• Title/Summary/Keyword: Environmental Aging

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Effects of Artificial Thermal Aging on Variations in Color of Commercial Papers (건열처리 인공노화가 시판지의 색상변화에 미치는 영향)

  • Choi, Eun-Yeon;Lee, Yong-Kyu;Cho, Byoung-Uk
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.4
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    • pp.54-61
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    • 2014
  • Effects of artificial thermal aging on color variations of various commercial papers (fine paper, coated paper, newsprint and filter paper) were investigated. With thermal aging at $105^{\circ}C$, most of papers showed a special trend in $a^*-b^*$ plane: the $a^*$ (red-green) values of the samples were initially reduced (heading to - $a^*$ side) and after a turning point they increased to +$a^*$ side while the $b^*$(blue-yellow) values were kept increased to +$b^*$ side (yellowing of paper). Different papers had different turning points for $a^*$ value. The filter paper consisted of a pure chemical pulp and the copy paper with OBA (optical brightening agent) showed the latest turing points. In addition, the papers without OBA showed less reduction in brightness compared with that with OBA, suggesting that OBA could adversely influence the brightness stability during thermal aging.

Impact of multiple component deterioration and exposure conditions on seismic vulnerability of concrete bridges

  • Ghosh, Jayadipta;Padgett, Jamie E.
    • Earthquakes and Structures
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    • v.3 no.5
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    • pp.649-673
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    • 2012
  • Recent studies have highlighted the importance of accounting for aging and deterioration of bridges when estimating their seismic vulnerability. Effects of structural degradation of multiple bridge components, variations in bridge geometry, and comparison of different environmental exposure conditions have traditionally been ignored in the development of seismic fragility curves for aging concrete highway bridges. This study focuses on the degradation of multiple bridge components of a geometrically varying bridge class, as opposed to a single bridge sample, to arrive at time-dependent seismic bridge fragility curves. The effects of different exposure conditions are also explored to assess the impact of severity of the environment on bridge seismic vulnerability. The proposed methodology is demonstrated on a representative class of aging multi-span reinforced concrete girder bridges typical of the Central and Southeastern United States. The results reveal the importance of considering multiple deterioration mechanisms, including the significance of degrading elastomeric bearings along with the corroding reinforced concrete columns, in fragility modeling of aging bridge classes. Additionally, assessment of the relative severity of exposure to marine atmospheric, marine sea-splash and deicing salts, and shows 5%, 9% and 44% reduction, respectively, in the median value bridge fragility for the complete damage state relative to the as-built pristine structure.

An Optimization of Aging Time for Low-Temperature Water-Gas Shift Over Cu-Zn-Al Catalyst (저온 수성가스 전이 반응용 Cu-Zn-Al 촉매의 숙성시간 최적화)

  • SHIM, JAE-OH;NA, HYUN-SUK;AHN, SEON-YONG;JANG, WON-JUN;ROH, HYUN-SEOG
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.2
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    • pp.103-110
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    • 2019
  • Cu-Zn-Al catalysts were prepared via co-precipitation method for low-temperature water-gas shift (LT-WGS) reaction under practical reaction condition. Aging time was systematically changed to find optimum point for LT-WGS under practical condition. The Cu-Zn-Al catalyst aged for 72 hours showed the highest CO conversion within low-temperature range as well as very stable catalytic activity for 200 hours despite the practical reaction condition.

Analysis on Spatial Pattern Changes of Aging Phenomenon and Relation between Aging Population and Regional Characteristics (고령화 현상의 공간적 패턴 변화와 지역특성과의 관계 분석)

  • Lee, Jimin
    • Journal of Korean Society of Rural Planning
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    • v.22 no.4
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    • pp.139-146
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    • 2016
  • Aging phenomenon is an important issue in Korea national policy. This aging phenomenon depends on the social and environmental characteristics of regions. Also aging phenomenon and regional characteristics have spatial dependency. The purpose of this study is to discover the spatial changes in aging population rate and to find local factors of regional aging phenomenon considering spatial autocorrelation. For spatial analysis of ageing phenomenon, local Moran's I and Geographically Weighted Regression (GWR) were applied. As the results, the most significant changes of aging phenomenon appeared between 2000 and 2005, and most of hot-spot regions (aged regions) were distributed in Jullanam-do and Jullabuk-do. The results of GWR (R-square: 0.681) shows that total fertility rate, the number of doctor per 1,000 people and forest area rate have positive relation with aging population rate, but the number of private academy per 1,000 people has negative relation.

Optimal Organic Solvent Extraction Method for Dewaxing of Beeswax-treated Hanji (밀랍도포한지의 탈랍을 위한 최적 유기용매 추출기법 탐색)

  • Choi, Do-Chim;Choi, Eun-Yeon;Jo, Byoung-Muk;Cho, Byoung-Uk
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.6
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    • pp.50-57
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    • 2012
  • In this study, the beeswax extraction methods using organic solvents were examined to develop a optimal dewaxing technology for beeswax-treated Hanji. Thermally-aged beeswax-treated Hanji was dewaxed using four types of extraction methods including dipping, Soxhlet extraction, ultrasonic washing and shaking methods. Then, the aging stability of the dewaxed Hanji was evaluated in terms of variations in paper strength and in the color of the printed area with muk. The experimental results suggested that the dewaxing methods allowing solvent to flow during extraction showed superior extraction efficiency. The dipping method in which the organic solvent does not flow showed the slowest extraction rate of beeswax compared to three other methods. In terms of variations in tensile strength and folding endurance, however, no obvious differences in the aging stability were observed amongst these four extraction methods. Regarding the aging stability in terms of the color of the printed area with muk, Soxhlet extraction method showed the best performance of dewaxing.

