• Title/Summary/Keyword: Enhanced nitrogen removal

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An Electrolytic Treatment of Shipboard Sewage by Using DSA Electrode (I) -Batch Electrolytic Treatment- (DSA 전극에 의한 선박오폐수의 전해처리(I)-회분식 전해처리-)

  • 김인수;조권희;남청도
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.3 no.2
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    • pp.69-76
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    • 1997
  • Each factor for the most effective electrolytic reaction in treating shipboard sewage was enhanced by means of batch electrolyitc reactor using DSA electrode. The effective clearance was 6mm and pH was 5-6. In such case, more than 20% of sea water concentration was needed to attain 90% of COD removal rate. The suspended solids was effectively removed by electro-floatation in proportion as charged current density. The nitrogen and posporous were effectively removed in the electrolytic device when mixed seawater.

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Nitrogen Removal Comparison in Porous Ceramic Media Packed-Bed Reactors by a Consecutive Nitrification and Denitrification Process

  • Han, Gee-Bong;Woo, Mi-Hee
    • Environmental Engineering Research
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    • v.16 no.4
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    • pp.231-236
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    • 2011
  • Biological nitrogen removal, using a continuous flow packed-bed reactor (CPBR) in a consecutive nitrification and denitrification process, was evaluated. An apparent decline in the nitrification efficiency coincided with the steady increase in $NH_4{^+}$-N load. Sustained nitrification efficiency was found to be higher at longer empty bed contact times (EBCTs). The relationship between the rate of alkalinity consumption and $NH_4{^+}$-N utilization ratio followed zero-order reaction kinetics. The heterotrophic denitrification rate at a carbon-tonitrogen (C/N) ratio of >4 was found to be >74%. This rate was higher by a factor of 8.5 or 8.9 for $NO_3{^-}$-N/volatile solids (VS)/day or $NO_3{^-}-N/m^3$ ceramic media/day, respectively, relative to the rates measured at a C/N ratio of 1.1. Autotrophic denitrification efficiencies were 80-90%. It corresponds to an average denitrification rate of 0.96 kg $NO_3{^-}-N/m^3$ ceramic media/day and a relevant average denitrification rate of 0.28 g $NO_3{^-}$-N/g VS/day, were also obtained. Results presented here also constitute the usability of an innovative porous sulfur ceramic media. This enhanced the dissolution rate of elemental sulfur via a higher contact surface area.

Effect of NOx Removal Efficiency according to Space Velocity and Linear Velocity of SCR Catalyst (SCR 촉매의 공간속도 및 선속도가 NOx 제거 효율에 미치는 영향)

  • Park, Jin-woo;Park, Sam-sik;Ku, Kun Woo;Hong, Jung Goo
    • Journal of ILASS-Korea
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    • v.21 no.2
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    • pp.71-77
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    • 2016
  • Air pollutants nitrogen oxides are inevitably generated in the combustion reaction. Its amount trend is steadily increasing because the rapid modern industrialization and population growth. For this reason, NOx is controlled to reducing the harmful components in the exhaust gas. So Marine Environment Protection Committee (MEPC) take effect 'Tier I', 'Tier II' of air pollution regulation in 2005 and 2011 respectively. According to NOx emissions are strictly regulated management of the vessel through them. In addition, since 2016 the regulation enter into force in the next step 'Tier III' was confirmed by MEPC 66th committee. It's 80% enhanced emissions limits than the 'Tier I' Alternatively these emission regulation, research is actively being carried out about exhaust gas after-treatment methods through the vessel application of Selective Catalytic Reduction(SCR). Therefore depending on the basic specification of cell density according to the Area velocity, Space velocity, Linear velocity is studied the effects of NOx removal efficiency

Nitritation Characteristics Depending on Influent Nitrogen Concentration in a Biological Aerated Filter (Biological Aerated Filter에서 유입 질소농도에 따른 아질산화 특성)

  • Yoo, Ik-Keun
    • Journal of Korean Society on Water Environment
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    • v.30 no.1
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    • pp.1-7
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    • 2014
  • The purpose of this study was to investigate the nitrification characteristics of biological aerated filter (BAF) packed with ceramic media, especially focusing on nitrite build-up during nitrification. When increasing the nitrogen load above $1.63kgNH_4{^+}-N/m^3{\cdot}d$, ammonium removal efficiency decreased to less than 60% and the nitrite ratio ($NO_2{^-}-N/NO_x-N$) of higher than 75% was achieved due to the inhibitory free ammonia (FA, $NH_3-N$) concentration and oxygen limitation. FA inhibition, however, is not recommended strategy to promote nitrite build-up since FA concentration in the reactor is coupled with decreased ammonium removal efficiency. Nitrite ratio in the effluent was also affected by aeration rate and influent ammonium concentration. Ammonium oxidation was enhanced at a higher aeration rate regardless of influent ammonium concentration but, the nitrite ratio was dependent on both aeration rate and influent ammonium concentration. While a higher nitrite ratio was obtained when BAFs were fed with $50mgNH_4{^+}-N/L$ of influent, the nitrite ratio significantly decreased for a greater influent concentration of $200-300mgNH_4{^+}-N/L$. Taken together, aeration rate, influent ammonium concentration and FA concentrations kept in the BAF were found to be critical variables for nitrite accumulation in the BAF system.

