra red spectroscopy, elemental analysis, thermogravimetric analysis and scanning electron microscopy. A recovery of 93.6% was obtained for the metal ion with 0.1 M, sulfuric acid as the eluting agent. The sorption capacity of the functionalized sorbent was 55.9 $mgg^{-1}$. The equilibrium sorption data of Ni(II) on polymeric sorbent were analyzed using Langmuir, Freundlich, Temkin and Redlich.Peterson models. Based on equilibrium adsorption data the Langmuir, Freundlich and Temkin constants were determined 0.87 (L mg-1), 25.87 ($mgg^{-1}$) $(Lmg^{-1})^{1/n}$ and 171.4 ($Jmol^{-1}$) respectively at pH 4.5 and $20^{\circ}C$.
Keywords
High capacity sorbent; Nickel; Preconcentration; Isotherm study;
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1 Ohta, K., Ishida, K., Itoh, S., Kaneco, S. and Mizuno, T. (1998), "Determination of nickel in water by electrothermal atomic absorption spectrometry with preconcentration on a tungsten foil", Mikrochim. Acta, 129(1-2), 127-132.   DOI   ScienceOn
2 Shemirani, F. and Abkenar, S.D. (2004), "Preconcentration and Determination of Trace Nickel Using 1-(2-Pyridylazo)-2-Naphtol (PAN) Immobilized on Surfactant-Coated Alumina", J. Anal. Chem., 59(4),327-330.   DOI
3 Tokman, N., Akman, S. and Bakircioglu, Y. (2004), "Preconcentration of Nickel and Cobalt prior to their determination by graphite furnace atomic absorption spectrometry using the water-soluble polymer poly (Vinyl Pyrrolidinone)", Microchim. Acta, 146(1), 31-34.   DOI
4 Cespon-Romero, R.M., Yebra-Biurrun, M.C. and Bermejo-Barrera, M.P. (1996), "Preconcentration and speciation of chromium by the determination of total chromium and chromium(III) in natural waters by flame atomic absorption spectrometry with a chelating ion-exchange flow injection system", Anal. Chim. Acta, 327(1), 37-45.   DOI   ScienceOn
5 Ahmad Panahi, H., Morshedian, J., Mehmandost, N., Moniri, E. and Galaev, I.Y. (2010), "Grafting of poly[1-(N,N-bis-carboxymethyl)amino-3-allylglycerol-co-dimethylacrylamide] copolymer onto siliceous support for preconcentration and determination of lead (II) in human plasma and environmental samples", J. Chromatogr. A, 1217(32), 5165-5172.   DOI   ScienceOn
6 Kojima, I. and Katsuzaki, M. (1997), "Selective extraction and "One-Drop" flame atomic absorption spectrometric determination of silver in biological standard reference materials", Anal. Sci., 13(6), 1021-1027.   DOI   ScienceOn
7 Ahmad Panahi, H., Mehmandost, N., Moniri, E. and Galaev, I.Y. (2012), "Iminodiacetic acid-containing polymer brushes grafted onto silica gel for preconcentration and determination of copper(II) in environmental samples", J. Appl. Polym. Sci., 126(2), 480-487.   DOI   ScienceOn
8 Ahmad Panahi, H., Nikpour Nezhati, M., Abedini Kashkoieh, R., Moniri, E. and Galaev, I.Y. (2012), "A siliceous support grafted with poly [1-(N,N-bis-carboxymethyl)amino-3-allylglycerol-codimethylacrylamide] brushes for removal of nickel from environmental samples", Toxicol. Environ. Chem., 94(5), 860-866.   DOI
9 Ahmad Panahi, H., Mehrdad Sharif, A.A., Bigonah, M. and Moniri, E. (2010), "Determination and Preconcentration of Nickel in Water with Flame Atomic Absorption Spectrometry by Thioureaformaldehhyde as Chelating Resin", Arab. J. Sci. Eng., 35(2A), 149-154.
10 Ahmad Panahi, H., Sid Kalal, H., Moniri, E., Nikpour Nezhati, M., Taheri Mendarjani, M. and Ranjbar Kelahrody, S. (2010), "Amberlite XAD-4 functionalized with m-phenylendiamine: Synthesis, characterization and applications as extractant for preconcentration and determination of rhodium (III) in water samples by Inductive Couple Plasma Atomic Emission Spectroscopy (ICP-AES)", Microchem. J., 93(1), 49-54.
