• Transactions of the Korean hydrogen and new energy society
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• v.32 no.1
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• pp.41-52
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• 2021

NiO and Co3O4-doped porous La(CoNi)O3 perovskite oxides were prepared from excess Ni addition by a hydrothermal method using porous silica template, and characterized as bifunctional catalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) for Zn-air rechargeable batteries in alkaline solution. Excess Ni induced to form NiO and Co3O4 in La(CoNi)O3 particles. The NiO and Co3O4-doped porous La(CoNi)O3 showed high specific surface area, up to nine times of conventionally synthesized perovskite oxide, and abundant pore volume with similar structure. Extra added Ni was partially substituted for Co as B site of ABO3 perovskite structure and formed to NiO and Co3O4 which was highly dispersed in particles. Excess Ni in La(CoNi)O3 catalysts increased OER performance (259 mA/㎠ at 2.4 V) in alkaline solution, although the activities (211 mA/㎠ at 0.5 V) for ORR were not changed with the content of excess Ni. La(CoNi)O3 with excess Ni showed very stable cyclability and low capacity fading rate (0.38 & 0.07 ㎶/hour for ORR & OER) until 300 hours (~70 cycles) but more excess content of Ni in La(CoNi)O3 gave negative effect to cyclability.

• Journal of the Korean Institute of Gas
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• v.24 no.6
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• pp.91-97
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• 2020

Lithium-ion batteries (LIBs) have a longer lifespan, higher energy density, and lower self-discharge rates than other batteries, therefore, they are preferred as an Energy Storage System (ESS). However, during years 2017-2019, 28 ESS fire accidents occurred in Korea, and accurate capacity estimation of LIB is essential to ensure safety and reliability during operations. In this study, data-driven modeling that predicts capacity changes according to the charging cycle of LIB was conducted, and developed models were compared their performance for the selection of the optimal machine learning model, which includes the Decision Tree, Ensemble Learning Method, Support Vector Regression, and Gaussian Process Regression (GPR). For model training, lithium battery test data provided by NASA was used, and GPR showed the best prediction performance. Based on this study, we will develop an enhanced LIB capacity prediction and remaining useful life estimation model through additional data training, and improve the performance of anomaly detection and monitoring during operations, enabling safe and stable ESS operations.

• Journal of Convergence for Information Technology
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• v.12 no.4
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• pp.338-344
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• 2022

It is necessarily required in developing Si-based anode materials for lithium ion batteries, and the related researches are actively working especially in Si-carbon composite material. On the other hand, the photovoltaic and semiconductor industries discard huge amount of Si resources, facing the environmental issue. In this study, recycled Si resource is adopted to obtain Si-carbon composite for LIB(Lithium-Ion Batteries). In order to improve high-capacity retention characteristics and cycle stability of a Si anode material for the LIB, two differenct composites having a mass ratio of silicon and pitch of 1:1 and 2:1 are synthesized and electrochemical characteristics of the anode material manufactured by simple self-assembly method. This result in excellent initial capacity with stable cycle life, and confirming the potential use of recycled Si material for LIB.

• Earthquakes and Structures
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• v.22 no.6
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• pp.539-548
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• 2022

Steel plate shear walls (SPSWs) are one of the most important and widely used lateral load-bearing systems. The reason for this is easier execution than reinforced concrete (RC) shear walls, faster construction time, and lower final weight of the structure. However, the main drawback of SPSWs is premature buckling in low drift ratios, which affects the energy absorption capacity and global performance of the system. To address this problem, two groups of SPSWs under cyclic loading were investigated using the finite element method (FEM). In the first group, several series of circular rings have been used and in the second group, a new type of SPSW with concentric circular rings (CCRs) has been introduced. Numerous parameters include in yield stress of steel plate wall materials, steel panel thickness, and ring width were considered in nonlinear static analysis. At first, a three-dimensional (3D) numerical model was validated using three sets of laboratory SPSWs and the difference in results between numerical models and experimental specimens was less than 5% in all cases. The results of numerical models revealed that the full SPSW undergoes shear buckling at a drift ratio of 0.2% and its hysteresis behavior has a pinching in the middle part of load-drift ratio curve. Whereas, in the two categories of proposed SPSWs, the hysteresis behavior is complete and stable, and in most cases no capacity degradation of up to 6% drift ratio has been observed. Also, in most numerical models, the tangential stiffness remains almost constant in each cycle. Finally, for the innovative SPSW, a relationship was suggested to determine the shear capacity of the proposed steel wall relative to the wall slenderness coefficient.

• Membrane Journal
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• v.32 no.1
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• pp.66-73
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• 2022

In this study, a method for stabilizing treated water was conducted while maintaining high flux using a metal flat membrane module made of stainless steel. This module had a pore size of 13 ㎛, so it was possible to operate at a high flux from 60 LMH to 100 LMH. However, although SS leaked about 30~50 ppm during initial operation, aggregation was possible because SS acted as aggregation nucleus. While polymer membrane permeate does not have aggregation nucleus, so coagulation is possible but not flocculation. Typically clay or bentonite, which is used as aggregation nucleus, is additionally administered. In this study, the total phosphorus treatment and the quality of the treated water were to promote stability because flocculation was achieved only with SS leakage without the need for such a aggregation nucleus. Finally, the feasibility of operating a metal membrane filter capable of high flux in stable treated water to be applied to the MBR system.

