• Title/Summary/Keyword: Environmental Degradation

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Open Channel Characteristics on Different Land Cover for Neponset River, Boston, MA (상이한 토지이용에서 나타나는 하천의 특성에 관한 연구 : 메사추세츠 보스턴의 네폰셋강의 사례연구)

  • Lee, Ja-Won
    • Journal of the Korean association of regional geographers
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    • v.16 no.2
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    • pp.100-109
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    • 2010
  • The study examines two different sites to analyze the difference of stream channel profile between two different landuse areas on Neponset River, Boston, MA. Landuse represents the current status of land in terms of human, agricultural or forest, industry and environmental activity types. According to the previous research, forest and urban area are significantly distinguished in chemical characteristic, shape and bed load of the stream. On the chosen sites, I look at the cross-section profile, the slope, velocity, and roughness of the channels. With the data collected at the site I determined the value for the channel bed material using Manning's equation, and compared with the result of HEC-RAS model with the cross-section profile data I measured. In the forest area, water surface elevation and bed material obtained through Manning's equation are very close to HEC-RAS model result. However, in the resident area the Manning's 'n' value calculated much higher than assumption which was considered as cobble whose 'n' value is 0.03-0.06. The difference could be caused by unusual steep elevation on the site and the dam present down further. With the steep elevation upside of dam, there is critical-depth condition occurs. The difference of Manning's 'n' value reflects the difference of depth. HEC-RAS model was run to analyze the difference and the result shows that depth is 0.36 much less than 0.688 what I computed when the Manning's n value is 0.03(cobble) instead of the result of the study (0.13292). Beside, dam is a major source of fragmentation and degradation of stream, and it's possibly inferred upstream water levels are increased and stream velocity is decreased. This study is meaningful for introduction of HEC-RAS in geography field to analyze different sites with channel bed material, and it is going to be used more actively to manage river and river side.

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A Study on Improvement of Fire-resistant and Flame-retardant Properties of Silicone Rubber Composites Containing Perlite (펄라이트를 첨가한 실리콘 고무 복합체의 내화 및 난연 특성 향상에 관한 연구)

  • Lee, Byung-Gab;Lee, Jong-Hyeok;Bang, Dae-Suk;Won, Jong-Pil;Jang, Il-Young;Park, Woo-Young;Jhee, Kwang-Hwan
    • Elastomers and Composites
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    • v.46 no.2
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    • pp.164-170
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    • 2011
  • In this study, silicone rubber filled with environmentally-friendly perlite was prepared by mechanical mixing in order to improve thermal properties, such as heat and fire resistances. We found that the properties of silicone rubber composites depended on perlite concentration by various characterization methods. Thermogravimetric analysis(TGA) indicated that the initial degradation temperature of silicone/perlite composite was higher than that of pristine silicone rubber. The gas torch test showed that the opposite side temperature of composite materials was remarkably low as compared to that of pristine silicone rubber. In addition, the composites containing 5 wt% and 10 wt% of perlite showed remarkable thermal stability at elevated temperatures according to the results of both fireproof furnace tests under the RABT condition and carbonization furnace tests. The images from a scanning electron microscope(SEM) showed the degree of dispersion of perlite in silicone rubber. Finally, it was confirmed that limited oxygen index(LOI) was increased with perlite concentration.

Novel pH/Temperature Sensitive Hydrogels of Poly (ethylene glycol)-Poly (caprolactone) -Poly (${\beta}-amino\;ester$) (PAE-PCLA-PEGPCLA-PAE) Biodegradable Polyester Block Copolymer

