• 설비공학논문집
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• 제11권6호
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• pp.766-773
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• 1999

A numerical analysis has been performed solidification problem using the fixed grid-enthalpy method with enthalpy-porosity relation. A modified standard $k-\varepsilon$ model was applied to describe the influence of turbulent flow. Computational procedures are based on the finite volume method and the non-staggered grid system. Comparisons with the different three experimental results show that applying a modified standard $k-\varepsilon$model in mushyzone is better than the previous computation results. This paper includes another EMBR's influences such as change of velocity field, Increasement of temperature and dispersion of flow out of nozzle into the flow field. These EMBR's influences are compared to case without EMBR.

• 설비공학논문집
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• 제11권6호
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• pp.891-897
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• 1999

The heat transfer characteristics at the interface between the mold and the casting is one of the major factors for the solidification speed which determines the casting structures. The thermal resistance exists due to air gap formation at the mold/casting interface during the freezing process. In this study one dimensional Stefan problem with the air-gap resistance in the cylindrical mold is considered and the heat transfer characteristics is numerically examined by using the enthalpy method which is convenient in solving the Stefan problem with mushy zone. The present results agreed very well with those of previous papers. The effects of major parameters such as thermal conductivity, heat transfer coefficient of mold, on the thermal characteristics are investigated.

• 한국기계기술학회지
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• 제20권6호
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• pp.872-878
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• 2018

Steam tables including superheated, saturated and compressed region were simultaneously modeled using the neural networks. Pressure and temperature were used as two inputs for superheated and compressed region. On the other hand Pressure and dryness fraction were two inputs for saturated region. The outputs were specific volume, specific enthalpy and specific entropy. The neural network model were compared with the linear interpolation model in terms of the percentage relative errors. The criterion of judgement was selected with the percentage relative error of 1%. In conclusion the neural networks showed better results than the interpolation method for all data of superheated and compressed region and specific volume of saturated region, but similar for specific enthalpy and entropy of saturated region.

• Elastomers and Composites
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• 제19권1호
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• pp.13-31
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• 1984

The purposes of this dissertation are to demonstrate that DSC theromoanaytical methods of vulcanization can provide useful informations on the vulcanization characteristics of industrial formulations and also provides the potential basis for a rapid and complete method of sulfur and vulcanizing accelerator analysis for quality control. The influences of those factors such as heating rate, scan temperature, vucanizing accelerator's type and concentration upon vulcanization exotherm in NR and NBR compounds in the presence of vulcanizing accelerators such as TMTD,MBTS,DPG,TMTM,CBS, and MBT were evaluated by means of DSC. In order to examine the credibility in the DSC method, the same samples which were used for DSC method were studied to compare the DSC results with the ODR (Oscillating Disk Rheometer) data. The results obtained were as follows 1. In the DSC dynamic experiments, the observed enthalpy results from vulcanization depends upon the heating rate; In the range of 2 to $20^{\circ}C/min$ of heating rate, as the heating rate was increased the enthalpy change was also increased. However, over the heating rate of $30^{\circ}C/min$ it was observed that the enthalpy change was decreased as the heating rate was further increased. Without regard to the change of enthalpy, tremendous instantaneous heat evolving was observed in the range of high heating rates. 2. For the samples which are added with various vulcanizing accelerators, the activation energies of vulcanization were as follows; 3. Regarding to the influences of vulcanizining accelerator's types upon the characteristics of vulcanization exotherm, NR and NBR compounds in the presence of thiuramsulphide compounds type accelerators such as TMTD, TMTM, were exhibited sharper and higher vulclanization exotherm than others. From the resuts of DSC thermograms which was distributed in even shape in the broad temperature range, it was clearly shown that the guanidine compounds type accelerator such as DPG acts as a delayed acting accelerator. 4. In the comparison of DSC and ODR results, the dependency of temperature in the cure rate and the observed conversions show good agreements between two results. 5. In the same curatives, by the comparison of glass transition temperatures, it was possible to predict relative values of maximum torques. Consequently, from the present studies, it is shown that the DSC thermoanalytical method can provide an alternate new method for rapid and complete quality control analysis of rubber industry.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 춘계학술대회논문집D
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• pp.319-324
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• 2001

A finite element model for the process of squeeze casting for metal matrix composites (MMCs) in cylindrical mold is developed. The fluid flow and the heat transfer are the fundamental phenomena in the squeeze casing process. To describe heat transfer with solidification of molten aluminum, the energy equation in terms of temperature and enthalpy are applied to two dimensional axisymmetric model which is similar to the experimental system. And one dimensional flow model is employed to simulate the transient metal flow. The direct iteration technique was used to solve the resulting nonlinear algebraic equations. A computer program is developed to calculate the enthalpy, temperature and fluid velocity. Cooling curves and temperature distribution during infiltration and solidification are calculated for pure aluminum. The temperature is measured and recorded experimentally. At two points of the perform inside and one point of the mold outside, thermocouple wire are installed. The time-temperature data are compared with the calculated cooling curves. The experimental results show that the finite element model can estimate the solidification time and predict the cooling process.