11 Atanassova, D., Stefanova, V. and Russeva, E. (1998), "Co-precipitative pre-concentration with sodium diethyldithiocarbamate and ICP-AES determination of Se, Cu, Pb, Zn, Fe, Co, Ni, Mn, Cr and Cd in water", Talanta, 47(5), 1237-1243.   DOI   ScienceOn
12 Carasek, E. (2000), "A low-cost flame atomic absorption spectrometry method for determination of trace metals in aqueous samples", Talanta, 51(1), 173-178.   DOI   ScienceOn
13 Cuesta, A., Todoli, J.L. and Canals, A. (1996), "Flow injection method for the rapid determination of chemical oxygen demand based on microwave digestion and chromium speciation in flame atomic absorption spectrometry", Spectrochim. Acta, Part B, 51(14), 1791-1798.   DOI   ScienceOn
14 Frendlich, H.M.A. (1906), "Uber die Adsorption in Losungen", J. Phys. Chem., 57, 385-470.
15 Gordeeva, V.P., Statkus, M.A., Sorokina, N.M., Tsizin, G.I. and Zolotov, Y.A. (2002), "X-ray fluorescence determination of heavy metals in solutions after the preconcentration of their pyrrolidinedithiocarbamate complexes on cellulose filters", J. Anal. Chem., 57(8), 701-707.   DOI
16 Kagaya, S., Saiki, M., Malek, Z.A., Araki, Y. and Hasegawa, K. (2001), "Coprecipitation Using Lanthanum Phosphate as a Separation and Preconcentration Technique for Iron(III) and Lead", Fresenius' J. Anal. Chem., 371(3), 391-397.   DOI   ScienceOn
17 Hall, K.L., Eagleton, L.C., Acrivos, A. and Vermeulen, T. (1966), "Pore- and Solid-Diffusion Kinetics in Fixed-Bed Adsorption under Constant-Pattern Conditions", Ind. Eng. Chem. Fundam., 5(2), 212-223.   DOI
18 Ho, Y.S. and Ofomaja, A.E. (2006), "Biosorption thermodynamics of cadmium on coconut copra meal as biosorbent", Biochem. Eng. J., 30(2), 117-123.   DOI   ScienceOn
19 Holynska, B., Ostachwicz, B. and Wegrzynek, D. (1996), "Simple method of determination of copper, mercury and lead in potable water with preliminary pre-concentration by total reflection X-ray fluorescence spectrometry", Spectrochim. Acta, Part B, 51(1), 769-773.   DOI   ScienceOn
20 Kara, D. and Alkan, M. (2001), "Selective preconcentration, separation and speciation of ferric iron in different samples using N,N′-bis(2-hydroxy-5-bromo-benzyl)1,2 diaminopropane", Talanta, 55(2),415-422.   DOI   ScienceOn
21 Kristiansen, J., Christensen, J.M., Henriksen, T., Nielsen, N.H. and Menne, T. (2000), "Determination of nickel in fingernails and forearm skin (stratum corneum)", Anal. Chim. Acta, 403(1-2), 265-273.   DOI   ScienceOn
22 Langmuir, I. (1918), "The adsorption of gases on plane surfaces of glass, mica and platimun", J. Am. Chem. Soc., 40(9), 1361-1368.   DOI
23 Matsumiya, H., Iki, N., Miyano, S. and Hiraide, M. (2004), "Preconcentration of copper, cadmium, and lead with a thiacalix[4]arenetetrasulfonate-loaded Sephadex A-25 anion-exchanger for graphite-furnace atomic-absorption spectrometry", Anal. Bioanal. Chem., 379(5-6), 867-873.
24 Singh, D.K. and Shraddha, M. (2010), "Synthesis, characterization and analytical applications of Ni(II)-ion imprinted polymer", Appl. Surf. Sci., 256(24), 7632-7637.   DOI   ScienceOn
25 Otero-Romani, J., Moreda-Pineiro, A., Bermejo-Barrera, P. and Martin-Esteban, A. (2009), "Ionic imprinted polymer for nickel recognition by using the bi-functionalized 5-vinyl-8-hydroxyquinoline as a monomer:Application as a new solid phase extraction support", Microchem. J., 93(2), 225-232.   DOI   ScienceOn
26 Persson, Per O., Andersson, Per S., Zhang, J. and Porcelli, D. (2011), "Determination of Nd isotopes in water: A chemical separation technique for extracting Nd from seawater using a chelating resin", Anal.Chem., 83(4), 1336-1341.   DOI   ScienceOn
27 Sabarudin, A., Noguchi, O., Oshima, M., Higuchi, K. and Motomizu, S. (2007), "Application of chitosan functionalized with 3,4-dihydroxy benzoic acid moiety for on-line preconcentration and determination of trace elements in water samples", Microchim. Acta, 159(3-4), 341-347.   DOI
28 Taher, M.A., Balani, S. and Puri, B.K. (2000), "Atomic absorption spectrometric determination of trace amounts of nickel after preconcentration with [1-(2-Pyridylazo)-2-Naphthol]-Naphthalene adsorbent or after adsorption of its complex on microcrystalline naphthalene", J. Anal. Chem., 55(10), 972-977.   DOI
29 Tsai, S.J.J., Jan, C.C. and Chang, L.L. (1994), "Determination of lead and bismuth in nickel-base alloys by graphite furnace atomic absorption spectrometry using continuum source background correction",Spectrochim. Acta, 49(8), 773-785.   DOI   ScienceOn