• Membrane and Water Treatment
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• v.8 no.3
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• pp.245-257
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• 2017

The separation of nicotine and tobacco-specific N-nitrosamines is a tough problem in tobacco industry. In this study, separation of nicotine from 4-(methylnitrosamino) -1-(3-pyridyl)-1-butanone (NNK) mixtures was investigated using electrodialysis by taking the principle of the protonation status difference between these two components. The results indicated that the solution pH has a dominant impact on the separation process. In a pH range of 5-7, nicotine molecules are existed as mono- and di-protonated ions and can be separated from the uncharged NNK molecules. The acidic electrolyte is conducive to the separation process from the point of flux and energy consumption; while the alkaline electrolyte has negative impact on the separation process. A current density of $10mA/cm^2$ is an appropriate value for the separation process. The lowest energy consumption of the separation process is 0.58 kWh/kg nicotine with the process cost to be estimated at only $0.208 /kg nicotine. Naturally, electrodialysis is a high-efficiency, cost-effective, and environmentally friendly process to separate and purify nicotine from tobacco juice.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.6
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• pp.712-720
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• 2016

When bioethanol and water are mixed at a proper ratio, phase separation can occur because of the immiscibility of biobutanol with water. Phase separation in bioethanol blends fuels is a major problem for gasoline vehicle users due to effect of octane number and component corrosion. Thus, in this study, the phase separation of bioethanol was examined effect of bioethanol blends (E3 (3 vo.% bioethanol in gasoline), E5 and E10) in presence of water. The effect were evaluated behavior with phase separation test, simulation test of fuel tank in gas station according to water addition volume and it was investigated change of water content, bioethanol content and octane number for gasoline phase in bioethanol blends (E3, E5 and E10) every 1 week after water addition. The E3 occurred phase separation more easily than the E5 and E10 in small water contents because solubility of water on ethanol content difference in gasoline-ethanol. It was kept a initial level of water content, bioethanol content, and octane number by repeated sample replacing in simulation test of fuel tank.

• Nuclear Engineering and Technology
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• v.8 no.1
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• pp.1-8
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• 1976

For tile rapid production of fluorine-18 for medical use, the up-to-date methods of separation such as the recoil separation, the alumina column chromatography, and the distillation are reviewed. The amount of the residue, the gamma emitting impurity, and the tritium content in the product obtained by each separation method are determined. The product obtained by the nuclear recoil separation or by the alumina column chromatography is inferior to that obtained by the distillation in the purity point of view. Thus, the separation by the distillation is tile most effective especially in the case of using a natural lithium carbonate target. Carrier free fluorine-18 of about 2 mCi can routinely be produced by irradiating 7g of the natural lithium carbonate under the neutron flux of about 1$\times$10$^{13}$ n/$\textrm{cm}^2$/sec for 3 hrs, and subsequent separation by the distillation. The over-all processing time is 35-40n1in.

• Membrane Journal
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• v.34 no.2
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• pp.114-123
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• 2024

Hydrogen isotopes can be categorized into light hydrogen, heavy hydrogen, and tritium based on the number of neutrons, each of which is used in specific fields. Specifically, deuterium is of interest in the electronics industry, nuclear energy industry, analytical technology industry, pharmaceutical industry, and telecommunications industry. Conventional methods such as cold distillation, thermal cycling absorption processes, Girdler sulfide processes, and water electrolysis have their own advantages and disadvantages, leading to the need for alternative technologies with high separation and energy efficiency. In this context, membrane-based hydrogen isotope separation is one of the promising solutions to reduce energy consumption. In this review, we will present the state-of-the-art in hydrogen isotope separation using membranes and their operating principles. The technology for separating hydrogen isotopes using membranes is just beginning to be conceptualized, and many challenges remain to be overcome. However, if achieved, the economic benefits are expected to be significant. We will discuss future research directions for this purpose.

