• Journal of Environmental Science International
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• v.19 no.6
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• pp.681-687
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• 2010

Mesoporous silica was prepared from hydrothermal synthesis using gel mixture of tetraethylorthosilcate (TEOS) as silica source and cetyltrimethylammonium bromide (CTMABr) as a surfactant. In the optimum synthesis cause, molar ratio of template and silica changed. The surface and structure properties of mesoporous silica were determined by XRD, SEM, TEM and BET. Also, surface potential of mesoporous silica was measured using zeta potential. $N_2$ adsorption isotherm characteristics, including the specific surface area ($S_{BET}$), total pore volume $V_T$), and average pore diameter ($D_{BJH}$), were determined by BET. As a result, SBET of $100m^2/g{\sim}1500m^2/g$ was determined from the $N_2$ adsorption isotherm. Also, the average pore diameter was 2 nm∼4 nm. Mesoporous silica's surface potential of minus charge was determined from zeta potential.

• Journal of Environmental Science International
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• v.28 no.2
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• pp.219-224
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• 2019

In this study, we evaluated the energy production from plant-microbial fuel cells using representative indoor plants, such as Scindapsus aureus and Clatha minor. The maximum power density of microbial fuel cell (MFC) using S. aureus ($3.36mW/m^2$) was about 2 times higher than that of the MFC using C. minor ($1.43mW/m^2$). It was confirmed that energy recovery is possible using plant-MFCs without fuel. However, further research is needed to improve the performance of plant-MFCs. Nevertheless, plant-MFCs have proved their potential as a novel energy source to overcome the limitations of the conventional renewable energy sources such as wind power and solar cells, and could be employed to a power source for the sensor in charge of the fourth industrial revolution.

• Korean Journal of Environmental Agriculture
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• v.33 no.4
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• pp.245-253
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• 2014

BACKGROUND: Oyster shell(OS) is alkaline with pH 9.8, porous, and has high concentration of $CaCO_3$. It could be used as an alternative of lime fertilizer to immobilize cadmium(Cd) in heavy metal contaminated arable soil. Therefore, this study has been conducted to compare effects of calcium(Ca) materials [OS and $Ca(OH)_2$] on Cd extractability in contaminated soil and determined mechanisms of Cd immobilization with OS. METHODS AND RESULTS: Both Ca materials were added at the rates of 0, 0.1, 0.2, 0.4, and 0.8% (wt Ca wt-1) in Cd contaminated soil and the mixtures were incubated at $25^{\circ}C$ for 4 weeks. Both Ca materials increased pH and negative charge of soil with increasing Ca addition and decreased 1N $NH_4OAc$ extractable Cd concentration. 0.1 N HCl extractable Cd concentration markedly decreased with addition of OS. 1 N $NH_4OAc$ extractable Cd concentration was related with pH and net negative charge of soil, but not with 0.1 N HCl extractable Cd concentration. We assumed that Cd immobilization with $Ca(OH)_2$ was mainly attributed to Cd adsorption resulted from increase in pH-induced negative charge of soil. Scanning electron microscope (SEM) images and energy dispersive spectroscopy(EDS) analyses were conducted to determine mechanism of Cd immobilization with OS. There was no visible precipitation on surface of both Ca materials. However, Cd was detected in innerlayer of OS by EDS analyses but not in that of $Ca(OH)_2$. CONCLUSION: We concluded that Cd immobilization with OS was different from that with $Ca(OH)_2$. OS might adsorbed interlayer of oyster shell or have other chemical reactions.

• Applied Microscopy
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• v.43 no.1
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• pp.9-13
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• 2013

The helium ion microscope (HIM) has recently emerged as a novel tool for imaging and analysis. Based on a bright ion source and small probe, the HIM offers advantages over the conventional field emission scanning electron microscope. The key features of the HIM include (1) high resolution (ca. 0.25 nm), (2) great surface sensitivity, (3) great contrast, (4) large depth-of-field, (5) efficient charge control, (6) reduced specimen damage, and (7) nanomachining capability. Due to the charge neutralization by flood electron beam, there is no need for conductive metal coating for the observation of insulating biological specimens by HIM. There is growing evidence that the HIM has substantial potential for high-resolution imaging of uncoated insulating biological specimens at the nanoscale.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.04c
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• pp.119-120
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• 2008

In this paper, viologen derivative is used as charge transfer material to develop sensors for detecting the organic pollutants which are the main reason of harbor pollution. We fabricated self-assembled monolayers of viologen derivative on gold electrode of QCM and investigated an electrochemical behavior property. We also determined electrochemical sensing property about environmental pollution materials such as bezene, phosphate and surfactant through quantitative and qualitative analysis of charge transfer using intrinsic property of viologen derivative by temperature and concentration change. From the achieved results, we can apply and develope the detecting sensors for harbor pollutants.

