• 제목/요약/키워드: Environmental Degradation

검색결과 2,025건 처리시간 0.026초

화염분무열분해법을 이용한 TiO2:Fe,V 나노분말의 제조 및 VOCs 분해 특성 (Preparation of TiO2:Fe,V nanoparticles by flame spray pyrolysis and photocatalytic degradation of VOCs)

  • 장한권;장희동;김태오;김선경;최진훈
    • 한국입자에어로졸학회지
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    • 제5권1호
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    • pp.1-7
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    • 2009
  • Fe- and V-doped titanium dioxide nanoparticles consisting of spherical primary nanoparticles were synthesized from a mixed liquid precursor by using the flame spray pyrolysis. The effects of dopant concentration on the powder properties such as morphology, crystal structure, and light adsorption were analyzed by TEM, XRD, and UV-Vis spectrophotometer, respectively. As the V/Ti molar ratio increased, pure anatase particles were synthesized. On the contrary, rutile phase particles were synthesized as the Fe/Ti ratio increased. Photocatalytic property of as-prepared $TiO_2:Fe,V$ nanoparticles was investigated by measuring the removal efficiency for volatile organic compounds (VOCs) under the irradiation of visible light. After 2 hrs under visible light, the removal efficiencies of benzene, p-xylene, ethylbenzene, and toluene were reached to 21.9%, 21.4%, 19.8% and 17.6% respectively.

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Saururus chinenesis Extracts Scavenge Reactive Oxygen Species and Modulate Nitric Oxide Production in Raw 264.7 Macrophages

  • Oh, Jang-Hee;Shon, Hee-Kyoung;Oh, Moon-You;Chung, An-Sik
    • Toxicological Research
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    • 제18권2호
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    • pp.117-127
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    • 2002
  • Saururus chinensis Baill has been used in Korean folk medicine for the treatment of various diseases such as edema, Jaundice, and furuncle. The components of this plant were extracted into four fraction. Among the four fraction, hexane and ethyl acetate fraction were highly toxic to 3T3 mouse embryo fibroblast and Raw 264.7 mouse macrophage, but n-butanol and residue fraction did not show any toxic effect to those cell lines. n-Butanol and residue fraction exhibited antioxidant effects on hydro-gen peroxide, hydroxyl radical, and superoxide anion directly in vitro and in the 3T3 fibroblasts. All the four fractions inhibited lipid peroxidation measured by thiobarbituric acid reactive substances (TBARS) formation. In addition, n-butanol and residue fraction showed inhibitory effects on lipopolysaccharide (LPS)-induced nitric oxide production, and also down-regulated inducible nitric oxide synthase (iNOS) mRNA transcription 6 h after LPS stimulation in Raw 204.7 cells. Only n-butanol fraction, which mainly consists of flavonoids, inhibited NF-kB activation by decreasing IkBa degradation 90 min after LPS stimulation. horn the results, it is suggested that this plant could be a good candidate material for drug development based on its antioxidant and/or anti-inflammatory constituents.

Determination of Goitrogenic Metabolites in the Serum of Male Wistar Rat Fed Structurally Different Glucosinolates

  • Choi, Eun-Ji;Zhang, Ping;Kwon, Hoonjeong
    • Toxicological Research
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    • 제30권2호
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    • pp.109-116
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    • 2014
  • Glucosinolates (GLSs) are abundant in cruciferous vegetables and reported to have anti thyroidal effects. Four GLSs (sinigrin, progoitrin, glucoerucin, and glucotropaeolin) were administered orally to rats, and the breakdown products of GLSs (GLS-BPs: thiocyanate ions, cyanide ions, organic isothiocyanates, organic nitriles, and organic thiocyanates) were measured in serum. Thiocyanate ions were measured by colorimetric method, and cyanide ions were measured with CI-GC-MS. Organic isothiocyanates and their metabolites were measured with the cyclocondensation assay. Organic nitriles and organic thiocyanates were measured with EI-GC-MS. In all treatment groups except for progoitrin, thiocyanate ions were the highest among the five GLS-BPs. In the progoitrin treated group, a high concentration of organic isothiocyanates (goitrin) was detected. In the glucoerucin treated group, a relatively low amount of goitrogenic substances was observed. The metabolism to thiocyanate ions happened within five hours of the administration, and the distribution of GLSs varied with the side chain. GLSs with side chains that can form stable carbocation seemed to facilitate the degradation reaction and produce a large amount of goitrogenic thiocyanate ions. Because goitrogenic metabolites can be formed without myrosinase, the inactivation of myrosinase during cooking would have no effect on the anti-nutritional effect of GLSs in cruciferous vegetables.