• Transactions of the Korean hydrogen and new energy society
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• v.31 no.3
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• pp.322-327
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• 2020

In this work, a study for the reduction of the electric power consumption has been estimated in main air compressors in the air separation unit through cryogenic distillation columns with PRO/II with PROVISION V10.2 at AVEVA company. Both required LNG mass flow rate and cold heat contained in 1 ton of LNG were also predicted using Peng-Robinson equation of state with Twu's new alpha function. Through this work, we concluded that 32.33-48.69% of electric power could be saved by using LNG cold heat.

• Nuclear Engineering and Technology
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• v.13 no.4
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• pp.254-263
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• 1981

Paper electrophoretic separation of fission products has been carried out by using the specially designed migration apparatus. In general, the isolation of rubidium, strontium, zirconium, ruthenium, cesium, cerium, molybdenum, and some short-lived fission products is more efficient under 0.1M HCl electrolyte as compared with 0.1M NaOH electrolyte. In addition to Np-239, 1-131∼135 were, in particular, observed with different iodine chemical species obtained by the paper-electrophoretic separation of short, neutron-irradiated uranyl nitrate solution.

• Journal of Communications and Networks
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• v.14 no.4
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• pp.410-417
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• 2012

One of the premier mechanisms used in extracting unobserved signals from observed mixtures in signal processing is employing a blind source separation (BSS) algorithm. Orthogonal frequency division multiplexing (OFDM) techniques are playing a prominent role in the sphere of multicarrier communication. A set of remedial solutions taken to mitigate deteriorative effects caused within the air interface of OFDM transmission with aid of BSS schemes is presented. Four energy functions are used in deriving the filter coefficients. Energy criterion functions to be optimized and the performance is justified. These functions together with iterative fixed point rule for receive signal are used in determining the filter coefficients. Time correlation properties of the channel are taken advantage for BSS. It is tried to remove colored noise and jamming components from themixture at the receiver. Themethod is tested in a slow fading channel with a receiver containing equal gain combining to treat the channel state information values. The importance is that, these are quite low computational complexity mechanisms.

• Journal of Institute of Control, Robotics and Systems
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• v.1 no.2
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• pp.119-126
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• 1995

The purpose of this study is to develop the technique of energy recovery and energy saving by using the optimization of heat exchanger network synthesis. This article proposes a new method of determining the optimal target of a heat exchanger network synthesis problem of which data feature multiple pinch points. The system separation method we suggest here is to subdivide the original system into independent subsystems with one pinch point. The optimal cost target was evaluated and the original pinch rules at each subsystem were employed. The software developed in this study was applied to the Alko prosess, which is an alcohol production process, for the synthesis of heat exchanger network. It was possible to save about 15% of the total annual cost.

• Journal of the Korean Magnetic Resonance Society
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• v.4 no.2
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• pp.82-90
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• 2000

Photoinduced charge separation of alkylphenothiazines in molecular assemblies such as positively, negatively and neutrally charged micelle interface results in the paramagnetic phenothiazine cation radical. This was studied as a model system for the light energy conversion into chemical energy. The photoproduced phenothaizne cation radical was identified and its amount was quantized with electron spin resonance (ESR). The microenvironment of photoproduced cation radical was studied with pulsed-ESR. Such a charge separation is enhanced by the optimization of various structural factors of the molecular assemblies. The structural factors of molecular assemblies have focused on the interface charge, interface structure with different headgroups and interfacial perturbation by disolving interface active organic additives.

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2005.05a
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• pp.109-112
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• 2005

The electrical pulse separation of concrete samples for the recycling purpose has been investigated by the electrical disintegration method using the discharged high voltageimpulse. First, when the consumed energy increased in electrical crushing, fracture section area increased clearly. This result suggests that crushing energy was consumed efficiently. Secondly, when conventional crushing after electrical disintegration is compared with only conventional crushing, gravels are more stable after electrical crushing. Thus, electrical crushing makes it easy to recover gravels from wasted concrete. In the next year, more efficient recovery of gravel for wasted concrete by electrical disintegration will be investigated. Thus, actual wasted concrete crushing by electrical separation and combination of conventional crushing will be carried out.