• Journal of the Korean Magnetic Resonance Society
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• v.7 no.1
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• pp.16-24
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• 2003

Nuclei with the spin quantum number not smaller than unity have not only the nuclear magnetic moment but also the electric quadrupole moment. The quadrupole moment couples with the electric field gradient (EFG) to produce the nuclear quadrupole interaction. It is well known that two independent parameters, i.e. the quadrupole coupling constant (QCC) and the asymmetry parameter ($\eta$) together with the principal axis directions can fully describe the interaction and are very sensitive to the local symmetry and structure of the solid. In order to obtain quantitative estimates of the EFG tensor for various simple ionic configurations surrounding the nucleus under consideration, we employ the simple point charge approximation and apply the calculated results to some real crystals. General agreement is rather satisfactory.

• 한국신재생에너지학회:학술대회논문집
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• 2008.10a
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• pp.349-352
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• 2008

The most concerning issue in these days is the energy crisis by increasing threat of global warming and depletion of natural resources. In the situations, the Plug-in Hybrid Electric Vehicle (PHEV) is drawing attention from many countries for the next generation's car which has higher fuel efficiency and lower environmental impact. This paper presents simulation results about the limit capacity of central power-grid which doesn't have enough surplus electric power for charging PHEVs. Therefore, this paper also presents a smart charging system that can charge the PHEVs with a function of distributing demands of charging. The smart charging system is an agent facility between the government and consumer, which can recommend the best time to charge the battery of PHEVs by the lowest energy cost. This function of choosing time-slots is the technical system for the government which wants to control the consumption rate of electric power for PHEVs. Finally, this paper presents the economic feasibility of PHEVs from the two kinds of price system, midnight electric price and home electric price.

• Bulletin of the Korean Chemical Society
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• v.26 no.7
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• pp.1083-1089
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• 2005

Most experimental studies available in the literature on filtration are based on observed average zeta potential of particles (usually 10 measurements). However, analyses of data using the average zeta potential alone can lead to misleading and erroneous conclusions about the attachment behavior because of the variation of particle zeta potentials and the heterogeneous distribution of the collector surface charge. To study characteristics of zeta potential, zeta potential distributions (ZPDs) of silica particles under 9 different chemical conditions were investigated. Contrary to many researchers’ assumptions, most of the ZPDs of silica particles were broad. The solids concentration removal was better near the isoelectric point (IEP) as many researchers have noticed, thus proper destabilization of particles is very important to achieve better particle removal in particle separation processes. While, the mean zeta potential of silica particles at a given coagulant dose was a function of particle concentration; the amount of needed coagulant for particle destabilization was proportional to the total surface charge area of particles in the suspension.

• Transactions of the Korean Society of Automotive Engineers
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• v.10 no.5
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• pp.58-64
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• 2002

A diesel engine has various merits such as high thermal-efficiency, superior fuel consumption and durability. Therefore the number of diesel engine in the world is increasing. As the seriousness of environmental pollution increases in the world, the method to reduce the noxious materials of CO2, NOx and P.M. is very important subject to correspond to exhaust gas regulations. A new concept, so called premixed charge compression ignition(PCCI), is focused among the various corresponding manners. In this study, we investigated the combustion characteristics of PCCI engine using a mixed fuels with that of commercial diesel engine. Finally we grasped a emission characteristics of PCCI engine. From this experiment, it could be found that NOx reduction is caused by the lower maximum temperature and soot reduction is caused by rapid combustion under diffusion combustion part. Also, it was found that 1st-combustion(cool flame) and 2nd-combustion(hot flame) is appeared in heat release curve, exhaust gas temperature is diminished and combustion variation is increased according to increasing of gasoline ratio.

• Proceedings of the KIEE Conference
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• 1995.07a
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• pp.274-277
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• 1995

Recent environmental pollutions have intensified the need to develop zero emission vehicles. The most effect method of such solutions is EV. EV is high energy efficiency, easy to maintain, repair and is possible to make high performance control. However, because energy density of batteries is constrained and the distance covered one charge is short range. Also because EV has disadvantage of poor accelation ability, development of high performance battery is required for large scale use of EV. EV charger analogous to gas apparatus must also be developed immediately. Charger is discriminate between on-vehicle type and off-vehicle type. As off-vehicle type is able to charge fast and safe, inductive charging is considered. This paper aims to develope off-vehicle inductive charging system. Therefore, it achieved power factor correction converter, high frequency DC/AC inverter control algorithm development which gives proof validity through simulation and formulated the basic concept of high frequency transformer design for inductive charging.