  • Huynh Dai Phu;Lee Doo-Sung
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.263-263
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    • 2006
  • Poly (ethylene glycol)(PEG) - Poly (${\varepsilon}-caprolactone(CL)$) - Poly (D,L lactide(LA) (PCLA-PEG-PCLA) was synthesized by ring-opening polymerization to form temperature sensitive hydrogel triblock copolymer. The triblock copolymer was acrylated by acryloyl chloride. ${\beta}-amino$ ester was used as a pH sensitive moiety, in this study ${\beta}$- amino ester obtained from 1,4-butandiol diacrylate, and 4, 4' trimethylene dipiperidine, it have pKb around 6.6. pH/temperature sensitive penta-block copolymer (PAE-PCL-PEG-PCL-PAE) was synthesized by addition polymerization from acrylated triblock copolymer, 1,4-butandiol diacrylate, and 4, 4' trimethylene dipiperidine. Their physicochemical properties of triblock and penta-block copolymers were characterized by $^1H-NMR$ spectroscopy and gel permeation spectroscopy. Sol-gel phase transition behavior of PAE-PCL-PEG-PCL-PAE block copolymers were investigated by remains stable method. Aqueous media of the penta-block copolymer (at 20 wt%) changed from a sol phase at pH 6.4 and $10^{\circ}C$ to a gel phase at pH 7.4 and $37^{\circ}C$. The sol-gel transition properties of these block copolymers are influenced by the hydrophobic/hydrophilic balance of the copolymers, block length, hydrophobicity, stereo-regularity of the hydrophobic of the block copolymer, and the ionization of the pH function groups in the copolymer depended on the changing of environmental pH, respectively. The degradation and the stabilization at pH 7.4 and $37^{\circ}C$, and the stabilization at pH 6.4 and $10^{\circ}C,\;5^{\circ}C,\;0^{\circ}C$, of the gel were determined. The results of toxicity experiment show that the penta block copolymer can be used for injection drug delivery system. The sol?gel transition of this block copolymer also study by in vitro test ($200{\mu}l$ aqueous solution at 20wt% polymer was injected to mouse). Insulin loading and releasing by in vitro test was investigated, the results showed that insulin can loading easily into polymer matrix and release time is around 14-16days. The PAE-PCL-PEG-PCL-PAE can be used as biomaterial for drug, protein, gene loading and delivery.

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Development of Moisture Content Prediction Model for Larix kaempferi Sawdust Using Near Infrared Spectroscopy (근적외선 분광분석법을 이용한 낙엽송 목분의 함수율 예측 모델 개발)

  • Chang, Yoon-Seong;Yang, Sang-Yun;Chung, Hyunwoo;Kang, Kyu-Young;Choi, Joon-Weon;Choi, In-Gyu;Yeo, Hwanmyeong
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.3
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    • pp.304-310
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    • 2015
  • The moisture content of sawdust must be measured accurately and controlled appropriately during storage and transportation because biological degradation could be caused by improper moisture. In this study, to measure the moisture contents of Larix kaempferi sawdust, the near-infrared reflectance spectra (Wavelength 1000-2400 nm) of sawdust were used as detection parameter. After acquiring the NIR reflection spectrum of specimens which were humidified at each relative humidity condition ($25^{\circ}C$, RH 30~99%), moisture content prediction model was developed using mathematical preprocessings (e.g. smoothing, standard normal variate) and partial least squares (PLS) analysis with the acquired spectrum data. High reliability of the MC regression model with NIR spectroscopy was verified by cross validation test ($R^2$ = 0.94, RMSEP = 1.544). The results of this study show that NIR spectroscopy could be used as a convenient and accurate method for the nondestructive determination of moisture content of sawdust, which could lead to optimize wood utilization.

West seacoast wetland monitoring using KOMPSAT series imageries in high spatial resolution (고해상도 KOMPSAT 시리즈 이미지를 활용한 서해연안 습지 변화 모니터링)