Effects of thermal aging on variations in paper color (강제열화에 따른 종이의 색상변화)

  • Kim, Sun-Kyung;Choi, Eun-Yeon;Lee, Yong-Kyu;Cho, Byoung-Uk
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2011.04a
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    • pp.235-241
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    • 2011
  • Effects of thermal aging on color variations of various papers were evaluated. With thermal aging, most of papers showed a special trend in $a^*$-$b^*$ plane: $a^*$ (red-green) values of the samples were reduced at beginning and after a turning point it was increased while $b^*$ (blue-yellow) was kept increased (yellowing of paper). In case of filter paper which consists of chemical pulps, the changes in $a^*$ value was occurred late compared with other samples. In case of the copy paper with optical brightening agent, the turning point in $a^*$ was not observed while a constant increase in $b^*$ was observed. In case of color paper, no specific trends in $a^*$-$b^*$ were found.

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Effects of Thermal Aging of Natural Rubber Bearing on Seismic Performance of Bridges (천연고무받침의 열 노화가 교량 내진성능에 미치는 영향)

  • Oh, Ju;Jung, Hie-Young
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.3
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    • pp.855-864
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    • 2013
  • The dynamic characteristics of natural rubber bearings, which are used as isolator, are dependent on the main rubber's dynamic behaviors and nonlinear properties. Rubber materials tend to undergo an aging process under the influence of mechanical or environmental factors, so they inevitably end up facing damage. A main cause of aging like this is known to be oxidization, which occurs through the heat of reaction at high temperatures. Accordingly, in this study an accelerated thermal aging test was carried out in order to compare the characteristic values of the bearings before and after thermal aging occurs. As a result of this experiment, it was found that a thermal aging phenomenon could have some effects on shear stiffness, energy absorption, and equivalent damping coefficients of the bearings. Furthermore, a deterioration in the dynamic properties of the natural rubber bearings caused by the thermal aging was applied to an actual bridge and then the effects of such thermal aging on the seismic performance of the bridge were also compared and analyzed based on numerical analysis. As a result of this analysis, it was found that the changes in the basic properties of the natural rubber bearings caused by the thermal aging bring only a minor effect on the seismic performance of bridges.

A Study of Aging Effect for Train Carbody Using Accelerated Aging Tester

  • Nam, Jeong-Pyo;LI, Qingfen;LI, Hong
    • International Journal of Railway
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    • v.1 no.3
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    • pp.113-116
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    • 2008
  • The long-tenn exposure of polymeric composite materials to extreme-use environments, such as pressure, temperature, moisture, and load cycles, results in changes in the original properties of the material. In this study, the effect of combined environmental factors such as ultraviolet ray, high temperature and high moisture on mechanical and thermal analysis properties of glass fabric and phenolic composites are evaluated through a 2.5 KW accelerated environmental aging tester. The environmental factors such as temperature, moisture and ultraviolet ray applied of specimens. A xenon-arc lamp is utilized for ultraviolet light and exposure time of up to 3000 hours are applied. Several types of specimens - tensile, bending, and shear specimens that are warp direction and fill direction are used to investigate the effects of environmental factors on mechanical properties of the composites. Mechanical degradations for tensile, bending and shear properties are evaluated through a Universal Testing Machine (UTM). Also, storage shear modulus, loss shear modulus and tan a are measured as a function of exposure time through a Dynamic Mechanical Analyzer (DMA). From the experimental results, changes in material properties of glass fabric and phenolic composites are shown to be slightly degraded due to combined environmental effects.

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Influence of Aging of Lead Rubber Bearing on Seismic Performance of Bridges (납고무받침의 노화가 교량의 내진성능에 미치는 영향)

  • Park, Seong-Kyu;Oh, Ju
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.2A
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    • pp.109-116
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    • 2012
  • The dynamic properties of lead rubber bearings, which are used as isolator, are dependent on the main rubber's dynamic behaviors and nonlinear qualities. Rubber materials tend to undergo an aging process under the influence of mechanical or environmental factors, so they can end up inevitably facing damage. A main cause of such aging is known to be oxidization, which occurs through the heat of reaction at high temperatures. Accordingly, in this study an accelerated thermal aging test was carried out in order to compare the characteristic values of the bearings with each other before and after thermal aging occurs. As a result of this experiment, it was found that a thermal aging phenomenon could have an effect on shear stiffness, energy absorption, and equivalent damping coefficients. Furthermore, a decline in the dynamic properties of the lead rubber bearings by means of the thermal aging process was applied to an actual bridge and the effects of such thermal aging on the seismic performance of the bridge were also compared and analyzed based on numerical analysis. As a result of this analysis, it was found that the changes in the basic properties of the lead rubber bearings have a minor effect on the seismic performance of bridges.

Mechanism of guanine-specific DNA damage by UVA and its role in photocarcinogenesis and photoaging

  • Kawanishi, Shosuke;Oikawa, Shinji;Hiraku, Yusuke
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.150-153
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    • 2002
  • Solar UV light is a well-known carcinogen. UVA radiation is probably carcinogenic to humans. In addition, recent investigations point to the importance of UVA irradiation in the photoaging. We investigated the mechanism of sequence- specific DNA damage using $\^$32/P-Iabeled DNA fragments in relation to carcinogenesis and aging. Furthermore, we investigated whether UVA accelerates the telomere shortening in human WI-38 fibroblasts. The exposure of double- stranded DNA fragments to 365 nm light in the presence of endogenous sensitizers produced sequence-specific cleavage at the 5' site of 5'-GG-3' and 5'-GGG-3' sequences. In addition, HPLC analysis revealed that sensitizers plus 365 nm light increased the 8-oxodG content of double-stranded DNA. We discuss the mechanisms of guanine-specific DNA damagecaused by excited photosensitizers in relation to carcinogenesis and aging.

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