Mechanics of the slaking of shales

  • Vallejo, Luis E.
    • Geomechanics and Engineering
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    • 제3권3호
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    • pp.219-231
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    • 2011
  • Waste fills resulting from coal mining should consist of large, free-draining sedimentary rocks fragments. The successful performance of these fills is related to the strength and durability of the individual rock fragments. When fills are made of shale fragments, some fragments will be durable and some will degrade into soil particles resulting from slaking and inter-particle point loads. The degraded material fills the voids between the intact fragments, and results in settlement. A laboratory program with point load and slake durability tests as well as thin section examination of sixty-eight shale samples from the Appalachian region of the United States revealed that pore micro-geometry has a major influence on degradation. Under saturated and unsaturated conditions, the shales absorb water, and the air in their pores is compressed, breaking the shales. This breakage was more pronounced in shales with smooth pore boundaries and having a diameter equal to or smaller than 0.060 mm. If the pore walls were rough, the air-pressure breaking mechanism was not effective. However, pore roughness (measured by the fractal dimension) had a detrimental effect on point load resistance. This study indicated that the optimum shales to resist both slaking as well as point loads are those that have pores with a fractal dimension equal to 1.425 and a diameter equal to or smaller than 0.06 mm.

Lifetime prediction of optocouplers in digital input and output modules based on bayesian tracking approaches

  • Shin, Insun;Kwon, Daeil
    • Smart Structures and Systems
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    • 제22권2호
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    • pp.167-174
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    • 2018
  • Digital input and output modules are widely used to connect digital sensors and actuators to automation systems. Digital I/O modules provide flexible connectivity extension to numerous sensors and actuators and protect systems from high voltages and currents by isolation. Components in digital I/O modules are inevitably affected by operating and environmental conditions, such as high voltage, high current, high temperature, and temperature cycling. Because digital I/O modules transfer signals or isolate the systems from unexpected voltage and current transients, their failures may result in signal transmission failures and damages to sensitive circuitry leading to system malfunction and system shutdown. In this study, the lifetime of optocouplers, one of the critical components in digital I/O modules, was predicted using Bayesian tracking approaches. Accelerated degradation tests were conducted for collecting the critical performance parameter of optocouplers, current transfer ratio (CTR), during their lifetime. Bayesian tracking approaches, including extended Kalman filter and particle filter, were applied to predict the failure. The performance of each prognostic algorithm was then compared using accuracy and robustness-based performance metrics.

Experimental study on seismic performance of steel reinforced concrete T-shaped columns

  • Liu, Zuqiang;Zhou, Chaofeng;Xue, Jianyang;Leon, Roberto T.
    • Steel and Composite Structures
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    • 제36권3호
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    • pp.339-353
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    • 2020
  • This study investigates the seismic performance of steel reinforced concrete (SRC) T-shaped columns under low cyclic loading tests. Based on test results of ten half-scale column specimens, failure patterns, hysteretic behavior, skeleton curves, ultimate strength, ductility, stiffness degradation and energy dissipation capacity were analyzed. The main variables included loading angles, axial compression ratios and steel ratios. The test results show that the average values of the ductility factor and the equivalent viscous damping coefficient with respect to the failure of the columns were 5.23 and 0.373, respectively, reflecting good seismic performance. The ductility decreased and the initial stiffness increased as the axial compression ratio of the columns increased. The strength increased with increasing steel ratio, as expected. The columns displaced along the web had higher strength and initial stiffness, while the columns displaced along the flange had better ductility and energy dissipation capacity. Based on the test and analysis results, a formula is proposed to calculate the effective stiffness of SRC T-shaped columns.