Shoot Cutting Effects on the Productivity and Nutrient Removal of Some Wetland Plants (습지식물의 지상부 제거가 생산력과 영양염류 제거량에 미치는 효과)

  • 정연숙;오현경;노찬호;황길순
    • Korean Journal of Environmental Biology
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    • v.17 no.4
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    • pp.459-465
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    • 1999
  • This work focused on the effects of the timing and the frequency of shoot cutting to maximize the productivity and the nutrient removal of three emergent macrophytes, Phragmites communis, Zizania latifolia and Typha angustifolia in natural wetlands. Shoot cutting significantly enhanced biomass production and resulted in more nitrogen and phosphorus removal from water in these three experimental species, compared to those of control. However, the frequency and the timing of shoot cutting, and the enhancement ratio were different among three species. For Phragmites stands, the highest productivity was 1.9 times of control in June treatment of the first year experiment, while 1.3 times in May treatment of the second year experiment. Zizania and Typha stands were both 1.2 times of control in August treatment and June and August treatment. Calculating the total annual removal rate of nitrogen and phosphorus based on the highest productivities among treatments, in Phragmites stands, 2.0 times of nitrogen and 1.8 times of phosphorus were removed in the first year, and both 1.4 times in the second year experiment. Likewise, for nitrogen and phosphorus; 2.4 and L.8 times in Zizania stands, and 1.8 and 1.9 times in Typha stands were removed. Overall, these results suggested that cutting treatment of shoots be effective. Thus, shoot cutting of two times during a growing season were recommended to maximize the effects: that is, in May or June, and October for Phragmites stands, and in August and October fur Zizania and Typha stands.

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The Experimental Study on Removal of Sulfur Dioxide and Nitrogen Oxide Using a Nano-Pulse Corona Discharger at Different Temperatures (나노펄스 코로나 방전의 온도 변화에 따른 이산화황 및 일산화질소 제거에 관한 실험적 연구)

  • Han, Bang-Woo;Kim, Hak-Joon;Kim, Yong-Jin
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.4
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    • pp.387-394
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    • 2011
  • A study on the removal of sulfur dioxide and nitrogen oxide was carried out using a non-thermal nano-pulse corona discharger at different gas temperatures. Pulse voltage with a high voltage of 50 kV, a pulse rising time of about 100 ns, a full width at half maximum of about 500 ns and a frequency of 1 kHz was applied to a wire-cylinder corona reactor. Ammonia and propylene gases were added into the corona reactor as additives with a static mixer. Ammonia addition had less effect on $SO_2$ reduction at the higher temperature because of the retardation of ammonium sulfate formation. However, propylene addition enhanced NO reduction at higher temperature due to increased gas mixture. $SO_2$ was further removed at the mixed $SO_2$ and NO gas due to increased $NO_2$ by the conversion of NO. The addition of ammonia and propylene gases was more highly dominant for the removal of sulfur dioxide compared to the sole pulse corona without the additives. However, the specific energy density per unit concentration of pulse corona as well as propylene additive was an important factor to remove NO gas. Therefore, the specific energy density per unit concentration of 0.04 Wh/($m^3{\cdot}ppm$) was necessary for the NO removal of more than 80% with the concentration ratio of 2.0 for propylene and NO. Hydrogen peroxide was another alternative additive to remove both $SO_2$ and NO in the nano-pulse corona discharger.

Nitrongen and Phosphorus Removal using Elutriated Acids of Food Waste as an External Carbon Source in SBR (음식물쓰레기 세정산발효액을 외부탄소원으로 주입한 SBR 공정에서 질소 및 인 제거)

  • Kwon, Koo-ho;Kim, Si-won;Lee, Min-jae;Min, Kyung-sok
    • Journal of Korean Society on Water Environment
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    • v.22 no.3
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    • pp.462-467
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    • 2006
  • An improvement of nitrogen and phosphorus removal in SBR using the elutriated acids from the food waste as an external carbon source was investigated in this study. The food waste was elutriated at $35^{\circ}C$ and pH 9 to produce the external carbon source. The elutriate of food waste were continuously collected. The elutriated liquid contained VFAs of 39,180 mg/L representing soluble COD of 44,700 mg/L. The SBR showed poor denitrification and EBPR (enhanced biological phosphorus removal) without elutriated VFAs addition. An average denitrification rate was 0.4 mg NOx-N/g MLVSS/day. In turn, EBPR was also inhibited by this poor denitrification because the remaining nitrate in anaerobic phase resulting a poor denitrification. On the other hand, the denitrification in anoxic phase significantly improved with an elutriated VFAs addition. Nitrate removal was 82% while the denitrification rate was 2.9 mg NOx-N/g MLVSS/day with 18.4 mL/cycle of elutriated VFAs. With the enhanced denitrification, nitrate concentration in anaerobic phase could effectively be controlled to a very low level. The elimination of nitrate inhibition in anaerobic phase resulted enhancement of EBPR. The specific phosphate release rate was $1.9mg\;PO_4^{3-}-P/g\; MLVSS/day$ with less than 0.5 mg/L of $PO_4^{3-}-P$ concentration.