• Journal of Soil and Groundwater Environment
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• v.29 no.4
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• pp.1-11
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• 2024

This study evaluated a method for prompt and periodic monitoring of moisture content in the waste layer of a landfill using a Time Domain Reflectometry (TDR) sensor, aimed at ensuring the stable operation of the bioreactor facility at the 2nd landfill of the SUDOKWON Landfill Site. It was found that the TDR sensor is sensitive to variables such as temperature changes and ion content in both the waste layer and leachate, indicating that a correction equation is necessary. A correction equation derived through regression analysis demonstrated a high correlation (correlation coefficient = 0.9647), and field verification experiments confirmed its reliability with an average deviation of only 1.5%. This verifies that the TDR sensor is effective for measuring and monitoring moisture content in landfills. It is also anticipated to be useful for various applications, including monitoring leachate levels, detecting leachate leakage, and assessing rainwater infiltration.

• Carbon letters
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• v.28
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• pp.31-37
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• 2018

This paper examines a simple one-step and catalyst-free method for synthesizing carbon nanoparticles from aliphatic alcohols and n-hexane with linear molecule formations by using a stable solution plasma process with a bipolar pulse and an external resistor. When the external resistor is adopted, it is observed that the current spikes are dramatically decreased, which induced production of a more stable discharge. Six aliphatic linear alcohols (methanol-hexanol) containing carbon with oxygen sources are studied as possible precursors for the massive production of carbon nanoparticles. Additional study is also carried out with the use of n-hexane containing many carbons without an oxygen source in order to enhance the formation of carbon nanoparticles and to eliminate unwanted oxygen effects. The obtained carbon nanoparticles are characterized with field emission-scanning electron microscopy, energy dispersive X-ray spectroscopy, and Raman spectroscopy. The results show that with increasing carbon ratios in alcohol content, the synthesis rate of carbon nanoparticles is increased, whereas the size of the carbon nanoparticles is decreased. Moreover, the degree of graphitization of the carbon nanoparticles synthesized from 1-hexanol and n-hexane with a high carbon (C)/oxygen (O) ratio and low or no oxygen is observed to be greater than that of the carbon nanoparticles synthesized from the corresponding materials with a low C/O ratio.

• Structural Engineering and Mechanics
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• v.74 no.1
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• pp.1-18
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• 2020

For the large deformation of shear walls under vertical and horizontal loads, there are difficulties in obtaining accurate simulation results using the response analysis method, even with fine mesh elements. Furthermore, concrete material nonlinearity, stiffness degradation, concrete cracking and crushing, and steel bar damage may occur during the large deformation of reinforced concrete (RC) shear walls. Matrix operations that are involved in nonlinear analysis using the traditional finite-element method (FEM) may also result in flaws, and may thus lead to serious errors. To solve these problems, a planar four-node element was developed based on vector mechanics. Owing to particle-based formulation along the path element, the method does not require repeated constructions of a global stiffness matrix for the nonlinear behavior of the structure. The nonlinear concrete constitutive model and bilinear steel material model are integrated with the developed element, to ensure that large deformation and damage behavior can be addressed. For verification, simulation analyses were performed to obtain experimental results on an RC shear wall subjected to a monotonically increasing lateral load with a constant vertical load. To appropriately evaluate the parameters, investigations were conducted on the loading speed, meshing dimension, and the damping factor, because vector mechanics is based on the equation of motion. The static problem was then verified to obtain a stable solution by employing a balanced equation of motion. Using the parameters obtained, the simulated pushover response, including the bearing capacity, deformation ability, curvature development, and energy dissipation, were found to be in accordance with the experimental observation. This study demonstrated the potential of the developed planar element for simulating the entire process of large deformation and damage behavior in RC shear walls.

• Journal of the Korean Institute of Intelligent Systems
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• v.3 no.2
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• pp.18-35
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• 1993

The water level control system of the steam generator in a pressurized water reactor and its control problems are analysed. In this work the stable control strategy during the low power operation and transient states is studied. To solve the problem, a fuzzy logic control method is applied as a basic algorithm of the controller. The control algorithm is based on the operator's knowledges and the experiences of manual operation for water level control at the compact nuclear simulator set up in Korea Atomic Energy Research Institute. From a viewpoint of the system realization, the control variables and rules are established considering simpler tuning and the input-output relation. The control strategy includes the dynamic tuning method and employs a substitutional information using the bypass valve opening instead of incorrectly measured signal at the low flow rate as the fuzzy variable of the flow rate during the pressure control mode of the steam generator. It also involves the switching algorithm between the control valves to suppress the perturbation of water level. The simulation results show that both of the fine control action at the small level error and the quick response at the large level error can be obtained and that the performance of the controller is improved.

• Geophysics and Geophysical Exploration
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• v.9 no.2
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• pp.139-147
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• 2006

We had conducted a numerical modeling to investigate seismic properties of gas hydrate with field parameters acquired over the East sea in 1998. We used a 2-D staggered grid finite difference method to generate synthetic elastic seismograms for multi-channel seismic survey, OBC (Ocean Bottom Cable) survey and VCS (Vertical Cable Seismic) survey. The results of this study showed that the method using staggered grid yielded stable results and could be used to seismic imaging. We could find out the high amplitude anomaly and the phase reversal phenomenon of reflection wave at interface between the gas hydrate layer and free gas layer such a BSR (Bottom Simulating Reflector) which is the evidence for existence of gas hydrate in seismic reflection data. And we computed the reflection coefficients at the incident angles corresponding to offset distance with the synthetic seismograms. The reflection coefficients acquired from the numerical modeling were nearly consistent with the reflection coefficient computed by Shuey's equation.