Inventory of Street Tree Population and Diversity in the Kumasi Metropolis, Ghana

  • Uka, Ufere N.;Belford, Ebenezer J.D.
    • Journal of Forest and Environmental Science
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    • 제32권4호
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    • pp.367-376
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    • 2016
  • Urban greenery is an important component of urban environment and is fast gaining prominence especially in the developing countries. The destruction of urban trees has resulted to the degradation of the environment, thus the introduction of green Kumasi project by Kumasi Metropolitan Assembly, Ashanti Region of Ghana. The composition and diversity of urban trees gives rise to adequate management and monitoring, thus an inventory of urban trees of the Metropolis was conducted to document complete information on its density, diversity, composition and distribution. A total tree population of 1,101 was enumerated in the principal roads of the Metropolis. The ten most encountered tree species accounted for 61.04% of all the individual tree populations with Mangifera indica being dominant. The dominant families: Fabaceae, Moraceae and Arecaceae constitute 38.57% of the tree population. Diversity of the tree species was very high. The minimum diversity criteria were met on analysis of the diversity of this population. The proportion of exotic species was high with 65.71% of the trees belonging to the introduced species. It is recommended that greater emphasis should be placed on the planting of indigenous trees in future tree planting exercise.

마이크로웨이브를 이용한 메틸렌 블루의 펜톤산화 (Microwave-assisted Fenton degradation of methylene blue)

  • 김신영;안종화
    • 산업기술연구
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    • 제37권1호
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    • pp.21-26
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    • 2017
  • This work experimentally determined the effect of combining of microwave irradiation and the Fenton process on decolorization of methylene blue ($C_{16}H_{18}N_3SCl$, MB). As [$H_2O_2$] increased from 2.65 to 4.41 mM, the decolorization of MB increased from 22.7 to 99.1%. As [$Fe^{2+}$] increased from 0.07 to 0.18 mM, the decolorization of MB increased from 24.0 to 98.5%. MB removal efficiencies were ${\geq}95%$ at $[H_2O_2]{\geq}3.5mM$ and $3.5{\leq}[H_2O_2]/[Fe^{2+}]{\leq}17.3$, but $[H_2O_2]/[Fe^{2+}]{\geq}20$ caused a decrease in MB removal. A two-stage kinetic model matched the experimental data well.

화재 발생시 열응력에 의한 복합재료 과량 시스템의 거동에 관한 연구 (Numerical Study of Lightweight FRP Bridge Deck System induced by Thermal Stress by Fire)

  • 정우영;이형길;박희광;심인섭;송영진
    • 한국전산구조공학회:학술대회논문집
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    • 한국전산구조공학회 2006년도 정기 학술대회 논문집
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    • pp.928-931
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    • 2006
  • Due to their light weight, high stiffness-to-weight and strength-to-weight ratios, and potentially high resistance to environmental degradation, resulting in lower life-cycle costs, polymer composites, are increasingly being considered for use in civil infrastructure applications. Recently, an FRP deck has been installed on a state highway, located in New York State. In this study, a thermal stress analysis was conducted using finite element method to study failure mechanisms of the superstructure. This analysis evaluated small and large temperature gradient effects on the FRP deck considering lightweight of FRP deck and ply orientations at the interface between steel girders and FRP deck Finite element model was verified using the load tests of the bridge deck. Finally, the analytical results shows the possible failure mechanism of FRP deck under various temperature changes and its corresponding index is suddenly varied depending on the rapid change of temperature on the deck plate.

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Matlab을 이용한 손상된 바이패스 다이오드가 포함된 PV 모듈의 출력 추정 (Estimation of Output Power for PV Module with Damaged Bypass Diode using MATLAB)

  • 신우균;고석환;주영철;장효식;강기환
    • 한국태양에너지학회 논문집
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    • 제36권5호
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    • pp.63-71
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    • 2016
  • Installed PV module in field is affected by shading caused by various field environmental factors. Bypass diodes are installed in PV module for preventing a power loss and degradation of PV module by shading. But, Bypass diode is easily damaged by surge voltage and has often initial a defect. This paper propose the electric characteristic variation and the power prediction of PV module with damaged bypass diode. Firstly, the resistance for normal bypass diode and damaged bypass diode of resistance was measured by changing the current. When the current increases, the resistance of normal bypass diode is almost constant but the resistance of damaged bypass diode increases. Next, To estimate power of PV module by damaged bypass diode, the equation for the current is derived using solar cell equivalent circuit. Finally, the derived equation was simulated by using MatLab tools, was verified by comparing experimental data.