Pore Condensation-Based Separation of VOCs by a Microporous Ceramic Membrane (미세다공성 세라믹 막에서의 가공응축기구에 의한 휘발성 유기화합물의 분리)

  • Cha, Jun-Seok
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.E
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    • pp.19-28
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    • 1996
  • A pore concensation-based separation technique was studied experimentally using toluene and xylene in a nitrogen stream. The removal rate of toluene and xylene on a microporous ceramic membrane was enhanced by increasing the partial pressure difference across the membrane, but the selectivity was reduced with increasing flux of nitrogen. This was found both in vacuum and pressure modes of operation. The experimental results from this study suggest that the pores mear the inlet portion of the module were filled with the organic solvent while the pores near the exit section of the module were slightly opened as the solvent concentration was depleted along the module. In the case of xylene, the rate of N$_{2}$ permeation was reduced considerably relative to toluene, resulting in a much higher separation gactor. Condensibility of xylene appeared to be higher than that of toluene, the potential for pore condensation-based separation of xylene was also found to be higher than that for toluene.

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Treatment of Dyeing Wastewater by Flocculation with Calsium and Magnesium salts (칼슘과 마그네슘염을 이용한 염색폐수의 응집처리)

  • 김재용;서완주
    • Journal of environmental and Sanitary engineering
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    • v.17 no.3
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    • pp.89-98
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    • 2002
  • The changes of conventional clarification process and an increase in treatment cost are required to meet increasingly stringent regulations related to the treated water quality. Although many enhanced coagulations have introduced to improve organic matter removal, the results to remove color, nitrogen and phosphorus as well as organic material have not been very efficient yet. The removal of waste matters such as SS, organic matter, color and turbidity contained in dyeing wastewater was carried out by using the combination of calcium hydroxide and magnesium sulfate. The flocculation was investigated as a function of coagulant dose, pH, mixing time, settling time and coagulant addition modes such as the sequential addition of the two coagulants and the simultaneous addition of them. The flocculation by the combination of calcium hydroxide and magnesium sulfate was compared with that by aluminum sulfate. The mechanism of flocculation was investigated as well. About 84% of color in dyeing watewater was removed by flocculation with combination of calcium hydroxide and magnesium sulfate.

Swine Wastewater Treatment Using Continuos Circulation Biofilm Process (연속순환 생물막 공정을 이용한 돈사 폐수 처리)

  • Goh, B.D.;Ra, C.S.
    • Journal of Animal Science and Technology
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    • v.49 no.2
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    • pp.279-286
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    • 2007
  • A submerged biofilm sequencing batch reactor (SBSBR) process, which liquor was internally circulated through sandfilter, was designed, and performances in swine wastewater treatment was evaluated under a condition of no external carbon source addition. Denitrification of NOx-N with loading rate in vertical and slope type of sandfilter was 19% and 3.8%, respectively, showing approximately 5 times difference, and so vertical type sandfilter was chosen for the combination with SBSBR. When the process was operated under 15 days HRT, 105L/hr.m3 of internal circulation rate and 54g/m3.d of NH4-N loading rate, treatment efficiencies of STOC, NH4-N and TN (as NH4-N plus NOx-N) was 75%, 97% and 85%, respectively. By conducting internal circulation through sandfilter, removal performances of TN were enhanced by 14%, and the elevation of nitrogen removal was mainly attributed to occurrence of denitrification in sandfilter. Also, approximately 57% of phosphorus was removed with the conduction of internal circulation through sandfilter, meanwhile phosphorus concentration in final effluent rather increased when the internal circulation was not performed. Therefore, It was quite sure that the continuous internal circulation of liquor through sandfilter could contribute to enhancement of biological nutrient removal. Under 60g/m3.d of NH4-N loading rate, the NH4-N level in final effluent was relatively low and constant(below 20mg/L) and over 80% of nitrogen removal was maintained in spite of loading rate increase up to 100g/m3.d. However, the treatment efficiency of nitrogen was deteriorated with further increase of loading rate. Based on this result, an optimum loading rate of nitrogen for the process would be 100g/m3.d.