  • Sunwoo, Wooyeon;Kim, Daeun;Kim, Seongkyun;Choi, Minha
    • Journal of Korea Water Resources Association
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    • v.50 no.6
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    • pp.429-440
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    • 2017
  • A series of multispectral high-resolution Korean Multi-Purpose Satellite (KOMPSAT) images were analyzed to detect the geographical changes in four different tidal flats in the west coast of South Korea. The method of unsupervised classification was used to generate a series of land use/land cover (LULC) maps from the satellite images, which were used as the input of the temporal trajectory analysis to detect the temporal change of coastal wetlands and its association with natural and anthropogenic activities. The accurately classified LULC maps extracted from the KOMPSAT images indicate that these multispectral high-resolution satellite data is highly applicable to generate good quality thematic maps for extracting wetlands. The result of the trajectory analysis showed that, while the tidal flat area of Gyeonggi and Jeollabuk provinces was estimated to have changed due to tidal effects, the reductive trajectory of the wetland areas belonging to the Saemangeum province was caused by a high degree of human-induced activities including large reclamation and urbanization. The conservation of the Jeungdo Wetland Protected Area in Jeollanam province revealed that the social and environmental policies can effectively protect coastal wetlands from degradation. Therefore, monitoring for wetland change using high resolution KOMPSAT is expected to be useful to coastal environment management and policy making.

Production of Lignin Degrading Enzymes and Decolorization of Various Dye Compounds by Wood-Rot Fungi (목재 부후균의 리그닌 분해효소 활성과 염료 화합물의 탈색)

  • Jang, Tae-Won;Jun, Sang-Cheol;Ahn, Tae-Seok;Kim, Kyu-Joong
    • Korean Journal of Microbiology
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    • v.42 no.1
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    • pp.34-39
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    • 2006
  • Wood-rot fungi produce extracellular lignin-degrading enzymes, the best known of which are lignin peroxidase, Mn-peroxidase and laccase. In this experiment, some of them produced all of three enzymes. Many other wood-rot fungi produced one or two of those enzymes with various combinations. In this experiment, we tried to clarify the relationship between the pattern of enzyme production and degradative activity of several dye compounds. From the 36 strains of 23 species of wood-rot fungi, Mn-peroxidase activity was found in 30 strains of the fungi tested, whereas the activity of lignin peroxidase and laccase was detected in 11 strains and 12 strains of species, repectively, in Kirks low nitrogen media. In relation to the activity of lignin degrading enzymes and degradation of dye compounds, the white-rot fungi with three kinds of enzymes tested showed the best dye decolorizers. The fungi with Mn-peroxidase activity only decolorized poly R-478 and remazol brilliant blue R dye in proportion to the enzyme activity, while methylene blue, bromophenol blue and congo red dye were degraded in regardless of enzyme activity. Those dyes were degraded in relation to the growth rate of mycelium. Brown-rot fungi did not degrade all the dye compounds except bromophenol blue, in spite of moderate growth rate.

Microbial Diversity in Three-Stage Methane Production Process Using Food Waste (음식물 쓰레기를 이용한 3단계 메탄생산 공정의 미생물 다양성)

  • Nam, Ji-Hyun;Kim, Si-Wouk;Lee, Dong-Hun
    • Korean Journal of Microbiology
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    • v.48 no.2
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    • pp.125-133
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    • 2012
  • Anaerobic digestion is an alternative method to digest food wastes and to produce methane that can be used as a renewable energy source. We investigated bacterial and archaeal community structures in a three-stage methane production process using food wastes with concomitant wastewater treatment. The three-stage methane process is composed of semianaerobic hydrolysis/acidogenic, anaerobic acidogenic, and strictly anaerobic methane production steps in which food wastes are converted methane and carbon dioxide. The microbial diversity was determined by the nucleotide sequences of 16S rRNA gene library and quantitative real-time PCR. The major eubacterial population of the three-stage methane process was belonging to VFA-oxidizing bacteria. The archaeal community consisted mainly of two species of hydrogenotrophic methanogen (Methanoculleus). Family Picrophilaceae (Order Thermoplasmatales) was also observed as a minor population. The predominance of hydrogenotrophic methanogen suggests that the main degradation pathway of this process is different from the classical methane production systems that have the pathway based on acetogenesis. The domination of hydrogenotrophic methanogen (Methanoculleus) may be caused by mesophilic digestion, neutral pH, high concentration of ammonia, short HRT, and interaction with VFA-oxidizing bacteria (Tepidanaerobacter etc.).