• 설비공학논문집
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• 제6권4호
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• pp.399-405
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• 1994

Beacuse of the energy resources exhaustion, the aggravating environmental air pollution and the smoke phenomena etc., the importance of clean gas fuel compared with liquid fuel is highly considered in recent years. The combustion system which consists of porous media is actively studied as a new method for solving above problems. Therefore, excess enthalpy combustion using porous media was interested by many researchers and investigated through numerical and experimental analysis. In this study, the simplified combustor has the unique combustion characteristics of mixture gas preheated effect using radiative and convective heat energy by changing the flow passage of unburned gas with solenoid valves and has the intensive excess enthalpy phenomena As the result of according to reduce equivalence ratio, flame temperature was remarkably higher than adiabatic flame temperature. This show the ability of super-lean combustion.

• Bulletin of the Korean Chemical Society
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• 제33권11호
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• pp.3607-3617
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• 2012

In this paper, the study of various ortho- and meta-substituted Magnolol derivatives is presented. The reaction enthalpies related to three antioxidant action mechanisms HAT, SET-PT and SPLET for substituted Magnolols have been calculated using DFT/B3LYP method in gas-phase and water. Calculated results show that electron-withdrawing substituents increase the bond dissociation enthalpy (BDE), ionization potential (IP) and oxidation/reduction enthalpy (O/RE), while electron-donating ones cause a rise in the proton dissociation enthalpy (PDE) and proton affinity (PA). In ortho- position, substituents show larger effect on reaction enthalpies than in meta-position. In comparison to gas-phase, water attenuates the substituent effect on all reaction enthalpies. In gas-phase, BDEs are lower than PAs and IPs, i.e. HAT represents the thermodynamically preferred pathway. On the other hand, SPLET mechanism represents the thermodynamically favored process in water. Results show that calculated enthalpies can be successfully correlated with Hammett constants (${\sigma}_m$) of the substituted Magnolols. Furthermore, calculated IP and PA values for substituted Magnolols show linear dependence on the energy of the highest occupied molecular orbital ($E_{HOMO}$).

• 대한화학회지
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• 제24권2호
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• pp.108-114
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• 1980

정전기적모델과 결합의 단순한 부가성을 이용하여 아주 극성인 화합물의 표준생성열$({\Delta}H_f\;^{\circ})$를 계산하는 간단한 방법을 제안하였다. 이 ${\Delta}H_f\;^{\circ}$에 대한 할로메탄의 bond 기여도는 각각 ${\Delta}H_f\;^{\circ}(C-F)=-36.44\;kcal/mole,\;{\Delta}H_f\;^{\circ}(C-Cl)=-2.57\;kcal/mole,\;{\Delta}H_f\;^{\circ}(C-Br)=5.32\;kcal/mole,\;{\Delta}H_f\;^{\circ}(C-I)=19.18\;kcal/mole,\;and\;{\Delta}H_f\;^{\circ}(C-H)=-3.61\;kcal/mole$로 얻어졌고 이 갑들과 정전기적 에너지들로부터 계산한 ${\Delta}H_f\;^{\circ}$는 실험치와 잘 일치함을 보였다.

• 대한기계학회논문집A
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• 제26권10호
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• pp.2104-2113
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• 2002

A finite element model is developed for the process of squeeze casting of metal matrix composites (MMCs) in cylindrical molds. The fluid flow and the heat transit. are fundamental phenomena in squeeze casting. To describe heat transfer in the solidification of molten aluminum, the energy equation is written in terms of temperature and enthalpy are applied in an axisymmetric model which is similar to the experimental system. A one dimensional flow model simulates the transient metal flow. A direct iteration technique was used to solve the resulting nonlinear algebraic equations, using a computer program to calculate the enthalpy, temperature and fluid velocity. The cooling curves and temperature distribution during infiltration and solidification were calculated fer pure aluminum. Experimentally, the temperature was measured and recorded using thermocouple wire. The measured time-temperature data were compared with the calculated cooling curves. The resulting agreement shows that the finite element model can accurately estimate the solidification time and predict the cooling process.

• 대한기계학회논문집B
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• 제22권12호
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• pp.1657-1668
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• 1998

In the analysis of a mushy solidification system with natural convection using a fixed grid method, the enthalpy method has been used to account for the release of latent heat. The variable viscosity, Darcy source, and hybrid methods have been employed for the velocity suppression in a mushy region. The choice of the values of solid viscosity and permeability constant in conjunction with the Darcy source term plays an important role in forming the location and shape of the phase boundaries. In this work the effects of these major parameters related to steady-state behavior in the system of mushy solidification are investigated through a simple test problem. The effective specific heat based on the spatial gradients of the enthalpy and temperature is adopted for the treatment of the release of latent heat. The effects of the Prandtl and Rayleigh numbers on the shape of mushy region are examined using the hybrid method.