Self-healing Engineering Materials: II. Inorganic Materials (자기치유 공학재료: II. 무기재료)

  • Kim, Min-Hee;Kang, Dong-Eun;Yoon, Ji-Hwan;Choi, Eun-Ji;Shim, Sang-Eun;Yun, Ju-Ho;Kim, Il
    • Clean Technology
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    • v.17 no.2
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    • pp.85-96
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    • 2011
  • Self-healing materials are a class of smart materials that have the structurally incorporated ability to repair damage caused by mechanical usage over time. A material (polymers, ceramics, metals, etc.) that can intrinsically correct damage caused by normal usage could lower production costs of a number of different industrial processes through longer part lifetime, reduction of inefficiency over time caused by degradation, as well as prevent costs incurred by material failure. The recent announcement from Nissan on the commercial release of scratch healing paints for use on car bodies has gained public interest on such a wonderful property of materials. This article is a second part of healing materials dealing with inorganic engineering materials such as metals, ceramics, and concrete. The healing mechanisms developed for the inorganic materials are to be discussed with the future prospect.

Recent Research Trends of Process Monitoring Technology: State-of-the Art (공정 모니터링 기술의 최근 연구 동향)

  • Yoo, ChangKyoo;Choi, Sang Wook;Lee, In-Beum
    • Korean Chemical Engineering Research
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    • v.46 no.2
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    • pp.233-247
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    • 2008
  • Process monitoring technology is able to detect the faults and the process changes which occur in a process unpredictably, which makes it possible to find the reasons of the faults and get rid of them, resulting in a stable process operation, high-quality product. Statistical process monitoring method based on data set has a main merit to be a tool which can easily supervise a process with the statistics and can be used in the analysis of process data if a high quality of data is given. Because a real process has the inherent characteristics of nonlinearity, non-Gaussianity, multiple operation modes, sensor faults and process changes, however, the conventional multivariate statistical process monitoring method results in inefficient results, the degradation of the supervision performances, or often unreliable monitoring results. Because the conventional methods are not easy to properly supervise the process due to their disadvantages, several advanced monitoring methods are developed recently. This review introduces the theories and application results of several remarkable monitoring methods, which are a nonlinear monitoring with kernel principle component analysis (KPCA), an adaptive model for process change, a mixture model for multiple operation modes and a sensor fault detection and reconstruction, in order to tackle the weak points of the conventional methods.

Characteristics of Fermented Wood Chips and Pig Manure (목질칩을 이용한 분뇨 발효 시 목질칩과 돈분뇨의 성분 변화)

  • Kim, Myung-Kil;Choi, Don-Ha;Choi, In-Gyu
    • Journal of Korea Foresty Energy
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    • v.24 no.2
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    • pp.1-9
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    • 2005
  • After manufacturing fermentation system for degrading pig manure using environmentally friendly technique, performance of the system and characteristics of wood chips and pig manure fermented in the system were analyzed. Results from this study shows that proper fermentation temperature($55{\sim}60^{\circ}C$) reached 3days after the system started and degradation rate, which expresses fermentation performance of system, was $180{\iota}$/day. Even as progressing the fermentation of wood chips and pig manure mixture, the amount of extractives drawn out by alkali, and alcohol-benzene and lignin content was not varied. However, ash content in wood was increased. The inorganic compounds in pig manure seem to be transferred into wood chip. On the other hand holocellulose contents in wood were decreased a little. Holocellulose seems to be consumed as the second carbon source in fermentation process. Results through analysis of inorganic- and heavy metal elements contents in wood chips and pig manure fermented in long term process shows that inorganic elements($Ca^{2+},\;Mg^{2+},\;K^+,\;Na^+$ etc.) contents were increased with fermentation time and heavy metal elements(Cd, As, Cu etc.) which cause environmental pollution were not detected. Number of microorganisms including bacteria, actinomycetes, and fungi, the number of C.F.U(Colony Forming Unit) was increased while temperature in fermentation system was abruptly increased.

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